Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
  • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
  • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
  • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
  • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
  • A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
  • A61Q5/04—Preparations for permanent waving or straightening the hair
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
  • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
  • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F8/00—Chemical modification by after-treatment
  • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
  • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F8/00—Chemical modification by after-treatment
  • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
  • D06M15/273—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having epoxy groups
  • D06M15/2735—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having epoxy groups of unsaturated carboxylic esters having mercapto groups
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F2810/00—Chemical modification of a polymer
  • C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority

Definitions

• the present invention relates to a new process for permanently pressing cloth or knitted materials made of wool, so that it will be resistant to wrinkles and permanently retain creases made therein at the time of treatment.
• creases may be obtained according to the invention in a simple and durable manner without causing damage to or weakening of the physical properties of the textile articles.
• One object of the present invention is to present a new process for making creases in textile articles made of keratinic fibers, this new process being characterized by the fact that the above-mentioned textile articles are impregnated with a basic solution of polysulfhydrylated polymers, then heated and pressed in the area in which a crease is desired, for example, by using an iron.
• the solution to be applied to the textile article contains about 1 to and preferably from 2 to 6% by weight of polysulfhydrylated polymers.
• the pH of this solution is between about 3.5 and 10 and is preferably between 9 and 9.5.
• polysulfhydrylated polymers which can be used to carry out the process according to the invention, are the polysulfhydrylated polymers corresponding to the following formula:
• Patented Apr. 27, 1971 ice or a --OCOCH radical, or a COOCH radical, or a CN radical, n is a whole number.
• the polysulfhydrylated polymers are of the formula:
• R is a hydrogen atom or a lower alkyl such as CH or C H or a lower hydroxy alkyl such as R is a hydrogen atom or a -CH radical
• q is a whole number between 2 and 6, inclusive
• p is a whole number equal to 0 or 1
• R and R" are hydrogen atoms or lower alkyl radicals, or phenyl radicals, or lower alkyloxy radicals, R and R being the same or different,
• R" is a hydrogen atom, or the -OCOCH radical, or the CEN radical, or the COOCH radical,
• n is a whole number.
• the polysulfhydrylated polymers are of the formula:
• R and R" which may be the same or different are hydrogen atoms, or lower alkyl radicals, or phenyl radicals, or lower alkyloxy radicals,
• R" is a hydrogen atom, or the OCOCH radical, or
• n is a whole number
• Q is a radical represented by the following formula:
• R1 is H or CH3
• R is H or COOH
• q is a whole number from 1 to 5, inclusive
• q is equal to 0 or 1
• p is equal to 0 or 1
• Q is a radical represented by the following formula:
• R is a hydrogen atom or a lower alkyl
• R is a lower alkyl, or a radical or formula r and r being the same or different lower alkyls, or being part of a heterocyclic ring such as that of morpholine or piperidine, m is a whole number equal to 2, 3 or 4.
• the polysulfhydrylated polymers are constituted by an anhydride homopolymer on which at least one mercapto-amine is condensed.
• the homopolymer may be a maleic polyanhydride polymer, an itaconic polyanhydride polymer, an acrylic polyanhydride polymer, a mixed acrylic-methacrylic polyanhydride polymer, or a methacrylic polymer, although this list is not exhaustive.
• Aminothiols having the following formula may be used to sulfhydrylate these homopolymers:
• R is an alkylene radical comprising preferably from 2 to 4 carbon atoms, which may be substituted by lower alkyls which may have up to 4 carbon atoms, or a carboxyl radical, or a carbalkyloxy group, and
• R is a hydrogen atom or a lower alkyl such as CH Among the aminothiols corresponding to the above formula, these may be cited as examples:
• R is H, --CH C H or CH CH OH, R is H or -COOH, q is a whole number between 1 and 5, inclusive, q is equal to 0 or 1, p is equal to O or 1.
• mercapto-amide amines corresponding to this last formula may be cited those which are obtained from esters of thioglycolic acid, thiolactic acid or ,B-mercaptopropionic acid and from diamines such as ethylene diamine, hexamethylene diamine, N-hydroxyethyl ethylene diamine.
• Another object of the present invention is to provide a new article of manufacture which consists of a composition for permanently creasing textile articles made from keratinic fibers.
• This composition is essentially characterized by the fact that it contains at least one polysulfhydrylated polymer and a base, the pH of this composition being between about 3.5 and and being preferably between 9 and 9.5.
• this last is placed in an aerosol bomb with a liquified gas propellant under pressure, from which it is permitted to escape as a lather or a jet of liquid which may be atomized.
• Res l SMA 1000A having the formula:
• the woolen cloth in which a permanent crease is desired is dampened with this solution; then the cloth is ironed to impress the crease using a hot iron and a damp cloth. 7
• EXAMPLE 2 A composition to obtain permanent creases in textile articles of keratinic fibers is prepared as follows:
• a polysulfhydrylated polymer as in Example 1 above 40 Ammonia at 20 B. to bring the pH of the solution to 9.5, about cc 60 De-ionized water g 900
• the following mixture is then placed in an aerosol container:
• Solution A 70 Dichlorodifluoromethane 15 Trichloromonofluoromethane 15
• the solution contained in the bomb is sprayed onto the textile article to be creased, then a crease is formed using a hot iron and a damp cloth.
• the permanent press thus obtained holds up well even when the cloth is placed in boiling water for an hour.
• Example 6 A polysulfhydrylated polymer as in Example 5 g 1.5 Ammonia at 20 B. q.s.p. pH 9.3. Silicone anti-foaming agent g 0.4 Water, q.s.p cc 100 The following mixture is then put in an aerosol container:
• a composition according to the invention which is in the form of a transient aerosol lather is made by first preparing a solution D having the following composition:
• the cloth to be treated is dampened by rolling the ball of the applicator over the area where pressing is desired, then ironing it with a hot iron.
• a composition according to the invention is made in the form of an aerosol by first preparing a solution C having the following composition:
• Silicone anti-foaming agent g 0.4 Polyethoxyether of alkylphenol g 0.2. Water, q.s.p cc 100 A mixture of the following is then placed in an aerosol bomb:
• Pressing is then done as in the preceding example, using a hot iron and a damp cloth and equally good results are obtained.
• EXAMPLE 8 A composition is prepared by mixing:
• Woolen cloth is pressed as in the preceding examples, using a hot iron and a damp cloth.
• the permanent press thus obtained holds up well, even when the cloth is immersed in hot water for an hour.
• a crease is made in a woolen cloth as in the preceding examples using a hot iron and a damp cloth; the crease thus obtained holds up well even when immersed in hot 'water for an hour, and remains after several washings.
• a composition according to the invention is prepared by mixing:
• the woolen cloth in which a permanent crease is desired is dampened with this solution.
• the cloth is ironed with a hot iron and a damp cloth to impress the crease nd a permanent crease is obtained which remains even ter several washings.
• the cloth to be treated is dampened by rolling the ball of the applicator over the area in which a crease is desired, then ironing with a hot iron.
• the crease may be formed in the textile article without using a hand iron by using another method such as a pressing machine which permits the simultaneous application of heat and pressure.
• the process according to the invention permits the formation of all sorts of creases in textile articles other than woven cloths.
• the process according to the invention permits the formation of creases in knitted materials, laces, felts and generally in keratinic textile fibers assembled in any manner whatever.
• the process according to the invention is not limited to textile processes carried out using exclusively keratinic fibers such as wool, alpaca, camels hair or mohair, for treatment according to the invention may be possible even if these keratinic fibers are mixed with other natural, artificial or synthetic textile fibers.
• a process for permanently pressing textile articles containing wool fibers which comprises impregnating the textile with an aqueous solution containing 1-20 weight of I-S, q is equal to or 1 and p is equal to O or I, O is a radical of the formula percent of a polysulfhydrylated polymer selected from the group consisting of:
• hydrogen and -CH R is selected from the group consisting of hydrogen and -COOH, q is an integer

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• Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Life Sciences & Earth Sciences (AREA)
• Public Health (AREA)
• General Health & Medical Sciences (AREA)
• Veterinary Medicine (AREA)
• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Animal Behavior & Ethology (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• General Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Birds (AREA)
• Epidemiology (AREA)
• Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
• Cosmetics (AREA)

Applications Claiming Priority (2)

Publications (1)

Family

ID=26162201

Family Applications (1)

Country Status (4)

Cited By (10)

Families Citing this family (1)

• 1966
  • 1966-02-17 NL NL6602090A patent/NL6602090A/xx unknown
  • 1966-02-21 US US528762A patent/US3576592A/en not_active Expired - Lifetime
  • 1966-02-22 GB GB7732/66A patent/GB1101628A/en not_active Expired
  • 1966-02-23 DE DE19661619132 patent/DE1619132A1/de active Pending

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