US3716744A - Hermetic end seals for envelope of a metal vapor lamp - Google Patents
Hermetic end seals for envelope of a metal vapor lamp Download PDFInfo
- Publication number
- US3716744A US3716744A US00171578A US3716744DA US3716744A US 3716744 A US3716744 A US 3716744A US 00171578 A US00171578 A US 00171578A US 3716744D A US3716744D A US 3716744DA US 3716744 A US3716744 A US 3716744A
- Authority
- US
- United States
- Prior art keywords
- seal
- envelope
- metal
- cap
- stem
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 19
- 239000002184 metal Substances 0.000 title claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- 239000003870 refractory metal Substances 0.000 claims description 9
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 239000011261 inert gas Substances 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 239000010955 niobium Substances 0.000 claims description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 5
- 238000005219 brazing Methods 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 4
- 239000000292 calcium oxide Substances 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000000374 eutectic mixture Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910001257 Nb alloy Inorganic materials 0.000 description 1
- LUTSRLYCMSCGCS-BWOMAWGNSA-N [(3s,8r,9s,10r,13s)-10,13-dimethyl-17-oxo-1,2,3,4,7,8,9,11,12,16-decahydrocyclopenta[a]phenanthren-3-yl] acetate Chemical compound C([C@@H]12)C[C@]3(C)C(=O)CC=C3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)C)C1 LUTSRLYCMSCGCS-BWOMAWGNSA-N 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/36—Seals between parts of vessels; Seals for leading-in conductors; Leading-in conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J5/00—Details relating to vessels or to leading-in conductors common to two or more basic types of discharge tubes or lamps
- H01J5/20—Seals between parts of vessels
- H01J5/22—Vacuum-tight joints between parts of vessel
- H01J5/26—Vacuum-tight joints between parts of vessel between insulating and conductive parts of vessel
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2893/00—Discharge tubes and lamps
- H01J2893/0033—Vacuum connection techniques applicable to discharge tubes and lamps
- H01J2893/0037—Solid sealing members other than lamp bases
- H01J2893/0041—Direct connection between insulating and metal elements, in particular via glass material
Definitions
- ABSTRACT An alkali-metal-vapor discharge lamp has an inner vitreous material hermetic seal between an electrode stem and translucent tubular envelope and an outer metal seal between a metal end cap and the envelope. The cap is also sealed to the stem which extends from the tube.
- the present invention relates to high-pressure alkalimetal vapor discharge lamps and particularly to highpressure sodium vapor lamps. More particularly, it relates to improvements in hermetic gas or vacuum tight seals which are made in manufacturing the lamps.
- the high-pressure alkali-metal-vapor discharge lamps comprise tubes of translucent polycrystalline alumina resistant to high pressure alkali-metal vapors. Such a tube is closed at its ends by pieces of refractory material also resistant to alkali-metal vapors.
- Pumping stems of refractory metal which are used as electrode supports and current leads for the electrodes, pass through the refractory material pieces.
- a refractory metal is selected among the following metals and alloys thereof: niobium, zirconium, titanium, vanadium, tantalum, and preferably niobium and its well-known alloy with zirconium (1 percent).
- the metal-alumina seal may be made either with eutectic mixtures of alumina and calcium oxide or a vitreous mixture of alumina, calcium oxide and magnesium oxide, or with active metals such as titanium, vanadium, zirconium or preferably combinations thereof.
- vitreous seal materials may become devitrified, which is another cause of leakage.
- active metal seals are used, they are made on the alumina tube end, which results in a short tight length compared with leakage line lengths, just a little longer than the tube thickness.
- a discharge impact spot may be located on a metal seal part, which can cause leaks,
- a purpose of the present invention is to provide a tight closure of the discharge area which does not present the above mentioned drawbacks.
- tight sealing of the discharge area is obtained by proper sealing of the tube and electrode stem with two end seals at each end of the tube.
- An outer end-seal is formed with a refractory metal cap sealed to the tube end by a combination of active metals and to the stem by brazing.
- An inner endseal is formed by a ring of alumina sealed to the tube and to the stem by a vitreous mixture.
- FIG. 1 shows a schematic cross-section view of one of the two ends of the discharge area before melting
- FIG. 2 shows the same elements after melting.
- FIG. 1 shows a schematic cross-section view of one end of the discharge tube before melting, the cross-section being obtained across a diametral plane.
- the gas or vacuum tight closure of the translucent polycrystalline alumina tube or envelope 1 is formed by two endseals.
- One end-seal 2 is made of a ring of highly pure alumina, which may be translucent or not.
- the other end-seal 7 is a cap made of refractory metal, preferably of niobium or niobium alloy.
- Those end-seals 2 and 7, through which the stem 4 passes, are sealed to the alumina tube 1 respectively by a ring 3 of vitreous material mainly constituted by alumina and calcium oxide, and by rings 10 of active metals such as titanium, vanadium and zirconium.
- FIG. 1 also shows the electrode 5 secured to the stem 4 by a weld 9 made by any known process.
- the hole 6 is provided for evacuating or filling the discharge area 11.
- the assemblies are heated to a high temperature, under vacuum or inertgas-filled condition, to cause melting of the various rings.
- the seals are as shown in the FIG. 2 which includes the same elements as in the FIG. 1, the same reference numbers being used in both figures.
- the end-seal cap 7 may be sealed to the stem 4 by a seal 8 made according to any known process such as brazing, either before the ring melting operation, or at the same time.
- the area 12 between the two seals is preferably evacuated or filled with an inert gas.
- FIG. 2 shows that, after melting, the ring 3 is shaped as shown by 3 and forms a tight hermetic seal between the end-seal 2 and the tube 1, on the one hand, and between the end-seal 2 and the stem 4, on the other hand.
- the rings 10 are then shaped as shown by 10 and form a tight seal between the tube 1 and the end-seal cap 7.
- the seal temperature is lowered during operation which results in less severe thermal shocks during the life-time of the lamp
- the seal is not in contact with alkali-metal vapor because the area 12 is evacuated or filled with inert gas, which reduces the risk of corrosion;
- the invention may also be utilized in any case where alumina-metal seals are in contact with alkali-metal vapors.
- a seal for a vapor discharge lamp comprising:
- said first seal includes a ring of alumina and a vitreous mixture hermetically sealing said ring to said stem and envelope.
- said second seal includes a ring of refractory metals selected from the group consisting of titanium, vanadium and zirconium.
- said envelope is of poly-crystalline alumina and said vitreous sealing mixture includes a eutectic mixture of alumina and calcium oxide.
Landscapes
- Vessels And Coating Films For Discharge Lamps (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7031286A FR2102865A5 (enrdf_load_stackoverflow) | 1970-08-27 | 1970-08-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3716744A true US3716744A (en) | 1973-02-13 |
Family
ID=9060614
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00171578A Expired - Lifetime US3716744A (en) | 1970-08-27 | 1971-08-13 | Hermetic end seals for envelope of a metal vapor lamp |
Country Status (2)
Country | Link |
---|---|
US (1) | US3716744A (enrdf_load_stackoverflow) |
FR (1) | FR2102865A5 (enrdf_load_stackoverflow) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2405335A1 (de) * | 1973-02-16 | 1974-08-22 | Philips Nv | Hochdruckentladungslampe |
US3832588A (en) * | 1972-09-25 | 1974-08-27 | Gen Electric | Ceramic discharge lamp having metal end cap |
US3916242A (en) * | 1974-07-30 | 1975-10-28 | Us Army | Electrode seal and electrode mount for alkali-metal vapor lamps |
EP0052843A1 (en) * | 1980-11-21 | 1982-06-02 | GTE Laboratories Incorporated | Vacuum-tight assembly |
EP0052844A1 (en) * | 1980-11-21 | 1982-06-02 | GTE Laboratories Incorporated | Vacuum-tight assembly |
US5620349A (en) * | 1991-12-11 | 1997-04-15 | Osram Sylvania Inc. | Method for amalgam relocation in an arc discharge tube |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3363133A (en) * | 1966-02-28 | 1968-01-09 | Sylvania Electric Prod | Electric discharge device having polycrystalline alumina end caps |
US3448319A (en) * | 1966-10-31 | 1969-06-03 | Gen Electric | Niobium end seal |
US3473071A (en) * | 1965-10-25 | 1969-10-14 | Gen Electric Co Ltd | Electric discharge lamps |
-
1970
- 1970-08-27 FR FR7031286A patent/FR2102865A5/fr not_active Expired
-
1971
- 1971-08-13 US US00171578A patent/US3716744A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3473071A (en) * | 1965-10-25 | 1969-10-14 | Gen Electric Co Ltd | Electric discharge lamps |
US3363133A (en) * | 1966-02-28 | 1968-01-09 | Sylvania Electric Prod | Electric discharge device having polycrystalline alumina end caps |
US3448319A (en) * | 1966-10-31 | 1969-06-03 | Gen Electric | Niobium end seal |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3832588A (en) * | 1972-09-25 | 1974-08-27 | Gen Electric | Ceramic discharge lamp having metal end cap |
DE2405335A1 (de) * | 1973-02-16 | 1974-08-22 | Philips Nv | Hochdruckentladungslampe |
US3916242A (en) * | 1974-07-30 | 1975-10-28 | Us Army | Electrode seal and electrode mount for alkali-metal vapor lamps |
EP0052843A1 (en) * | 1980-11-21 | 1982-06-02 | GTE Laboratories Incorporated | Vacuum-tight assembly |
EP0052844A1 (en) * | 1980-11-21 | 1982-06-02 | GTE Laboratories Incorporated | Vacuum-tight assembly |
US5620349A (en) * | 1991-12-11 | 1997-04-15 | Osram Sylvania Inc. | Method for amalgam relocation in an arc discharge tube |
US6100634A (en) * | 1991-12-11 | 2000-08-08 | Gte Products Corporation | Method for amalgam relocation in an arc discharge tube |
Also Published As
Publication number | Publication date |
---|---|
FR2102865A5 (enrdf_load_stackoverflow) | 1972-04-07 |
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