US3556290A - Long life packaging of electrolytic recording paper and the like - Google Patents
Long life packaging of electrolytic recording paper and the like Download PDFInfo
- Publication number
- US3556290A US3556290A US729478A US3556290DA US3556290A US 3556290 A US3556290 A US 3556290A US 729478 A US729478 A US 729478A US 3556290D A US3556290D A US 3556290DA US 3556290 A US3556290 A US 3556290A
- Authority
- US
- United States
- Prior art keywords
- parts
- paper
- package
- recording paper
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004806 packaging method and process Methods 0.000 title abstract description 5
- 239000003792 electrolyte Substances 0.000 claims abstract description 31
- 239000004615 ingredient Substances 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- 238000005470 impregnation Methods 0.000 claims description 8
- 238000007789 sealing Methods 0.000 claims description 7
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 5
- 230000009977 dual effect Effects 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 235000010333 potassium nitrate Nutrition 0.000 claims description 3
- 239000004323 potassium nitrate Substances 0.000 claims description 3
- 235000010344 sodium nitrate Nutrition 0.000 claims description 3
- 239000004317 sodium nitrate Substances 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 235000011008 sodium phosphates Nutrition 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 230000006866 deterioration Effects 0.000 abstract description 3
- 238000005868 electrolysis reaction Methods 0.000 abstract description 2
- 239000007769 metal material Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- -1 pyrocatechin Chemical class 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/32—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
- B65D81/3261—Flexible containers having several compartments
- B65D81/3266—Flexible containers having several compartments separated by a common rupturable seal, a clip or other removable fastening device
Definitions
- Barber ABSTRACT The impregnants for electrolytic recording paper are divided into two or more parts thereby separating parts which may react with time, and/or be oxidized by atmosphere or light from those used to cause other reactions when in contact with metallic substances, which may ionize in an electrolyte, resulting in a long life package. Not only may there be electrolysis, but there may also be reactions with the paper or extraneous ingredients in the paper. Paper and electrolyte packaged in this manner will not only keep for long periods but will also withstand very severe environmental conditions without change or deterioration. Such packaging is of a special utility in military applications.
- the moisture content of the paper for storage may be reduced to a low value to further promote stability but should not be reduced so far as to render the paper brittle or easily damaged.
- Another way of greatly increasing the useful life of electrolytic recording paper is to impregnate the paper completely, drive off substantially all the moisture for storage purposes and prior to marking, to restore the optimum water content by merely putting back the proper amount of water.
- FIG. 1 is a view in perspective of one form of dual package for electrolytic recording paper and electrolyte in accordance with one form of the present invention.
- FIG. 2 is a view in perspective of a form of core for the paper roll useful in connection with the present invention.
- FIG. 3 is a view in perspective of a second form of the present invention.
- FIG. 4 is a view of a second form of closure which may be employed as sealing means between the'two parts of the package which provides a third enclosure useful for enclosing anindicator which shows whether or not there has been leakage between the main packages.
- FIG. 5 is a plan view of a paper roll suitable for use in accordance with the. present invention wherein the paper roll is coreless.
- FIG. 1 shows a roll of electrolytic recording paper or the like 1 wound on a suitablecore 2 (although coreless paper rolls may also be used as shown in FIG. 5) and enclosed in a first portion 3 of a two-part sealed package.
- the second part of the package 6 contains an electrolytic solution 7, an end seal 9 and a clamp 4-5 effectively separating the two portions or parts of the package and preventing electrolyte 7 from reaching paper 1 until clamp 4-5 is removed.
- the electrolyte 7 in the second part of the package contains the marking compounds such as pyrocatechin, a stabilizer such as thiourea, and an optional wetting agent to promote diffusion of the electrolyte when it comes in contact with the paper and sufficient water to produce optimum moisture content of the impregnated paper when the marking compound plus stabilizer (such as thiourea is released into the paper-containing part of the package and when the electrolyte has been absorbed by the paper.
- the marking compound plus stabilizer such as thiourea is released into the paper-containing part of the package and when the electrolyte has been absorbed by the paper.
- the exact amount will depend on the characteristics of the paper and the desired final moisture content.
- electrolytic paper can be stored for prolonged periods without discoloration and, in particular, that environmental conditions such as elevated temperatures can also be tolerated without color change of the stored paper or deterioration or chemical reaction of the ingredients of the electrolyte and paper impurity reactions.
- the clamp 4-5 may be removed and electrolyte 7 allowed to penetrate the paper roll 1. As soon as this penetration is complete, the package may be opened and the paper placed in the facsimile recorder or similar marking device ready for use.
- FIG. 3 Another method of greatly prolonging the useful life of electrolytic-recording paper is to impregnate the paper with all of the various marking compounds and then to remove the water content as by vacuum drying whereupon the paper is sealed and may be stored for long periods.
- the second part of FIG. 3 is a modified form of two-part package in which a large outer package 10 sealed along one end at 11 contains the paper roll 1-2 treated as described above and a second package 13 containing the electrolyte 14 as described above and sealed along one end at 15. When the time comes to complete the impregnation of the paper, the second package 13 is ruptured allowing the electrolyte 14 to complete the impregnation whereupon the paper is ready for use and the outer package 10 may be opened.
- FIG. 4 shows a modified form of package in which the neck 16-26 from one part of the package to the other is closed by a first clamp 17-18-19-20 and a second clamp 22-23-24-25 or a dual clamp provided by connecting the two as at 27 leaving a small pocket 21 therebetween.
- This third pocket may contain an indicator such as litmus compounds which changes color when in contact with the electrolyte. Thus, if any of the electrolyte leaks past one of the clamps, the indicator will change color showing that this leakage has taken place.
- This provision is a means for showing the condition inside the two parts of the package.
- FIG. 5 shows a paper roll 1 produced to be coreless, that is the inner opening 28 of the roll is mainly self-supporting.
- end plugs 29 and 30 may be provided for mounting the paper roll in the recording machine. Where such end plugs are used, they are provided with openings 31 and 32 to permit electrolyte to pass into the inside of the roll to speed impregnation.
- said roll of paper is impregnated with a solution comprising a predetermined selection from the ingredients making up an electrolytic marking solution exclusive of marking compounds and a solution of the balance of the ingredients of said solution comprising said electrolyte in the second of said parts.
- an electrolyte including a marking compound along with a
- an electrolytic recording paper package the combination of:
- a two part package means for sealing one of said parts from the other; a recording paper roll impregnated with a salt chosen from the l group comprising sodium nitrate and potassium nitrate, sodium phosphate, and oxalic acid sufficient to provide pH of the order of 3 to 5 and enough water to provide a predetermined moisture content contained in one of said parts; and an electrolyte comprising a marking compound, a stabilizer, a wetting agent and sufficient water to provide a v predetermined liquid content to said electrolytic recording paper in combination with said predetermined moisture content contained in the second of said parts.
- a salt chosen from the l group comprising sodium nitrate and potassium nitrate, sodium phosphate, and oxalic acid sufficient to provide pH of the order of 3 to 5 and enough water to provide a predetermined moisture content contained in one of said parts
- an electrolyte comprising a marking compound, a stabilizer, a wetting agent and sufficient water to provide a v predetermined liquid content to said electrolytic
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Paper (AREA)
- Packages (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US72947868A | 1968-04-17 | 1968-04-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3556290A true US3556290A (en) | 1971-01-19 |
Family
ID=24931220
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US729478A Expired - Lifetime US3556290A (en) | 1968-04-17 | 1968-04-17 | Long life packaging of electrolytic recording paper and the like |
Country Status (4)
Country | Link |
---|---|
US (1) | US3556290A (enrdf_load_stackoverflow) |
DE (1) | DE1919168A1 (enrdf_load_stackoverflow) |
FR (1) | FR2006382A1 (enrdf_load_stackoverflow) |
GB (1) | GB1232548A (enrdf_load_stackoverflow) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4805767A (en) * | 1987-06-18 | 1989-02-21 | Newman Duncan A C | Package system |
US5951160A (en) * | 1997-11-20 | 1999-09-14 | Biomet, Inc. | Method and apparatus for packaging, mixing and delivering bone cement |
US20080202962A1 (en) * | 2007-02-23 | 2008-08-28 | Brouard Roger H | Tool bag |
US7717257B1 (en) * | 2006-05-02 | 2010-05-18 | Henkel Corporation | Multi-section package for a mold release agent and a wipe |
EA016989B1 (ru) * | 2009-11-26 | 2012-08-30 | Открытое Акционерное Общество "Смит-Ярцево" | Пленочный контейнер-смеситель реактивов и зажим для пленочного контейнера-смесителя |
CN106628648A (zh) * | 2015-07-28 | 2017-05-10 | 李和伟 | 一种改性膜布的新型包装装置 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2229700A (en) * | 1989-03-31 | 1990-10-03 | Graham Lowe | Packaging for hair products etc |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1857126A (en) * | 1929-09-18 | 1932-05-10 | Siemens Ag | Chemical picture telegraphy receiver |
US2111776A (en) * | 1936-06-05 | 1938-03-22 | Radio Inventions Inc | Recording paper system |
US2339267A (en) * | 1940-04-15 | 1944-01-18 | Faximile Inc | Electrolytic recording |
US2358839A (en) * | 1940-10-25 | 1944-09-26 | Faximile Inc | Electrolytic recording |
GB686449A (en) * | 1949-05-23 | 1953-01-28 | Smith & Nephew | Improvements in and relating to medical or surgical bandages |
US3120662A (en) * | 1957-05-24 | 1964-02-04 | Timefax Corp | Facsimile recording on dry electrolytic blanks |
US3149943A (en) * | 1961-11-20 | 1964-09-22 | Martin R Amador | Chemical refrigerant package |
US3250384A (en) * | 1964-01-27 | 1966-05-10 | Milprint Inc | Multiple layer rupturable packaging film and containers therefrom |
US3392826A (en) * | 1967-01-19 | 1968-07-16 | Roy Y. Powlan | Surgical plaster dressing package |
US3393796A (en) * | 1965-12-08 | 1968-07-23 | Minnesota Mining & Mfg | Packaged article and method of packaging |
-
1968
- 1968-04-17 US US729478A patent/US3556290A/en not_active Expired - Lifetime
-
1969
- 1969-04-14 GB GB1232548D patent/GB1232548A/en not_active Expired
- 1969-04-16 DE DE19691919168 patent/DE1919168A1/de active Pending
- 1969-04-17 FR FR6911975A patent/FR2006382A1/fr not_active Withdrawn
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1857126A (en) * | 1929-09-18 | 1932-05-10 | Siemens Ag | Chemical picture telegraphy receiver |
US2111776A (en) * | 1936-06-05 | 1938-03-22 | Radio Inventions Inc | Recording paper system |
US2339267A (en) * | 1940-04-15 | 1944-01-18 | Faximile Inc | Electrolytic recording |
US2358839A (en) * | 1940-10-25 | 1944-09-26 | Faximile Inc | Electrolytic recording |
GB686449A (en) * | 1949-05-23 | 1953-01-28 | Smith & Nephew | Improvements in and relating to medical or surgical bandages |
US3120662A (en) * | 1957-05-24 | 1964-02-04 | Timefax Corp | Facsimile recording on dry electrolytic blanks |
US3149943A (en) * | 1961-11-20 | 1964-09-22 | Martin R Amador | Chemical refrigerant package |
US3250384A (en) * | 1964-01-27 | 1966-05-10 | Milprint Inc | Multiple layer rupturable packaging film and containers therefrom |
US3393796A (en) * | 1965-12-08 | 1968-07-23 | Minnesota Mining & Mfg | Packaged article and method of packaging |
US3392826A (en) * | 1967-01-19 | 1968-07-16 | Roy Y. Powlan | Surgical plaster dressing package |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4805767A (en) * | 1987-06-18 | 1989-02-21 | Newman Duncan A C | Package system |
US5951160A (en) * | 1997-11-20 | 1999-09-14 | Biomet, Inc. | Method and apparatus for packaging, mixing and delivering bone cement |
US7717257B1 (en) * | 2006-05-02 | 2010-05-18 | Henkel Corporation | Multi-section package for a mold release agent and a wipe |
US20080202962A1 (en) * | 2007-02-23 | 2008-08-28 | Brouard Roger H | Tool bag |
EA016989B1 (ru) * | 2009-11-26 | 2012-08-30 | Открытое Акционерное Общество "Смит-Ярцево" | Пленочный контейнер-смеситель реактивов и зажим для пленочного контейнера-смесителя |
CN106628648A (zh) * | 2015-07-28 | 2017-05-10 | 李和伟 | 一种改性膜布的新型包装装置 |
Also Published As
Publication number | Publication date |
---|---|
GB1232548A (enrdf_load_stackoverflow) | 1971-05-19 |
DE1919168A1 (de) | 1969-10-23 |
FR2006382A1 (enrdf_load_stackoverflow) | 1969-12-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3480402A (en) | Time indicator | |
US3556290A (en) | Long life packaging of electrolytic recording paper and the like | |
US6666988B2 (en) | Methods of using an oxygen scavenger | |
US4169811A (en) | Oxygen indicator | |
US4502605A (en) | Container closure integrity system | |
US2270603A (en) | Humidification of goods and air conditioning of containers | |
JPS6132951A (ja) | 密閉型鉛蓄電池 | |
US5215192A (en) | Method for improving the archival properties of processed photographic film in a storage assembly for achieving the same | |
US3146070A (en) | ph indicator unit | |
US2717843A (en) | Sheet for protection of metals from corrosion and method of making | |
US6395195B1 (en) | Oxygen scavenger accelerator | |
US2923632A (en) | Methods and devices for preventing stalk rot in fruit stalks | |
US2942057A (en) | Primary galvanic cell | |
US1949781A (en) | Tarnishproof cloth | |
US2848297A (en) | Manganese ethylenebisdithiocarbamate stabilized by desiccant; method and package | |
JPH0130530B2 (enrdf_load_stackoverflow) | ||
JP2580157B2 (ja) | 酸素検知剤 | |
US2605164A (en) | Method of protecting color chart in determination of chromate concentrations | |
JPH0532285A (ja) | 衣類密封収納保存法並びに衣類密封収納保存袋 | |
US4543336A (en) | Indicator for determining sulfur dioxide | |
JP3613659B2 (ja) | 酸素検知剤 | |
US3557946A (en) | Package of recording paper | |
US2320835A (en) | Hectograph blanket conditioning container | |
US2820016A (en) | Corrosion inhibiting composition and indicator therefor | |
US3259584A (en) | Bleaching composition |