US3619343A - Roofing material - Google Patents

Roofing material Download PDF

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Publication number
US3619343A
US3619343A US3619343DA US3619343A US 3619343 A US3619343 A US 3619343A US 3619343D A US3619343D A US 3619343DA US 3619343 A US3619343 A US 3619343A
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layer
neoprene
roof
present
weight
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Clarence S Freeman
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/30Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being formed of particles, e.g. chips, granules, powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D3/00Roof covering by making use of flat or curved slabs or stiff sheets
    • E04D3/35Roofing slabs or stiff sheets comprising two or more layers, e.g. for insulation
    • E04D3/351Roofing slabs or stiff sheets comprising two or more layers, e.g. for insulation at least one of the layers being composed of insulating material, e.g. fibre or foam material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/025Polyolefin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/08Closed cell foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/41Opaque
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/712Weather resistant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/08Dimensions, e.g. volume
    • B32B2309/10Dimensions, e.g. volume linear, e.g. length, distance, width
    • B32B2309/105Thickness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • B32B2419/06Roofs, roof membranes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/92Fire or heat protection feature
    • Y10S428/921Fire or flameproofing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24364Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.] with transparent or protective coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495Thickness [relative or absolute]
    • Y10T428/24967Absolute thicknesses specified
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249982With component specified as adhesive or bonding agent
    • Y10T428/249985Composition of adhesive or bonding component specified
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987With nonvoid component of specified composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249994Composite having a component wherein a constituent is liquid or is contained within preformed walls [e.g., impregnant-filled, previously void containing component, etc.]
    • Y10T428/249995Constituent is in liquid form
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31815Of bituminous or tarry residue

Definitions

  • Van Balen Attorney-Donald Gunn ABSTRACT An expanded plastic roof product having a first layer of open cell expanded material, the material being preferably a polyoiefin on density from about 1 to about 25 pounds per cubic foot and there being additional layers thereon for weather protection, coloration, styling and appearance preferably like that of current roofing materials.
  • roofing products currently available for residences, commercial buildings, apartments, factories and the like may be generally classed in the following groups.
  • a number of buildings are covered with metal surfaces, tiles, stone, slate, and the like. Such materials are so very expensive as to be excluded from the greater bulk of the market of roofing material.
  • built-up roofs typically formed of asphalt and gravel require custom installation, and hence, are likewise quite expensive.
  • the greater bulk of roofing material used today includes either wood shingles or asphalt shingles.
  • Wood shingles typically are formed of cedar or other untreated naturally occurring wood products, and, as a generalization, serve as a prestige home roofing material.
  • asphalt shingles The greater portion of the home roofing market is served by various grades and qualities of asphalt shingles.
  • asphalt shingles By asphalt shingles, reference is had to the shingle which is formed of a typically fibrous base of felt or similar matter which is impregnated with low grade asphalts and which is imbedded with colored granules to give a surface texture and color.
  • asphalt shingles have been found wanting in numerous regards in that they are brittle and have very low mechanical strength. They must be applied in a piecemeal fashion utilizing expensive hand labor. They are as flammable as cedar shingles, and provide negligable insulation to the building.
  • Particularly damaging, asphalt shingles have been found wanting in life in that, dependent on the sun load and weather in a particular climate, aging effects color, tendency to break or fracture and form openings in the roof which initiate leaks into the building proper.
  • the installed asphalt roof is particularly susceptable to weather damage.
  • Hail stones of any size tend to at least dent the asphalt shingle, and the dents become fractures or breaks which seriously accelerate leakage of the roof.
  • surface winds of moderate velocities have little difficulty in getting beneath a single shingle and peeling it back from the rest of the roof. Once this happens during a storm or other inclement weather, an entire portion of the roof may be peeled back and blown away.
  • the apparatus of the present invention overcomes these and other deficiencies, and further provides a roof which has an essentially indefinite life. That is to say, the life of the roof of the present invention is approximately equal to that of the structure itself, and more specifically, appears to be in excess of 30 years, ranging upwards to 45 or 50 years.
  • the present invention is summarized as providing a roof formed of a base material in the range of preferably V410 about 54inch thickness, formed of an expanded plastic sheeting which provides insulative thermal properties and which is flame resistant. More specifically, one embodiment of the present invention envisions the use of a foamed polyolefin base in the range of about 1 to 25 pounds per cubic foot, after foaming, with the preferred weight being approximately 4 pounds per cubic foot.
  • the base is utilized, as will be described in several species of the present invention, to
  • one embodiment of the present invention envisions the use of a secondary sealant placed on the exposed or outer surface of the expanded plastic sheeting to serve as a sealant, adhesive, surface appearance means, and for other purposes as will be denoted.
  • a third layer can be added to totally simulate roofing products to which the public has grown accustomed, namely the use of small colored granules of numerous sizes and weights with which to simulate asphalt shingles, all embodiments of the present invention being adapted to be shaped in various sizes and widths and to take on surface imprints, surface variations, to either simulate products currently known in the market place and well recognized by the purchasing public, or to implement new or unknown surface appearances.
  • the present invention envisions the use of an expanded plastic sheeting to be placed on the roof of the structure.
  • the expanded plastic sheeting preferably covers the entirety of the roof, and at the juncture, it is sufficient to note that it may take on any surface appearance, may be installed in any acceptable manner, may have variations in cross section such as needed to simulate other products, and may be adapted or varied from the preferred embodiments set forth herein in numerous ways.- For ease of discussion, the preferred embodiment will be described as an essentially rectangular sheet of generally uniform cross section although the variations and alterations generally referred to above may be introduced without departing from the scope of the present invention.
  • the expanded plastic of the present invention preferably utilizes a polyolefin foam.
  • the foam preferably has a weight of approximately 1 to 25 pounds per cubic foot of the completed product.
  • the 1 pound limitation noted above is governed primarily by the need to provide some mechanical strength, and foams lighter than one pound per cubic foot are also essentially commercially unavailable.
  • the limitation of approximately 25 pounds per cubic foot is governed by economics, and, as the density increases, the thermal conductivity of the completed product likewise increases.
  • the foam is preferably maintained materially lighter than the 25 pound limitation noted above. Also, the economics of the base material are materially improved through the use of a lighter foam.
  • Suitable polyolefins found acceptable for the present invention include polyethylene, polypropylene, and numerous copolymers which include ethylene as a principal or major component. Numerous manufacturers commercially market these polyolefins either in bulk or in the completed foam sheeting in several thicknesses. Further, the commercially available materials for the present invention may be obtained with or without the additives described hereinafter added so that the point in time and procedure of mixing the various additives is immaterial to the present invention.
  • the polymer is foamed to the approximate range of finished densities noted above.
  • the foaming agent selected for the present invention is not considered critical for the present invention and may be any of commercially available foaming agents.
  • the freon series may be readily used to form the closed cell bubbles in the finished product to achieve the range of densities noted above for the preferred version.
  • the foaming agent may include those materials which at least partially or totally evolve gas under controlled conditions such as elevated temperature. Numerous inorganic compounds break down and evolve gas under elevated temperatures, and one example is sodium bicarbonate.
  • foaming agents include commercially available products sold under the names Uni-cell,”Celogen, and Freon l2 orFreon 114.”
  • the expanded plastic sheeting of the present invention preferably includes an ultraviolet absorber to enhance and improve its weatherability.
  • the ultraviolet radiation from the sun tends to embrittle unprotected polyolefin products.
  • the present invention preferably incorporates an ultraviolet inhibitor or a covering which, in and of itself, reflects, absorbs, or otherwise prevents the ultraviolet radiation from reaching the foamed or expanded plastic sheeting of the present invention.
  • an ultraviolet inhibitor is finely divided carbon black. While other inhibitors are known, carbon black is materially less expensive and has been found perfectly satisfactory for this purpose.
  • the range of carbon black to-be added to the present invention as an ultraviolet inhibitor is from a low of perhaps 1 /2 percent for a very finely divided carbon black such as channel black, to a high of perhaps 5 to percent by weight for a coarse but cheaper thermal carbon black. As will be seen, the fineness of the carbon black particles reduces the percentage by weight required to achieve the desired inhibition of ultraviolet penetration. This materially is related to the weatherability and long life of the present invention.
  • Untreated foamed polyolefins will be recognized as being slow burners" by those skilled in the art. If total fire retardancy is desired, numerous additives may be added to the foamed plastic sheeting of the present invention to render it self-extinguishing.
  • suitable flame retardants include antimony trioxide with a chlorine source. Such flame retardants are readily available commercially from numerous manufacturers. The flame retardant ranges from 0 percent upward to perhaps percent or more by weight of the finished product dependent on degree of flame retardancy desired. As will be recognized, if no flame retardant is added, the foam base is slow burning" as noted above. The degree of retardancy desired at least partially controls the amount of retardant added, although in a construction which includes a nonflarnmable but intimate second layer, there is little incentive to load the base with fire retardants.
  • the preferred flame retardant noted above tends only to slightly affect the color or appearance of the finished product. A small percentage of carbon black renders the completed product, whether fire retarded or not, totally black. Coloring pigments may be added to the product although one species of the generic invention to be described hereinafter will obviate the need of adding a pigment to the foamed base of the present invention.
  • a foamed material having a closed cell structure which is ultraviolet inhibited and which may be made flame retardant, as taught previously, is provided.
  • the thickness and other dimensions ofthe product may vary widely, although suitable insulation and mechanical qualities as a roofing material are achieved with thicknesses in the range of about A to about inches thickness.
  • the preferred embodiment of the present invention is preferably extruded to a desired shape, width and thickness. Locking devices, step shingles, and other cross sectional devices may be incorporated in the completed product in the extrusion process.
  • the extruding and foaming process occurs simultaneously, and as the product is derived from the extrusion equipment, it may be processed by other machinery, such as print rolls, embossing rolls, and other apparatus which will further alter the size, shape, contour, surface finish, and other factors of the completed product.
  • the extrusion process maintains the individual discrete cells in the flowable product a small size and prevents their congregating the larger bubbles which materially efiect the mechanical characteristics of the completed product.
  • a small cell size is desirable for the mechanical characteristics of the completed product, proper thermal characteristics, and appearance factors.
  • large bubbles in the completed product are not desirable and are readily eliminated by proper manufacturing techniques.
  • a sealant may be applied such as various rubber based materials including, by way of example and not limitation, a coating of neoprene. It serves as a secondary sealant inasmuch as the base material, described above, is also a weather proofing layer which is one of the primary functions of a roofing material.
  • the preferred embodiment of the present invention best utilizes a neoprene layer which serves as the secondary sealant, as an adhesive for purposes to be described, and as a further covering which enhances all the characteristics of the present invention.
  • the neoprene layer s of nominal thickness, in the range of perhaps 2 to 10 mils. It is not necessary to make it any thicker for the purposes described above, and, in view of the cost, the thickness is preferably limited.
  • the neoprene coating is applied to the base material either dissolved in a suitable solvent or by applying a sheet with a suitable adhesive to the material. In either case, the neoprene is allowed to dry on the base material and form the uniform, leakproof layer.
  • a neoprene layer serving as a secondary sealant is particularly advantageous when the exterior appearance of the roofing material is modified to simulate a particular roofing material presently in common use.
  • Solvents for maintaining the neoprene in a tacky state on the upper surface are readily known, and, in conjunction with such solvents, colored rock granules may be applied to the roofing material and pressed into the neoprene.
  • a three layer roof is formed comprising the base material defined above with all the features noted thereat, a secondary sealant which is also used as an adhesive, and a granular layer of material which simulates roofing products as presently on the market.
  • the granules are typically rock or other ceramic material, and are of suitable fineness to comprise several thousand particles to the pound.
  • the rocks, chips, or granules currently in use with asphalt shingling are quite acceptable for this pur' pose.
  • the present invention is also material improvement over asphalt roofing in the fact of the degree of attachment of the rocks or granules to the roofing. ln asphalt shingles. the granules are merely pressed into the soft or tacky asphalt and are easily detached. However, the present invention actually lOlOO) 0640 bonds the granules to the roofing material and the tendency of the granules to flake or otherwise fall from the roof is considerably reduced.
  • the granules and neoprene coating which comprise portions of the preferred embodiment are applied in the following manner.
  • the sheet of base material is coated on its upper surface with a layer of neoprene in the tacky state.
  • the mode of application may be sprayed, brushed, rolled, etc., by any suitable process for this purpose.
  • the rocks, granules, chips, or the like, are then sprinkled generously on the neoprene layer while tacky.
  • a roller under moderate pressure passes over the surface after sprinkling with granules and the granules are pressed into the tacky neoprene.
  • the granules are totally and completely joined to the neoprene and are bonded into the roof.
  • chips which may be brushed, blown, or otherwise mechanically removed from the surface.
  • the outer surfaces has then been so modified to simulate the appearance of products currently on the market, and the size and shape may be obtained through the use of a scoring wheel or other cutting apparatus.
  • the present invention provides a means whereby cedar shingles or other wooden shingles may be simulated through the application of a coloring agent on the outer surface, passing the roofing material beneath a suitable embossing wheel or the like, cutting the roof to shape, and conforming the thickness with that of the roofing material to be simulated. Without going into the details thereof, it is believed that the present apparatus provides a roofing material whereby the foregoing may be accomplished.
  • the roofing material of the present invention is preferably formed in sheets of arbitrary dimensions. Should the roofing material be applied to a house of 50 foot width, clearly the sheets can be 50 feet in length. The width is variable also. It may be formed in strips of relatively narrow widths with a view of simulating products currently used as roofing materials, or the sheeting material may be formed quite wide so that only two or three strips are required on a roof.
  • the roofing material is particularly lightweight and moreover, is inexpensive to transport, is easy to lift from the ground onto a roof at a building site location, and does not require excessive labor to actually lay and install.
  • the roof of the present invention as described hereinbefore is particularly long lived.
  • the base material as noted above has an essentially indefinite life which approximates that of the basic structure itself.
  • the preferred material noted above does not in any way or manner decrease the life of the roofing material.
  • the insulation properties are particularly to be noted.
  • asphalt shingles provide essentially no insulation properties.
  • cedar shingles in view of the fact that the two most common residential roofing materials provide little, if any, insulation, most houses now built incorporate a substantial thermal barrier in the attic or ceiling to at least protect the living quarters of the house. It is legend that the attics of most houses in the summer time will rise to temperatures in the range of perhaps 150 F. or greater dependent upon the shade available, the color of the roof, the outside temperature, and other factors.
  • a. a first layer of about one-fourth to three-fourths inch thickness of a flexible, bendable foamed aliphatic polymono-olefin having a closed cell structure with a density in the range of about 1 pound to about 25 pounds per cubic foot;
  • said first layer includes an ultraviolet inhibitor dispersed therein.
  • said adhesive material is a thin layer of neoprene which is applied coextensive with the surface of said first layer and extends fully thereover and serves as a secondary sealant.
  • said first layer is formed of foamed polyethylene and has therein a flame retardant additive ranging up to about 20 percent by weight;
  • said adhesive layer is neoprene in a thickness of up to about 0.050 inches thick;
  • said opaque chips are sufficient in quantity to prevent the suns ultraviolet rays from reaching said first layer.
  • the invention of claim 1 including from approximately 0 to approximately 20 percent by weight of flame retardant material.
  • said flame retardant material at least includes a portion of antimony trioxide.
  • Neoprene is approximately 0.00l" to 0.050 thick.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Building Environments (AREA)

Abstract

An expanded plastic roof product having a first layer of open cell expanded material, the material being preferably a polyolefin on density from about 1 to about 25 pounds per cubic foot and there being additional layers thereon for weather protection, coloration, styling and appearance preferably like that of current roofing materials.

Description

United States Patent Clarence S. Freeman P.O. Box 1204, Beaumont, Tex. 77704 Appl. No. 818,778
Filed Apr. 23, 1969 Inventor Patented Nov. 9, 1971 ROOFING MATERIAL 15 Claims, No Drawings US. Cl 161/160, 52/309,161/162,161/165,161/l68,161/403, 260/2.5 Int. Cl B32b 5/02, B32b 5/16 Field 01 Search 260/2.5 FP;
3,502,540 3/1970 Pietrocola FOREIGN PATENTS 260,229 1/1963 Australia Primary Examiner-William .1. Van Balen Attorney-Donald Gunn ABSTRACT: An expanded plastic roof product having a first layer of open cell expanded material, the material being preferably a polyoiefin on density from about 1 to about 25 pounds per cubic foot and there being additional layers thereon for weather protection, coloration, styling and appearance preferably like that of current roofing materials.
SUMMARY OF PROBLEM AND SOLUTION Roofing products currently available for residences, commercial buildings, apartments, factories and the like, may be generally classed in the following groups. A number of buildings are covered with metal surfaces, tiles, stone, slate, and the like. Such materials are so very expensive as to be excluded from the greater bulk of the market of roofing material. Additionally, built-up roofs typically formed of asphalt and gravel require custom installation, and hence, are likewise quite expensive. The greater bulk of roofing material used today includes either wood shingles or asphalt shingles. Wood shingles typically are formed of cedar or other untreated naturally occurring wood products, and, as a generalization, serve as a prestige home roofing material. However, problems exist with regard to availability, price, flammability, limitations in color and shape, and difficulties of piece-meal installation.
The greater portion of the home roofing market is served by various grades and qualities of asphalt shingles. By asphalt shingles, reference is had to the shingle which is formed of a typically fibrous base of felt or similar matter which is impregnated with low grade asphalts and which is imbedded with colored granules to give a surface texture and color. Briefly, asphalt shingles have been found wanting in numerous regards in that they are brittle and have very low mechanical strength. They must be applied in a piecemeal fashion utilizing expensive hand labor. They are as flammable as cedar shingles, and provide negligable insulation to the building. Particularly damaging, asphalt shingles have been found wanting in life in that, dependent on the sun load and weather in a particular climate, aging effects color, tendency to break or fracture and form openings in the roof which initiate leaks into the building proper.
Moreover, the installed asphalt roof is particularly susceptable to weather damage. Hail stones of any size tend to at least dent the asphalt shingle, and the dents become fractures or breaks which seriously accelerate leakage of the roof. Even though individual shingles are quite heavy, and even though they are nailed to the roof in an overlapping fashion, nevertheless, surface winds of moderate velocities have little difficulty in getting beneath a single shingle and peeling it back from the rest of the roof. Once this happens during a storm or other inclement weather, an entire portion of the roof may be peeled back and blown away. Once a shingle is bent to any extent, the portion which is bent upwardly breaks free of that portion which is nailed to the roof, and also tends to bend upwardly and away from the roof the nearby shingle. Hence, a wind storm may begin peeling shingles from a portion of the roof and the entire area of the roof to the crown or peak of the roof will be denuded. Because of these factors, asphalt shingle roofs have a limited life, perhaps in the range of years, in most climates.
With the foregoing in view, it will be observed that the roofing products which predominate in the home market, and in a great number of the smaller commercial buildings, have been measurably found wanting in numerous regards. Further, in the event of a fire at a nearby location, burning embers and even larger and heavier fire brands are lifted by the updraft at the point of the fire and are typically wind borne to fall out on nearby or surrounding buildings. It is not uncommon for a spark to fall on the roof of a house located several hundred feet or a fraction ofa mile away and initiate a fire on that roof. Typically the ember or fire brand will fall on the roof and start a fire at the spot of contact, which will spread on the roof and penetrate into the upper portions of the structure.
The apparatus of the present invention overcomes these and other deficiencies, and further provides a roof which has an essentially indefinite life. That is to say, the life of the roof of the present invention is approximately equal to that of the structure itself, and more specifically, appears to be in excess of 30 years, ranging upwards to 45 or 50 years.
The present invention is summarized as providing a roof formed of a base material in the range of preferably V410 about 54inch thickness, formed of an expanded plastic sheeting which provides insulative thermal properties and which is flame resistant. More specifically, one embodiment of the present invention envisions the use of a foamed polyolefin base in the range of about 1 to 25 pounds per cubic foot, after foaming, with the preferred weight being approximately 4 pounds per cubic foot. The base is utilized, as will be described in several species of the present invention, to
receive a pigmentation for stability, weatherability, and v coloration. Moreover, one embodiment of the present invention envisions the use ofa secondary sealant placed on the exposed or outer surface of the expanded plastic sheeting to serve as a sealant, adhesive, surface appearance means, and for other purposes as will be denoted. In further particular, a third layer can be added to totally simulate roofing products to which the public has grown accustomed, namely the use of small colored granules of numerous sizes and weights with which to simulate asphalt shingles, all embodiments of the present invention being adapted to be shaped in various sizes and widths and to take on surface imprints, surface variations, to either simulate products currently known in the market place and well recognized by the purchasing public, or to implement new or unknown surface appearances.
Briefly, many objects and advantages of the present invention will become more readily apparent from a consideration of the following specification which describes the present invention, and its preferred embodiment, numerous species thereof, all without drawings.
Considering the present invention first generally, the present invention envisions the use of an expanded plastic sheeting to be placed on the roof of the structure. The expanded plastic sheeting preferably covers the entirety of the roof, and at the juncture, it is sufficient to note that it may take on any surface appearance, may be installed in any acceptable manner, may have variations in cross section such as needed to simulate other products, and may be adapted or varied from the preferred embodiments set forth herein in numerous ways.- For ease of discussion, the preferred embodiment will be described as an essentially rectangular sheet of generally uniform cross section although the variations and alterations generally referred to above may be introduced without departing from the scope of the present invention.
The expanded plastic of the present invention preferably utilizes a polyolefin foam. The foam preferably has a weight of approximately 1 to 25 pounds per cubic foot of the completed product. The 1 pound limitation noted above is governed primarily by the need to provide some mechanical strength, and foams lighter than one pound per cubic foot are also essentially commercially unavailable. The limitation of approximately 25 pounds per cubic foot is governed by economics, and, as the density increases, the thermal conductivity of the completed product likewise increases. To obtain the good insulation characteristics of the present invention, the foam is preferably maintained materially lighter than the 25 pound limitation noted above. Also, the economics of the base material are materially improved through the use of a lighter foam.
Suitable polyolefins found acceptable for the present invention include polyethylene, polypropylene, and numerous copolymers which include ethylene as a principal or major component. Numerous manufacturers commercially market these polyolefins either in bulk or in the completed foam sheeting in several thicknesses. Further, the commercially available materials for the present invention may be obtained with or without the additives described hereinafter added so that the point in time and procedure of mixing the various additives is immaterial to the present invention.
Utilizing the principal polymer or copolymer, as the case may be, denoted above, the polymer is foamed to the approximate range of finished densities noted above. The foaming agent selected for the present invention is not considered critical for the present invention and may be any of commercially available foaming agents. For instance, the freon series may be readily used to form the closed cell bubbles in the finished product to achieve the range of densities noted above for the preferred version. The foaming agent may include those materials which at least partially or totally evolve gas under controlled conditions such as elevated temperature. Numerous inorganic compounds break down and evolve gas under elevated temperatures, and one example is sodium bicarbonate. Also, organic chemicals such as the above mentioned freon series simply vaporize to form substantial volumes of gas in comparison with the volume of material in the liquid or solid state. it is immaterial whether or not the foaming agent leaves a residue as in the case of sodium bicarbonate, or whether the entirety of the foaming agent evolves into a gaseous material. Typically available foaming agents include commercially available products sold under the names Uni-cell,"Celogen, and Freon l2 orFreon 114."
The expanded plastic sheeting of the present invention preferably includes an ultraviolet absorber to enhance and improve its weatherability. The ultraviolet radiation from the sun tends to embrittle unprotected polyolefin products. The present invention preferably incorporates an ultraviolet inhibitor or a covering which, in and of itself, reflects, absorbs, or otherwise prevents the ultraviolet radiation from reaching the foamed or expanded plastic sheeting of the present invention. When the polyolefin per se is exposed to sunlight, a small quantity or measure of the inhibitor is preferably dispersed throughout the completed product to protect it from the cracking and crazing noted above. One suitable ultraviolet inhibitor is finely divided carbon black. While other inhibitors are known, carbon black is materially less expensive and has been found perfectly satisfactory for this purpose. The range of carbon black to-be added to the present invention as an ultraviolet inhibitor is from a low of perhaps 1 /2 percent for a very finely divided carbon black such as channel black, to a high of perhaps 5 to percent by weight for a coarse but cheaper thermal carbon black. As will be seen, the fineness of the carbon black particles reduces the percentage by weight required to achieve the desired inhibition of ultraviolet penetration. This materially is related to the weatherability and long life of the present invention.
Untreated foamed polyolefins will be recognized as being slow burners" by those skilled in the art. If total fire retardancy is desired, numerous additives may be added to the foamed plastic sheeting of the present invention to render it self-extinguishing. By way of example and not limitation, suitable flame retardants include antimony trioxide with a chlorine source. Such flame retardants are readily available commercially from numerous manufacturers. The flame retardant ranges from 0 percent upward to perhaps percent or more by weight of the finished product dependent on degree of flame retardancy desired. As will be recognized, if no flame retardant is added, the foam base is slow burning" as noted above. The degree of retardancy desired at least partially controls the amount of retardant added, although in a construction which includes a nonflarnmable but intimate second layer, there is little incentive to load the base with fire retardants.
The preferred flame retardant noted above tends only to slightly affect the color or appearance of the finished product. A small percentage of carbon black renders the completed product, whether fire retarded or not, totally black. Coloring pigments may be added to the product although one species of the generic invention to be described hereinafter will obviate the need of adding a pigment to the foamed base of the present invention.
Summarizing the material and the various aspects only to this juncture, it will be noted that a foamed material having a closed cell structure which is ultraviolet inhibited and which may be made flame retardant, as taught previously, is provided. The thickness and other dimensions ofthe product may vary widely, although suitable insulation and mechanical qualities as a roofing material are achieved with thicknesses in the range of about A to about inches thickness.
To this juncture, little has been said of the manufacture of the present invention. The preferred embodiment of the present invention is preferably extruded to a desired shape, width and thickness. Locking devices, step shingles, and other cross sectional devices may be incorporated in the completed product in the extrusion process. Preferably, the extruding and foaming process occurs simultaneously, and as the product is derived from the extrusion equipment, it may be processed by other machinery, such as print rolls, embossing rolls, and other apparatus which will further alter the size, shape, contour, surface finish, and other factors of the completed product. Of significance is the fact that the extrusion process maintains the individual discrete cells in the flowable product a small size and prevents their congregating the larger bubbles which materially efiect the mechanical characteristics of the completed product. In brief, a small cell size is desirable for the mechanical characteristics of the completed product, proper thermal characteristics, and appearance factors. In brief, large bubbles in the completed product are not desirable and are readily eliminated by proper manufacturing techniques.
To this juncture, a product has been described which is totally and completely functional and operative as a roof which has the many features set forth in the present disclosure. The material described may be used by itselfinasmuch as it fulfills the function of a roof. However, additional flexibility is achieved and certain improvements are obtained as will be noted. For instance, an outer coating may be applied to the base material. Many coatings which impart either visual or sealing characteristics to the base material, that term being applied hereinafter to the expanded plastic sheeting described briefly and in detail hereinabove, may be added. By way of example, the appearance of the base material may be enhanced through the application of a colored coating to achieve a desired or simulated result. A sealant may be applied such as various rubber based materials including, by way of example and not limitation, a coating of neoprene. It serves as a secondary sealant inasmuch as the base material, described above, is also a weather proofing layer which is one of the primary functions of a roofing material. The preferred embodiment of the present invention best utilizes a neoprene layer which serves as the secondary sealant, as an adhesive for purposes to be described, and as a further covering which enhances all the characteristics of the present invention. The neoprene layer s of nominal thickness, in the range of perhaps 2 to 10 mils. It is not necessary to make it any thicker for the purposes described above, and, in view of the cost, the thickness is preferably limited.
The neoprene coating is applied to the base material either dissolved in a suitable solvent or by applying a sheet with a suitable adhesive to the material. In either case, the neoprene is allowed to dry on the base material and form the uniform, leakproof layer.
The use ofa neoprene layer serving as a secondary sealant is particularly advantageous when the exterior appearance of the roofing material is modified to simulate a particular roofing material presently in common use. Solvents for maintaining the neoprene in a tacky state on the upper surface are readily known, and, in conjunction with such solvents, colored rock granules may be applied to the roofing material and pressed into the neoprene. Thus, a three layer roof is formed comprising the base material defined above with all the features noted thereat, a secondary sealant which is also used as an adhesive, and a granular layer of material which simulates roofing products as presently on the market. The granules are typically rock or other ceramic material, and are of suitable fineness to comprise several thousand particles to the pound. As a matter of fact, the rocks, chips, or granules currently in use with asphalt shingling are quite acceptable for this pur' pose. The present invention is also material improvement over asphalt roofing in the fact of the degree of attachment of the rocks or granules to the roofing. ln asphalt shingles. the granules are merely pressed into the soft or tacky asphalt and are easily detached. However, the present invention actually lOlOO) 0640 bonds the granules to the roofing material and the tendency of the granules to flake or otherwise fall from the roof is considerably reduced.
The granules and neoprene coating which comprise portions of the preferred embodiment are applied in the following manner. The sheet of base material is coated on its upper surface with a layer of neoprene in the tacky state. The mode of application may be sprayed, brushed, rolled, etc., by any suitable process for this purpose. The rocks, granules, chips, or the like, are then sprinkled generously on the neoprene layer while tacky. Preferably, a roller under moderate pressure passes over the surface after sprinkling with granules and the granules are pressed into the tacky neoprene. At this juncture the granules are totally and completely joined to the neoprene and are bonded into the roof. Of course, there may be a surplus of chips which may be brushed, blown, or otherwise mechanically removed from the surface. At this juncture, the outer surfaces has then been so modified to simulate the appearance of products currently on the market, and the size and shape may be obtained through the use of a scoring wheel or other cutting apparatus.
The foregoing describes the method of modifying the present invention to simulate conventional asphalt shingles. It is likewise possible to simulate cedar shingles. Of course, a different texture material having different colors and striation marks is required. Again, this is the matter of artistic detail and the particular coloration ingredients selected may likewise be varied. In any event, the present invention provides a means whereby cedar shingles or other wooden shingles may be simulated through the application of a coloring agent on the outer surface, passing the roofing material beneath a suitable embossing wheel or the like, cutting the roof to shape, and conforming the thickness with that of the roofing material to be simulated. Without going into the details thereof, it is believed that the present apparatus provides a roofing material whereby the foregoing may be accomplished.
The roofing material of the present invention is preferably formed in sheets of arbitrary dimensions. Should the roofing material be applied to a house of 50 foot width, clearly the sheets can be 50 feet in length. The width is variable also. It may be formed in strips of relatively narrow widths with a view of simulating products currently used as roofing materials, or the sheeting material may be formed quite wide so that only two or three strips are required on a roof. The roofing material is particularly lightweight and moreover, is inexpensive to transport, is easy to lift from the ground onto a roof at a building site location, and does not require excessive labor to actually lay and install. The roof of the present invention as described hereinbefore is particularly long lived. The base material as noted above has an essentially indefinite life which approximates that of the basic structure itself. When a secondary sealant layer is used, either for this purpose singly or as an adhesive, the preferred material noted above does not in any way or manner decrease the life of the roofing material. The insulation properties are particularly to be noted. Presently, asphalt shingles provide essentially no insulation properties. The same is also true of cedar shingles. in view of the fact that the two most common residential roofing materials provide little, if any, insulation, most houses now built incorporate a substantial thermal barrier in the attic or ceiling to at least protect the living quarters of the house. It is legend that the attics of most houses in the summer time will rise to temperatures in the range of perhaps 150 F. or greater dependent upon the shade available, the color of the roof, the outside temperature, and other factors. The roof of the present preferred embodiment, several variations thereof, and to note the various forms and shapes which the present invention may assume. Numerous variations and expansions on the preferred embodiment maybe adopted by one skilled in the art. However, the definitions included herein in the specification extend to the claims which are appended hereto.
What is claimed is:
l. A roofing material having the appearance of a typical roofing material and being adapted to be exposed to the weather, comprising:
a. a first layer of about one-fourth to three-fourths inch thickness of a flexible, bendable foamed aliphatic polymono-olefin having a closed cell structure with a density in the range of about 1 pound to about 25 pounds per cubic foot;
b. an outer layer of opaque chips spread generally evenly over the exposed surface of said first layer; and,
c. an adhesive material extending over said first layer for joining by embediment and adhesion said opaque chips to said first layer.
2. The invention of claim 1 wherein said first layer includes an ultraviolet inhibitor dispersed therein.
3. The invention of claim 2 wherein said ultraviolet inhibitor is finely divided carbon black.
4. The invention of claim 3 wherein said carbon black ranges from about 1 /2to 5 /zpercent by weight of said fist layer.
5. The invention of claim 1 in which said adhesive material is a thin layer of neoprene which is applied coextensive with the surface of said first layer and extends fully thereover and serves as a secondary sealant.
6. The invention of claim 3 wherein said fist, outer, and adhesive layers have a weight approximating 20 to 50 pounds per roofing square.
7. The invention of claim 1 wherein:
a. said first layer is formed of foamed polyethylene and has therein a flame retardant additive ranging up to about 20 percent by weight;
b. said adhesive layer is neoprene in a thickness of up to about 0.050 inches thick; and,
c. said opaque chips are sufficient in quantity to prevent the suns ultraviolet rays from reaching said first layer.
8. The invention of claim 1 including from approximately 0 to approximately 20 percent by weight of flame retardant material.
9. The invention of claim 8 wherein said flame retardant material at least includes a portion of antimony trioxide.
10. The invention of claim 9 wherein said antimony trioxide is in the presence of chlorine liberating material.
11. The invention of claim 5 wherein said Neoprene is approximately 0.00l" to 0.050 thick.
12. The invention of claim 1 wherein said first layer is formed of polyethylene.
13. The invention of claim 2 wherein said first layer is comprised substantially of polyethylene.
14. The invention of claim 5 wherein said thin layer of neoprene is joined to said first layer which is formed of polyethylene.
15. The invention of claim 5 wherein said thin layer of neoprene has a thickness of up to about 0.05 inches.

Claims (14)

  1. 2. The invention of claim 1 wherein said first layer includes an ultraviolet inhibitor dispersed therein.
  2. 3. The invention of claim 2 wherein said ultraviolet inhibitor is finely divided carbon black.
  3. 4. The invention of claim 3 wherein said carbon black ranges from about 1 1/2 to 5 1/2 percent by weight of said fist layer.
  4. 5. The invention Of claim 1 in which said adhesive material is a thin layer of neoprene which is applied coextensive with the surface of said first layer and extends fully thereover and serves as a secondary sealant.
  5. 6. The invention of claim 3 wherein said first, outer, and adhesive layers have a weight approximating 20 to 50 pounds per roofing square.
  6. 7. The invention of claim 1 wherein: a. said first layer is formed of foamed polyethylene and has therein a flame retardant additive ranging up to about 20 percent by weight; b. said adhesive layer is neoprene in a thickness of up to about 0.050 inches thick; and, c. said opaque chips are sufficient in quantity to prevent the sun''s ultraviolet rays from reaching said first layer.
  7. 8. The invention of claim 1 including from approximately 0 to approximately 20 percent by weight of flame retardant material.
  8. 9. The invention of claim 8 wherein said flame retardant material at least includes a portion of antimony trioxide.
  9. 10. The invention of claim 9 wherein said antimony trioxide is in the presence of a chlorine liberating material.
  10. 11. The invention of claim 5 wherein said Neoprene is approximately 0.001'''' to 0.050'''' thick.
  11. 12. The invention of claim 1 wherein said first layer is formed of polyethylene.
  12. 13. The invention of claim 2 wherein said first layer is comprised substantially of polyethylene.
  13. 14. The invention of claim 5 wherein said thin layer of neoprene is joined to said first layer which is formed of polyethylene.
  14. 15. The invention of claim 5 wherein said thin layer of neoprene has a thickness of up to about 0.05 inches.
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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3899855A (en) * 1972-02-11 1975-08-19 Kanrich Nathaniel G Peaked roof structure of polyurethane molded building panels with integral, bonded, low-density urethane insulation backing
US4038447A (en) * 1976-02-05 1977-07-26 Brock Wayne C Flame resistant insulation blanket
US4172168A (en) * 1977-07-05 1979-10-23 Firma Carl Freudenberg Lay-flat flooring slab
US4288490A (en) * 1975-03-27 1981-09-08 Dynamit Nobel Aktiengesellschaft Engine hood lining for automotive vehicles
EP0079080A1 (en) * 1981-11-10 1983-05-18 The Dow Chemical Company Foamable electroconductive polyolefin resin compositions
US4397906A (en) * 1980-04-30 1983-08-09 Sekisui Kagaku Kogyo Kabushiki Kaisha Multilayer structural building material
US4416756A (en) * 1982-12-30 1983-11-22 Inland Steel Company Electrotreating apparatus with depletable anode roll
US4453358A (en) * 1980-09-03 1984-06-12 Bayer Aktiengesellschaft Insulated one-piece roof
US4467007A (en) * 1983-10-26 1984-08-21 Elgie Don R Wall covering
US4947603A (en) * 1987-09-16 1990-08-14 Alois Goertz Unitary foam/gravel roof
US5232530A (en) * 1987-12-04 1993-08-03 Elk Corporation Of Dallas Method of making a thick shingle
US5305569A (en) * 1989-04-19 1994-04-26 Elk Corporation Of Dallas Thick shingle
US5373026A (en) * 1992-12-15 1994-12-13 The Dow Chemical Company Methods of insulating with plastic structures containing thermal grade carbon black
US5670178A (en) * 1995-08-16 1997-09-23 West; Richard A. Method and apparatus for applying foam plastic materials to a roof deck
US6426309B1 (en) 1998-12-30 2002-07-30 Owens Corning Fiberglas Technology, Inc. Storm proof roofing material
US20040014385A1 (en) * 1998-12-30 2004-01-22 Greaves Gerald G. Storm resistant roofing material
US6910307B1 (en) * 1999-06-22 2005-06-28 Scott D. Maurer Architectural molding
US6918977B1 (en) 2000-06-21 2005-07-19 Scott D. Maurer Architectural molding
US20060130419A1 (en) * 2003-02-18 2006-06-22 Modco Technology (Canada) Ltd. Roofing panel system
US20070092708A1 (en) * 2005-10-24 2007-04-26 Gleich Klaus F Processes for forming a fiber-reinforced product

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3266206A (en) * 1962-07-03 1966-08-16 Allied Chem Insulated built up roof and insulation therefor
US3466222A (en) * 1967-07-26 1969-09-09 Lexsuco Inc Fire retardant insulative structure and roof deck construction comprising the same
US3502540A (en) * 1964-03-04 1970-03-24 Roberto Pietrocola Novel composite but monolithic laminated plastic and process of manufacturing thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3266206A (en) * 1962-07-03 1966-08-16 Allied Chem Insulated built up roof and insulation therefor
US3502540A (en) * 1964-03-04 1970-03-24 Roberto Pietrocola Novel composite but monolithic laminated plastic and process of manufacturing thereof
US3466222A (en) * 1967-07-26 1969-09-09 Lexsuco Inc Fire retardant insulative structure and roof deck construction comprising the same

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3899855A (en) * 1972-02-11 1975-08-19 Kanrich Nathaniel G Peaked roof structure of polyurethane molded building panels with integral, bonded, low-density urethane insulation backing
US4288490A (en) * 1975-03-27 1981-09-08 Dynamit Nobel Aktiengesellschaft Engine hood lining for automotive vehicles
US4038447A (en) * 1976-02-05 1977-07-26 Brock Wayne C Flame resistant insulation blanket
US4172168A (en) * 1977-07-05 1979-10-23 Firma Carl Freudenberg Lay-flat flooring slab
US4397906A (en) * 1980-04-30 1983-08-09 Sekisui Kagaku Kogyo Kabushiki Kaisha Multilayer structural building material
US4453358A (en) * 1980-09-03 1984-06-12 Bayer Aktiengesellschaft Insulated one-piece roof
EP0079080A1 (en) * 1981-11-10 1983-05-18 The Dow Chemical Company Foamable electroconductive polyolefin resin compositions
US4416756A (en) * 1982-12-30 1983-11-22 Inland Steel Company Electrotreating apparatus with depletable anode roll
US4467007A (en) * 1983-10-26 1984-08-21 Elgie Don R Wall covering
US4947603A (en) * 1987-09-16 1990-08-14 Alois Goertz Unitary foam/gravel roof
US5232530A (en) * 1987-12-04 1993-08-03 Elk Corporation Of Dallas Method of making a thick shingle
US5305569A (en) * 1989-04-19 1994-04-26 Elk Corporation Of Dallas Thick shingle
US5373026A (en) * 1992-12-15 1994-12-13 The Dow Chemical Company Methods of insulating with plastic structures containing thermal grade carbon black
US5670178A (en) * 1995-08-16 1997-09-23 West; Richard A. Method and apparatus for applying foam plastic materials to a roof deck
US6426309B1 (en) 1998-12-30 2002-07-30 Owens Corning Fiberglas Technology, Inc. Storm proof roofing material
US20040014385A1 (en) * 1998-12-30 2004-01-22 Greaves Gerald G. Storm resistant roofing material
US6709994B2 (en) 1998-12-30 2004-03-23 Owens Corning Fiberglas Technology, Inc. Storm proof roofing material
US6910307B1 (en) * 1999-06-22 2005-06-28 Scott D. Maurer Architectural molding
US6918977B1 (en) 2000-06-21 2005-07-19 Scott D. Maurer Architectural molding
US20060130419A1 (en) * 2003-02-18 2006-06-22 Modco Technology (Canada) Ltd. Roofing panel system
US20070092708A1 (en) * 2005-10-24 2007-04-26 Gleich Klaus F Processes for forming a fiber-reinforced product
US7601282B2 (en) 2005-10-24 2009-10-13 Johns Manville Processes for forming a fiber-reinforced product

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