US3566073A - Out-of-position automatic cored welding electrode - Google Patents
Out-of-position automatic cored welding electrode Download PDFInfo
- Publication number
- US3566073A US3566073A US718588A US3566073DA US3566073A US 3566073 A US3566073 A US 3566073A US 718588 A US718588 A US 718588A US 3566073D A US3566073D A US 3566073DA US 3566073 A US3566073 A US 3566073A
- Authority
- US
- United States
- Prior art keywords
- arc
- ingredients
- electrode
- barium
- halides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000003466 welding Methods 0.000 title claims abstract description 85
- 239000004615 ingredient Substances 0.000 claims abstract description 76
- 229910052751 metal Inorganic materials 0.000 claims abstract description 46
- 239000002184 metal Substances 0.000 claims abstract description 46
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910052788 barium Inorganic materials 0.000 claims abstract description 41
- 239000002893 slag Substances 0.000 claims abstract description 38
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 37
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims abstract description 37
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 11
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229910001634 calcium fluoride Inorganic materials 0.000 claims abstract description 11
- 239000010959 steel Substances 0.000 claims abstract description 11
- 238000012546 transfer Methods 0.000 claims abstract description 8
- 150000004820 halides Chemical class 0.000 claims description 35
- 239000000463 material Substances 0.000 claims description 32
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 25
- 229910052749 magnesium Inorganic materials 0.000 claims description 25
- 239000011777 magnesium Substances 0.000 claims description 25
- 229910001209 Low-carbon steel Inorganic materials 0.000 claims description 24
- 229910052782 aluminium Inorganic materials 0.000 claims description 24
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 24
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 18
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 18
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 18
- 229910052791 calcium Inorganic materials 0.000 claims description 18
- 239000011575 calcium Substances 0.000 claims description 18
- 239000010936 titanium Substances 0.000 claims description 18
- 229910052719 titanium Inorganic materials 0.000 claims description 18
- 229910052726 zirconium Inorganic materials 0.000 claims description 18
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 17
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 17
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 17
- 229910052744 lithium Inorganic materials 0.000 claims description 17
- 229910052783 alkali metal Inorganic materials 0.000 claims description 16
- 150000001340 alkali metals Chemical class 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 claims description 15
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 claims description 15
- 230000006872 improvement Effects 0.000 claims description 15
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 claims description 10
- 229910001632 barium fluoride Inorganic materials 0.000 claims description 10
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 6
- 238000005275 alloying Methods 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 229910000951 Aluminide Inorganic materials 0.000 claims description 3
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 claims description 3
- 229910002113 barium titanate Inorganic materials 0.000 claims description 3
- FVRNDBHWWSPNOM-UHFFFAOYSA-L strontium fluoride Chemical compound [F-].[F-].[Sr+2] FVRNDBHWWSPNOM-UHFFFAOYSA-L 0.000 claims description 3
- 229910001637 strontium fluoride Inorganic materials 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 2
- 230000005484 gravity Effects 0.000 abstract description 8
- 230000009471 action Effects 0.000 abstract description 3
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 17
- 230000004907 flux Effects 0.000 description 15
- 229910001018 Cast iron Inorganic materials 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 238000010561 standard procedure Methods 0.000 description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
- 239000000395 magnesium oxide Substances 0.000 description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 5
- 239000011324 bead Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001618 alkaline earth metal fluoride Inorganic materials 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910001422 barium ion Inorganic materials 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- CKRNPRFOXFWMGH-UHFFFAOYSA-K calcium;potassium;trifluoride Chemical compound [F-].[F-].[F-].[K+].[Ca+2] CKRNPRFOXFWMGH-UHFFFAOYSA-K 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 230000005288 electromagnetic effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- -1 fluoride Magnesium Calcium carbonate Magnesium oxide Aluminum Chemical compound 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003438 strontium compounds Chemical class 0.000 description 1
- 229910001427 strontium ion Inorganic materials 0.000 description 1
- PWYYWQHXAPXYMF-UHFFFAOYSA-N strontium(2+) Chemical compound [Sr+2] PWYYWQHXAPXYMF-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3601—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
- B23K35/3603—Halide salts
- B23K35/3605—Fluorides
Definitions
- This invention pertains to the art of electric arc-welding and, more particularly, to a cored-type welding electrode particularly intended for automatic out-of-position arc-welding.
- automatic By automatic is meant feeding a welding electrode of indefinite length longitudinally past an electric contact forming part of a welding head toward the workpiece to be welded and simultaneously advancing the electrode laterally to deposit a weld bead.
- the welding head may be either mechanically supported and sidewardly moved in which case the welding may be referred to as fully automatic welding" or manually held, in which case the welding is generally referredto as semiautomatic welding.”
- out-of-position is meant that the surface of the workpiece being welded is at an angle relative to an upwardly facing horizontal plane.
- the amount of out-of-position is determined by the angle of the workpiece relative to the horizontal; being upwardly facing horizontal-in which case the welding is termed downhand; 90 being vertical; and, l80 being downwardly facing horizontal in which case the welding is termed overhead.
- the arc melts both the workpiece to form a molten puddle and the electrode end to form molten droplets which continuously transfer across the arc gap, mix with the metal in the molten puddle and form a weld bead as the metal then rapidly solidifies.
- Means such as a granular flux, shielding gases or, and more recently, flux positioned inside of a cored or tubular electrode, are used to shield the are from the atmosphere.
- Cored-type welding electrodes are particularly desirable for out-of-position welding because they do not require externally supplied gases with the attendant pressurized containers, pressure regulator valves, etc. Nor do they require a bulky welding head and heavy hoses connecting the welding head with the containers which make holding the head in an elevated position for semiautomatic welding quite difficult. Cored-type welding electrodes also do not require the use of independently suppliedgranular fluxes which are-not only messy, but extremely difficult, if not impossible, to hold in place when the workpiece angle exceeds 45.
- a large part of out-of-position welding is performed on the thinner or light gauge sheet metals.
- Such metals require the use of relatively low arc currents, e.g., on the order of 50 to I00 amperes to prevent burnthrough of the metal.
- the arc is unstable and undefined and also has insufficient force to transfer the molten droplets from the electrode end to the molten weld pool against the force of gravity.
- Cored-type welding electrodes heretofore have worked best at the higher welding currents, e.g., from 300 to 500 amperes. Such currents present two problems as far as out-of-position welding is concerned. They are so high that welding cannot be performed on the thinner gauge metals without burnthrough.
- the higher currents melt so much metal that the amount of molten metal which exists at any one time is usually greater than that which the surface tension of the molten metal can hold in place.
- a cored-type electrode containing a flux comprised usually of oxides of one or more metals such as magnesium, titanium, zirconium, aluminum, silicon or the like; and at least one or more highly reactive deoxidizers (or killing agents) such as magnesium, titanium, zirconium, aluminum, silicon, calcium, lithium or the like; and at least one or more halides of the alkali and alkaline earth metal or aluminum fluoride was described and claimed in US Pat. No. 2,909,778 owned by the assignee of this application.
- the oxides need not always be employed so long as the deoxidizer provides an oxide in the slag system.
- the core of such electrode contains a slag forming and are protecting system cdmprised principally of calcium fluoride and highly reactive metals, such as magnesium and aluminum, which react with the oxygen in the air and in the weld metal to form oxides which would then become part of the slag system.
- a slag forming and are protecting system cdmprised principally of calcium fluoride and highly reactive metals, such as magnesium and aluminum, which react with the oxygen in the air and in the weld metal to form oxides which would then become part of the slag system.
- the present invention contemplates a cored-type electrode of this general type containing in addition, other ingredients which overcome all of the difficulties above referred to and enable a cored-type welding electrode to readily perform outof-position arc welds.
- an electrode of the type referred to has an additional and essential ingredient barium, and/or strontium and/or compounds thereof.
- a cored-type electrode has aslagfonning and arc-protecting system comprised principally of calcium fluoride, magnesium and aluminum and/or the oxides thereof and also contains as an additional and essential ingredient (s): barium and/or strontium and/or compounds thereof.
- the high-viscosity slag tends to provide a dam preventing the molten metal from running out of the weld pool under the force of gravity.
- the pinch effect provides a confining action on the are giving it force at the lower currents and assisting in the transfer of the molten metal from the electrode end .to a definite spot on the weld pool, thus, assisting the welder in following and laying down a narrow weld bead on the thinner gauge metals.
- the penetration is less resulting in less danger of burnthrough of the workpiece and also the amount of metal melted off is much less so that the amount of molten metal in the weld pool is less than or approaches that which the surface tension of the molten metal can hold in place against the force of gravity.
- the electrode also works well at the higher currents.
- the molten metal remained in position for approximately 0.09 minutes from the instant that the arc was struck to the instant that the mass of molten metal and slag fell away under the force of gravity.
- standard procedures The exact conditions under which these tests were performed are set forth in detail hereinafter and will be referred to herein as standard procedures.”
- the time will be referred to as the arc pool breakaway time.
- a cored electrode wherein the slag system has a viscosity such that the arc pool breakaway time under standard procedures is between 0.1 l and 0.40 minutes.
- a selfshielded flux cored welding electrode comprised of a tube of low carbon steel having on the inside thereof flux ingredients having the following range of weight percents of the total weight of the electrode.
- Cast iron powder is used to add carbon to the ingredients. Usually such carbon is present in the cast iron in amounts of from 2 to 6 percent. By balancing the amounts of iron powder and cast iron powder, the desired amounts of carbon may be added to the weld bead.
- the total weight percent of flux ingredients to total electrode weight is from 1 l percent to 35 percent, 13.5 percent to 22.0 percent is preferred.
- the principal object of the present invention is the provision of a new and improved cored-type welding electrode which readily welds in all positions.
- Another object of the invention is the provision of a new and improved cored welding electrode wherein the slag has a substantially higher viscosity than previously known electrodes.
- Still another object of the invention is the provision of a new and improved cored welding electrode wherein in addition to the usual shielding ingredients, barium, strontium or a compound of barium or strontium is included for the purpose of increasing the molten slag viscosity.
- Another object of the invention is the provision of a coredtype welding electrode which when fed toward a spot on A- inch steel at a 90 angle at 22 volts and 250 amperes provides a molten pool of steel and slag which remains in position for at least 0.11 minutes.
- Another object is the provision of an automatic cored electrode which will weld satisfactorily at lower arc currents than heretofore.
- Another object of the invention is a cored electrode for automatic welding capable of welding all thicknesses of metal including sheet metal in all electrode positions.
- Still another object is the provision of a welding electrode for automatic welding which will weld sheet metal in out-ofposition.
- the invention may take physical form in certain welding electrodes and slag systems and the characteristics thereof as defined by certain test procedures which are illustrated in the accompanying drawing, which forms a part hereof and wherein:
- FIG. 1 is a side elevational view of a short length of a welding electrode with portions broken away illustrating a preferred embodiment of the invention
- FIG. 2 shows a view somewhat schematic of the test apparatus used in connection with the present invention.
- FIG. 3 is a graph showing the arc pool breakaway time obtained with various electrodes plotted against the out-of-position angle of the workpiece surface.
- FIG. 1 shows a welding electrode E comprised of a tube 10 of steel having on the inside thereof in tightly compacted condition welding ingredients 11 of a formulation in accordance with the present invention, which will produce a slag system of the desired viscosity.
- the tube 10 is preferably made from ordinary low carbon or mild steel, as is conventional in the welding art. It may either be a seamless tube or it may be made from a ribbon having its edges 12 in overlapping, or as shown and preferably in abutting relationship.
- the electrode of FIG. 1 is manufactured by: providing the various flux ingredients to be described hereinafter in the proper weights and carefully blending them so that they are uniformly distributed throughout the entire mass; providing the steel in the form of a U-shaped ribbon of generally uniform thickness; filling the U with the blended flux ingredients to the desired weight percentage; bringing the ends of the U together to form a tube; and then drawing the tube to the desired final diameter.
- This drawing operation compacts all of the flux ingredients 11 on the inside of the tube together and prevents the various ingredients from becoming segregated as a result of vibration caused by handling of the electrode, either in shipment or in use.
- the diameter of the electrode may be as desired, e.g. from one thirty-second inch to five thirty-second inch. Preferred diameters are one-sixteenth through one-eighth inch.
- the wall thickness of the preferred electrode is such as to have a crosssectional area equivalent to a solid electrode of .058 to three thirtysecond inches in diameter.
- FIG. 2 illustrates a standard test apparatus and procedures developed in connection with the present invention for defining a slag system having a viscosity coming within the scope of the invention. So that this apparatus and procedure may be readily duplicated for future comparison purposes, and for determining infringement, it will be described in considerable detail and will be referred to hereinafter and in the claims as standard procedures.
- the apparatus consists of a table 20 having a workpiece facing surface 21.
- the opposite surface has a leg 22 pivoted by a horizontally extending shaft 24 to a vertically-extending fixed leg 23.
- Clamping means 25 are provided for clamping the table 20 at any desired angle so that the surface 21 can be moved from 0 when it is horizontal and upwardly facing to when it is vertical.
- the table 20 is shown in solid lines in the 45 position and in phantom lines in the 90 position.
- the workpiece W consists of a flat plate of mild steel having a thickness of one-fourth inch, a width of 2 inches, and a length of 18 inches.
- the workpiece W is mounted in spaced relationship to the surface 21 by copper blocks having a width of 3 inches, a thickness of three-eighth inch, and length of 1 inch. These blocks are mounted between the workpiece W and the table 20 so that their long edge is flush with the ends of the workpiece W.
- Clamps C are employed for the purpose of holding the workpiece W in firm heat-conducting and electrical conducting relationship with the blocks 30.
- the electrode E feeding and energizing apparatus is a conventional handheld welding gun and is shown somewhat schematically as consisting of a pair of electrode feed rolls 35 driven by an electric motor M which can be adjusted to any desired speed, and when once adjusted will operate continuously at such speed.
- the rolls 35 advance the electrode E past contacts 36, the ends of which are spaced a distance of 1% inches from the surface of the workpiece W. This distance is known as the electrical stick out.
- the electrode used in the standard procedures was a five sixty-fourth diameter cored-type electrode as previously described above.
- a direct current generator G has its negative terminal connectedto the contacts 36 and its positive terminal connected to the workpiece W. No provision is made for advancing the electrode sidewardly relative to the workpiece. In other words, the tests to prove the invention simply involve advancing the electrode E towards a single spot on the workpiece W. The arc pool breakaway time commenced with the striking of the arc and stopped when the molten pool fell away fromthe spot under the force of gravity.
- he generator used was a standard SAF 300-F 162 gas engine welding generator manufactured by The Lincoln Electric Company of Cleveland, Ohio, the assignee of this application.
- the generator voltage-ampere curve was such that at no current the open circuit voltage at the terminals was 30 volts, at 250 amperes the voltage was 22 volts, and at short circuit the current was 750 amperes.
- the electrode E to be tested was inserted and fed toward a specimen workpiece and the proper adjustments of the speed of the motor M made so that the welding current was 250 amperes as measured on a standard meter.
- the workpiece W at room temperature was clamped on the worktable, as shown, and the table then moved to the desired angle.
- the electrode E was then fed on a line of movement at right angles to the surface of the workpiece W toward a single spot.
- the timing started and thereafter the molten slag and metal were allowed to build up.
- the slag formed a circular dam surrounding and supporting the molten metal as a puddle in the middle.
- Curve 50 is the curve of an electrode manufactured by The Lincoln Electric Company, the assignee of this application under the trademark NS-3M, and was the best curve of any electrode then obtainable.
- the maximum arc pool breakaway time obtainable was 0.09 minutes, which time increased but slightly as the outof-position angle was decreased until the out-of-position angle was approximately 60, at which time the time increased substantially.
- the arc pool breakaway time of curve 50 is unsatisfactory for welding'in the 90 of out-of-position angle.
- Curve 52 shows the results obtained with electrode V, it being noted that the time at the 90 out-of-position angle is approximately 144 percent greater than the time in minutes of curve 50 which, as stated, was the best electrode then known for this purpose.
- the slag system of electrode V is more viscous, such that welding with it becomes somewhat more difficult in some applications. lt.is believed the upper limit of viscosity for the usual applications will be about 0.40 minutes at 90 from the horizontal.
- the total weight percent of the flux ingredients to the total electrode weight can vary from 11 percent to 35 percent, but 13.5 percent to 22.0 percent is preferred.
- Electrode IV Barium tetra aluminide 1. 02
- Electrode VII Another formulation which has worked satisfactorily is as follows:
- the barium fluoride is employed as the shielding medium.
- calcium fluoride is principally employed as the shielding medium.
- the magnesium and aluminum function as deoxidizers while their oxides contribute to the slag viscosity along with the barium or strontium compound which is employed both for the purpose of increasing the viscosity of the slag as well as giving a pinch effect on the molten metal as it forms on the electrode end forcing it to transfer to the workpiece in small droplets. It is apparent from a study of curves 53 and 54 in relation to curves 51 and 52 that barium fluoride alone will not accomplish the desired results.
- the higher viscosity results from the combination of all the compounds in the slag system, e.g., calcium fluoride, aluminum oxide, magnesium oxide, and the barium or strontium ion, it being known that the heat distribution in the arc, the freezing temperatures and the viscosity of a molten slag mixture will vary with changes in the relative proportions of the various elements or compounds as contained therein.
- the compounds in the slag system e.g., calcium fluoride, aluminum oxide, magnesium oxide, and the barium or strontium ion
- a still further em bodiment of the invention is as follows:
- An arc-welding electrode comprised of a tube of mild steel having on the inside thereof as major ingredients 0.34- 5.56 of one or more highly reactive deoxidizer (s) taken from the class consisting of magnesium, aluminum, zirconium, titanium, calcium, lithium, and the like; l.l912.4l of one or more materials selected from the class consisting of calcium fluoride, the halides of the alkali metals and the alkaline earth metals other than barium and strontium and/or materials capable of breaking down or combining in the heat of the arc to form such halides; and barium and/or strontium and/or compounds thereof in the amounts of l 7-5. l 0.
- highly reactive deoxidizer s
- l.l912.4l of one or more materials selected from the class consisting of calcium fluoride, the halides of the alkali metals and the alkaline earth metals other than barium and strontium and/or materials capable of breaking down or combining in the heat of the arc to form such
- An arc-welding electrode comprised of a tube of mild steel having on the inside thereof as major ingredients one or more highly reactive deoxidizer(s) taken from the class consisting of magnesium, aluminum, zirconium, titanium, calcium, lithium and the like; one or more materials selected from the class consisting of aluminum fluoride, the halides of alkali metals and the alkaline earth metals other than barium and strontium and/or materials capable of breaking down or combining in the heat of the arc to form such halides; the improvement which comprises barium and/or strontium and/or compounds thereof, said ingredients being comprised of the following elements or compounds in percent weight of the total electrode weight:
- An arc welding electrode comprised of a tube of mild steel having on the inside thereof ingredients comprised of the following elements or compounds in percent weight of the total electrode weight:
- the weight of said flux ingredients to the weight of said electrode being 1 l 35 percent.
- An arc-welding electrode comprised of a tube of mild steel having on the inside thereof as major ingredients one or more highly reactive deoxidizer(s) taken from the class consisting of magnesium, aluminum, zirconium, titanium, calcium, lithium and the like; one or more materials selected from the class consisting of aluminum fluoride, the halides of alkali metals and the alkaline earth metals other than barium and strontium and/or materials capable of breaking down or combining in the heat of the arc to form such halides; the improvement which comprises incorporating in said ingredients barium fluoride.
- An arc welding electrode comprised of a tube of mild steel having on the inside thereof as major ingredients one or more highly reactive deoxidizer(s) taken from the class consisting of magnesium, aluminum, zirconium, titanium, calcium, lithium and the like; one or more materials selected from the class consisting of aluminum fluoride, the halides of alkali metals and the alkaline earth metals other than barium and strontium and/or materials capable of breaking down or combining in the heat of the arc to form such halides; the improvement which comprises incorporating in said ingredients barium titanate.
- An arc-welding electrode comprised of a tube of mild steel having on the inside thereof as major ingredients one or more highly reactive deoxidizer(s) taken from the class consisting of magnesium, aluminum, zirconium, titanium, calcium, lithium and the like, one or more materials selected from the class consisting of aluminum fluoride, the halides of alkali metals and the alkaline earth metals other than barium and strontium and/or materials capable of breaking down or combining in the heat of the arc to form such halides; the improvement which comprises incorporating in said ingredients barium carbonate.
- An arc-welding electrode comprised of a tube of mild steel having on the inside thereof as major ingredients one or more highly reactive deoxidizer(s) taken from the class consisting of magnesium, aluminum, zirconium, titanium, calcium, lithium and the like; one or more materials selected from the class consisting of aluminum fluoride, the halides of alkali metals and the alkaline earth metals other than barium and strontium and/or materials capable of breaking down or combining in the heat of the arc to form such halides; the improvement which comprises incorporating in said ingredients barium tetra aluminide.
- An arc-welding electrode comprised of a tube of mild steel having on the inside thereof as major ingredients one or more highly reactive deoxidizer(s) taken from the class consisting of magnesium, aluminum, zirconium, titanium, calcium, lithium and the like; one or more materials selected-from the class consisting of aluminum fluoride, the halides of alkali metals and the alkaline earth metals other than barium and strontium and/or materials capable of breaking down or combining in the heat of the arc to form such halides; the improvement'which comprises incorporating in said ingredients strontium fluoride.
- An arc-welding electrode comprised of a tube of mild steel having on the inside thereof as major ingredients one or more highly reactive deoxidizer(s) taken from the class consisting of magnesium, aluminum, zirconium, titanium, calcium, lithium and the like; one or more materials selected from the class consisting of aluminum fluoride, the halides of alkali metals and the alkaline earth metals other-than barium and strontium andlor materials capable of'breaking down or combining in the heat of the arc to form such halides; the improvement which comprises barium and/or strontium and/or compounds thereof, said electrode having an arc pool breakaway time under standard conditions between 0.11 and 0.40
- An arc-welding electrode comprised of a tube of mild steel having on the inside thereof ingredients approximately as follows:
- a method of out-of-position arc-welding a steel workpiece which comprises: feeding a self-shielded consumable electrode comprised of a metal steel tube containing slagforming ingredients including at least one member from the group consisting of barium, strontium and compounds thereof in small effective amounts to stabilize arcs at low currents and to provide viscous s'lags during welding; and passing current between said workpiece and said electrode to establish an arc, which melts aportion of said workpiece to form an arc pool and which melts and transfers metal and slag-forming ingredients from said electrode to said are pool to produce a viscous slag over the arc pool to provide a breakaway time in excess of 0.11 minute as determined for an electrode five sixty-fourth inch in diameter and melted againsta plate inthe position under standard-conditions.
- the weight of said flux ingredients to the weight of said electrode being 11 35 percent.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Nonmetallic Welding Materials (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US71858868A | 1968-04-03 | 1968-04-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3566073A true US3566073A (en) | 1971-02-23 |
Family
ID=24886654
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US718588A Expired - Lifetime US3566073A (en) | 1968-04-03 | 1968-04-03 | Out-of-position automatic cored welding electrode |
Country Status (5)
Country | Link |
---|---|
US (1) | US3566073A (enrdf_load_stackoverflow) |
BE (1) | BE730986A (enrdf_load_stackoverflow) |
DE (1) | DE1916838C3 (enrdf_load_stackoverflow) |
FR (1) | FR2005469A1 (enrdf_load_stackoverflow) |
GB (1) | GB1268827A (enrdf_load_stackoverflow) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3883713A (en) * | 1973-04-25 | 1975-05-13 | Samuil Gurevich | Flux cored electrode |
US3924091A (en) * | 1970-08-12 | 1975-12-02 | Nippon Steel Corp | Welding method and materials |
US4139758A (en) * | 1976-01-12 | 1979-02-13 | Pinfold Brian E | Method of arc welding under water |
US4186293A (en) * | 1978-05-08 | 1980-01-29 | The Lincoln Electric Company | Cored type welding electrode |
JPS5942198A (ja) * | 1982-08-31 | 1984-03-08 | Kobe Steel Ltd | セルフシ−ルドア−ク溶接用フラツクス入りワイヤ |
JPH0275495A (ja) * | 1988-09-07 | 1990-03-15 | Kobe Steel Ltd | セルフシールドアーク溶接フラックス入りワイヤ |
JPH0284295A (ja) * | 1988-09-21 | 1990-03-26 | Kobe Steel Ltd | セルフシールドアーク溶接フラックス入りワイヤ |
US5155333A (en) * | 1990-07-24 | 1992-10-13 | Kabushiki Kaisha Kobe Seiko Sho | Low hydrogen type coated electrode |
US20060070983A1 (en) * | 2004-10-06 | 2006-04-06 | Lincoln Global, Inc. | Method of AC welding with cored electrode |
US20060096966A1 (en) * | 2004-11-08 | 2006-05-11 | Lincoln Global, Inc. | Self-shielded flux cored electrode for fracture critical applications |
US20060219685A1 (en) * | 2005-04-05 | 2006-10-05 | Lincoln Global, Inc., A Corporation Of The State Of Delaware | Flux cored electrode with fluorine |
EP1743730A1 (en) * | 2005-07-12 | 2007-01-17 | Lincoln Global, Inc. | Barium and lithium ratio for flux cored electrode |
US20070095807A1 (en) * | 2005-10-31 | 2007-05-03 | Lincoln Global, Inc. | Short arc welding system |
US20070102406A1 (en) * | 2004-04-29 | 2007-05-10 | Lincoln Global, Inc. | Electric arc welder system with waveform profile control for cored electrodes |
US20070108174A1 (en) * | 2004-04-29 | 2007-05-17 | Lincoln Global, Inc. | Gas-less process and system for girth welding in high strength applications |
US20070170163A1 (en) * | 2006-01-20 | 2007-07-26 | Lincoln Global, Inc. | Synergistic welding system |
US10421160B2 (en) | 2013-03-11 | 2019-09-24 | The Esab Group, Inc. | Alloying composition for self-shielded FCAW wires with low diffusible hydrogen and high Charpy V-notch impact toughness |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3778589A (en) * | 1972-07-31 | 1973-12-11 | Union Carbide Corp | Air operating cored wire |
DE3233751A1 (de) * | 1982-09-11 | 1984-03-15 | Messer Griesheim Gmbh, 6000 Frankfurt | Zusatzwerkstoff mit leicht oxidierbaren elementen |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2731373A (en) * | 1954-08-10 | 1956-01-17 | Eutectic Welding Alloys | Electrode flux covering for copper and copper-base alloy core materials |
US3177340A (en) * | 1961-11-24 | 1965-04-06 | Soudure Electr Autogene Sa | Flux-cored electrode and process of welding |
-
1968
- 1968-04-03 US US718588A patent/US3566073A/en not_active Expired - Lifetime
-
1969
- 1969-04-02 GB GB07193/69A patent/GB1268827A/en not_active Expired
- 1969-04-02 DE DE1916838A patent/DE1916838C3/de not_active Expired
- 1969-04-02 FR FR6910148A patent/FR2005469A1/fr active Pending
- 1969-04-03 BE BE730986D patent/BE730986A/xx not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2731373A (en) * | 1954-08-10 | 1956-01-17 | Eutectic Welding Alloys | Electrode flux covering for copper and copper-base alloy core materials |
US3177340A (en) * | 1961-11-24 | 1965-04-06 | Soudure Electr Autogene Sa | Flux-cored electrode and process of welding |
Cited By (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3924091A (en) * | 1970-08-12 | 1975-12-02 | Nippon Steel Corp | Welding method and materials |
US3883713A (en) * | 1973-04-25 | 1975-05-13 | Samuil Gurevich | Flux cored electrode |
US4139758A (en) * | 1976-01-12 | 1979-02-13 | Pinfold Brian E | Method of arc welding under water |
US4186293A (en) * | 1978-05-08 | 1980-01-29 | The Lincoln Electric Company | Cored type welding electrode |
JPS5942198A (ja) * | 1982-08-31 | 1984-03-08 | Kobe Steel Ltd | セルフシ−ルドア−ク溶接用フラツクス入りワイヤ |
JPH0275495A (ja) * | 1988-09-07 | 1990-03-15 | Kobe Steel Ltd | セルフシールドアーク溶接フラックス入りワイヤ |
JPH0284295A (ja) * | 1988-09-21 | 1990-03-26 | Kobe Steel Ltd | セルフシールドアーク溶接フラックス入りワイヤ |
US5155333A (en) * | 1990-07-24 | 1992-10-13 | Kabushiki Kaisha Kobe Seiko Sho | Low hydrogen type coated electrode |
US9333580B2 (en) | 2004-04-29 | 2016-05-10 | Lincoln Global, Inc. | Gas-less process and system for girth welding in high strength applications |
US20070108174A1 (en) * | 2004-04-29 | 2007-05-17 | Lincoln Global, Inc. | Gas-less process and system for girth welding in high strength applications |
US20070102406A1 (en) * | 2004-04-29 | 2007-05-10 | Lincoln Global, Inc. | Electric arc welder system with waveform profile control for cored electrodes |
US20060070983A1 (en) * | 2004-10-06 | 2006-04-06 | Lincoln Global, Inc. | Method of AC welding with cored electrode |
US9956638B2 (en) | 2004-10-06 | 2018-05-01 | Lincoln Global, Inc. | Electric arc welder for AC welding with cored electrode |
US8759715B2 (en) | 2004-10-06 | 2014-06-24 | Lincoln Global, Inc. | Method of AC welding with cored electrode |
US20060096966A1 (en) * | 2004-11-08 | 2006-05-11 | Lincoln Global, Inc. | Self-shielded flux cored electrode for fracture critical applications |
US7829820B2 (en) * | 2005-04-05 | 2010-11-09 | Lincoln Global, Inc. | Flux cored electrode with fluorine |
US20060219685A1 (en) * | 2005-04-05 | 2006-10-05 | Lincoln Global, Inc., A Corporation Of The State Of Delaware | Flux cored electrode with fluorine |
US7812284B2 (en) | 2005-07-12 | 2010-10-12 | Lincoln Global, Inc. | Barium and lithium ratio for flux cored electrode |
US20070012673A1 (en) * | 2005-07-12 | 2007-01-18 | Lincoln Global, Inc. | Barium and lithium ratio for flux cored electrode |
EP1743730A1 (en) * | 2005-07-12 | 2007-01-17 | Lincoln Global, Inc. | Barium and lithium ratio for flux cored electrode |
US20070095807A1 (en) * | 2005-10-31 | 2007-05-03 | Lincoln Global, Inc. | Short arc welding system |
US7842903B2 (en) | 2005-10-31 | 2010-11-30 | Lincoln Global, Inc. | Short arc welding system |
US20070170163A1 (en) * | 2006-01-20 | 2007-07-26 | Lincoln Global, Inc. | Synergistic welding system |
US8704135B2 (en) | 2006-01-20 | 2014-04-22 | Lincoln Global, Inc. | Synergistic welding system |
US10421160B2 (en) | 2013-03-11 | 2019-09-24 | The Esab Group, Inc. | Alloying composition for self-shielded FCAW wires with low diffusible hydrogen and high Charpy V-notch impact toughness |
US11648630B2 (en) | 2013-03-11 | 2023-05-16 | The Esab Group, Inc. | Alloying composition for self-shielded FCAW wires |
Also Published As
Publication number | Publication date |
---|---|
DE1916838B2 (de) | 1977-12-15 |
DE1916838C3 (de) | 1978-08-03 |
FR2005469A1 (enrdf_load_stackoverflow) | 1969-12-12 |
BE730986A (enrdf_load_stackoverflow) | 1969-09-15 |
DE1916838A1 (de) | 1969-10-09 |
GB1268827A (en) | 1972-03-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3566073A (en) | Out-of-position automatic cored welding electrode | |
US3947655A (en) | Cored type electrode welding | |
US5132514A (en) | Basic metal cored electrode | |
US5225661A (en) | Basic metal cored electrode | |
US4463243A (en) | Welding system | |
US2282175A (en) | Welding flux | |
US3585352A (en) | Arc welding process and electrode for stainless steel | |
US3778588A (en) | Self-shielding cored wire to weld cast iron | |
US4149063A (en) | Flux cored wire for welding Ni-Cr-Fe alloys | |
CA2436445C (en) | Flux-cored wire formulation for welding | |
US3542998A (en) | Cored electrode for welding in air | |
EP0231570B1 (en) | Weld bead composition and electrode for producing same | |
US3558851A (en) | Special welding electrodes | |
US3560702A (en) | Composite electrode for consumable electrode arc welding process | |
US3843867A (en) | Process for out-of-position welding | |
US4368371A (en) | Process for the submerged-arc welding of light metals such as aluminum and aluminum alloys | |
US3223818A (en) | Method of welding | |
US3221136A (en) | Method and electrode for electric arc welding | |
US3778589A (en) | Air operating cored wire | |
US4021637A (en) | Flux-cored wires for electrogas welding | |
US3818178A (en) | Gas shielded core wire electrode | |
US3825721A (en) | Electrode for vertical-up open arc welding using molding shoes | |
EP0958098B1 (en) | Multi-purpose, multi-transfer, multi-position shielding gas for arc welding | |
US3272667A (en) | Submerged arc welding process and flux composition utilizing fluorocarbon | |
US3491225A (en) | Special welding electrodes |