US3717459A

US3717459A - Method of imaging involving pre-heating using interdigitated electrodes, a photoconductive layer and a magnetic imaging layer

Info

Publication number: US3717459A
Application number: US00029583A
Authority: US
Inventors: R Mcclure
Original assignee: Bell and Howell Co
Current assignee: Bell and Howell Co
Priority date: 1970-04-17
Filing date: 1970-04-17
Publication date: 1973-02-20
Anticipated expiration: 1990-02-20

Abstract

A composite recording medium comprises a photoconductive layer, a plurality of interdigitated first and second electrodes in electrical contact with and contiguous to the photoconductive layer, and an electrically conductive magnetic recording layer in electrical contact with and contiguous to the photoconductive layer. Methods and apparatus for magnetically recording an image with the assistance of this composite recording medium are also disclosed.

Description

United States Patent [m McClure [4 Feb. 20, 1973 [54] METHOD OF IMAGING INVOLVING [56] References Cited PRE-HEATING USING INTERDIGITATED ELECTRODES, A UNITED STATES PATENTS PHOTOCONDUCTIVE LAYER AND A 2,798,959 7/1957 Moncrieff-Yeates .96/1 E 3,485,621 12/1969 Kazan ....96/l I 4 MAGNETIC IMAGING LAYER 3,288,602 ll/l966 Snelling et al. ..96/l [75] Inventor: Richard J. McClure, Altadena, 3,137,762 6/1964 Baumgartner et al. ..96/l X Calif. Prima ExaminerGeor e F. Lesmes [73] Asslgnee: Howell Company chlcago Assisu t ExaminerRola nd E. Martin, Jr.-

' Attorney-Luc P. Benoit 2 7 Appl' No; 29583 A composite recording medium comprises a v photoconductive layer, a plurality of interdigitated v first and second electrodes in electrical contact with US. Cl. n R, E, and contiguous to the photoconductive layer and an 346/74M,346/74MT,117/211,117/217, electrically conductive magnetic recording layer in 117/218 electrical contact with and contiguous to the I111. CI. ..-....G03g 13/14, 603g 13/22 photoconductivg layen Methods and apparatus for I Field of Search "96/1, 1,5, 1 E; 346/74 MT magnetically recording an image with the assistance of this composite recording medium are also disclosed.

11 Claims, 6 Drawing Figures METHOD OF IMAGING INVOLVING PRE- IIEATING USING INTERDIGITATED ELECTRODES, A PHOTOCONDUCTIVE LAYER AND A MAGNETIC IMAGING LAYER 5 CROSS-REFERENCE TO RELATED APPLICATION Subject matter of the present application is disclosed in the following copending application, the disclosure of which is herewith incorporated by reference herein:

Patent application Ser. No. 29,584, MAGNETIC IMAGING, filed Apr. 17, 1970, by Sherman W. Duck, James U. Lemke and Frederick J. Jeffers, and assigned to the present assignee.

BACKGROUND OF THE INVENTION 1. Field of the Invention The subject invention relates to magnetic recording and, more particularly, to the magnetic recording of images with the assistance of thermal gradients.

2. Description of the Prior Art Magnetic imaging has been the subject of serious investigation in recent years, since it has several advantages over more conventional imaging techniques.

For instance, magnetic imaging offers the prospect of an avoidance of time-consuming and delicate chemical processing steps now required in customary photography. Magnetic imaging also offers the prospect of an avoidance of expensive and potentially dangerous highvoltage equipment now required in electrostatic xerography and related techniques.

Unfortunately, magnetic imaging techniques which have become publically known to date cannot compete in terms of light sensitivity and exposure speed with photographic methods or even with electrostatic xerography.

SUMMARY OF THE INVENTION The subject invention overcomes or materially alleviates the above mentioned disadvantages and, from one aspect thereof, resides in a method of magnetically recording an image, comprising in combination the steps of providing a plurality of interdigitated first and second electrodes, providing a photoconductive layer electrically connected and contiguous to the interdigitated first and second electrodes, and providing an electrically conductive magnetic image recording layer susceptible to an image-wise change of magnetization in response to a thermal image pattern and electrically connected to the interdigitated first and second electrodes and contiguous to said photoconductive layer. This method further includes the steps of connecting said interdigitated first and second electrodes to opposite terminals, respectively, of a source of electric energy and applying electrical energy to the interdigitated first and second electrodes by way of said opposite terminals to provide electrical current through the electrically conductive magnetic recording layer so as to pre-heat the magnetic recording layer to a temperature below the temperature at which said imagewise change of magnetization occurs, exposing the photoconductive layer to the image and continuing to apply electrical energy from said source to said interdigitated electrodes by way of said opposite terminals so as to produce with the aid of electrical energy from said source a thermal pattern corresponding to the image and constituting said thermal image pattern; and magnetically recording said image by changing the state of magnetization of the heated recording layer with the aid of the thermal pattern.

From another aspect thereof, the subject invention resides in apparatus for magnetically recording an image, comprising in combination a plurality of interdigitated first and second electrodes, a photoconductive layer electrically connected to the interdigitated first and second electrodes, and an electrically conductive magnetic recording layer electrically connected to the interdigitated first and second electrodes. This apparatus further includes means for applying electrical energy to the interdigitated first and second electrodes to establish electrical currents in the electrically conducting magnetic recording layer for heating the magnetic recording layer, means for exposing the photoconductive layer to the image to produce with the aid of the electrical energy a thermal pattern corresponding to the image, and means operatively associated with the magnetic recording layer for changing the state of magnetization of the heated recording layer with the aid of the thermal pattern whereby a magnetic record of the image is established.

Thesubject invention further resides in a photoelectric composite recording medium operable with a source of electric energy having opposite terminals;

comprising in combination a plurality of interdigitated first and second electrodes means for connecting said interdigitated first and second electrodes to opposite terminals, respectively, of said source of electric energy, a photoconductive layer electrically connected and contiguous to the interdigitated first and second electrodes, and a thermally responsive electrically conductive magnetic image recording layer electrically connected to the interdigitated first and second electrodes and contiguous to said photoconductive layer.

As is explained in the above mentioned copending patent application, a composite magnetic recording medium comprising a combination of a photoconductive layer, interdigitated electrodes, and a magnetic recording medium possesses several advantages over combinations in which the photoconductive layer is sandwiched between two sheet electrodes.

These advantages may be summarized as follows: Improved electrical current rheology, improved halftone rendition, facilitated premagnetization, decreased sensitivity to pin holes and lumps in the photoconductor, increase in light sensitivity by a factor two or more, and possibility of considerable reduction of instantaneous electrical current flow.

The subject invention further provides substantial advantages which result in a convenient and advantageous heating of the magnetic recording layer and a substantial decrease of the thermal load on the photoconductive layer.

BRIEF DESCRIPTION OF THE DRAWINGS The invention will become more readily apparent from the following detailed description of preferred embodiments thereof, illustrated by way of example in the accompanying drawings, in which:

FIG. 1 is a perspective view of an imaging apparatus in accordance with a preferred embodiment of the subject invention;

FIG. 2 illustrates a first phase in the operation of the apparatus of FIG. 1;

FIG. 3 illustrates further phases in the operation of the apparatus of FIG. 1;

FIG. 4 is a cross-section, on an enlarged scale, of a fraction of the composite recording medium shown in FIG. 1;

FIG. 5 is a cross-section, on an enlarged scale, of a fraction of a composite recording medium in accordance with a further preferred embodiment of the invention; and

FIG. 6 is a cross-section, or an enlarged scale, of a composite recording medium in accordance with yet another preferred embodiment of the subject invention.

Like reference numerals in the drawings designate like or functionally equivalent parts.

DESCRIPTION OF PREFERRED EMBODIMENTS The apparatus 10 of FIG. 1 includes a composite photoelectromagnetic recording medium 12 which embodies key features of the subject invention. The composite recording medium 12 includes a transparent substrate 13 which may be a sheet of glass or of an organic equivalent thereof, such as a high-temperature polyimide or polybenzamidazole.

An interdigitated electrode structure 14 including interdigitated first and

second electrodes

15 and 16 is in the preferred embodiments of FIGS. 1 and 4 located on the transparent substrate 13. The deposition of electrode structures on a transparent substrate is a wellestablished art and does not as such form part of the subject invention. Suffice to say therefore, that the electrode structure 14 may be deposited on the substrate 13 by evaporation, painting or sputtering, and that preferred electrode materials include gold, indium, chromium, and aluminum.

A photoconductive layer 18 is deposited on the substrate 13 and electrode structure 14. Suitable photoconductive materials include cadmium sulfide, cadmium selenide, alloys of cadmium sulfide or cadmium selenide, and sensitized zinc sulfide. High-gain photoconductor materials are presently preferred, since they provide for the large currents needed for heating of the magnetic material but require only moderate input light levels. The thickness of the layer 18 is not generally critical, but a layer thickness of about 3 to 10 microns is presently preferred for resolutions of more than about 10 line pairs per millimeter.

The composite recording medium 12 further includes an electrically conductive magnetic recording layer 20 which is pressed against, coated on, or deposited on the photoconductive layer 18 and in electrical contact therewith. As is well known, there are several materials which are both electrically conductive and amenable to thermomagnetic change at temperatures below 200 C. By way of example and not by way of limitation, ferromagnetic chromium dioxide is a material that is not only electrically conductive, but also has a sufficiently low Curie point to be practically suitable for information-controlled therrnoremanent magnetization or thermo-induced demagnetization, as may for instance be seen from U.S. Pat. No. 3,250,636, by R.A. Wilferth, issued May 10, 1966, U.S. Pat. No. 3,364,496, by Greiner et al., and British Pat. Specification No. 1,139,232, filed Apr. 27, 1966, by E.I. du Pont de Nemours and Company. Other suitable materials for the magnetic recording layer 20 include manganese arsenide alloys and compounds which are not only electrically conductive but typically have a Curie temperature significantly below 100 C.

If desired, the magnetic material for the medium 20 may be provided in the form of an integral layer, by such techniques as vapor deposition. A preferred known method for providing manganese arsenide layers resides in a superimposition of manganese and arsenide strata and an alloying thereof in situ.

The magnetic recording medium 20 preferably has an acute temperature-dependent transition between the ferromagnetic and paramagnetic states. Where the requisite acuity is not inherent in the material, it may, according to the allowed Patent application, Ser. No. 649,540, Magnetic Information Recording, filed June 28, 1967, by James U. Lemke, and assigned to the subject assignee, now U.S. Pat. No. 3,541,577, be realized by providing the low-Curie point magnetic particles with a shape anisotropy that dominates their crystal anisotropy. By way of preferred example, the magnetic recording medium 20 may comprise acicular ferromagnetic chromium dioxide particles dispersed in a temperature-resistant binder, such as an acrylic copolymer, polyamide or polyurethane binder, all of which may be obtained in thermosetting form.

If the magnetic recording layer 20 comprises acicular ferromagnetic particles, having long axes and short axes, then these particles are in accordance with a preferred embodiment of the subject invention so oriented that the long axes extend in geometrical planes that intersect the

electrodes

15 and 16. In this manner the electrical conductivity of the recording layer is maximized from electrode to electrode. A preferred arrangement of this type is shown in a somewhat idealized manner in FIG. 5.

The composite recording medium 12 of FIG. 5 comprises the above mentioned transparent substrate 13, the electrode structure 14 including interdigitated first and

second electrodes

15 and 16, the photoconductive layer 18, as well as a magnetic recording layer 201.

In accordance with the preferred embodiment illustrated in FIG. 5, the magnetic recording medium layer 201 comprises, in a binder layer 202, acicular particles 203 of a ferromagnetic material, such as chromium dioxide. As shown in FIG. 5, the acicular recording material particles are oriented with their long axes extending in geometrical planes (here planes parallel to the paper on which FIG. 5 is drawn) which intersect the

electrodes

15 and 16 at right angles. In electrical circuit terms this means that the direction of lowest electrical resistivity or highest electrical conductivity extends at right angles to the

electrodes

15 and 16, which greatly to remain cooler than portions of the medium located, so to say, midway between adjacent electrodes. Accordingly, if the path of maximum thermal conductivity extend at right angles to the electrodes and 16, then heat generated in response to a light stimulus acting on the photoconductive layer 18 can readily spread to the cooler regions below the

electrodes

15 and 16. This effect may be employed to at least narrow the widths of cool medium portions in which no information-induced magnetization changes take place.

By way of contrast, the preferred embodiment of FIG. 5 also lends itself to an improved rendition of gray-scale values at increased resolution. Since the intensity of the currents 80, shown in FIG. 4 and occurring also in the embodiment of FIG. 5, is one factor that determines the temperature of the recording medium 201, it is readily possible to maintain, by an intensity adjustment of the currents 80, the cool portions of the recording medium 201 immediately below electrodes 15 and electrodes 16 at temperatures that remain, despite the flow of heat along the acicular particles 203, at temperatures which are lower than those required for an information-controlled magnetization change.

In consequence, practically unavoidable heat transfers occur chiefly from information-representative heated portions of the recording medium 201 into areas of a cooler gray-scale pattern that corresponds to the electrode structure 14. Accordingly, practically unavoidable heat transfers are conveniently channeled without a corresponding undue broadening of recorded image elements in the general direction of the currents 80.

An undue broadening of recorded image elements in directions parallel or substantially parallel to the electrodes l5 and 16 is in addition avoided in the preferred embodiment of FIG. 5 by the fact that electrical and thermal conductivities are at a minimum in a direction perpendicular to the long axes of the acicular particles 203. It will thus be recognized that the preferred embodiment of FIG. 5 affords maximum image resolution coupled with a superior image recording speed and efficiency. A desired orientation of the particles 203 presents no problem, since several particle orientation techniques, including the use of a doctor blade or of an orienting magnetic field, are well known in the related art of magnetic recording tape manufacture.

In the further course of this description, reference will primarily be made to a composite recording medium of the type shown in FIG. 4, but it should be understood that the composite medium 12' of FIG. 5 may in all method and apparatus embodiments be substituted for the composite medium 12 of FIG. 4.

If the recording medium 20 is present in the form of an integral layer, a sufficient electrical conductivity is typically assured by the integral nature of the layer. If the medium 20 is present inthe form of particles, a sufficient electrical conductivity is also attainable without particular problems, since techniques for rendering metallic paints electrically conductive are well known in the conductive paint art and also in areas of the printed circuit field. By way of example, we have found that the electrical conductivity of the magnetic recording layer is easily controlled by varying the amount or loading of ferromagnetic particles per volume unit in the magnetic recording layer. In accordance with a preferred embodiment, but not by way of limitation, the

layer

20 or 201 contains up to 40% by volume of ferromagnetic particles. Also in accordance with a preferred embodiment of the subject invention, the average electrical resistivity of the magnetic recording layer in the direction of maximum electrical conduction is substantially intermediate between the resistivity of the photoconductor layer in the dark condition and the resistivity of the photoconductor layer in the lightexposed condition.

Two preferred magnetic recording techniques include information-selective thermal demagnetization and information-selective thermoremanent magnetization. In selective demagnetization the recording medium 20 is typically premagnetized and is thereupon demagnetized by above-Curie point heating until the remaining magnetized areas present a record of the input image. In thermoremanent magnetization a thermal pattern which represents the input image is imposed upon the typically unmagnetized recording medium 20 so that selected portions of that medium are heated above Curie point. These portions are thereupon cooled in the presence of a magnetic field whereby an amplified thermoremanent magnetization of the type described by CD. Mee, The Physics of Magnetic Recording (North-Holland Publishing Company, 1964), pp. -84, and in the above mentioned Greiner et al. US patent and British du Pont Patent Specification takes place. If desired, strong positive magnetic records may beproduced in the manner disclosed in Patent applications, Ser. Nos. 821,232 and 821,432, filed by Luc P. Benoit on May 2, 1969, and assigned to the subject assignee, now U.S. Pats. Nos. 3,611,420 and 3,582,877 respectively. As will become apparent in the further course of this disclosure, either of these magnetic recording techniques, or a combination of these techniques to be more fully described below, may be employed in the practice of the subject invention.

The apparatus 10 further includes a source of light 22, such as an incandescent lamp or a fluorescent tube, which is energized from an electric power source 23 and which is combined with a reflector and shade 24 that defines a narrow longitudinal slit 15 for the emission of a sheet of light 26. The light sheet is reflected by a mirror 28 which is tiltable about a longitudinal axis 29 and which reflects the impinging light in the form of a light sheet 30 onto a master record 31 that may, for instance, be supported on a sheet of glass (not shown).

The light 32 reflected by the master record 31 is imaged by a lens 34 onto the interdigitated electrode structure 14 and photoconductive layer 18.

The first and

second electrodes

15 and 16 of the interdigitated electrode structure 14 are connected to opposite terminals of a source of electric energy 36. A switch 37 and a variable resistor 38 are connected in this circuit to control timing and intensity of the current flow to the electrode structure 14.

As illustrated in FIG. 4, application of electrical energy to the interdigitated

electrodes

15 and 16 results in the flow of electrical currents 80 in the electrically conductive magnetic recording medium 20. These currents enter and leave the magnetic recording medium 20 by way of current paths that extend through the photoconductive layer 18 between the electrodes and 16 and the magnetic recording layer as shown in FIG. 4. These current paths owe their existence not only to the conductivity of the magnetic recording layer 20, but also to the finite dark resistance of the photoconductive layer 18.

In one preferred embodiment of the subject invention, the dark resistivity of the photoconductor portions covered by or below the

electrodes

15 and 16 is substantially lower than the dark resistivity of photoconductor portions located between these electrodes, so that the currents 80 are sufficiently intense to heat the recording medium 20 to a temperature in the vicinity of the Curie point. The requisite relatively low dark resistance may for instance to provided by a photoconductive layer construction or design in which the distance between any

electrode

15 or 16 and the magnetic recording layer is substantially smaller than the distance between

adjacent electrodes

15 and 16. Many doping techniques which lower the resistance of photoconductors are well known in semiconductor technology and may if desired be applied at regions below the

electrodes

15 and 16 to lower the dark resistivity. Alternatively, light may be shone through the magnetic recording layer 20 so as to lower the resistivity of photoconductor portions below the

electrodes

15 and 16 for the desired heating of the magnetic recording medium by the currents 80.

It should be understood at this juncture that I do not intend to limit myself to methods and apparatus in which the heating of the magnetic recording medium by the currents 80 precedes an information-controlled light exposure of the photoconductive layer 18 in time and is thus a preheating in the strict sense of the word. To be sure, such a preheating is, indeed, intended to be covered herein in accordance with a preferred embodiment of the subject invention. But even where a temporal succession of heating and light exposure is expressed herein by way of example or for the purpose of explanation or streamlined definition, it is to be understood that heating by the currents 80 may commence simultaneously or concurrently with the light exposure to the input image.

In fact, concurrent commencement of the heating of the recording layer 20 to the vicinity of the Curie point and of the exposure of the photoconductive layer 18 is preferred in accordance with a further embodiment of the subject invention in situations where heat energies provided by a temporal preheating step would be dissipated too quickly as to be of benefit during the image exposure step.

The variable resistor 38 shown in FIG. 1 is adjusted so that the electric currents 80 heat the magnetic recording layer 20 toward the temperature at which the desired magnetic transition is to take place for image recording. In the illustrated embodiment, the currents 80 heat the magnetic recording layer 20 to a temperature in the vicinity of the Curie point and somewhat below the acutely declining region of the remanenceversus-temperature curve.

In such heating step, the dark photoconductive layer 18, the

electrodes

15 and 16 and the substrate 13 act as a heat sink which prevents the thermal energy provided by the electrical currents 80 from heating the medium 20 to temperatures too close to and through the Curie point. Since the

electrode

15 and 16 are better thermal conductors than the photoconductive layer 18, the temperature of the recording layer 20 is typically lower below the

electrodes

15 and 16 than in recording layer portions midway between these electrodes. As will be apparent as this description proceeds, this fact may be exploited to provide halftone premagnetization patterns.

If a light stimulus 82 impinges on the photoconductive layer 18 between a pair of

electrodes

15 and 16, electrical photocurrents 83 occur in response to the increased conductivity of the photoconductive layer at the particular location. These photocurrents produce thermal energy between the

electrodes

15 and 16, which impairs the flow of heat from the magnetic recording layer 20 to the

electrodes

15 and 16 and to the substrate 13 at the particular location. The resulting localized and temporary loss of a heat sink causes an aboveCurie point rise in temperature of the particular portion of the magnetic recording medium 20. In this manner, a thermal pattern corresponding to the image to be recorded can be provided and impressed on the magnetic recording layer 20.

If the magnetic record is to be established by thermoremanent magnetization, then the apparatus 10 requires means for magnetizing portions of the magnetic recording layer 20 that, after an image-wise thermal exposure, cool down through the Curie point of the magnetic recording medium. If the magnetic record is to be established by selective demagnetization, then the apparatus 10 requires means for premagnetizing the magnetic recording layer 20 prior to its image-wise thermal exposure. The same elongated magnetizing head 40 may be employed for both methods with the difference that the magnetic field provided by the head 40 is applied to the magnetic recording layer 20 prior to image exposure if the record is to be established by selective demagnetization, and is applied after thermal exposure during the subsequent cooling step if the record is to be established by thermoremanent magnetization.

By way of example, it is assumed that the illustrated apparatus 10 operates with a combination of the two methods by imposing a premagnetization through the agency of thermoremanent magnetization and by establishing the magnetic record by an image-wise selective demagnetization.

The magnetizing head 40 has an air gap 42, as well as an energizing winding 43 which is connected to a source of electric energy 44 through a switch 45 and a variable resistor 46 which serve to control the timing and intensity of the magnetic field 48 provided at the air gap 42.

To provide for a premagnetization, the photoconductive layer 18 and interdigitated electrode structure 14 are subjected to a uniform exposure. A flood lamp (not shown) which uniformly irradiates the electrode structure 14 and photoconductive layer 18 may be provided for this purpose. A light exposure which operates within a narrow exposure band 50 that'extends across the alternating

electrodes

15 and 16 and that progresses in the direction of an arrow 51 parallel to the

electrodes

15 and 16 is, however, preferred for two reasons. First, if the exposure is at any instant limited to a narrow exposure band, then the intensity of electric current flow is very substantially reduced relative to intensities that would occur if the entire composite medium were exposed at that instant. Secondly, it is easier to impose a premagnetization that has the requisite uniformity over the recording layer if such premagnetization takes place successively along a progressing band, rather than over the entire recording layer at once. Also, the total electric current flow is distributed over the electrodes if the exposure band extends across the electrodes rather than parallel thereto.

Accordingly, a light-reflecting element 53, only part of which has been shown, is initially substituted for the master record 31. The reflecting element 53, may, for instance, include a white sheet of paper or a mirror. The exposure band 50 is then swept across the composite recording medium 20 in the direction of the arrow 51 by a tilting of the mirror 28 about its axis 29. This tilting motion is effected by a drive 54 which is coupled to the mirror 28 and also to the magnetizing head 40 vso as to move this head in the direction of an arrow 56 and in proportion to the tilting motion of the mirror 28, in such mutual synchronism that the magnetic field 48, which extends across the magnetic recording layer 20, follows the exposure band 50 in the direction of the arrow 51.

In this manner successive portions of the magnetic recording layer 20 are heated above the Curie point of the magnetic recording medium, and do thereupon cool through the Curie point as the exposure band 50 travels along the arrow 51. The position of the traveling magnetizing head 40 relative to the moving exposure band 50 is selected such that the magnetic field 48, which extends in parallel to the exposure band 50, trails this exposure band at such a distance that the magnetic field 48 is successively present at all the magnetic layer portions that cool back through their Curie point.

In preparation of this thermoremanent magnetization, the switch 45 is closed and the variable resistor 46 is adjusted so that the magnetic field 48 has an intensity which is insufficient to magnetize the layer 20 while the same remains at a temperature below its Curie point, but which is sufficient to magnetize portions of the layer 20 that cool through their Curie point. As is known in magnetics, thermoremanent magnetization has the highest efficiency and linearity of all forms of magnetization.

The source 44 which energizes the magnetizing head 40 may be a source of direct current, in which case the thermoremanent premagnetization produces in the layer 20 a pattern of magnetized lines that extend in parallel to the electrodes and 16 and occupy regions that correspond to areas located between the interdigitated first and second electrodes. This magnetic line pattern effect is brought about by the fact that light exposure of the photoconductive layer 18 takes place between the

interdigitated electrodes

15 and 16 whereby areas below these electrodes remain colder than adjacent areas between these electrodes. To be sure, areas below the electrodes can be heated by thermal diffusion from adjacent regions, but a diffusion effeet can easily be overcome by decreasing the light intensity of the source 22 or by increasing the traveling speed of the exposure region 50, or by a combination of these measures. Also, the heatsink effect which drains thermal energy from the magnetic recording layer during heating by the currents 80 (see FIG. 4) is stronger below the

flat electrodes

15 and 16 than midway between these electrodes, so that the areas of the recording medium 20 below the electrodes tend to remain cooler than the areas between these electrodes.

In contrast to a uniform premagnetization, a line-pattern premagnetization provides a multitude of sharp magnetic gradients which promote large-area fill-in, increased contrast and increased resolution.

If a point-pattern, rather than a line-pattern, is desired, then the reflecting element 53 may be provided with a pattern of alternating light-reflecting and light-absorbing areas, or the source 44 may be a source of current pulses, whereby every line 58 is only magnetized along spaced points, as shown at 60 in FIG. 2. Point-patterns are sometimes preferred to line-patterns as is well known in the book and newspaper printing arts.

If the source 44 is a source of alternating current, each of the premagnetization lines 58 possesses a pattern of alternating magnetizations as shown in FIG. 2 at 62. In practice, this corresponds to a point-pattern magnetization, since no magnetizing effect takes place at and adjacent the zero crossovers of the alternating current. A strong toner attraction may result in this type of pattern from the alternating polarity of the magnetized points.

After the premagnetization step has been completed the reflecting element 53 is replaced by an information master record 31 that may, for instance, be a drawing, a writing, or a printed text. By way of example, it is assumed in FIG. 1 that the master record 31 is a white sheet of paper on which a black character has been printed.

For imaging according to the embodiment shown in FIG. 1, the switch 45 is opened and the magnetizing head 40 is decoupled from the drive 54 so that no magnetic field 48 follows the exposure band 50. The mirror 28 is, however, coupled to the drive 54 so that the light sheet 30 is moved across the master record 31 whereby successive portions of the master record are illuminated within a traveling narrow band 64. As before, the lens 34 images the band 64 onto the composite recording medium 12 whereby the latter is exposed within an exposure band 50 that travels in the direction of the arrow 51.

As mentioned above, the photocurrents 83 occurring in the photoconductive layer at the areas of light impingement cause an above-Curie point heating of corresponding portions of the recording medium 20. An application of magnetic fields to the recording layer 20 is avoided at this stage to preclude an undesired remagnetization of demagnetized areas through the agency of thermoremanent magnetization.

No significant light is reflected by the black character 65, whereby portions of the photoconductive layer that correspond to that character remain dark. Since no photoelectric currents 83 are caused to flow at those corresponding portions the temperature of the magnetic recording layer 20 remains below its Curie point within an outline occupied by an image of the character 65. The resulting lack of demagnetization of the premagnetization line or point-pattern leads to a magnetic record 68 of the character 65 as shown in FIG. 3.

Special advantages of the subject invention may again be considered at this juncture. First, since the electric currents 80 heat the magnetic recording layer close to its Curie temperature, the photocurrents 83 only need to be strong enough to cause the occurrence of a temperature increment of a few degrees in the Curie point region. Secondly, since the photoconductive layer is part of a heat sink arrangement, its heating in response to luminous stimuli need only be strong enough to reduce the drainage of heat from the magnetic recording layer. This stands in favorable contrast to arrangements in which the thermal image pattern is generated in the photoconductive layer 18 to be thereupon applied by thermal conduction to the magnetic recording layer 20.

The magnetic image 68 may be stored in the magnetic recording medium 20 and printed out as often as desired. A magnetic toner 70 may be applied to the magnetic image 68 to render the same visible or printable. Magnetic toners typically comprise magnetically attractable particles 72 in powdered form or liquid suspension. Suitable materials for the toner particles 72 include iron, nickel, cobalt or ferromagnetic alloys. By way of example and not by way of limitation, preferred materials for the toner particles 72 include submicron particles of iron, carbonyl iron, and magnetite (Fe O Magnetic toners, toning techniques, and toning apparatus are disclosed in U.S. Pat. No. 2,932,278, by J.C. Sims, issued Apr. 12, I960; U.S. Pat. No. 3,052,564, by F.K. Kulesza, issued Sept. 4, 1962; and U.S. Pat. No. 3,250,636, by R.A. Wilferth, issued May 10, 1966.

The toner image 74 resulting from a toning of the magnetic image 68 may be printed out on a sheet of paper, on a film, or on another material having similar surface qualities. If desired, a sheet of paper 75 may be provided with an adhesive coating 76 to assure a transfer and retention of the toner image 74 in the form ofa copy 78 or the original character 65. To effect such a transfer, the adhesive paper 75 is pressed onto the magnetic recording layer 20 and is thereupon removed whereby the toner image 74 adheres to and is pulled off together with the paper 75. As is known in the art of magnetic printing, the toner 70 may be present in the form of a magnetic ink that is absorbed by the paper 75, or the toner particles may be provided with shells of a thermoplastic or other fusible material that may be fused to the paper 75 by a combination of pressure and heat. No adhesive coating 76 is provided if a magnetic ink or a fusible material is employed.

If no further printout or storage is desired, the magnetic image 68 may be erased by such conventional methods as an exposure of the magnetic recording layer 20 to anhysteretic magnetic erasing fields, or to above-Curie point heating. The latter may be effected by a sweeping of the light sheet 32 across the interdigitated electrode structure 14 and photoconductive layer 18, while the electrodes are connected to the electric energy source 36 and the reflective element 53 is substituted for the information record 51.

The magnetic recording layer 20 may be permanently deposited on the photoconductive layer 18. Since the magnetic recording layer 20 is typically much cheaper than the combined interdigitated electrode structure 14 and photoconductive layer 18, it may be advantageous to provide the magnetic recording layer 20 on a substrate that is selectively movable into contact with, and removable from, the photoconductive layer 18.

In accordance with a further preferred embodiment of the subject invention the

interdigitated electrodes

15 and 16 are located adjacent the magnetic recording layer 20 in electrical contact with both the photoconductive layer 18 and the electrically conductive recording layer 20. In this embodiment the electrical resistivity of the magnetic recording medium is sufficient to prevent a short-circuiting of the photoconductive layer 18. More specifically, the resistivity of the magnetic recording layer 20 is lower than the dark resistivity of the photoconductive layer 18 to provide for a flow of the above mentioned electric currents 80 through the magnetic recording layer 20; and the resistivity of the magnetic recording layer 20 is comparable with or higher than the light resistivity of the photoconductive layer 18 to permit the flow of the above mentioned photocurrents 83 in response to a light stimulus 82 and at sufficient intensities to provide for a localized above Curie-point heating of the magnetic recording layer 20. If desired, the recording layer 20 in FIG. 6 may be replaced by the recording layer 201 of FIG. 5.

The embodiment of FIG. 6 has the advantage that the

electrodes

15 and 16 do not obscure incoming light at the substrate 13, and that the electric heating currents 80 need not traverse portions of the photoconductive layer 18. In this connection, itshould however be noted that it is intended to be within the scope of the subject invention that the

interdigitated electrodes

15 and 16 may be embedded within the photoconductive layer 18 at locations spaced from both the substrate 13 and the

magnetic recording medium

20 or 201.

Also, by way of explanation and not by way of limitation, an electrode arrangement of the type shown in FIG. 4 in which the interdigitated electrodes are located at the substrate 13 is presently preferred, since available manufacturing techniques favor a deposition of interdigitated electrodes on a substrate over a deposition of such electrodes on a photoconductive layer, and since incoming light stimuli have to penetrate a lesser depth of the photoconductive layer when the electrodes are located at the transparent substrate rather than being remote therefrom.

In accordance with another preferred embodiment of the subject invention, the

interdigitated electrodes

15 and 16 and the photoconductor layer 18 together form an assembly to which the electrically conducting magnetic recording layer 20 or 201.is selectively applicable and from which such magnetic recording layer is selectively removable. This embodiment, which is applicable to any of the composite recording media of FIGS. 1, 4,, 5 and 6, has chiefly the advantage of in creased economy, since the less expensive

magnetic recording layer

20 or 201 can be made disposable, while the more expensive electrode and photoconductor assembly has a more permanent character.

Since a uniform electrical and thermal contact between the

layer

20 and 201 and the electrode and photoconductor assembly are important, mounting and spring devices of the type shown for instance in U.S. Pat. No. 2,798,960, Photoconductive Thermography, by AJ. Moncrieff-Yeates, issued July 9, 1957, and

the illustrated substrate 13.

I claim: 1. A method of magnetically recording an image, comprising in combination the steps of:

providing a plurality of interdigitated first and second electrodes;

providing a photoconductive layer electrically connected and contiguous to said interdigitated first and second electrodes;

providing an electrically conductive magnetic image recording layer susceptible to an image-wise change of magnetization in response to a thermal image pattern and electrically connected to said interdigitated first and second electrodes and contiguous to said photoconductive layer;

connecting said interdigitated first and second electrodes to opposite terminals, respectively, of a source of electric energy;

applying electrical energy from said source to said interdigitated first and second electrodes by way of said opposite terminals to provide electrical currents through said electrically conductive magnetic recording layer so as to pre-heat said magnetic recording layer to a temperature below the temperature at which said image-wise change of magnetization occurs;

exposing said photoconductive layer to said image and continuing to apply electrical energy from said source to said interdigitated electrodes by way of said opposite terminals so as to produce with the aid of electrical energy from said source a thermal pattern corresponding to said image and constituting said thermal image pattern; and

magnetically recording said image by changing the state of magnetization of said heated recording layer with the aid of said thermal pattern.

2. A method as claimed in claim 1, wherein:

said electrically conductive magnetic recording layer is electrically connected to said interdigitated first and second electrodes through portions of said photoconductive layer.

3. A method as claimed in claim 1, wherein:

said interdigitated first and second electrodes are located on a substrate;

said photoconductive layer is located on said substrate and said interdigitated first and second electrodes; and

said electrically conductive magnetic recording layer is located on said photoconductive layer so as to be electrically connected to said first and second interdigitated electrodes through portions of said photoconductive layer.

4. A method as claimed in claim 1, wherein:

said photoconductive layer is progressively exposed to said image in a direction progressing parallel to said interdigitated electrodes.

5. A method as claimed in claim 1, wherein:

said interdigitated electrodes are made to protrude into said photoconductive layer in a direction toward said magnetic recording la er. 6. A method as claimed in claim w erem:

each of said interdigitated first and second electrodes is spaced more from each of the adjacent electrodes than from said magnetic recording layer.

7. A method as claimed in claim 1, wherein:

said electrically conductive magnetic recording layer is provided by a process including the steps of providing acicular magnetic recording medium particles having long axes and short. axes, and orienting said recording particles so that said long axes substantially extend in geometrical planes intersecting said first and second electrodes.

8. A method as claimed in claim 7, wherein:

said acicular particles are so oriented that said long axes substantially extend in geometrical planes intersecting said first and second electrodes at right angles.

9. A photoelectric composite recording medium operable with a source of electric energy having opposite terminals, comprising in combination:

a plurality of interdigitated first and second electrodes;

said interdigitated first and second electrodes connected to opposite terminals, respectively, of said source of electric energy;

a photoconductive layer electrically connected and contiguous to said interdigitated first and second electrodes; and

a thermally responsive electrically conductive magnetic image recording layer electrically connected to said interdigitated first and second electrodes and contiguous to said photoconductive layer, said electrically conductive magnetic recording layer comprises acicular magnetic recording medium particles having short axes, and having long axes extending substantially in geometrical planes intersecting said first and second electrodes.

10. A composite recording medium as claimed in claim 9, wherein:

said long axes of said particles extend substantially in geometrical planes intersecting said first and second electrodes at right angles.

11. A composite recording medium as claimed in claim 9, wherein;

said plurality of interdigitated first and second electrodes and said photoconductive layer are in the form of an assembly; and

said electrically conductive magnetic recording layer is selectively applicable to, and selectively removable from, said assembly.

Claims

1. A method of magnetically recording an image, comprising in combination the steps of: providing a plurality of interdigitated first and second electrodes; providing a photoconductive layer electrically connected and contiguous to said interdigitated first and second electrodes; providing an electrically conductive magnetic image recording layer susceptible to an image-wise change of magnetization in response to a thermal image pattern and electrically connected to said interdigitated first and second electrodes and contiguous to said photoconductive layer; connecting said interdigitated first and second electrodes to opposite terminals, respectively, of a source of electric energy; applying electrical energy from said source to said interdigitated first and second electrodes by way of said opposite terminals to provide electrical currents through said electrically conductive magnetic recording layer so as to pre-heat said magnetic recording layer to a temperature below the temperature at which said image-wise change of magnetization occurs; exposing said photoconductive layer to said image and continuing to apply electrical energy from said source to said interdigitated electrodes by way of said opposite terminals so as to produce with the aid of electrical energy from said source a thermal pattern corresponding to said image and constituting said thermal image pattern; and magnetically recording said image by changing the state of magnetization of said heated recording layer with the aid of said thermal pattern.

2. A method as claimed in claim 1, wherein: said electrically conductive magnetic recording layer is electrically connected to said interdigitated first and second electrodes through portions of said photoconductive layer.

3. A method as claimed in claim 1, wherein: said interdigitated first and second electrodes are located on a substrate; said photoconductive layer is located on said substrate and said interdigitated first and second electrodes; and said electrically conductive magnetic recording layer is located on said photoconductive layer so as to be electrically connected to said first and second interdigitated electrodes through portions of said photoconductive layer.

4. A method as claimed in claim 1, wherein: said photoconductive layer is progressively exposed to said image in a direction progressing parallel to said interdigitated electrodes.

5. A method as claimed in claim 1, wherein: said interdigitated electrodes are made to protrude into said photoconductive layer in a direction toward said magnetic recording layer.

6. A method as claimed in claim 1, wherein: each of said interdigitated first and second electrodes is spaced more from each of the adjacent electrodes than from said magnetic recording layer.

7. A method as claimed in claim 1, wherein: said electrically conductive magnetic recording layer is provided by a process including the steps of providing acicular magnetic recording medium particles having long axes and short axes, and orienting said recording particles so that said long axes substantially extend in geometrical planes intersecting said first and second electrodes.

8. A method as claimed in claim 7, wherein: said acicular particles are so oriented that said long axes substantially extend in geometrical planes intersecting said first and second electrodes at right angles.

9. A photoelectric composite recording medium operable with a source of electric energy having opposite terminals, comprising in combination: a plurality of interdigitated first and second electrodes; said interdigitated first and second electrodes connected to opposite terminals, respectively, of said source of electric energy; a photoconductive layer electrically connected and contiguous to said interdigitated first and second electrodes; and a thermally responsive electrically conductive magnetic image recording layer electrically connected to said interdigitated first and second electrodes and contiguous to said photoconductive layer, said electrically conductive magnetic recording layer comprises acicular magnetic recording medium particles having short axes, and having long axes extending substantially in geometrical planes intersecting said first and second electrodes.

10. A composite recording medium as claimed in claim 9, wherein: said long axes of said particles extend substantially in geometrical planes intersecting said first and second electrodes at right angles.