US3619352A - Flame retardant hardboard and its manufacture - Google Patents

Flame retardant hardboard and its manufacture Download PDF

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Publication number
US3619352A
US3619352A US745706A US3619352DA US3619352A US 3619352 A US3619352 A US 3619352A US 745706 A US745706 A US 745706A US 3619352D A US3619352D A US 3619352DA US 3619352 A US3619352 A US 3619352A
Authority
US
United States
Prior art keywords
flame retardant
wood
layer
asbestos
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US745706A
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English (en)
Inventor
Donald Alfred Bell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BOWATERS PAPER Co Ltd UK
Original Assignee
BOWATERS PAPER CO Ltd UK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BOWATERS PAPER CO Ltd UK filed Critical BOWATERS PAPER CO Ltd UK
Application granted granted Critical
Publication of US3619352A publication Critical patent/US3619352A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/92Fire or heat protection feature
    • Y10S428/921Fire or flameproofing

Definitions

  • This invention relates to flame retardant hardboard and to its manufacture.
  • Hardboard having flame retardant properties for example Class I as defined in British Standard 8.8.476 is known and is produced by subjecting the finished board to a further process such as impregnation with chemicals.
  • This has the disadvantage that it is as a rule outside the control of the board manufacturer and it produces a board which, after being treated to impart the flame retardant properties, is markedly inferior to the same board before treatment. Boards processed in this way lose much of their strength, the water absorption rate is greatly increased and often the surfaces of the boards are blemished with crystal deposits from the chemicals used in the flame retardant processing.
  • a known process for producing hardboard comprises the steps of conveying wood logs to a chipper which reduces the logs to chips, conveying the chips to a defibrator wherein the wood chips are treated by steam at pressures up to 170 lbs. per square inch before being fed to means for breaking the chips into basic wood fibers, feeding the resultant mixture of wood fibers and water (hereinafter referred to as wood pulp) to a thickener which removes a percentage of the water, processing the wood pulp in a refiner which breaks down the larger fibers and thereby produces a consistently fine wood pulp, feeding the refined wood pulp into a box or chamber where chemicals (normally containing aluminum sulfate) are added to the refined wood pulp, feeding the chemically treated wood pulp through a cyclone where foreign particles such as, for example, sand and grit are removed, conveying the cleansed wood pulp to the headbox or hopper of a mat forming machine from whence the wood pulp is spread evenly upon a continuous wire mesh belt moving below the headbox and through
  • the present invention seeks to overcome the aforesaid disadvantage and according to the present invention a process of manufacturing flame retardant hardboard includes forming, in continuous manner, a travelling layer of wet wood fiber, con tinuously forming on a surface ofsaid wood fiber layer as it advances, a layer comprising wet asbestos or mica fibers and wood pulp, and subsequently removing water from the two layers whereby the two layers combine and unite together.
  • starch is present with the asbestos or mica fibers to assist in the bonding thereof to the wood fiber.
  • asbestos or mica fibers it is envisaged that other similar chemically inert noncellulosic heat-insulating materials could be used.
  • flame retardant hardboard comprising a composite board having two layers bonded together in the process of production of the composite board, one layer thereof being produced from wood fiber and the other layer thereof being produced from a mixture ofwood fiber, asbestos fiber and starch.
  • the surface of the wood-asbestos or mica layer is treated with flame retardant chemicals some of which enetrate to the wood fiber layer.
  • a secondary headbox is provided, in the mat forming machine mentioned hereinbefore, above the continuous wire and before the vacuum.
  • a mixture of wood fiber, asbestos fiber or mica fiber, starch and water is supplied to this secondary headbox from which it is disposed, in the form ofa layer, upon the wet mat of wood pulp formed in the mat forming machine and, following passage through the pressure rollers, the upper surface of the lap is sprayed with a chemical some of which passes through the asbestos or mica-wood layer to the wood fiber layer.
  • the presence of starch ensures that the wood fiber and asbestos or mica fibers bond together.
  • the chemical contains a mixture of Polybor (a trade name for a mixture of boric acid and borax), Urea FX (a trade name for a powder mixture having a high nitrogen content and containing urea) and Formalin (a trade name for formaldehyde) dissolved in water, the chemical being sprayed onto the exterior surface of the asbestos-wood layer from whence it penetrates to the wood fiber layer.
  • Polybor a trade name for a mixture of boric acid and borax
  • Urea FX a trade name for a powder mixture having a high nitrogen content and containing urea
  • Formalin a trade name for formaldehyde
  • the chemically treated composite board is then sprayed with a Tall Oil emulsion which obviates any tendency for the board to stick to the surface plate following compression in the hydraulic press.
  • the asbestos fiber and wood fiber mixture is prepared by adding 250 gallons of water to 50 lbs. of asbestos fiber to form an asbestos slurry, mixing 30 lbs. of wood pulp in 150 gallons of water, mixing the asbestos slurry and the diluted wood pulp thoroughly and adding 4 lbs. of starch, the starch additive being equivalent to 8 percent of the dry weight of asbestos fiber.
  • the mixing of the asbestos fiber, wood fiber and starch is effected in a tank or chest and is applied to the surface of the wet mat of wood pulp through the intermediary of the second headbox referred to above, so that 7 lbs. of asbestos (dry basis) is spread evenly over square feet of wet lap.
  • the quantity described above would, therefore, be sufficient to cover approximately 560 square feet.
  • Preferred portions in the chemical mixture are 23 lbs. polybor, 31 lbs. Urea FX and 3,400 ccs. of Formalin l5 percent Methanol) with water added to constitute a mixture of 1 L25 gallons.
  • the chemical may advantageously be applied at the rate of2 gallons per 18 4" of wet lap.
  • a primary advantage of the composite board produced according to the present invention is that, when subjected to flame, the wood fiber in the finished asbestos-wood surface will carbonize and, together with the asbestos will provide insulation against the heat.
  • a process of manufacturing flame retardant hardboard consisting of the steps of forming in a continuous manner a first travelling layer of wet wood fiber, continuously forming on a surface of the wood fiber layer as it advances a second layer comprising an admixture of wet noncellulosic heat-insulating fibers and wood fibers, applying to an upper exposed surface of the second layer a flame retardant chemical in an amount sufficient to pass through the second layer and reach the first layer, and subsequently pressing and drying the two layers whereby the two layers combine and unite together to provide a high density hardboard.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Paper (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Labeling Devices (AREA)
US745706A 1967-07-26 1968-07-18 Flame retardant hardboard and its manufacture Expired - Lifetime US3619352A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB34299/67A GB1185330A (en) 1967-07-26 1967-07-26 Flame Retardant Hardboard and its Manufacture.

Publications (1)

Publication Number Publication Date
US3619352A true US3619352A (en) 1971-11-09

Family

ID=10363891

Family Applications (1)

Application Number Title Priority Date Filing Date
US745706A Expired - Lifetime US3619352A (en) 1967-07-26 1968-07-18 Flame retardant hardboard and its manufacture

Country Status (5)

Country Link
US (1) US3619352A (en:Method)
GB (1) GB1185330A (en:Method)
IE (1) IE32206B1 (en:Method)
IL (1) IL30436A (en:Method)
NO (1) NO126959B (en:Method)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130101786A1 (en) * 2010-04-28 2013-04-25 MB Ädelträ AB Method for treatment of a board and a board element
US9669564B2 (en) 2014-06-04 2017-06-06 Koppers Performance Chemicals Inc. Methods of conferring fire retardancy to wood and fire-retardant wood products
US10500756B2 (en) 2014-06-04 2019-12-10 Koppers Performance Chemicals Inc. Methods of conferring fire retardancy to wood and fire-retardant wood products

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1687599A (en) * 1922-10-04 1928-10-16 Harrison Upson W Fiber board and method of making same
US1730849A (en) * 1929-10-08 of chicago
US2030653A (en) * 1931-12-18 1936-02-11 Int Paper Co Fireproofing
GB1006567A (en) * 1961-04-26 1965-10-06 Feldmuehle Ag Process and apparatus for the manufacture of multi-layer webs of fibrous material
US3248257A (en) * 1960-10-24 1966-04-26 Woods Conversion Company Flame-resistant mineral fiber tile

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1730849A (en) * 1929-10-08 of chicago
US1687599A (en) * 1922-10-04 1928-10-16 Harrison Upson W Fiber board and method of making same
US2030653A (en) * 1931-12-18 1936-02-11 Int Paper Co Fireproofing
US3248257A (en) * 1960-10-24 1966-04-26 Woods Conversion Company Flame-resistant mineral fiber tile
GB1006567A (en) * 1961-04-26 1965-10-06 Feldmuehle Ag Process and apparatus for the manufacture of multi-layer webs of fibrous material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Casey, Pulp and Paper 2nd edition, Vol. III, page 1742. *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130101786A1 (en) * 2010-04-28 2013-04-25 MB Ädelträ AB Method for treatment of a board and a board element
US9669564B2 (en) 2014-06-04 2017-06-06 Koppers Performance Chemicals Inc. Methods of conferring fire retardancy to wood and fire-retardant wood products
US10500756B2 (en) 2014-06-04 2019-12-10 Koppers Performance Chemicals Inc. Methods of conferring fire retardancy to wood and fire-retardant wood products

Also Published As

Publication number Publication date
IE32206L (en) 1969-01-26
GB1185330A (en) 1970-03-25
IE32206B1 (en) 1973-05-16
NO126959B (en:Method) 1973-04-16
IL30436A0 (en) 1968-09-26
IL30436A (en) 1972-08-30

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