US3615379A - High-grade zinc alloys - Google Patents
High-grade zinc alloys Download PDFInfo
- Publication number
- US3615379A US3615379A US832508A US3615379DA US3615379A US 3615379 A US3615379 A US 3615379A US 832508 A US832508 A US 832508A US 3615379D A US3615379D A US 3615379DA US 3615379 A US3615379 A US 3615379A
- Authority
- US
- United States
- Prior art keywords
- grade zinc
- copper
- alloys
- titanium
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001297 Zn alloy Inorganic materials 0.000 title claims abstract description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052802 copper Inorganic materials 0.000 claims abstract description 14
- 239000010949 copper Substances 0.000 claims abstract description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011701 zinc Substances 0.000 claims abstract description 10
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- 239000010936 titanium Substances 0.000 claims abstract description 9
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 9
- 229910045601 alloy Inorganic materials 0.000 abstract description 11
- 239000000956 alloy Substances 0.000 abstract description 11
- 238000005097 cold rolling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 241001424392 Lucia limbaria Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- -1 zinc-titanium-aluminum Chemical compound 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
- C22C18/02—Alloys based on zinc with copper as the next major constituent
Definitions
- German Patent application P 15 33 390. there is described a creep-resistant zinc alloy consisting of to 1% lead, 0 to 0.05% cadmium, 0 to 1.2% copper and which additionally contains titanium in an amount of 0.05 to 0.25%, aluminum in an amount of at least 0.003 but less than 0.05%, preferably in an amount of 0.01 to 0.03% in addition to highgrade zinc and/or smelter zinc and which is free of any magnesium, lithium, beryllium and calcium.
- alloys can be identified as zinc-titanium-aluminum type alloys in which the titanium content determines the creep strength, the aluminum content the casting behavior and therewith the economy and efficiency in use. in addition to their practicality, which has been confirmed in use, the highgrade alloys of this type have also demonstrated other ad vantageous and surprising effects.
- titanium containing zinc alloys The stability of titanium containing zinc alloys is increased by providing them with copper contents offrom 0.15 to 2%.
- copper contents offrom 0.15 to 2%.
- the invention therefore lies in the finding that high-grade zinc alloys consisting of 0.05 to 0.25% titanium, 0.02 to 0.20% copper, 0.005 to 0.05% aluminum, the remainder of highgrade zinc having a degree of purity of 99.9 to 99.995% are highly suitable as creep resistant and ductile alloys when cold rolled.
- EXAMPLE 1 [A110 to 0.89; copper, 0.1 to 0.15% titanium. Aluminum maximum 0.001%, remainder high grade zino.]
- EXAMPLE 2 [All0y0- .2 to 0.57 copper, 0.1 to 0.15% titanium. Aluminum maximum 0.001% remainder high grade zinc.]
- the titanium-aluminum sheet alloy having high copper contents of less than 0.2% and preferably of less than 0.05 to 0.1% had a considerable resistance to creep on working without evidence of any breakage in the rolled state. This is a decisive advance in the art, as the heretofore produced alloys with higher copper contents and no aluminum lose most of their creep strength following permanent annealing, when the thusly treated sheet material was cold cast during processing, as for example by pressing.
- the possible heat treatment of the alloy in accordance with the invention can be carried out advantageously in the tem perature range of from 120 to C. 1n the same temperature range, the alloy can also be warrnrolled.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Metal Rolling (AREA)
- Conductive Materials (AREA)
- Heat Treatment Of Steel (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Printing Plates And Materials Therefor (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19681758489 DE1758489C3 (de) | 1968-06-12 | Verwendung einer Feinzinklegierung |
Publications (1)
Publication Number | Publication Date |
---|---|
US3615379A true US3615379A (en) | 1971-10-26 |
Family
ID=5695062
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US832508A Expired - Lifetime US3615379A (en) | 1968-06-12 | 1969-06-11 | High-grade zinc alloys |
Country Status (6)
Country | Link |
---|---|
US (1) | US3615379A (enrdf_load_stackoverflow) |
BE (1) | BE734497A (enrdf_load_stackoverflow) |
FR (1) | FR2010778A1 (enrdf_load_stackoverflow) |
GB (1) | GB1221382A (enrdf_load_stackoverflow) |
NL (1) | NL155598B (enrdf_load_stackoverflow) |
NO (1) | NO120654B (enrdf_load_stackoverflow) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4717430A (en) * | 1984-06-18 | 1988-01-05 | Copper Development Association, Inc. | Soldering compositions, fluxes and methods of use |
US5945066A (en) * | 1997-11-20 | 1999-08-31 | Griffin; James D. | Zinc-copper based alloy and castings made therefrom |
US20040173294A1 (en) * | 1998-11-17 | 2004-09-09 | Grillo-Werke Ag | Use of zinc alloys |
EP3578675A1 (en) * | 2018-06-07 | 2019-12-11 | Grillo-Werke Aktiengesellschaft | Highly malleable, ductile zinc strip |
-
1969
- 1969-06-02 NO NO2276/69A patent/NO120654B/no unknown
- 1969-06-03 GB GB27989/69A patent/GB1221382A/en not_active Expired
- 1969-06-09 NL NL6908766.A patent/NL155598B/xx not_active IP Right Cessation
- 1969-06-11 US US832508A patent/US3615379A/en not_active Expired - Lifetime
- 1969-06-12 FR FR6919530A patent/FR2010778A1/fr active Pending
- 1969-06-12 BE BE734497D patent/BE734497A/xx not_active IP Right Cessation
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4717430A (en) * | 1984-06-18 | 1988-01-05 | Copper Development Association, Inc. | Soldering compositions, fluxes and methods of use |
US5945066A (en) * | 1997-11-20 | 1999-08-31 | Griffin; James D. | Zinc-copper based alloy and castings made therefrom |
US20040173294A1 (en) * | 1998-11-17 | 2004-09-09 | Grillo-Werke Ag | Use of zinc alloys |
EP3578675A1 (en) * | 2018-06-07 | 2019-12-11 | Grillo-Werke Aktiengesellschaft | Highly malleable, ductile zinc strip |
Also Published As
Publication number | Publication date |
---|---|
DE1758489B2 (de) | 1974-08-08 |
NL6908766A (enrdf_load_stackoverflow) | 1969-12-16 |
GB1221382A (en) | 1971-02-03 |
NO120654B (enrdf_load_stackoverflow) | 1970-11-16 |
BE734497A (enrdf_load_stackoverflow) | 1969-11-17 |
NL155598B (nl) | 1978-01-16 |
FR2010778A1 (enrdf_load_stackoverflow) | 1970-02-20 |
DE1758489A1 (de) | 1971-02-11 |
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