US3592633A - High strength low alloy steel possessing sufficient weldability containing small amounts of nb,ti,and b - Google Patents

High strength low alloy steel possessing sufficient weldability containing small amounts of nb,ti,and b Download PDF

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Publication number
US3592633A
US3592633A US802715*A US3592633DA US3592633A US 3592633 A US3592633 A US 3592633A US 3592633D A US3592633D A US 3592633DA US 3592633 A US3592633 A US 3592633A
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United States
Prior art keywords
steel
high strength
low alloy
strength low
small amounts
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Expired - Lifetime
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US802715*A
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English (en)
Inventor
Tatsumi Osuka
Junichi Tanaka
Michio Hayashida
Yoshiaki Ono
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JFE Engineering Corp
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Nippon Kokan Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron

Definitions

  • the present invention relates to high strength low alloy steels and, more particularly, to high strength steels for welding structural services.
  • the low carbon steel possesses a yield point of more than 70 kg./mrn. and superior toughness and has been proved in reduced hardenability in welding and decreased crack sensitivity.
  • the invention also contemplates providing a unique steel particularly adapted to be employed in the Welding structure.
  • the present invention contemplates the manufacture of steels heat-treated with quenching of adapting liquids (containing water), gases (containing air), or mixtures of above media at a temperature from AC point to 1050 C. and then with tempering at a temperature of less than AC point.
  • the steels of the present invention are composed of the following constituents:
  • Carbon is one of the more potent and more economical strengthening elements. It is well known that carbon has the strongest influence upon hardenability of weld zone. Accordingly, it is to be desired that carbon content be low as much as possible. Carbon of more than 0.05%, however, is practical from this point of steel making. The upper limit of carbon content, which is 0.15%, is recommended, owing to the need of making 0.01 to 0.03% Nb solute at a quenching temperature of 900 C. to 1000 C., so as to cause Nb-carbide after tempering treatment.
  • Niobium content must be determined in consideration of carbon content. According to our experimentations, it is shown that Nb of more than 0.05% scarcely contributed to strength steel. Also, it is impossible to obtain the required strength when Nb content is less than 0.005%
  • the suitable Nb content in the present invention consists in the range of 0.005 to 0.05%.
  • Manganese of 0.50% which is the lower limit is adopted in consideration of this point of steel making and of hotworkability. Also, 1.60% Mn which is the upper limit is determined in consideration of weldability.
  • 0.15% to 0.7% molybdenum possibly causes strength of steel to markedly increase. However, when the content is more than 0.7%, weldability of steel is spoiled and when the content is less than 0.15 strength of steel is harmed.
  • titanium is a useful element for improving hardenability of steel and for increasing strength of steel owing to precipitation of Ti-carbide in the tempering treatment stage.
  • Nitrogen content has a serious influence on combination of Nb-Ti-B which is the main point in the present invention.
  • the content must be limited within the range in which it is impossible to form its nitride. More than 0.007% nitrogen harms toughness of steel, owing to the formed Ti-nitride and causes Ti-carhide, which is effective for strength of steels 4 Examining the above-mentioned values, it is understood that maximum hardness in taper hardness test is far lower than the maximum value required by the same kind of high strength steel, such as Hv$430 in Japanese WES Standard. This fact shows that hardness of welding zone to decrease.
  • Nitrogen content of the lower limit is 0.002% is markedly lowered according to keeping yield strength according to a restriction of steel making process. of 70 kg.mm. by means of a suitable combination of II! the range of the above-mentioned C l C Nb+Ti+B and at the same time main alloying elements, position, the following range is recommended as preferred such as C, Mn, Ni, Cr, Mo and the like, are far less than values: ordinary high-strength steels.
  • High strength low alloy steels composed of 0.05 to As mentioned above, the present invention steel is com- 015% to t0 L posed of alloying of a small quantity of components, and to 150% Mn, and t0 5 t 080% demonstrates yield strength of more than 70 kg./mm. Cu, to 100% to (110% 0-002 to superior toughness and excellent weldability according to N, 0-005 to 0.04% Nb, 0.0005 to 0-00 heat treatment of quenching mother steel from more than 0-005 to (105% T1 and havlhg a V 4 Strength Q more 4C temperature and then of tempering at more than than Q' and POSSeSSIhg sufficleht weldahlllty- 5 C.
  • High strength low alloy steels in accordance with The following Table 1 shows examples of the present inclalm 1h Whlch the alloying ingredients wmprise vention steel.
  • steels are the presto 012% c, to 050% Si, L00 t0 ent invention steels.
  • H to K which are out of 020 to 040% Cu, to 050% 0420 to 0360% the range of components based on the present invention, 04010 to 0'050% 0.005 to (105% 0- to these steels are shown in comparison with the present in- 0.03 Ti, 0.001 to 0.003% B, up to 0.005% N, vention steel.
  • L steel is an ordinary high-strength low alloy 3.
  • High strength low alloy steel in accordance with claim 2 wherein the steel following heat treatment is 5 quenched at a temperature from AC to 1050 C. and 3,368,887 2/1968 Clark 75-128R then is tempered at less than AC temperature.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
US802715*A 1968-01-22 1969-01-22 High strength low alloy steel possessing sufficient weldability containing small amounts of nb,ti,and b Expired - Lifetime US3592633A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP338968 1968-01-22

Publications (1)

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US3592633A true US3592633A (en) 1971-07-13

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US802715*A Expired - Lifetime US3592633A (en) 1968-01-22 1969-01-22 High strength low alloy steel possessing sufficient weldability containing small amounts of nb,ti,and b

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US (1) US3592633A (enrdf_load_stackoverflow)
DE (1) DE1903070A1 (enrdf_load_stackoverflow)
FR (1) FR2000542A1 (enrdf_load_stackoverflow)
GB (1) GB1210795A (enrdf_load_stackoverflow)
SE (1) SE344215B (enrdf_load_stackoverflow)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3717508A (en) * 1970-11-04 1973-02-20 Bethlehem Steel Corp Method of improving stability of boron hardenability effect in alloy steels
US3955971A (en) * 1974-12-11 1976-05-11 United States Steel Corporation Alloy steel for arctic service
US4043807A (en) * 1974-01-02 1977-08-23 The International Nickel Company, Inc. Alloy steels
US4062705A (en) * 1973-07-31 1977-12-13 Nippon Steel Corporation Method for heat treatment of high-toughness weld metals
US4065331A (en) * 1976-10-08 1977-12-27 Alan Wood Steel Company Rolled low carbon niobium steel
US4080225A (en) * 1976-10-08 1978-03-21 Alan Wood Steel Company Low temperature, weldable, low alloy steel
US4115155A (en) * 1974-05-03 1978-09-19 Bethlehem Steel Corporation Low carbon high yield and tensile strength steel and method of manufacture
US4123261A (en) * 1976-10-21 1978-10-31 Stora Kopparbergs Bergslags Ab Titanium-stabilized deep drawing steel suitable for hot galvanizing
US4185998A (en) * 1978-12-07 1980-01-29 United States Steel Corporation Steel with improved low temperature toughness
US4210445A (en) * 1977-10-18 1980-07-01 Kobe Steel, Ltd. Niobium-containing weldable structural steel having good weldability
US5743929A (en) * 1995-08-23 1998-04-28 The Boc Group, Inc. Process for the production of high purity carbon dioxide
US6315946B1 (en) 1999-10-21 2001-11-13 The United States Of America As Represented By The Secretary Of The Navy Ultra low carbon bainitic weathering steel
FR2847592A1 (fr) * 2002-11-27 2004-05-28 Ispat Unimetal Acier pour deformation a froid ou a chaud, piece mecanique prete a l'emploi realisable avec cet acier et son procede de fabrication
US10392285B2 (en) 2012-10-03 2019-08-27 Johns Manville Submerged combustion melters having an extended treatment zone and methods of producing molten glass

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2396805A2 (fr) * 1977-07-06 1979-02-02 Ugine Aciers Aciers a caracteristiques mecaniques ameliorees par additions controlees de b, al, n et ti
GB2155035B (en) * 1984-02-29 1988-07-27 Skf Steel Eng Ab Steel ring
CA2043836A1 (en) * 1990-06-05 1991-12-06 Rao V. Bangaru High performance high strength low alloy steel
US5213634A (en) * 1991-04-08 1993-05-25 Deardo Anthony J Multiphase microalloyed steel and method thereof
FR2688009B1 (fr) * 1992-02-28 1994-05-27 Lorraine Laminage Procede d'elaboration d'une tole d'acier et tole d'acier obtenue par ce procede.
FR2764308B1 (fr) * 1997-06-04 1999-07-23 Thyssen France Sa Procede de fabrication d'un acier pour moules de grandes dimensions

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3717508A (en) * 1970-11-04 1973-02-20 Bethlehem Steel Corp Method of improving stability of boron hardenability effect in alloy steels
US4062705A (en) * 1973-07-31 1977-12-13 Nippon Steel Corporation Method for heat treatment of high-toughness weld metals
US4043807A (en) * 1974-01-02 1977-08-23 The International Nickel Company, Inc. Alloy steels
US4115155A (en) * 1974-05-03 1978-09-19 Bethlehem Steel Corporation Low carbon high yield and tensile strength steel and method of manufacture
US3955971A (en) * 1974-12-11 1976-05-11 United States Steel Corporation Alloy steel for arctic service
US4065331A (en) * 1976-10-08 1977-12-27 Alan Wood Steel Company Rolled low carbon niobium steel
US4080225A (en) * 1976-10-08 1978-03-21 Alan Wood Steel Company Low temperature, weldable, low alloy steel
US4123261A (en) * 1976-10-21 1978-10-31 Stora Kopparbergs Bergslags Ab Titanium-stabilized deep drawing steel suitable for hot galvanizing
US4210445A (en) * 1977-10-18 1980-07-01 Kobe Steel, Ltd. Niobium-containing weldable structural steel having good weldability
US4185998A (en) * 1978-12-07 1980-01-29 United States Steel Corporation Steel with improved low temperature toughness
US5743929A (en) * 1995-08-23 1998-04-28 The Boc Group, Inc. Process for the production of high purity carbon dioxide
US6315946B1 (en) 1999-10-21 2001-11-13 The United States Of America As Represented By The Secretary Of The Navy Ultra low carbon bainitic weathering steel
FR2847592A1 (fr) * 2002-11-27 2004-05-28 Ispat Unimetal Acier pour deformation a froid ou a chaud, piece mecanique prete a l'emploi realisable avec cet acier et son procede de fabrication
WO2004050935A1 (fr) * 2002-11-27 2004-06-17 Mittal Steel Gandrange Piece mecanique prete a l'emploi en acier bas carbone pour deformation plastique et son procede de fabrication
US20070051434A1 (en) * 2002-11-27 2007-03-08 Ispat-Unimetal Ready-use low-carbon steel mechanical component for plastic deformation and method for making same
US10392285B2 (en) 2012-10-03 2019-08-27 Johns Manville Submerged combustion melters having an extended treatment zone and methods of producing molten glass

Also Published As

Publication number Publication date
DE1903070A1 (de) 1972-06-15
SE344215B (enrdf_load_stackoverflow) 1972-04-04
FR2000542A1 (enrdf_load_stackoverflow) 1969-09-12
GB1210795A (en) 1970-10-28

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