US3594223A - Process of producing a lubricated heat bonded thermoplastic fiber fabric and the lubricated fabric - Google Patents

Process of producing a lubricated heat bonded thermoplastic fiber fabric and the lubricated fabric Download PDF

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US3594223A
US3594223A US3594223DA US3594223A US 3594223 A US3594223 A US 3594223A US 3594223D A US3594223D A US 3594223DA US 3594223 A US3594223 A US 3594223A
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Prior art keywords
fabric
fibers
lubricated
bat
lubricant
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Ralph H Via
Arthur Kramer
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Phillips Petroleum Co
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Phillips Petroleum Co
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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/06Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by welding-together thermoplastic fibres, filaments, or yarns
    • DTEXTILES; PAPER
    • D05SEWING; EMBROIDERING; TUFTING
    • D05CEMBROIDERING; TUFTING
    • D05C17/00Embroidered or tufted products; Base fabrics specially adapted for embroidered work; Inserts for producing surface irregularities in embroidered products
    • D05C17/02Tufted products
    • D05C17/023Tufted products characterised by the base fabric
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0068Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by the primary backing or the fibrous top layer
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00Chemical constitution of the fibres, threads or yarns
    • D06N2201/02Synthetic macromolecular fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00Chemical constitution of the fibres, threads or yarns
    • D06N2201/02Synthetic macromolecular fibres
    • D06N2201/0254Polyolefin fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00Chemical constitution of the fibres, threads or yarns
    • D06N2201/02Synthetic macromolecular fibres
    • D06N2201/0263Polyamide fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/1628Dimensional stability
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2311Coating or impregnation is a lubricant or a surface friction reducing agent other than specified as improving the "hand" of the fabric or increasing the softness thereof

Definitions

  • This invention relates to the formation of a nonwoven textile fabric formed from a bat of fibers having improved physical properties.
  • this invention relates to the bonding of a nonwoven bat of needled fibers disposed in a random nonparallel fashion by heating near the crystalline melting point followed by application of an ethoxylated alcohol lubricant.
  • this invention relates to the production of carpet backing from bats of needled polypropylene fibers by heating with heated rollers to fuse into a bonded fabric and then lubricating the fabric thus formed with an ethoxylated alcohol lubricant.
  • nonwoven coherent fabrics can be formed by depositing a mass of fibers or filaments in either random or ordered orientation to form a bat, needling the bat to intermix the fibers, and bonding the fibers together to form a fabric.
  • One method of bonding the fibers is to pass the needled bat through a heating device wherein at least a portion of the fibers in the bat fuse, thus interlocking the individual fibers into a coherent fabric.
  • lubricants can be applied to textile materials including fabrics to improve various characteristics.
  • One of the problems encountered with many of the prior art products is the problem of fiber breakage and lack of strength and dimensional stability for the textile material.
  • a further object of this invention is to provide a lubricant for textile materials which will substantially improve the physical properties of the textile products.
  • the process for improving physical properties of synthetic fiber nonwoven fabrics formed from thermoplastic fibers comprises passing bats of thermoplastic fibers through a needling zone to intermix the fibers, then through a heating zone to fuse the fibers into a fabric and then applying to said fabric a lubricant consisting of an ethoxylated alcohol.
  • carpet backing is produced by passing needled bats of polypropylene fibers between heated rolls to fuse the fibers into a fabric and then applying a lubricant consistnited States Patent ICC ing of an ethoxylated alcohol to the product for reduced fiber breakage and noise and for increased strength and dimensional stability.
  • carpet backing is produced consisting essentially of nonwoven fabric of highly crystalline and molecularly oriented needled fibers disposed in a random nonparallel fashion and a coating of a lubricant consisting of an ethoxylated alcohol.
  • the invention can be used with any bat containing fusible organic thermoplastic fibers.
  • the bat can consist entirely of such fusible fibers, or can be a blend of fusible fibers with other synthetic or natural fibrous materials.
  • the bat can be formed by any conventional means.
  • the fibers can be supplied by a carding machine in the form of a unidirectionally oriented web, in which case all fibers would be oriented in the direction of the mat travel.
  • the fibers can be cross-lapped by layering a unidirectionally oriented web from one or more cards or garnets back and forth on a moving conveyor. Further, the fibers can be deposited on a conveyor belt by air deposition, thereby giving a random orientation.
  • the heat fusible materials which can be used in forming bats for the process of the invention include substantially all of the synthetic organic thermoplastic materials.
  • Polyolefins such as the polymers of ethylene, propylene, butene, and copolymers thereof, are particularly suitable.
  • polyesters and polyamides and other known organic thermoplastics which are capable of being formed into filaments.
  • Bats formed by any of the above methods can be taken directly to the bonding process or can be subjected to some preliminary treatment which would increase the coherency of the mat prior to heat bonding.
  • the mat is subjected to a conventional textile needling operation prior to the fusion bonding process.
  • the bat of thermoplastic fibers or filaments is bonded by heating briefly to a temperature above the softening .point.
  • the fibers of the needled bat are heated briefly to a temperature up to about 350 F. by passage between heated rolls. Temperature of the heated rolls will be in the range of 325 to 400 F. Under these conditions the fibers in the center of the bat may remain unfused or unbonded.
  • the continuous nonwoven fabrics used as carpet backing in the present invention are from 10 to 30 mils thick and preferably in the range 10-25 mils thick.
  • the filaments or fibers making up the nonwoven sheet material have a denier between about 3 and 15 d.p.f.
  • the bat may also include a sheet of cheesecloth which may be positioned at the bottom or in the middle of the several layers of fibers.
  • a warp of spun yarns of cotton, rayon, polyester, etc. may also be positioned within the bat.
  • the cheesecloth or warp yarn gives the finished fabric additional strength and is inserted in the bat prior to needling.
  • the lubricant used in percent concentration consisting of ethoxylated alcohol is applied to the bonded fabric to reduce fiber breakage and noise during tufting and for increasing strength and dimensional stability of the product.
  • the amount of lubricant applied to the fabric ordinarily will range from 0.1 to 2.0 weight percent of the fabric as measured by methanol extraction.
  • the ethoxylated alcohols employed according to the invention have the formula wherein x is from 8 to 16, preferably -14, and n is 1- 10, preferably 2-5.
  • the presently preferred ethoxylated alcohol has an x value of 10-12 and an n value of 3.
  • the ethoxylated alcohols employed according to the invention have a molecular weight in the range of 200 to 1000, preferably from 300 to 500. Ethoxylated alcohols with molecular weights above 1000 cannot be used as liquids in 100 percent concentrations and are therefore undesirable.
  • the operable ethoxylated alcohol lubricant in the invention can be applied to the self-bonded, nonwoven fabric by any of the methods known in the art. Thus, application by spraying, padding, roll coating, etc. can be used. As indicated above, the lubricant is applied without a diluent or other additive.
  • Nonwoven fabric was produced as described previously in detail and briefly by depositing layers of 4 /2 denier polypropylene stable fibers upon a warp of polyester threads. The bat thus formed was needled and heat fused by passage between fusion rolls heated to a temperature of 350 F. The fused fabric was then passed continuously through a bath of ethoxylated alcohol lubricant with the formula Such a lubricant is sold by Continental Oil Company under the tradename of Alfonic 1412-4 ethoxylate.
  • thermoplastic fibers which compises (a) heating bats of thermoplastic fibers above the softening point of the thermoplastic to fusion bond the fibers into a fabric and (b) applying a coating to said fused hat of a liquid lubricant consisting of an ethoxylated alcohol having a molecular weight in the range 200-1000 and the formula wherein x is from 8-16 and n is 1-10 in an amount sufficient to reduce fiber breakage and increase dimensional stability of the mat product.
  • a liquid lubricant consisting of an ethoxylated alcohol having a molecular weight in the range 200-1000 and the formula wherein x is from 8-16 and n is 1-10 in an amount sufficient to reduce fiber breakage and increase dimensional stability of the mat product.
  • thermoplastic fiber is polypropylene
  • step (a) is formed by being passed between heated rollers maintained at a temperature in the range of 325 to 400 F.
  • a textile product consisting essentially of (a) a non-woven bat of fusion bonded highly crystalline and molecularly oriented continuous filaments disposed in a random nonparallel fashion and overlapping and intersecting throughout the thickness of the sheet and (b) a coating of a liquid lubricant consisting of an ethoxylated alcohol having a molecular weight in the range 200-1000 and the formula wherein x is 8-16 and n is 1-10.
  • a product according to claim 6 wherein said filaments are formed from polypropylene and wherein said ethoxylated alcohol has an at value of 10-12 and an 11 value of 3.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nonwoven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

IMPROVED CARPET BACKING FORMED FROM HIGHLY CRYSTALLINE AND MOLECULARLY ORIENTED FIBERS THAT HAVE BEEN NEEDLED INTO A COHESIVE BAT, BONDED TOGETHER BY HEATING, AND FOLLOWED BY APPLICATION OF AN ETHOXYLATED ALCOHOL LUBRICANT.

Description

3,594,223 PROCESS OF PRODUCING A LUBRICATED HEAT BONDED THERMOPLASTIC FIBER FABRIC AND THE LUBRICATED FABRIC Ralph H. Via and Arthur Kramer, Greenville, S.C., assignors to Phillips Petroleum Company No Drawing. Filed Nov. 8, 1968, Ser. No. 774,526 Int. Cl. D06m 13/16, 13/52 US. Cl. 117138.8 8 Claims ABSTRACT OF THE DISCLOSURE Improved carpet backing formed from highly crystalline and molecularly oriented fibers that have been needled into a cohesive bat, bonded together by heating, and followed by application of an ethoxylated alcohol lubricant.
BACKGROUND OF THE INVENTION This invention relates to the formation of a nonwoven textile fabric formed from a bat of fibers having improved physical properties. In accordance with one aspect, this invention relates to the bonding of a nonwoven bat of needled fibers disposed in a random nonparallel fashion by heating near the crystalline melting point followed by application of an ethoxylated alcohol lubricant. In accordance with a further aspect, this invention relates to the production of carpet backing from bats of needled polypropylene fibers by heating with heated rollers to fuse into a bonded fabric and then lubricating the fabric thus formed with an ethoxylated alcohol lubricant.
It is known in the art that nonwoven coherent fabrics can be formed by depositing a mass of fibers or filaments in either random or ordered orientation to form a bat, needling the bat to intermix the fibers, and bonding the fibers together to form a fabric. One method of bonding the fibers is to pass the needled bat through a heating device wherein at least a portion of the fibers in the bat fuse, thus interlocking the individual fibers into a coherent fabric. Also it is known in the art that lubricants can be applied to textile materials including fabrics to improve various characteristics. However, a number of major difficulties arise with the prior art methods of heating and lubricating textile materials. One of the problems encountered with many of the prior art products is the problem of fiber breakage and lack of strength and dimensional stability for the textile material.
Accordingly, it is an object of this invention to provide a method for forming nonwoven textile fabrics having improved physical characteristics.
A further object of this invention is to provide a lubricant for textile materials which will substantially improve the physical properties of the textile products.
Other objects and aspects, as well as the several advantages of the invention, will be apparent to those skilled in the art upon reading the specification and the appended claims.
SUMMARY OF THE INVENTION According to the invention, the process for improving physical properties of synthetic fiber nonwoven fabrics formed from thermoplastic fibers is provided which comprises passing bats of thermoplastic fibers through a needling zone to intermix the fibers, then through a heating zone to fuse the fibers into a fabric and then applying to said fabric a lubricant consisting of an ethoxylated alcohol.
In accordance with a specific embodiment of the invention carpet backing is produced by passing needled bats of polypropylene fibers between heated rolls to fuse the fibers into a fabric and then applying a lubricant consistnited States Patent ICC ing of an ethoxylated alcohol to the product for reduced fiber breakage and noise and for increased strength and dimensional stability.
In accordance with a further embodiment of the invention, carpet backing is produced consisting essentially of nonwoven fabric of highly crystalline and molecularly oriented needled fibers disposed in a random nonparallel fashion and a coating of a lubricant consisting of an ethoxylated alcohol.
DESCRIPTION OF THE PREFERRED EMBODIMENTS The invention can be used with any bat containing fusible organic thermoplastic fibers. The bat can consist entirely of such fusible fibers, or can be a blend of fusible fibers with other synthetic or natural fibrous materials.
The bat can be formed by any conventional means. For example, the fibers can be supplied by a carding machine in the form of a unidirectionally oriented web, in which case all fibers would be oriented in the direction of the mat travel. Alternately, the fibers can be cross-lapped by layering a unidirectionally oriented web from one or more cards or garnets back and forth on a moving conveyor. Further, the fibers can be deposited on a conveyor belt by air deposition, thereby giving a random orientation.
The heat fusible materials which can be used in forming bats for the process of the invention include substantially all of the synthetic organic thermoplastic materials. Polyolefins, such as the polymers of ethylene, propylene, butene, and copolymers thereof, are particularly suitable. Also suitable are polyesters and polyamides and other known organic thermoplastics which are capable of being formed into filaments.
Bats formed by any of the above methods can be taken directly to the bonding process or can be subjected to some preliminary treatment which would increase the coherency of the mat prior to heat bonding. Preferably the mat is subjected to a conventional textile needling operation prior to the fusion bonding process. The bat of thermoplastic fibers or filaments is bonded by heating briefly to a temperature above the softening .point. In order to fuse fibers of polypropylene the fibers of the needled bat are heated briefly to a temperature up to about 350 F. by passage between heated rolls. Temperature of the heated rolls will be in the range of 325 to 400 F. Under these conditions the fibers in the center of the bat may remain unfused or unbonded.
The continuous nonwoven fabrics used as carpet backing in the present invention are from 10 to 30 mils thick and preferably in the range 10-25 mils thick. The filaments or fibers making up the nonwoven sheet material have a denier between about 3 and 15 d.p.f.
The bat may also include a sheet of cheesecloth which may be positioned at the bottom or in the middle of the several layers of fibers. Alternatively, a warp of spun yarns of cotton, rayon, polyester, etc. may also be positioned within the bat. The cheesecloth or warp yarn gives the finished fabric additional strength and is inserted in the bat prior to needling.
Following bonding or fusing of the fibrous bat, the lubricant used in percent concentration consisting of ethoxylated alcohol is applied to the bonded fabric to reduce fiber breakage and noise during tufting and for increasing strength and dimensional stability of the product. The amount of lubricant applied to the fabric ordinarily will range from 0.1 to 2.0 weight percent of the fabric as measured by methanol extraction.
The ethoxylated alcohols employed according to the invention have the formula wherein x is from 8 to 16, preferably -14, and n is 1- 10, preferably 2-5. The presently preferred ethoxylated alcohol has an x value of 10-12 and an n value of 3.
The ethoxylated alcohols employed according to the invention have a molecular weight in the range of 200 to 1000, preferably from 300 to 500. Ethoxylated alcohols with molecular weights above 1000 cannot be used as liquids in 100 percent concentrations and are therefore undesirable.
The operable ethoxylated alcohol lubricant in the invention can be applied to the self-bonded, nonwoven fabric by any of the methods known in the art. Thus, application by spraying, padding, roll coating, etc. can be used. As indicated above, the lubricant is applied without a diluent or other additive.
SPECIFIC EXAMPLE Nonwoven fabric was produced as described previously in detail and briefly by depositing layers of 4 /2 denier polypropylene stable fibers upon a warp of polyester threads. The bat thus formed was needled and heat fused by passage between fusion rolls heated to a temperature of 350 F. The fused fabric was then passed continuously through a bath of ethoxylated alcohol lubricant with the formula Such a lubricant is sold by Continental Oil Company under the tradename of Alfonic 1412-4 ethoxylate.
Fabrics containing 0, 1.44, and 3.95 weight percent lubricant as measured by methanol extraction were thus roduced and used as carpet backing for the production of tufted carpeting. The finished carpeting was then studied for the following performance characteristics:
(1) Growth or shrinkage in width during tufting. (2) Growth or shrinkage through finishing. (3) Noise, pounding and needle heat. (4) Carpet strength. (5) Tufting efiiciency.
The results of the tests of the finished carpeting made with the non-woven carpet backing with 0, 1.44, and 3.95 weight percent lubricant were as follows:
(1) Noise, pounding and needle heat The nonlubricated carpeting gave increased noise and needle heat (during tufting). All others were equivalent.
(2) Tufting growth and shrinkage The nonlubricated carpeting gave excessive tufting growth in some cases. The 3.95 percent lubricant level permitted excessive tufting shrinkage. The 1.5 percent lubricant level gave the best balance between tufting growth and shrinkage.
(3) Growth and shrinkage throughout finishing of the carpet The nonlubricated carpet gave excessive instability during piece dyeing; that is, both growth and shrinkage were encountered. The high and low levels of lubricant application gave excellent stability.
(4) Carpet strength The carpeting made with nonlubricated fabric backing was unsatisfactory in this test. The lubricated product was satisfactory.
4 (5) Tufting efiiciency No observable differences.
The improved performance characteristics of the carpeting made with lubricated backing is thus evident with an application level of 1.44 weight percent being optimum based on superiority in tufting growth and shrinkage.
We claim:
1. A process for improving the physical properties of synthetic fiber fabric formed from thermoplastic fibers Which compises (a) heating bats of thermoplastic fibers above the softening point of the thermoplastic to fusion bond the fibers into a fabric and (b) applying a coating to said fused hat of a liquid lubricant consisting of an ethoxylated alcohol having a molecular weight in the range 200-1000 and the formula wherein x is from 8-16 and n is 1-10 in an amount sufficient to reduce fiber breakage and increase dimensional stability of the mat product.
2. The process according to claim 1 wherein the amount of polyoxyalkylene applied is in the range 0.1 to 2.0 weight percent.
3. The process according to claim 1 wherein said thermoplastic fiber is polypropylene.
4. The process according to claim 3 wherein x in said ethoxylated alcohol ranges from 10-12 and n is 3.
5. The process according to claim 4 wherein said fused hat of step (a) is formed by being passed between heated rollers maintained at a temperature in the range of 325 to 400 F.
6. A textile product consisting essentially of (a) a non-woven bat of fusion bonded highly crystalline and molecularly oriented continuous filaments disposed in a random nonparallel fashion and overlapping and intersecting throughout the thickness of the sheet and (b) a coating of a liquid lubricant consisting of an ethoxylated alcohol having a molecular weight in the range 200-1000 and the formula wherein x is 8-16 and n is 1-10.
7. A product according to claim 6 wherein said filaments are formed from polypropylene and wherein said ethoxylated alcohol has an at value of 10-12 and an 11 value of 3.
8. A textile product according to claim 6 wherein the amount of polyoxyalkylene present is in the range 0.1 to 2 weight percent.
References Cited UNITED STATES PATENTS 2,525,691 10/1950 Lee et al 117-139.5X 3,245,854 4/1966 Etchison et al. 1618 1X 3,317,335 5/1967 Marrinan et al. 117138.8X 3,484,283 12/1969 Simpson et al 11714O WILLIAM D. MARTIN, Primary Examiner T. G. DAVIS, Assistant Examiner US. 01. X.R. 117-139.5,
US3594223D 1968-11-08 1968-11-08 Process of producing a lubricated heat bonded thermoplastic fiber fabric and the lubricated fabric Expired - Lifetime US3594223A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0010328A1 (en) * 1978-10-20 1980-04-30 Shell Internationale Researchmaatschappij B.V. A process for the manufacture of tufted textile articles; lubricating oil compositions and primary backing fabrics
US4288331A (en) * 1979-06-13 1981-09-08 Shell Oil Company Lubricating compositions for primary backing fabrics used in the manufacture of tufted textile articles

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0010328A1 (en) * 1978-10-20 1980-04-30 Shell Internationale Researchmaatschappij B.V. A process for the manufacture of tufted textile articles; lubricating oil compositions and primary backing fabrics
US4288331A (en) * 1979-06-13 1981-09-08 Shell Oil Company Lubricating compositions for primary backing fabrics used in the manufacture of tufted textile articles

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