US3661568A - Copper base alloy - Google Patents
Copper base alloy Download PDFInfo
- Publication number
- US3661568A US3661568A US50893A US3661568DA US3661568A US 3661568 A US3661568 A US 3661568A US 50893 A US50893 A US 50893A US 3661568D A US3661568D A US 3661568DA US 3661568 A US3661568 A US 3661568A
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- United States
- Prior art keywords
- base alloy
- copper base
- percent
- alloy according
- present
- Prior art date
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- 239000000956 alloy Substances 0.000 title claims abstract description 57
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 57
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 42
- 239000010949 copper Substances 0.000 title claims abstract description 42
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- 239000011701 zinc Substances 0.000 claims abstract description 10
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011574 phosphorus Substances 0.000 claims abstract description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 5
- 239000011572 manganese Substances 0.000 claims abstract description 5
- 230000000704 physical effect Effects 0.000 abstract description 9
- 239000000463 material Substances 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 abstract description 6
- 238000000137 annealing Methods 0.000 description 10
- 238000005275 alloying Methods 0.000 description 4
- 238000005266 casting Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000007792 addition Methods 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/04—Alloys based on copper with zinc as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
Definitions
- the present disclosure teaches an improved copper base alloy commuatlon-m-part 0f June containing iron and manganese and a material selected from I967. abandonedthe group consisting of phosphorus and zinc and mixtures thereof.
- the alloys of the present invention are characterized 1 75/1575, 75/l53, M3/32-5 by improved physical properties, in particular high strength [5
- lt is a further object of the present invention to provide an improved copper base alloy having a combination of high strength, high conductivity, and other excellent physical properties.
- lt is an additional object of the present invention to provide a copper base alloy which is inexpensive and wherein the eacellent physical properties are easily obtainable.
- the alloy of the present invention comprises a copper base alloy consisting essentially of from 1.5 to 3.5 percent iron, from 0.01 to 0,l2 percent manganese, a material selected from the group consisting of phosphorous from 0.01 to 0.10 percent, zinc from 0.05 to 0.20 percent and mixtures thereof and the balance essentially copper.
- a copper base alloy consisting essentially of from 1.5 to 3.5 percent iron, from 0.01 to 0,l2 percent manganese, a material selected from the group consisting of phosphorous from 0.01 to 0.10 percent, zinc from 0.05 to 0.20 percent and mixtures thereof and the balance essentially copper.
- both phosphorous and zinc should be present since the best combination of properties in conjunction with ease of manufacturing are obtained thereby.
- all percentages are percentages by weight.
- the alloys of the present invention have an unexpected im provement in electrical conductivity. Namely, there is readily obtained an lACS electrical conductivity in excess of 60 percent lACS and generally over 70 percent IACS. Furthermore, the alloys of the present invention have excellent annealing characteristics, with the ability to attain various strength levels as a result of different annealing treatments. In addition, the alloys of the present invention attain high rolled temper strength levels. Still further the high electrical conductivity of the alloys of the present invention is coupled with excellent annealed tensile strength properties of approximately 55,000 psi and higher. The strength and physical properties of the alloys of the present invention are not significantly variable if small amounts of impurities are present. In addition to the foregoing, the alloys of the present invention are inexpensive and their excellent physical properties are easily obtainable.
- composition of the alloys of the present invention is as stated heretofore.
- the preferred iron content is from 1.8 to
- the preferred manganese content is from 0.03 to 0.10 percent.
- the preferred zinc content is from 0.05 to 0.15 percent and the preferred phosphorus content is from 0.01 to 0.08 percent.
- the alloying ingredients are important.
- the alloys of the present invention attain improvement over conventional alloys in a wide range of processing. Naturally, however, particular processing will result in variation in properties.
- the manner of casting the material is not particularly critical, with conventional casting methods for these types of alloys being readily utilizable, it being noted that higher temperatures should be used in order to solutionize the iron. It is preferred to cast the alloy into billets of conventional size, subjecting them to hot working, as by rolling in the conventionalsize.
- the alloy After casting the alloy should be hot rolled at an elevated temperamre, i.e., from 800 to 1,050 C., with a temperature of about 950 C. being preferred. The alloy should then be cold rolled to gage, with intermediate anneals, with cold reduction in excess of 50 percent between anneals being preferred. Annealing temperatures of from 400 to 600 C. are preferred, with annealing time at temperature preferably being a minimum of 2 hours. Longer times may be utilized, if desired, to improve electrical conductivity. Continuous strand annealing of strip or mill products will achieve the same high level of physical properties as with Bell annealing, but will not achieve as high a level of electrical conductivity. Therefore, for development of both high annealed strength and electrical conductivity, final annealing and preferably in process annealing must be in batches with conventional furnace cooling, such as. Bell annealing.
- EXAMPLE 1 Alloys were prepared in the following manner. High purity copper and high purity iron were melted together in a low frequency, slot type induction furnace under a charcoal cover at approximately 1,200 C. About 10 percent of the copper charge was held back and the melt was slightly overheated to about l,300 C. in order to put the iron into solution. High purity alloying additions were added when the molten mass was at about 1,300 C. The balance of the copper was added and the melt brought to the pouring temperature of about 1,200 C. The melt was then poured into a water-cooled ingot mold of 28 56 X 5 X 96 inches at a pouring rate of 21.3 inches per minute.
- the alloys thus prepared had the following composition.
- a high conductivity, high strength copper base alloy consisting essentially of from 1.5 to 3.5 percent iron, from 0.01 to 0.l2 percent manganese, a material selected from the group consisting of phosphorus from 0.0l to 0. l0 percent, zinc from 0.05 to 0.20 percent and mixtures thereof and the balance copper.
- a copper base alloy according to claim 1 containing both phosphorus and zinc.
- a copper base alloy according to claim 1 in the flat rolled condition 3.
- a copper base alloy according to claim I having an electrical conductivity of at least percent [ACS and an annealed tensile strength of at least 55,000 psi.
- a copper base alloy according to claim 1 having an electrical conductivity of at least 60 percent lACS.
- a copper base alloy according to claim I in the cold rolled condition.
- a copper base alloy according to claim 1 in the cold rolled and annealed condition 10.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Conductive Materials (AREA)
Abstract
The present disclosure teaches an improved copper base alloy containing iron and manganese and a material selected from the group consisting of phosphorus and zinc and mixtures thereof. The alloys of the present invention are characterized by improved physical properties, in particular high strength and high conductivity.
Description
I United States Patent n51 3,661,568
McLain 1 *May 9, 1972 s41 COPPER BASE ALLOY [56] References Cited [72] Inventor: Charles D. MQLIIII, Alton, Ill. UNITED STATES PATENTS [731 Assifim: 2,l55,406 4/1939 Crampton ..75/: 57.5 x l a 1 Notice; The portion f the term f this patent m 3,522,039 7/1970 McLain 75/ I 57.5
sequent to July 28, 1987, has been disclaimed. Primary E.\'aminerl... Dewayne Rutledge Assistant Examiner-J. E. Legru [22] filed: 1970 Attorney-Robert H. Bachman and Gordon G. Menzies [21] Appl. No.: 50,893
57 ABSTRACT Related U.S. Application Data The present disclosure teaches an improved copper base alloy commuatlon-m-part 0f June containing iron and manganese and a material selected from I967. abandonedthe group consisting of phosphorus and zinc and mixtures thereof. The alloys of the present invention are characterized 1 75/1575, 75/l53, M3/32-5 by improved physical properties, in particular high strength [5| Int. Cl ..C22c 9/00, C22c 9/04 and high conductivity [58] Field of Search ..75/l53, l57.$, 162
10 Claims, No Drawings COPPER BASE ALLOY This application is a continuation-impart of copendingapplication Ser. No. 648,953 for "Copper Base Alloy" by Charles D. McLain, filed June 26, 1967 now abandoned.
BACKGROUND OF THE INVENTION As is well known in the art, copper is an excellent conductor of electricity. Numerous alloying additions have been proposed in order to increase the strength of copper. in so doing, the electrical conductivity of the copper is markedly reduced.
It is, therefore, highly desirable to provide a copper base alloy characterized by high conductivity and increased strength.
Accordingly, it is a principal object of the present invention to provide a copper base alloy characterized by high electrical conductivity and high strength properties.
it is a further object of the present invention to provide a copper base alloy with annealed physical properties whichdo not have a wide variation.
[t is a further object of the present invention :to provide a copper base alloy having the ability to attain various strength levels as a result of different annealing treatments, even when small amounts of impurities are present.
lt is a further object of the present invention to provide an improved copper base alloy having a combination of high strength, high conductivity, and other excellent physical properties.
lt is an additional object of the present invention to provide a copper base alloy which is inexpensive and wherein the eacellent physical properties are easily obtainable.
Further objects and advantages of the present invention will appear from the ensuing specification.
SUMMARY OF THE INVENTION In accordance with the present invention it has been found that an improved copper base alloy is provided which effectively achieves the foregoing objects and advantages. The alloy of the present invention comprises a copper base alloy consisting essentially of from 1.5 to 3.5 percent iron, from 0.01 to 0,l2 percent manganese, a material selected from the group consisting of phosphorous from 0.01 to 0.10 percent, zinc from 0.05 to 0.20 percent and mixtures thereof and the balance essentially copper. in the preferred embodiment it has been found that both phosphorous and zinc should be present since the best combination of properties in conjunction with ease of manufacturing are obtained thereby. Throughout the ensuing specification all percentages are percentages by weight.
In accordance with the present invention, it has been surprisingly found that the foregoing alloys are characterized by numerous unexpected and surprising advantages. For example, the alloys of the present invention have an unexpected im provement in electrical conductivity. Namely, there is readily obtained an lACS electrical conductivity in excess of 60 percent lACS and generally over 70 percent IACS. Furthermore, the alloys of the present invention have excellent annealing characteristics, with the ability to attain various strength levels as a result of different annealing treatments. In addition, the alloys of the present invention attain high rolled temper strength levels. Still further the high electrical conductivity of the alloys of the present invention is coupled with excellent annealed tensile strength properties of approximately 55,000 psi and higher. The strength and physical properties of the alloys of the present invention are not significantly variable if small amounts of impurities are present. In addition to the foregoing, the alloys of the present invention are inexpensive and their excellent physical properties are easily obtainable.
DETAILED DESCRIPTION The composition of the alloys of the present invention is as stated heretofore. The preferred iron content is from 1.8 to
2.9 percent and the preferred manganese content is from 0.03 to 0.10 percent. The preferred zinc content is from 0.05 to 0.15 percent and the preferred phosphorus content is from 0.01 to 0.08 percent.
the alloying ingredients are important.
In addition to the foregoing, small amounts of additional alloying ingredients may be, of course, included in order to achieve-particularly desirable results. For example, silicon up to 0.l8 percent and aluminum up to 0.07 percent. Also, small amounts of impurities may, of course, be tolerated.
The alloys of the present invention attain improvement over conventional alloys in a wide range of processing. Naturally, however, particular processing will result in variation in properties.
The manner of casting the material is not particularly critical, with conventional casting methods for these types of alloys being readily utilizable, it being noted that higher temperatures should be used in order to solutionize the iron. It is preferred to cast the alloy into billets of conventional size, subjecting them to hot working, as by rolling in the conventionalsize.
After casting the alloy should be hot rolled at an elevated temperamre, i.e., from 800 to 1,050 C., with a temperature of about 950 C. being preferred. The alloy should then be cold rolled to gage, with intermediate anneals, with cold reduction in excess of 50 percent between anneals being preferred. Annealing temperatures of from 400 to 600 C. are preferred, with annealing time at temperature preferably being a minimum of 2 hours. Longer times may be utilized, if desired, to improve electrical conductivity. Continuous strand annealing of strip or mill products will achieve the same high level of physical properties as with Bell annealing, but will not achieve as high a level of electrical conductivity. Therefore, for development of both high annealed strength and electrical conductivity, final annealing and preferably in process annealing must be in batches with conventional furnace cooling, such as. Bell annealing.
Detailed processing and preferred processing parameters consonant with the foregoing are found in copending application, Ser. No. 648,742 for "Process For Treating Copper Base Alloy", filed June 26, 1967, by C. D. McLain, now U.S. Pat. No. 3,522,112.
The present invention will be more readily understandable from aconsideration of the following illustrative examples.
EXAMPLE 1 Alloys were prepared in the following manner. High purity copper and high purity iron were melted together in a low frequency, slot type induction furnace under a charcoal cover at approximately 1,200 C. About 10 percent of the copper charge was held back and the melt was slightly overheated to about l,300 C. in order to put the iron into solution. High purity alloying additions were added when the molten mass was at about 1,300 C. The balance of the copper was added and the melt brought to the pouring temperature of about 1,200 C. The melt was then poured into a water-cooled ingot mold of 28 56 X 5 X 96 inches at a pouring rate of 21.3 inches per minute.
The alloys thus prepared had the following composition.
3 EXAMPLE I] Alloys 1 and 2 prepared in Example I were processed as follows. The alloys were hot rolled at from 900 to 940 C., followed by a water spray quench to room temperature. The materials were then cold rolled to 0.100 inch, bell annealed at 480-600 C. (l to 4 hours at temperature), cold rolled to 0.050 inch, bell annealed at 460 to 480 C. (l to 3 hours at temperature), and cold rolled to 0.025 inch gage and bell annealed at 44 to 480 C. (l to 3 hours at temperature).
The alloys were then tested for physical properties with the results being shown in the following table.
TABLE II Yield Tensile Electrical strength, strength, Elongation conductivity Alloy p.s l p.s.l. perceni percent IACQ ing and range of equivalency are intended to be embraced therein.
What is claimed is:
l. A high conductivity, high strength copper base alloy consisting essentially of from 1.5 to 3.5 percent iron, from 0.01 to 0.l2 percent manganese, a material selected from the group consisting of phosphorus from 0.0l to 0. l0 percent, zinc from 0.05 to 0.20 percent and mixtures thereof and the balance copper.
2. A copper base alloy according to claim 1 containing both phosphorus and zinc.
3. A copper base alloy according to claim 1 in the flat rolled condition.
4. A copper base alloy according to claim I having an electrical conductivity of at least percent [ACS and an annealed tensile strength of at least 55,000 psi.
5. A copper base alloy according to claim 1 having an electrical conductivity of at least 60 percent lACS.
6. A copper base alloy according to claim I wherein the zinc content is from 0.05 to 0.15 percent.
7. A copper base alloy according to claim 1 wherein the iron content is from I .8 to 2.9 percent.
8. A copper base alloy according to claim 1 wherein the manganese content is from 0.03 to 0. l0 percent.
9. A copper base alloy according to claim I in the cold rolled condition.
10. A copper base alloy according to claim 1 in the cold rolled and annealed condition.
I i t i ll
Claims (9)
- 2. A copper base alloy according to claim 1 containing both phosphorus and zinc.
- 3. A copper base alloy according to claim 1 in the flat rolled condition.
- 4. A copper base alloy according to claim 1 having an electrical conductivity of at least 70 percent IACS and an annealed tensile strength of at least 55,000 psi.
- 5. A copper base alloy according to claim 1 having an electrical conductivity of at least 60 percent IACS.
- 6. A copper base alloy according to claim 1 wherein the zinc content is from 0.05 to 0.15 percent.
- 7. A copper base alloy according to claim 1 wherein the iron content is from 1.8 to 2.9 percent.
- 8. A copper base alloy according to claim 1 wherein the manganese content is from 0.03 to 0.10 percent.
- 9. A copper base alloy according to claim 1 in the cold rolled condition.
- 10. A copper base alloy according to claim 1 in the cold rolled and annealed condition.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5089370A | 1970-06-29 | 1970-06-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3661568A true US3661568A (en) | 1972-05-09 |
Family
ID=21968124
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US50893A Expired - Lifetime US3661568A (en) | 1970-06-29 | 1970-06-29 | Copper base alloy |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3661568A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5489417A (en) * | 1992-09-02 | 1996-02-06 | Olin Corporation | Spray cast copper-manganese-zirconium alloys having reduced porosity |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2155406A (en) * | 1938-04-28 | 1939-04-25 | Chase Brass & Copper Co | Electrical conductor |
| US3522039A (en) * | 1967-06-26 | 1970-07-28 | Olin Mathieson | Copper base alloy |
-
1970
- 1970-06-29 US US50893A patent/US3661568A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2155406A (en) * | 1938-04-28 | 1939-04-25 | Chase Brass & Copper Co | Electrical conductor |
| US3522039A (en) * | 1967-06-26 | 1970-07-28 | Olin Mathieson | Copper base alloy |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5489417A (en) * | 1992-09-02 | 1996-02-06 | Olin Corporation | Spray cast copper-manganese-zirconium alloys having reduced porosity |
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