US3706682A - Hot tops and mixture of materials therefor - Google Patents
Hot tops and mixture of materials therefor Download PDFInfo
- Publication number
- US3706682A US3706682A US109647A US3706682DA US3706682A US 3706682 A US3706682 A US 3706682A US 109647 A US109647 A US 109647A US 3706682D A US3706682D A US 3706682DA US 3706682 A US3706682 A US 3706682A
- Authority
- US
- United States
- Prior art keywords
- sand
- mixture
- metal
- layer
- vitreous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title abstract description 30
- 239000000203 mixture Substances 0.000 title abstract description 14
- 239000004576 sand Substances 0.000 abstract description 21
- 239000002184 metal Substances 0.000 abstract description 18
- 238000002844 melting Methods 0.000 abstract description 12
- 230000008018 melting Effects 0.000 abstract description 12
- 239000000835 fiber Substances 0.000 abstract description 7
- 235000012054 meals Nutrition 0.000 abstract description 5
- 229920001131 Pulp (paper) Polymers 0.000 abstract description 4
- 239000002023 wood Substances 0.000 abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
- 229910000831 Steel Inorganic materials 0.000 description 12
- 239000010959 steel Substances 0.000 description 12
- 239000010410 layer Substances 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 239000011819 refractory material Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 4
- 238000005266 casting Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 2
- 239000010459 dolomite Substances 0.000 description 2
- 229910000514 dolomite Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000013379 molasses Nutrition 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000011044 quartzite Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 238000003887 surface segregation Methods 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D7/00—Casting ingots, e.g. from ferrous metals
- B22D7/06—Ingot moulds or their manufacture
- B22D7/10—Hot tops therefor
Definitions
- the wall material is made from a mixture of granular or powdered aerated concrete or porous concrete and organic fibre material such as Wood meal, sawdust, mechanical wood pulp and a binder, and according to the invention the mixture also comprises sand of such a rate of refractability that the melting temperature of the sand is lower than the temperature of the molten metal, said sand, under the influence of the heat from the molten metal, providing a thin vitreous mineralic layer.
- This invention relates to hot tops for casting steel and to a Wall material particularly suited to such hot tops.
- hot tops from exothermic, combustible, ceramic and refractory material. Furthermore, it is known to manufacture hot tops from porous insulating materials such as aerated concrete, kieselguhr, asbestos or vermiculite and to provide these hot tops, on the side facing the steel or metal, with a surface layer of refractory material such as chamotte meal, quartzite powder or dolomite powder.
- molten steel when tapped into the chill has a temperature of between -1600" C. it is natural that in constructing hot tops an effort should be made to use material having as high a melting point as possible in order to prevent the material of the hot top from melting. For this reason refractory material such as quartzite powder, dolomite powder, etc., is often used.
- the basic idea of the invention is to provide a wall material for the hot top having such a composition that the surface contacting the molten steel or other metal will be covered with a smooth, gastight, thin vitreous mineralic layer when contacting the molten steel or metal.
- the wall material of the hot top is made from a mixture of granular or powdered aerated concrete or porous concrete and organic fibre material such as wood meal, sawdust, mechanical wood pulp and a binder, and according to the invention the mixture also comprises sand of such a rate of refractability that melting temperature of the sand is lower than the temperature of the molten metal, said sand, under the influence of the heat from the molten metal, will define a thin vitrous, mineralic layer.
- the sand may, for example contain felspar, preferably having finer particles than the aerated concrete.
- the upper limit of the melting temperature or melting temperature interval of the steel is 1570-1610 C.
- the liquidus temperature (melting temperature interval) of the steel may vary, for example, between 1450 and 1550 C.
- the melting temperature of the sand should be lower than this lquidus temperature or melting temperature interval.
- the melting process is limited to a thin zone since the vitreous mineralic layer contains a large number of porous relatively coarse concrete particles which render the vitreous layer extremely heat-insulating and since a large number of such coarser, unmelted grains of porous concrete in the vitreous layer will cause the melting point of the vitreous layer to be much higher than the average analysis of the ceramics would in fact indicate.
- the vitreous layer will protect the steel or metal against carburization and other impurities and will impart a smooth surface to the hot top and the billet. Normally no remnants of the hot top will stick to the resultant smooth casting or billet surface. The heat radiation from the smooth surface will also become less than from the normal, somewhat rough surface.
- Suitable particle sizes are, for non-refractory sand of the kind now defined, max. 1.5 mm. and at least lower than 0.5 mm. and for porous concrete max. 6 mm. and at least 80% lower than 3 mm.
- the particle size of the porous concrete exceeds that of the sand.
- the ratio by weight between sand and porous concrete should be between 1:2 and 4:1, suitably 2:1.
- the best quantity of sawdust or other organic fibre material is between 5-10% by weight.
- the binder should be of organic nature.
- An extremely suitable binder is an emulsion of polyvinyl acetate. It can be used alone, but can also very well be combined with dextrine, molasses, sulphite lye, core oil and phenolic resins.
- Hot tops made in one integral piece or in the form of slabs of this material can be manufactured by mixing the dry materials with binder in conventional way and then pressing the mixture in moulds. The material is then allowed to dry in a drying furnace at 200 C. It is possible to produce hot top material having a low volume weight as low as 0.7-0.8 g./cm. which means an extremely high insulating capacity.
- Wall material for hot tops for chill casting of steel or other metal comprising a mixture of granular and powdered porous concrete having a particle size not exceeding about 6 mm., at least one of a group of organic fibre materials selected from wood meal, sawdust and mechanical wood pulp, a binder for said organic fibre material comprising an emulsion of polyvinyl acetate, and sand having a particle size not exceeding about 0.5 mm., said organic fibre material comprising between 5% and 10% by weight of the entire mixture, the ratio by weight of sand to porous concrete being between 1:2 and 4:1, the ratio of refractability of said sand being such that the melting temperature of the sand is lower than the temperature of the molten metal, said sand, under the influence of heat from the molten metal, providing a thin vitreous, mineralic layer at the surface of the wall material contacting the molten metal.
- said binder consists of an emulsion of polyvinyl acetate combined with an element from the group consisting of dextrine, molasses, sulphitic lye, core oil and phenolic resin.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Moulds, Cores, Or Mandrels (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Mold Materials And Core Materials (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE01322/70A SE352256B (enrdf_load_stackoverflow) | 1970-02-02 | 1970-02-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3706682A true US3706682A (en) | 1972-12-19 |
Family
ID=20257999
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US109647A Expired - Lifetime US3706682A (en) | 1970-02-02 | 1971-01-25 | Hot tops and mixture of materials therefor |
Country Status (5)
Country | Link |
---|---|
US (1) | US3706682A (enrdf_load_stackoverflow) |
DE (1) | DE2103028A1 (enrdf_load_stackoverflow) |
FR (1) | FR2080948B3 (enrdf_load_stackoverflow) |
GB (1) | GB1304982A (enrdf_load_stackoverflow) |
SE (1) | SE352256B (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3878142A (en) * | 1971-12-03 | 1975-04-15 | Tidd Chemisch Tech Produkte G | Compositions for lining casting moulds and related articles and method of making such articles |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2301812C3 (de) * | 1973-01-15 | 1981-05-07 | C.G. Sproule and Associates, Inc., Wynnewood, Pa. | Wärmeisolationsplatte für Steiger von Gießformen |
JPS5131015B2 (enrdf_load_stackoverflow) * | 1973-04-06 | 1976-09-04 |
-
1970
- 1970-02-02 SE SE01322/70A patent/SE352256B/xx unknown
-
1971
- 1971-01-22 DE DE19712103028 patent/DE2103028A1/de active Pending
- 1971-01-25 US US109647A patent/US3706682A/en not_active Expired - Lifetime
- 1971-02-02 FR FR7103414A patent/FR2080948B3/fr not_active Expired
- 1971-04-19 GB GB2014271A patent/GB1304982A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3878142A (en) * | 1971-12-03 | 1975-04-15 | Tidd Chemisch Tech Produkte G | Compositions for lining casting moulds and related articles and method of making such articles |
Also Published As
Publication number | Publication date |
---|---|
FR2080948A7 (enrdf_load_stackoverflow) | 1971-11-26 |
SE352256B (enrdf_load_stackoverflow) | 1972-12-27 |
GB1304982A (enrdf_load_stackoverflow) | 1973-01-31 |
FR2080948B3 (enrdf_load_stackoverflow) | 1976-01-09 |
DE2103028A1 (de) | 1971-08-12 |
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