US3713903A - Trim members and production thereof - Google Patents
Trim members and production thereof Download PDFInfo
- Publication number
- US3713903A US3713903A US00115363A US3713903DA US3713903A US 3713903 A US3713903 A US 3713903A US 00115363 A US00115363 A US 00115363A US 3713903D A US3713903D A US 3713903DA US 3713903 A US3713903 A US 3713903A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- stainless steel
- body member
- conversion
- trim
- Prior art date
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- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title abstract description 13
- 239000010935 stainless steel Substances 0.000 abstract description 32
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 32
- 229910052782 aluminium Inorganic materials 0.000 abstract description 31
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 31
- 230000007797 corrosion Effects 0.000 abstract description 12
- 238000005260 corrosion Methods 0.000 abstract description 12
- 238000007744 chromate conversion coating Methods 0.000 abstract description 11
- 239000002131 composite material Substances 0.000 abstract description 8
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract description 7
- 238000007746 phosphate conversion coating Methods 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 description 9
- 229910000975 Carbon steel Inorganic materials 0.000 description 8
- 239000010962 carbon steel Substances 0.000 description 7
- 238000007739 conversion coating Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 230000000712 assembly Effects 0.000 description 6
- 238000000429 assembly Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- -1 e.g. Inorganic materials 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F13/00—Inhibiting corrosion of metals by anodic or cathodic protection
- C23F13/02—Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
Definitions
- the present invention relates to stainless steel composites in the form of trim members and to a method for producing them and more particularly to conversioncoated, aluminum-striped stainless steel composites in the form of trim members and to a method for producing them. It further relates to conversion-coated, aluminumstriped stainless steel composites suitable for fabrication into trim members and to assemblies comprised of conversion-coated, aluminum-striped stainless steel trim members in combination with body members.
- Stainless steel is known to serve a particularly good purpose in those applications where brightness and stain resistance to a variety of contaminants is required and is ideally suited for use as automotive trim.
- the use of stainless steel can result in galvanic corrosion.
- Carbon steel is anodic to stainless steel and generally corrodes in the vicinity of stainless steel in the presence of an electrolyte, such as moisture.
- FIG. 1 is a sectional view of a stainless steel trim member
- FIG. 2 is a perspective view of a stainless steel trim member.
- the present invention encompasses a composite suitable for fabrication into a stainless steel trim member, a composite in the form of a stainless steel trim member, a method for producing stainless steel trim members and an assembly comprising a stainless steel trim member in combination with a body member.
- the body member is comprised of metal, e.g., plain carbon steel, which is less noble in the electromotive series than stainless steel.
- metal is interpreted as including metal which is painted and coated as well as bare.
- the stainless steel trim member has a contact surface and an exposure surface.
- the contact surface abuts the body member after assembly and the exposure surface is subject to view.
- Adhered to the contact surface is a layer of aluminum.
- the aluminum is generally at least 0.5 of a mil thick and preferably between 3 and 5 mils. Covering the aluminum is a conversion coating from the group consisting of chromate and phosphate conversion coatmgs.
- FIGS. 1 and 2 are respectively a sectional and perspective view of a stainless steel trim member 1 which meets the requirements of this invention. It comprises an exposed surface 2, contact surfaces 4, aluminum strips 6, and conversion coatings 8.
- the method of this invention includes the steps of shaping a stainless steel sheet into a trim member having an exposed surface and at least one contact surface and adhering aluminum to those portions of the sheet which are the contact surfaces of the finally formed trim member. Any of the well-known methods of shaping, e.g., roll forming, and adhering; e.g., roll pressure bonding, are within the scope of this invention.
- the method additionally involves the step of applying a conversion coating to the aluminum either before or after shaping. It can be any of the well-known chromate or phosphate conversion coatings.
- a typical chromate conversion coating consists of 0.99 ounce of sodium dichromate, 0.132 ounce of sodium flouride, 0.66 ounce of potassium ferricyanide, 3 cubic centimeters of nitric acid, and 1 gallon of water. It is applied at a temperature between ambient and F. for a period of time between 5 seconds and 8 minutes.
- a typical phosphate conversion coating consists of 1 gallon of water and 10-20 ounces of solution composed of 61.7% ammonium phosphate, 22.9% ammonium flouride, and 15.4% potassium dichromate. It is applied at a temperature between 110 and 120 F. for a period of time between one and five minutes.
- a number of stainless steel trim members were prepared with stripes of aluminum adhered to their contact surface. Half of the trim members were assembled onto carbon steel body members without further treatment. The other half were given a chromate conversion coating prior to assembly. Coating was accomplished by dipping the aluminum stripes into a bath maintained at ambient temperature. Immersion times ranged from 1 to 3 minutes. The bath contained Iridite No. 14-2, a chromate conversion coating sold by Allied Research Products, Inc., Baltimore, Md.
- All of the assemblies i.e., those with and those without chromate conversion coatings, were subject to salt spray tests in order to demonstrate the efiectiveness of the conversion coatings. These tests are considered to be accelerated tests insofar as they produce corrosive conditions far more severe than those encountered by automotive bodies under normal road conditions.
- Aluminum corrosion products were well in evidence on the untreated assemblies, i.e., those without chromate conversion coat ings, after 24 hours of testing.
- the treated assemblies i.e., those with chromate conversion coatings, were essentially free of aluminum corrosion products after 80 hours of testing and provided the carbon steel body member with galvanic protection equivalent to that provided by the untreated assemblies.
- a stainless steel strip is shaped into a trim member having an exposed surface and at least one contact surface and wherein an aluminum layer having a thickness in excess of 0.5 of a mil is adhered to portions of said stainless steel which become contact surfaces of the finally shaped trim member, the improvement which comprises: applying a conversion coating from the group consisting of chromate and phosphate conversion coatings onto the aluminum.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
ALUMINUM-STRIPED STAINLESS STEEL COMPOSITES SUITABLE FOR FABRICATION INTO TRIM MEMBERS AND A METHOD FOR PRODUCING CONVERSION-COATED, ALUMINUM-STRIPED STAINLESS STEEL TRIM MEMBERS.
THE APPLICATION DESCRIBES ASSEMBLIES COMPRISED OF A BODY MEMBER IN COMBINATION WITH A STAINLESS STEEL TRIM MEMBER HAVING A CONTACT SURFACE WHICH ABUTS THE BOODY MEMBER AND AN EXPOSURE SURFACE SUBJECT TO VIEW. ADHERED TO THE CONTACT SURFACE AND LOCATED BETWEEN THE CONTACT SURFACE AND THE BODY MEMBER IS A LAYER OF ALUMINUM WHICH PROVIDES GALVANIC PROTECTION FOR THE BODY MEMBER. COVERINGS THE ALUMINUM IS A CHROMATE OR PHOSPHATE CONVERSION COATING WHICH PROVIDES PROTECTION AGAINST ALUMINUM GALVANIC CORROSION WITHOUT DETRIMENTALLY AFFECTING THE GALVANIC PROTECTION WHICH ALUMINUM PROVIDES FOR THE BODY MEMBER. ALSO DESCRIBED ARE CONVERSION-COATED,
THE APPLICATION DESCRIBES ASSEMBLIES COMPRISED OF A BODY MEMBER IN COMBINATION WITH A STAINLESS STEEL TRIM MEMBER HAVING A CONTACT SURFACE WHICH ABUTS THE BOODY MEMBER AND AN EXPOSURE SURFACE SUBJECT TO VIEW. ADHERED TO THE CONTACT SURFACE AND LOCATED BETWEEN THE CONTACT SURFACE AND THE BODY MEMBER IS A LAYER OF ALUMINUM WHICH PROVIDES GALVANIC PROTECTION FOR THE BODY MEMBER. COVERINGS THE ALUMINUM IS A CHROMATE OR PHOSPHATE CONVERSION COATING WHICH PROVIDES PROTECTION AGAINST ALUMINUM GALVANIC CORROSION WITHOUT DETRIMENTALLY AFFECTING THE GALVANIC PROTECTION WHICH ALUMINUM PROVIDES FOR THE BODY MEMBER. ALSO DESCRIBED ARE CONVERSION-COATED,
Description
Jan. 30, 1973 o. R. ZAREMSKI 3. 5
- TRIM MEMBERS AND PRODUCTION THEREOF Original Filed Sept. 24, 1969 INVE/V TOR. DOA/AND R. ZAREMSK/ A Horney United States Patcnt O 3,713,903 TRIM MEMBERS AND PRODUCTION THEREOF Donald R. Zaremski, Cheswick, Pa., assignor to Allegheny Ludlum Industries, Inc., Pittsburgh, Pa. Original application Sept. 24, 1969, Ser. No. 860,541. Divided and this application Feb. 16, 1971, Ser. No. 115,363
Int. Cl. (1231: 7/14, 7/26 US. Cl. 148-6.15 R 4 Claims ABSTRACT OF THE DISCLOSURE The application describes assemblies comprised of a body member in combination With a stainless steel trim member having a contact surface which abuts the body member and an exposure surface subject to view. Ad-- hered to the contact surface and located between the contact surface and the body member is a layer of aluminum which provides galvanic protection for the body member. Covering the aluminum is a chromate or phosphate conversion coating which provides protection against aluminum galvanic corrosion without detrimentally affecting the galvanic protection which aluminum provides for the body member. Also described are conversion-coated, aluminum-striped stainless steel composites suitable for fabrication into trim members and a method for producing conversion-coated, aluminum-striped stainless steel trim members.
This application is a division of copending application Ser. No. 860,541 filed Sept. 24, 1969, now Pat. No. 3,637,- 354 issued Jan. 25, 1972.
The present invention relates to stainless steel composites in the form of trim members and to a method for producing them and more particularly to conversioncoated, aluminum-striped stainless steel composites in the form of trim members and to a method for producing them. It further relates to conversion-coated, aluminumstriped stainless steel composites suitable for fabrication into trim members and to assemblies comprised of conversion-coated, aluminum-striped stainless steel trim members in combination with body members.
Stainless steel is known to serve a particularly good purpose in those applications where brightness and stain resistance to a variety of contaminants is required and is ideally suited for use as automotive trim. However, since most automotive bodies are constructed of carbon steel, the use of stainless steel can result in galvanic corrosion. Carbon steel is anodic to stainless steel and generally corrodes in the vicinity of stainless steel in the presence of an electrolyte, such as moisture.
To protect carbon steel it has been the practice to coat stainless strips with a non-ferrous sacrificial metal which is anodic to mild carbon steel prior to or after forming the strips into trim members. The coating is preferably aluminum. It is applied to those sections of the strip which will eventually contact the automotive body, i.e., the return flange of the fabricated trim member.
Testing under normal road conditions has indicated that the use of aluminum solves the galvanic corrosion problem faced by automotive manufacturers. However, when the aluminum corrodes, it results in the formation and bleeding of aesthetically objectionable aluminum corrosion products (white corrosion products).
I have discovered that the formation and bleeding of aluminum corrosion products can be minimized without adversely affecting the galvanic protection provided by the aluminum, through application of a protective chromate or phosphate conversion coating to the aluminum. These coatings have been applied in non-related environ- Patented Jan. 30, 1973 ments to aluminum for protection against general corrosion and to very thin layers of zinc, for protection against galvanic corrosion. My work has shown that they offer protection against aluminum galvanic corrosion without detrimentally affecting the galvanic protection which aluminum provides for carbon steel in the vicinity of stainless steel.
It is accordingly an object of this invention to provide a conversion-coated, aluminum-striped stainless steel composite.
It is another object of this invention to provide a method for producing a conversion-coated, aluminum-striped stainless steel trim member.
It is a further object of this invention to provide an assembly comprised of a body member in combination with a conversion-coated, aluminum-striped stainless steel trim member which provides galvanic protection for the body member.
The foregoing and other objects of the invention will be best understood from the following description, reference being bad to the accompanying drawing, wherein:
FIG. 1 is a sectional view of a stainless steel trim member; and
FIG. 2 is a perspective view of a stainless steel trim member.
The present invention encompasses a composite suitable for fabrication into a stainless steel trim member, a composite in the form of a stainless steel trim member, a method for producing stainless steel trim members and an assembly comprising a stainless steel trim member in combination with a body member. The body member is comprised of metal, e.g., plain carbon steel, which is less noble in the electromotive series than stainless steel. In the context of this application, the term metal is interpreted as including metal which is painted and coated as well as bare.
The stainless steel trim member has a contact surface and an exposure surface. The contact surface abuts the body member after assembly and the exposure surface is subject to view. Adhered to the contact surface is a layer of aluminum. The aluminum is generally at least 0.5 of a mil thick and preferably between 3 and 5 mils. Covering the aluminum is a conversion coating from the group consisting of chromate and phosphate conversion coatmgs.
FIGS. 1 and 2 are respectively a sectional and perspective view of a stainless steel trim member 1 which meets the requirements of this invention. It comprises an exposed surface 2, contact surfaces 4, aluminum strips 6, and conversion coatings 8.
The method of this invention includes the steps of shaping a stainless steel sheet into a trim member having an exposed surface and at least one contact surface and adhering aluminum to those portions of the sheet which are the contact surfaces of the finally formed trim member. Any of the well-known methods of shaping, e.g., roll forming, and adhering; e.g., roll pressure bonding, are within the scope of this invention. The method additionally involves the step of applying a conversion coating to the aluminum either before or after shaping. It can be any of the well-known chromate or phosphate conversion coatings. A typical chromate conversion coating consists of 0.99 ounce of sodium dichromate, 0.132 ounce of sodium flouride, 0.66 ounce of potassium ferricyanide, 3 cubic centimeters of nitric acid, and 1 gallon of water. It is applied at a temperature between ambient and F. for a period of time between 5 seconds and 8 minutes. A typical phosphate conversion coating consists of 1 gallon of water and 10-20 ounces of solution composed of 61.7% ammonium phosphate, 22.9% ammonium flouride, and 15.4% potassium dichromate. It is applied at a temperature between 110 and 120 F. for a period of time between one and five minutes.
The following example illustrates several aspects of the invention.
A number of stainless steel trim members were prepared with stripes of aluminum adhered to their contact surface. Half of the trim members were assembled onto carbon steel body members without further treatment. The other half were given a chromate conversion coating prior to assembly. Coating was accomplished by dipping the aluminum stripes into a bath maintained at ambient temperature. Immersion times ranged from 1 to 3 minutes. The bath contained Iridite No. 14-2, a chromate conversion coating sold by Allied Research Products, Inc., Baltimore, Md.
All of the assemblies, i.e., those with and those without chromate conversion coatings, were subject to salt spray tests in order to demonstrate the efiectiveness of the conversion coatings. These tests are considered to be accelerated tests insofar as they produce corrosive conditions far more severe than those encountered by automotive bodies under normal road conditions. Aluminum corrosion products were well in evidence on the untreated assemblies, i.e., those without chromate conversion coat ings, after 24 hours of testing. The treated assemblies, i.e., those with chromate conversion coatings, were essentially free of aluminum corrosion products after 80 hours of testing and provided the carbon steel body member with galvanic protection equivalent to that provided by the untreated assemblies.
It will be apparent to those skilled in the art that the novel principles of the invention disclosed herein in connection with specific examples thereof will suggest various other modifications and applications of the same. It is accordingly desired that in construing the breadth of the appended claims they shall not be limited to the specific examples of the invention described herein.
I claim:
1. In the method of producing a stainless steel trim member, wherein a stainless steel strip is shaped into a trim member having an exposed surface and at least one contact surface and wherein an aluminum layer having a thickness in excess of 0.5 of a mil is adhered to portions of said stainless steel which become contact surfaces of the finally shaped trim member, the improvement which comprises: applying a conversion coating from the group consisting of chromate and phosphate conversion coatings onto the aluminum.
2. A method according to claim 1 wherein said conversion coating is a chromate conversion coating.
3. A method according to claim 1 wherein said conversion coating is a phosphate conversion coating.
4. A method according to claim 1 wherein said aluminum has a thickness of from about 3 mils to about 5 mils.
References Cited UNITED STATES PATENTS 3,201,210 8/1965 Harkins et a1. 29195 T X 3,201,212 8/1965 Zaremski 29-195 T X 3,340,597 9/1967 Stein et al 29-196.2 3,536,459 10/ 1970 Bates 29191.6 3,284,319 11/1966 Hill 1486.2 X 3,063,877 11/1962 Schiffman 1486.2 X 2,769,737 11/1956 Russell 1486.15 R 2,514,941 7/1950 Drysdale et a1. 148--6.15 R 3,484,350 12/ 1969 Zaremski 29--196.2 3,201,211 8/1965 Renshaw et a1. 29196.5 X 2,762,771 9/ 1956 Preiser 29--196.2 X
RALPH S. KENDALL, Primary Examiner US. Cl. X.R.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11536371A | 1971-02-16 | 1971-02-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3713903A true US3713903A (en) | 1973-01-30 |
Family
ID=22360905
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00115363A Expired - Lifetime US3713903A (en) | 1971-02-16 | 1971-02-16 | Trim members and production thereof |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3713903A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3948689A (en) * | 1969-06-30 | 1976-04-06 | Alloy Surfaces Company, Inc. | Chromic-phosphoric acid coated aluminized steel |
| JPS5192742A (en) * | 1975-02-13 | 1976-08-14 | FUNTAITOSONOMAESHORIHOHO | |
| JPS5576077A (en) * | 1978-12-01 | 1980-06-07 | Nippon Paint Co Ltd | Pretreatment of brazed iron or steel prior to painting |
-
1971
- 1971-02-16 US US00115363A patent/US3713903A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3948689A (en) * | 1969-06-30 | 1976-04-06 | Alloy Surfaces Company, Inc. | Chromic-phosphoric acid coated aluminized steel |
| JPS5192742A (en) * | 1975-02-13 | 1976-08-14 | FUNTAITOSONOMAESHORIHOHO | |
| JPS55472B2 (en) * | 1975-02-13 | 1980-01-08 | ||
| JPS5576077A (en) * | 1978-12-01 | 1980-06-07 | Nippon Paint Co Ltd | Pretreatment of brazed iron or steel prior to painting |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: ALLEGHENY LUDLUM CORPORATION Free format text: CHANGE OF NAME;ASSIGNOR:ALLEGHENY LUDLUM STEEL CORPORATION;REEL/FRAME:004779/0642 Effective date: 19860805 |
|
| AS | Assignment |
Owner name: PITTSBURGH NATIONAL BANK Free format text: SECURITY INTEREST;ASSIGNOR:ALLEGHENY LUDLUM CORPORATION;REEL/FRAME:004855/0400 Effective date: 19861226 |
|
| AS | Assignment |
Owner name: PITTSBURGH NATIONAL BANK Free format text: ASSIGNMENT OF ASSIGNORS INTEREST. RECORDED ON REEL 4855 FRAME 0400;ASSIGNOR:PITTSBURGH NATIONAL BANK;REEL/FRAME:005018/0050 Effective date: 19881129 |