US3512968A - Method of proofing and screening color separations using the manifold imaging process - Google Patents

Method of proofing and screening color separations using the manifold imaging process Download PDF

Info

Publication number
US3512968A
US3512968A US468683A US3512968DA US3512968A US 3512968 A US3512968 A US 3512968A US 468683 A US468683 A US 468683A US 3512968D A US3512968D A US 3512968DA US 3512968 A US3512968 A US 3512968A
Authority
US
United States
Prior art keywords
layer
imaging
acid
manifold
image
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US468683A
Other languages
English (en)
Inventor
Vsevolod Tulagin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xerox Corp
Original Assignee
Xerox Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xerox Corp filed Critical Xerox Corp
Application granted granted Critical
Publication of US3512968A publication Critical patent/US3512968A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02—Charge-receiving layers
    • G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G13/00—Electrographic processes using a charge pattern
    • G03G13/26—Electrographic processes using a charge pattern for the production of printing plates for non-xerographic printing processes
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G17/00—Electrographic processes using patterns other than charge patterns, e.g. an electric conductivity pattern; Processes involving a migration, e.g. photoelectrophoresis, photoelectrosolography; Processes involving a selective transfer, e.g. electrophoto-adhesive processes; Apparatus essentially involving a single such process
    • G03G17/08—Electrographic processes using patterns other than charge patterns, e.g. an electric conductivity pattern; Processes involving a migration, e.g. photoelectrophoresis, photoelectrosolography; Processes involving a selective transfer, e.g. electrophoto-adhesive processes; Apparatus essentially involving a single such process using an electrophoto-adhesive process, e.g. manifold imaging

Definitions

  • ABSTRACT OF THE DISCLOSURE A method of proofing and screening color separations and providing either positive or negative images of said color separations wherein the blue, green and red separations are imaged respectively on yellow, magenta and cyan manifold sets. The positive images obtained from the manifold sets are superimposed to subtractively synthesize a proof of the image.
  • the present invention relates in general to imaging and, more specifically, to a new system for the formation of high gamma images by layer transfer in image configuration and the use of such a system in color proofing and in the production of color separations.
  • imaging techniques based on layer transfer of a colored material have been known in the past, these techniques have always been clumsy and difficult to operate because they depend upon photochemical reactions and generally involve the use of distinct layer materials for the two functions of image-wise transfer and image coloration.
  • a typical example of the complex structures and sensitive materials employed in prior art techniques is described in U.S. Pat. 3,091,529 to Buskes. Not only does this type of prior art imaging system tend towards complexity in structure in that it employs separate materials for final image coloration and image-wise transfer, but, in addition, image-wise transfer generally depends upon a photo-induced ch mical reaction which changes the adherence of the layer so exposed.
  • a still further object of this invention is to provide an improved system for color proofing
  • Yet another object of this invention is to provide an improved system capable of producing color separations and proofs in one simultaneous exposure
  • a layer of a cohesively weak photoresponsive imaging material on a substrate are termed the donor.
  • the imaging layer may then be activated by treating it with a swelling agent or partial solvent for the material, if required to further weaken it. This step may be eliminated, of course, if the layer retains suflicient residual solvent after having been coated on the substrate from a solution or paste.
  • the activating step serves the dual function of making the top surface of the imaging layer slightly tacky and, at the same time, weakening it structurally so that it can be fractured more easily along a sharp line which defines the image to be reproduced.
  • an electrical field is then applied across this manifold set while it is exposed to a pattern of light and shadow representative of the image to be reproduced.
  • the imaging layer fractures along the lines defined by the pattern of light and shadow to which it has been exposed with part of this layer being transferred to the receiver sheet while the remainder is retained on the donor substrate so that a positive image is produced on one while a negative is produced on the other.
  • At least one of the donor substrate and the receiver sheet is transparent and, in fact, both may be transparent so that exposure may be made from either side of the manifold set.
  • the manifold I et may include separate electrodes on opposite sides of the donor substrate and receiver sheet for the application of the field or they may be directly on the back surfaces of these members and integral therewith.
  • one or both of the donor substrate and receiver sheet may be made of a conductive material. At least one of these is transparent so as to permit exposure of the imaging layer through this electrode.
  • the imaging layer serves the dual function of imparting light sensitivity to the system while at the same time acting as the colorant for the final image produced, although other colorants such as dyes and pigments may be added to it so as to intensify or modify the color of the final images produced when image color is important.
  • the imaging layer may be homogeneous; however, in a preferred form of the invention which has produced superior results a material such as a pigment, which is preferably metal-free phthalocyanine, is dispersed in a cohesively weak insulating binder. Other materials including particles made up of two or more layers, blends of materials, complexes, photoresponsive polymers, etc., may also be dispersed in this type of binder.
  • the three (or four) separations are screened on different colored manifold sets so that the blue separation is screened on the yellow set, the green separation on a magenta set, the red separation on a cyan set and the black separation on a black set (if a black separation is used).
  • the negative or the positive sheets of the manifold set automatically provide an immediate proof of the process at that point by superposing these sheets and viewing the transparency thus produced.
  • Direct screening of the separations (as described by F. R. Clapper Improved Colour Separation of Transparencies by Direct Screening J. Phot. Sci. 12, 28 Jan.- Feb. 1964) may also be used in which case the screened separations are merely exposed to the correct manifold set for proofing.
  • manifold sets with selective spectral response so that the yellow set responds only to blue light, the magenta set responds only to green light and the cyan set responds only to red light or by using suitable filters with sets which have broader spectral responses these sets may be employed directly to produce the screened separations. This is particularly advantageous in direct screening.
  • the complementary images produced in each of the sets are then superposed for proofing so that color separation, screening and proofing is combined into one quick virtually dry process.
  • FIG. 1 is a side sectional view of a photosensitive imaging member for use in the invention
  • FIG. 2 is a side sectional view of a second embodiment of the imaging member
  • FIG. 3 is a process flow diagram of the method steps of the invention.
  • FIGS. 3a and 3b are side sectional views diagrammatically illustrating the process steps of FIG. 3.
  • FIG. 1 of the drawings there is seen a supporting donor substrate layer 11 and an imaging layer generally designated 12.
  • layer 12 is coated on substrate 11 so that it adheres thereto.
  • These layers are collectively referred to as the imaging donor or merely the donor.
  • layer 12 consists of photoconductive pigment 13 dispersed in a binder 14.
  • This two-phase system has so far been found to constitute a preferred form for imaging layer 12; however, homogeneous layers made up, for example, of a single component or a solid solution of two or more components are employed where these layers exhibit the desired photoresponse and have the desired physical properties.
  • the basic physical property desired in layer 12 is that it be frangible, having a relatively low level of cohesive strength either in the as-coated condition or after it has been suitably activated as described more fully hereinafter.
  • layer 12 serves as the photoresponsive element of the system as well as the colorant in the final image produced, the components of this layer are in most cases preferably selected so as to have a high level of photoresponse while at the same time being intensely colored so that a high contrast image can be formed by the high gamma system of the invention.
  • intensely colored photo responsive pigments such as phthalocyanine blues, quinacridone reds and the like are preferred.
  • the alpha and X crystalline forms of metal-free phthalocyanine are especially preferred pigments for use in the invention because of their very high sensitivity.
  • the X crystalline form is described in copending application No. 375,191, filed June 15, 1964 now abandoned, and entitled Electrophotographic Element. It is to be understood, however, that since the binder itself may be dyed or pigmented with additional colorant in either the single-phase or twophase system, intense coloration of the photoresponsive material itself, while being preferred, is not critical in any sense even for high contrast imaging. Accordingly, even transparent materials may be used.
  • the main characterizing property of the system is that it is essentially a go or no go system, so that the imaging layer either stays on the donor substrate or transfers to the receiver sheet.
  • the difference between the maximum density of the imaging layer and the substrate or receiver sheet upon which it is supported after imaging may be very small because of the use of a relatively transparent imaging layer.
  • the system may be defined as a high gamma system; that is, one in which the slope of the density vs. log of exposure curve is very large in that portion of the curve where the imaging layer responds.
  • any suitable photoresponsive material may be employed in this system with the choice depending largely upon the photosensitivity required, the spectral sensitivity, the degree of contrast desired in the final image, whether a heterogeneous or a homogeneous system is desired and similar considerations.
  • Typical photoconductors include substituted and unsubstituted phthalocyanine, quinacridones, zinc oxide, mercuric sulfide, Algol yellow (Cl. No. 67,300), cadmium sulfide, cadmium selenide, Indofast brilliant scarlet toner (C.I. No.
  • 71,140 zinc sulfide, selenium, antimony sulfide, mercuric oxide, indium trisulfide, titanium dioxide, arsenic sulfide, Pb O gallium triselenide, zinc cadimum sulfide, lead iodide, lead selenide, lead sulfide, lead telluride, lead chromate, gallium telluride, mercuric selenide, and the iodides, sulfides, selenides and tellurides of bismuth aluminum and molybdenum.
  • Any suitabe Lei: acid (electron acceptor) may be employed un erfigned plexing conditions with many of the aforemen of more soluble organic materials and also with many the more insoluble organics to impart very rmportan an ⁇ creases in photosensitivity to those materials.
  • 532px Lewis acids are 2,4,7-trinitro-9-fluorenone; 2 4.56 c He nitro-9-fluorenone; picric ac1d; l,?,5 tnmtro e nze e chloranil; benzo-quinone; 2,5 dICI IlOIO-bEHZOqUlIIOIIJIe: 2 6 dichlorobenzo-quinone; chloranil; naphthocpgnoui' (l,4); 2,3 dichloronaphthoqmnone (1,4), lat; flagranone; 2 methyl-anthraqulnone; 1,4 drmet y-a2 car quinone; 1 chloroanthraqumone; anthraqumongoroltboxylic acid; 1,5 dichloroanthraqumone, 1 0 themenitroanthraquinone; PheIlanthlfillglcglllgzeu?ggfigp
  • acetophenone benzophenone 2 acetylnaphthalene; benzil; benzoin; S-benzoyl acenaphthene; biacene-dione; 9-acetyl-anthracene; 9-benzoyl-anthracene; 4 (4 dimethylamino cinnamoyl) 1 acetylbenzene; acetoacetic acid anilide; indandi'one-(1,3)-(l-3-diketohydrindene); acenaphthene quinone
  • photoconductors may be formed by complexing one or more suitable Lewis acids with poly mers which are ordinarily not thought of as photoconductors.
  • Typical polymers which may be complexcd in this manner include the following illustrative materials: polyethylene terephthalate, polyamides, polyimides, polycarbonates, polyacrylates, polymethylmethacrylates, polyvinyl fluorides, polyvinyl chlorides, polyvinyl acetates, polystyrene, styrene-butadiene copolymers, polymethacrylates, silicone resins, chlorinated rubber, and mixtures and copolymers thereof Where applicable; thermosetting resins such as epoxy resins, phenoxy resins, phenolics, epoxy-phenolic copolymers, epoxy ureaformaldehyde copolymers, epoxy melamine-formaldehyde copolymers and mixtures thereof, where applicable.
  • Other typical resins are epoxy esters, vinyl epoxy resins, tall-oil modified
  • the photoconductive particles themselves may consist of any suitable one or more of aforementioned photoconductors, either organic or inorganic, dispersed in, in solid solution in, or copolymerized with, any suitable insulating resin whether or not the resin itself is photoconductive.
  • This particular type of particle may be particularly desirable to facilitate dispersion of the particle, to prevent undesirable reac tions between the binder 14 and the photoconductor or between the photoconductor and the activator and for similar purposes.
  • Typical resins of this type include polyethylene, polypropylene, polyamides, polymethacrylates, polyacrylates, polyvinyl chlorides, polyvinyl acetates, olystyrene, polysilixoxanes, chlorinated rubbers, polyacrylonitrile, epoxies, phenolics, hydrocarbon resins and other natural resins such as rosin derivatives as well as mixtures and copolymers thereof.
  • the ratio of photoconductor 13 to binder 14 by volume in the heterogeneous system may range from about to 1 to about 1 to 10, but it is generally been found that proportions in the range of from about 1 to 2 to about 2 to I produce the best results and, accordingly, this constitute-s a preferred range.
  • imaging layer 12 has relatively low cohesive strength either in the as-coated condition or after it has been suitably activated. This, of course, is true for both the homogeneous system and the heterogeneous system.
  • One technique for achieving low cohesive strength in the layer 12 is to employ relatively weak, low molecular weight materials therein.
  • a monomeric compound or a low molecular weight polymer complexed with a Lewis acid to impart a high level of photoresponse to the layer may be employed.
  • either one or both of the components of the solid solution may be a low molecular Weight material so that the layer has the desired low level of cohesive strength.
  • This approach may also be taken in connection with the heterogeneous layer 12 illustrated in FIG. 1.
  • the binder material 14 in the heterogeneous system may in itself be photoresponsive, it does not necessarily have this property so that minerals such as microcrystalline wax, paraffin wax, low molecular weight polyethylene and other low molecular weight polymers may be selected for use as this binder material solely on the basis of physical properties and the fact that they are insulating materials without regard to their photoresponse.
  • imaging layer 12 Any other technique for achieving low cohesive strength in imaging layer 12 may also be employed.
  • suitable blends of incompatible materials such as a blend of a polysiloxane resin with a polyacrylic ester resin may be used either as binder layer 14 in a heterogeneous system or in conjunction with a homogeneous system in which the photoresponsive material may be either one of the incompatible components (complexed with a Lewis acid) or a separate and additional component of the layer.
  • the thickness of imaging layer 12 is not critical and layers from about 0.5 to about 10 microns have been used.
  • imaging layer 12 is a third or receiving layer 16.
  • This receiver sheet is ordinarily supplied as a separate layer which does not initially adhere to layer 12. Accordingly, although the whole imaging member or manifold set may be supplied in a convenient threelayer sandwich as shown in FIG. 1, receiving layer 16 may also be supplied as a separate sheet or roll if desired. On the other hand, in those systems where activation of the imaging layer is not required or where imaging layer 12 has been preactivated at the factory, layer 16 adheres to or is at least tacked onto imaging layer 12. In the particular embodiment of the manifold set shown in FIG. 1, both the donor substrate 11 and the receiver sheet 16 are made up of an electrically conductive material such as cellophane with at least one of them being optically transparent to provide for the exposure of layer 12.
  • imaging layer 12 There should be a fairly close balance between the adherence of imaging layer 12 for the donor and receiver layers 11 and 16, respectively, with a slightly stronger adherence to the donor at the time of imaging. Accordingly, layers 11 and 16 should be selected with this in mind.
  • One way to easily accomplish this balance is to use the same material for layer 16 as is used for layer 11.
  • FIG. 2 Although the structure of FIG. 1 represents one of the simplest forms which the manifold set may take, another embodiment is illustrated in FIG. 2 where imaging layer 12 may take any one of the forms as described above in connection with FIG. 1.
  • imaging layer 12 is deposited on an insulating donor substrate 17 which is backed with a conductive electrode layer 18 while the image receiving portion of the manifold set also consists of an insulating receiver sheet 19 backed with a conductive electrode layer 21.
  • either or both of the pairs of layers 17-18 and layers 1921 may be transparent so as to permit exposure of imaging layer 12.
  • Flexible, transparent conductive materials, such as cellophane which may be used in the FIG.
  • FIG. 1 embodi ment of the invention are, for the most part, relatively weak materials with the choice of these materials being quite limited.
  • the FIG. 2 structure which uses an insulating donor substrate and receiver sheet 17 and 19, respectively, allows for the use of high strength insulating polymers such as polyethylene, polypropylene, olyethylene terephthalate, cellulose acetate, Saran (vinyl chloridevinylidene chloride copolymer) and the like. Not only does the use of this type of high strength polymer provide a strong substrate for the positive and negative images formed on the donor substrate and receiver sheet, but in addition, it provides an electrical barrier between the electrodes and the imaging layer 12 which tends to inhibit electrical breakdown of the system. Combinations of the structure described in FIGS. 1 and 2 may also be used in carrying out the invention with a relatively conductive layer immediately in contact with one side of imaging layer 12 and a conductively backed insulating layer on the other side of the imaging layer.
  • the first step in the imaging process is the activation step.
  • the manifold set is opened and the activator is applied to imaging layer 12 following which these layers are closed back together again as indicated in the second block of the process flow diagram of FIG. 3.
  • the activator may be applied by any suitable technique such as with a brush, with a smooth or rough surfaced roller, by flow coating, by vapor condensation or the like
  • FIG. 3a which diagramatically illustrates the first two process steps shows the activator fluid 23 being sprayed on to imaging layer 12 of the manifold set from a container 24.
  • the set is closed by a roller 26 which also serves to squeegee out any excess activator fluid which may have been deposited.
  • the activator serves to create an adhesive bond between imaging layer 12 and receiver sheet 16 as Well as to swell or otherwise weaken and thereby lower the cohesive strength of imaging layer 12.
  • the activator should also have a high level of resistivity so that it will not provide an electrically conductive path through imaging layer 12 and in addition so that the imaging layer will support the electrical field which is applied through it during the exposure. Accordingly, it will generally be found to be desirable to purify commercial grades of activators so as to remove impurities which might impart a higher level of conductivity to the activating fluids.
  • the activator may consist of any suitable solvent having the aforementioned properties and which has the above-described effect on imaging layer 12.
  • solvent shall be understood to include not only materials which are conventionally throught of as solvents but also those which are thought of as partial solvents, swelling agents or softening agents for imaging layer 12. It is generally preferable that the activator solvents have a relatively low boiling point so that fixing can be accomplished after image formation by solvent evaporation with mild heating at most. It is to be understood, however, that the invention is not limited to the use of these relatively volatile activators.
  • Typical solvent include Sohio odorless solvent 3440 an aliphatic (kerosene) hydrocarbon fraction available from Standard Oil Co.
  • halogenated hydrocarbons such as chloroform, methylene chloride, trichloroethylene, perchloroethylene, chlorobenzene, trichloromonofluoromethane, tetrachlorodifluoroethane, trichlorotrifluoroethane, amides such as formamide, dimethyl formamide, esters such as ethyl acetate, isopropyl acetate, butyl acetate, amyl acetate, cyclohexyl acetate, isobutyl propionate and butyl lactate, ethers such as diethyl ether, diisopropyl ether, dioxane, tetrahydrofuran, ethyleneglycol monoethyl ether, aromatic and aliphatic hydrocarbons such as benzene
  • the first two steps of the imaging process may be omitted.
  • a manifold set which is preactivated at the factory may be supplied or if imaging layer 12 is initially fabricated to have a low enough cohesive strength, activation may be omitted and receiving layer 16 may be adhered to the surface of imaging layer 12 at the time when that layer is coated on substrate 11 either from solution or from a hot melt.
  • activation step it is generally preferable, however, to include an activation step in the imaging process because if this step is included then a stronger and more permanent imaging layer 12 may be provided which can withstand storage and transportation prior to imaging and which will provide a more permanent final image after imaging.
  • imaging layer 12 fractures along the edges of exposed areas and the surface where it is adhered to either substrate 11 or receiving sheet 16. Accordingly, once separation is complete, exposed portions of imaging layer 12 are retained on one of layers 11 and 16 while unexposed portions are retained on the other layer, resulting in the simultaneous formation of a high gamma positive image on one of those sheets and a high gamma negative on the other.
  • an imaging layer made up of finely divided metal-free phthalocyanine particles dispersed in a microcrystalline wax
  • the best images are formed when the donor is positioned at the illuminated electrode which is made negative and the non-illuminated electrode is positive.
  • the reversal of this polarity generally results in a poorer image or lower sensitivity and sometimes in a reversal of position in that a duplicate of the exposed original is formed on the non-illuminated side of the manifold set instead of at the illuminated side which is the usual case.
  • potential source 28 shown in FIG. 3b is indicated as having its negative side connected to substrate 18 through which exposure is made by light rays 29.
  • Preferred field strengths are in the range of about 1,500 to 2,000 volts per mil.
  • the preferred applied voltage is 6,000 to 8,000 volts across the electrodes outside these Mylar sheets.
  • suitable images are also produced with voltages of from about 4,000 to about 10,000 volts.
  • the receiver sheet is rolled down onto the activated imaging layer 12 with the power on.
  • a fairly large resistance is preferably inserted in series with the power supply to limit the flow of current and the rate of charging of the capacitor which the manifold set forms.
  • resistor 30 provides a path for discharging the capacitor at an adequate rate to prevent sparking during separation of the donor and the receiver sheet.
  • a visible light source, an ultraviolet light source or any other suitable source of actinic electromagnetic radiation may be used to expose the manifold set of this invention.
  • Better quality images are produced by exposing from the donor side of the imaging layer and, accordingly, the receiver sheet 16 is usually separated from the other layers of the manifold set just after image exposure and generally with the power on both electrodes. This operation involves a current flow because as the layers are separated, the capacitance of the manifold set is reduced and charge stored in this capacitor is caused to flow back through the resistor in the circuit which dissipates this current as in PR heat loss. Short delays in separation after the exposure step seem to have no deleterious effects on the images produced.
  • a relatively volatile activator such as petroleum ether or carbon tetrachloride, Freon 215
  • fixing occurs almost instantaneously after separation of the layer because the relatively small quantity of activator in the 2-5 micron layer of imaging material flashes off very rapidly.
  • activators such as the Sohio odorless solvent 3440 or Freon 214 described above
  • fixing may be accelerated by blowing air over the images or warming them to about 150 F.
  • the even less volatile activators, such as transformer oil fixing is accomplished by absorption of the activator into another layer such as paper substrate to which the image is transferred.
  • Many other fixing techniques and methods for protecting the images such as overcoating, laminating with a transparent thermoplastic sheet and the like will occur to those skilled in the art.
  • Increased image durability and hardness may also be achieved by treatment with an image material hardening agent or with a hard polymer solution which will wet the image material but not the donor substrate.
  • the apparatus for carrying out the imaging procedure described above will employ the elements illustrated in FIGS. 3a and 3b including a source of activator fluid, a squeegee roller to remove excess activator fluid, a power supply with series resistor and a set of electrodes which may or may not be built in to the manifold set. Opening the manifold set for activation, closing the set for exposure and opening again for separation and image formation may be accomplished by an one of a number of techniques which will be obvious to those skilled in the art. However, one straightforward way to accomplish this result is to supply the imaging materials in the form of long webs which can be entrained over rollers so as to provide opening and closing of the set during the imaging process.
  • manifold sets may be supplied in any color desired either by taking advantage of the natural color of the photoresponsive or binder materials in the imaging layer of the manifold set or by the use of additional dyes and pigments therein whether photoresponsive or not, and, of course, various combinations of these photoresponsive and nonphotoresponsive colorants may be used in the imaging layer so as to produce the desired color.
  • manifold images are in the form of transparencies when first produced, these images may be laminated with opaque backing material of various contrasting colors to produce prints.
  • manifold images using different colored imaging layers such as cyan, magenta and yellow may be combined to produce tfull natural color images by super position of transparencies.
  • photoresponsive materials have different spectral responses and that the spectral response of many photoresponsive materials may be modified by dye sensitization so as to either increase and narrow the spectral response of a material to a peak or to broaden it to make it more panchromatic in its response.
  • the material can be used to make ordinary black and white images using panchromatic response while narrow spectral response materials may be employed for the production of color separations or the like.
  • the blue separation is screened on a yellow manifold set, the green separation on a magenta manifold set, the red separation on a cyan manifold set, and the black separation on a black manifold set.
  • the manifold sets need not necessarily have peaked spectral responses so long as they show response to the color of light of the particular separation to which they are exposed.
  • the yellow, magenta and cyan sets respond, respectively, to blue, green and red light only. In this way no filter is required since each set only responds to the desired color of color reproducing this light image in its complementary color.
  • sets with broader spectral response are exposed with filters.
  • the proofing transparencies are produced by the complementary images on the other side of the manifold sets and proofing is again accomplished by merely superposing the transparencies and viewing them together.
  • the X-form phthalocyanine thus produced is used to prepare the imaging layer according to the following procedure: 5 grams of Sunoco 1290, a microcrystalline wax with a melting point of 178 F. is dissolved in 100 cc. of reagent grade petroleum ether heated to 50 C. and quenched immersing the container in cold water to form small wax crystals. Five grames of the purified and milled phthalocyanine produced according to the above procedure are then added to the wax paste along with /2 pint of clean porcelain balls in a 1 pint mill jar. This formulation is then ball milled in darkness for 3 /2 hours at 70 r.p.m. and after milling 20 cc.
  • Sohio solvent 3440 is added to the paste.
  • This paste is then coated in subdued green light on a 2 mil. Mylar sheet with a No. 12 wire-wound drawdown rod which produces a 2.5 micron thick coating after drying.
  • the same paste is also applied on three other Mylar sheets with a No. 8 drawdown rod to produce a coating thickness of 1 /2 microns, with a No. 24 rod to produce a coating thickness of 5 microns and a No. 36 rod to produce a coating thickness of 7 /2 microns.
  • Each of these coatings is then heated to about 140 F. in darkness in order to dry it.
  • the coated donors are placed on the tin oxide surface of NESA glass plates with their coatings facing away from the tin oxide.
  • a receiver sheet also of 2 mil. thick Mylar is then placed on the coated surface of each donor. Then a sheet of black, electrically conductive paper is placed over the receiver sheet to form the complete manifold set. The receiver sheet is then lifted up and the phthalocyanine wax layer is activated with one quick brush stroke of a wide camels hair brush saturated with petroleum ether. The receiver sheet is then lowered back down and a roller is rolled slowly once over the closed manifold set with light pressure to remove excess petroleum ether. The negative terminal of an 8,000 volt DC. power supply is then connected to the NESA coating in series with a 5,500 megohm resistor and the positive terminal is connected to the black opaque electrode and grounded.
  • a white incandescent light image is projected upward through the NESA glass using a Wollensak mm., f4.5 enlarger lens with illumination of approximately 1/ foot-candle applied for 5 seconds for a total incident energy of 0.05 foot-candle-seconds.
  • the receiver sheet is peeled from the set with the potential source still connected.
  • the small amount of petroleum ether present evaporates within a second or so after separation of the sheets yielding a pair of excellent quality images with a duplicate of the original on the donor sheet and a reversal of the original on the receiver sheet.
  • Example VIII When these donors are imaged accordin Example VI, 1 to 5 in Example VII and 1 to in ing to the procedure of Example I, all produce dense high resolution images with the exception of Example VIII which produces a coating of lower reflection density and noticeably lower resolution.
  • Example XII a low molecular weight polyethylene sold by Eastman Chemical Products Inc. under the tradename Epolene C-12 having an approximate molecular weight of 3,700, a ring and ball softening point of 92 C., an acid number of 0.05 and a density at 25 C. of 0.893 is used; for Example XIII grade N-ll of the Epolene low molecular weight polyethylene series is employed having an approximate molecular weight of 1,500, a ring and ball softening point of 107 C., a density at 25 C. of .924 and an acid number of 0.05.
  • Example I Each of these coatings is imaged according to the procedure of Example I and all are found to produce good quality images although Sunoco 5825 microcrystalline wax of Example IX and 5512 paraflin wax of Example XI produce some blue haze in the background of the image which remains on the donor apparently because of the fact that these waxes are softer than the other materials tested.
  • Example XIV-XVIII Five donors are prepared according to the procedure of Example I and images according to the procedure given in that example with the exception that the following activators used in each of the examples.
  • Example XIV it is activated with Sohio odorless solvent 3440
  • Example XV is activated with carbon tetrachloride
  • Example XVI is activated with Freon 214 (tetrachlorotetrafluoropropane)
  • Example XVII is activated with Dow-Corning silicone oil D0200 (dimethylpolysiloxane)
  • Example XVIII is activated with Wemco-C transfer oil, a very high boiling point long chain aliphatic oil available from Westinghouse Electric.
  • the activators produce a high quality image upon separation.
  • the final images require mild heating at most to dry ofi the activator and harden the image, while in the case of Examples XVII and XVIII the non-drying activator maintains the image in a wet condition. These two images are then rolled off on an absorbent paper substrate which picks up most of the activator thereby hardening the imaging material on the surface.
  • Example XIX-XXIV In Examples XIX-XXIV six doners are made according to the procedure of Example I and the imaging procedure of Example I is followed with the only exception that the pigment used in forming the imaging layer is as follows: in Example XIX the stabilized alpha crystalline form of metal-free phthalocyanine is employed. This material is prepared by acetone extraction of the commercial metalfree phthalocyanine and sulfuric acid solution reprecipitation of the extracted material as in Example I followed by neat milling for one day of the precipitated material in a porcelain mill with Burundum balls. This milling stabilizes the alpha for-m conversion to the beta form. In Example XX the beta form of metal-free phthalocyanine is used.
  • Example XXI Algol yellow GC Color Index No. 67,300 (l,2,5,6-di(C,C'-diphenyl) thiazole anthraquinone) is used.
  • Example XXII the pigment used is 2,9-dimethylquinacn'done.
  • Example XXIII French process zinc oxide is used as the pigment.
  • Example XXIV mercuric sulfide is used as the pigment.
  • Example XIX has about one order lower sensitivity as the X-crystal form of Example I
  • beta phthalocyanine is about two orders of magni- EXAMPLES XXV-XXVIII
  • imaging members or manifold sets are made up and imaged according to the procedure of Example I with the exception that various electrodes, donor substrates and receivers are employed as follows:
  • Example Base Donor Receiver Upper No electrode substrate sheet electrode XXV Cellophane Electrode. Electrode Cellophane. XXl/I .do Mylar .do Do. XXVII. NE SA Cellulose Cellulose Conductive glass. acetate. acetate. black paper aluminum.
  • EXAMPLE XXIX Eight parts by weight of 2,5-bis (p-aminophenyD- 1,3,4-oxidiazole and 12 parts by weight of Lucite 2008, a low molecular weight polymethyhnethacrylate available from E. I. du Pont & Co. are dissolved in parts by weight of methylethyl ketone along with 0.25 part by weight of bromphenol blue dye. This solution is then coated on a 2 mil. Mylar substrate and before the coating is fully dried it is dipped in a water bath which dilutes the solution causing the solids to precipitate out in a weak semi-particulate form in which the individual particles are bonded at their interfaces much like a sintered layer.
  • the donor thus prepared is imaged according to the procedure of Example I with Mylar receiver sheet beneath'an electrically conductive black paper electrode and using a transparent NESA glass electrode beneath the Mylar layer of the donor.
  • the dye increases the sensitivity of the layer somewhat and imparts a pink tinge to it, both the sensitivity of the system and the resolution of the image produced are lower than that of the system of Example I.
  • EXAMPLE XXX Twenty parts by weight of polyvinylcarbarzole is dissolved in 80 parts by weight of toluene along with 2 parts by weight of a 2,4,7-trinitro-9-fluorenone charge transfer complexing agent and 005 part by weight of a bromphenol blue sensitizing dye. After partial drying of the coating, it is dipped in acetone which causes precipitation of the solids from solution in the same type of physical structure as described above in connection with Example XXIX. This donor is imaged according to the same procedure as used in connection with Example XXIX and is somewhat more sensitive than the coating of Example XXIX.
  • a method of proofing color separations comprising forming positive images by imaging with actinic electromagnetic radiation the blue, green and red separations from a color image respectively on yellow, magenta and cyan cohesively weak, electrically photosensitive imaging layers of manifold sets, said layers each being structurally fracturable in response to the combined effect of an applied electrical field and exposure to electromagnetic radiation to which said layer is sensitive, and said sets each comprising one of said imaging layers sandwiched between a donor layer and a receiver layer, at least one of said donor and receiver layers being at least partially transparent to actinic electromagnetic radiation, said imaging performed while the imaging layers of each set are subjected to an electric field, separating each of said sets while said imaging layers are under said electric fields whereby said imaging layer fractures in imagewise configuration to provide positive images on one of said donor and receiver layers, and superimposing said positive images to subtractively synthesize a proof of the image.
  • a method of simultaneously proofing and screen ing color separations made from a natural color original comprising imaging with actinic electromagnetic radiation the blue, green and red separations made from said original through a screen, respectively on yellow, magenta and cyan cohesively weak, electrically photosensitive imaging layers of manifold sets, said layers each being structurally fracturable in response to the combined effect of applied electrical field and exposure to electromagnetic radiation to which said layer is sensitive, and said sets each comprising one of said imaging layers sandwiched between a donor layer and a receiver layer, at least one of said donor and receiver layers being at least partially transparent to actinic electromagnetic radiation, said imaging performed while the imaging layers of each set are subjected to an electric field, separating each of said sets while said imaging layers are under said electric fields whereby said imaging layer fractures in imagewise configuration to provide positive images on one of said donor andreceiver layers and superimposing the screened positive images formed from said manifold sets to subtractively synthesize a proof of the image.
  • a method for the simultaneous formation of color separations, separation screening and proofing comprising successively imaging with actinic electromagnetic radiation a colored original on at least yellow, magenta and cyan cohesively weak electrically photosensitive imaging layers of manifold sets, said layers each being structurally fracturable in response to the combined effect of an applied electrical field and exposure to electromagnetic radiation to which said layer is sensitive, and said sets each comprising one of said imaging layers which shows electrophotosensitivity in essentially only that portion of the visible spectrum which is absorbed by that particular imaging layer sandwiched between adonor layer and a receiver layer, at least one of said donor and receiver layers being at least partially transparent to actinic electromagnetic radiation, said imaging performed while the imaging layers of each set are subjected to an' electric field, separating each of said sets while said imaging layers are under said electric fields whereby said imaging layer fractures in imagewise configuration to provide positive images on one of said donor and receiver layers with each of said images being made by exposure through a screen, and superimposing the positive images formed from said manifold sets to subtractively synthesize
  • the method of claim 1 further including the step of using at least one of the negative and positive images produced from said manifold sets for printing plate preparation.
  • the method of claim 3 further including the step of using at least one of the screened negative images and screened positive images produced from said manifold sets for printing plate preparation.
  • a method according to claim'l further including imaging a black separation from said color image on a black manifold set, using at least one of the black negaformed from said manifold set on the other three positive images to synthesize said proof.
  • a method according to claim 2 further including the step of exposing a black separation to a'black manifold set through a screen, and superimposing the screened positive manifold image on the other three positives.
  • a method according to claim 2 further including I the step of exposing a black separation'on a black manifold set through a screen, using at least one of the screened black negative images and screened black positive images for the formation of a black printer plate and superimpos ing the screened positive image on the other three positives to subtractively synthesize a proof of the image.
  • a method according to claim 3 further including the step of imaging the colored original on a black manifold set through a screen, using at least one of the screened black negative image and the screened black positive image for the formation of a black printer plate and superimposing the black screened positive manifold image on the other three positives.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Photoreceptors In Electrophotography (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
  • Light Receiving Elements (AREA)
  • Printing Plates And Materials Therefor (AREA)
US468683A 1965-05-03 1965-07-01 Method of proofing and screening color separations using the manifold imaging process Expired - Lifetime US3512968A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US45264165A 1965-05-03 1965-05-03
US46868365A 1965-07-01 1965-07-01
US70838068A 1968-02-26 1968-02-26

Publications (1)

Publication Number Publication Date
US3512968A true US3512968A (en) 1970-05-19

Family

ID=27412539

Family Applications (2)

Application Number Title Priority Date Filing Date
US468683A Expired - Lifetime US3512968A (en) 1965-05-03 1965-07-01 Method of proofing and screening color separations using the manifold imaging process
US708380A Expired - Lifetime US3707368A (en) 1965-05-03 1968-02-26 Manifold imaging process

Family Applications After (1)

Application Number Title Priority Date Filing Date
US708380A Expired - Lifetime US3707368A (en) 1965-05-03 1968-02-26 Manifold imaging process

Country Status (10)

Country Link
US (2) US3512968A (xx)
JP (1) JPS4832682B1 (xx)
AT (1) AT290985B (xx)
CH (2) CH494989A (xx)
DE (1) DE1522744C3 (xx)
FR (1) FR1478172A (xx)
GB (1) GB1150381A (xx)
IL (1) IL25681A (xx)
NO (1) NO124561B (xx)
SE (2) SE352752B (xx)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3638567A (en) * 1969-05-13 1972-02-01 Xerox Corp Method of preparing and utilizing a gravure printing master
US3649117A (en) * 1970-01-02 1972-03-14 Xerox Corp Imaging process
US3653892A (en) * 1969-07-01 1972-04-04 Xerox Corp Manifold imaging process wherein the imaged elements may be recombined and reused
US3653889A (en) * 1969-07-28 1972-04-04 Xerox Corp Method of fixing manifold images
US3658519A (en) * 1969-12-24 1972-04-25 Xerox Corp Image transfer process from conductive substrates
US3661454A (en) * 1967-01-09 1972-05-09 Xerox Corp Combination of electrography and manifold imaging
US3718462A (en) * 1969-06-03 1973-02-27 Xerox Corp Manifold electrification process
US3723112A (en) * 1967-10-17 1973-03-27 Xerox Corp Manifold imaging method wherein the activator carries a plastic coating material
US3768902A (en) * 1965-05-03 1973-10-30 Dorn W Van Manifold imaging
US3798030A (en) * 1967-11-01 1974-03-19 Xerox Corp Photoelectrosolographic imaging method utilizing powder particles
US3837883A (en) * 1969-12-22 1974-09-24 Xerox Corp Image transfer process
US3839031A (en) * 1969-09-02 1974-10-01 Xerox Corp Electrode development migration imaging method
US3857707A (en) * 1965-11-30 1974-12-31 Xerox Corp Photoelectrophoretic imaging process using dry pigment coated substrate
US3861910A (en) * 1969-01-13 1975-01-21 Xerox Corp Manifold imaging process
US3870517A (en) * 1969-10-18 1975-03-11 Matsushita Electric Ind Co Ltd Color image reproduction sheet employed in photoelectrophoretic imaging
US3918967A (en) * 1970-01-02 1975-11-11 Xerox Corp Contact reflex manifold imaging process
US3964904A (en) * 1974-08-22 1976-06-22 Xerox Corporation Manifold imaging member and process employing a dark charge injecting layer
US4052208A (en) * 1973-05-04 1977-10-04 Martinelli Michael A Image recording medium employing photoconductive granules and a heat disintegrable layer
US4081273A (en) * 1970-01-02 1978-03-28 Xerox Corporation Migration imaging method

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3573904A (en) * 1967-01-09 1971-04-06 Xerox Corp Combination of electrography and manifold imaging
US3565612A (en) * 1967-01-09 1971-02-23 Xerox Corp Duplicating masters by the manifold process
US3876937A (en) * 1968-09-27 1975-04-08 Xerox Corp Layer transfer imaging system
US3901697A (en) * 1971-10-04 1975-08-26 Xerox Corp Manifold imaging process using electrically photosensitive material subject to light fatigue
CA978790A (en) * 1971-11-17 1975-12-02 John B. Wells Imaging compositions
US3850626A (en) * 1973-02-26 1974-11-26 Xerox Corp Imaging member and method
US3955975A (en) * 1974-03-28 1976-05-11 Xerox Corporation Manifold imaging member and process employing a metal soap
US4113482A (en) * 1976-01-22 1978-09-12 Xerox Corporation Migration imaging method involving color change

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2940847A (en) * 1957-07-03 1960-06-14 None i red
US3316088A (en) * 1963-02-11 1967-04-25 Ibm Process of electrophotography based on electrophotolytic reactions and element therefor

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2940847A (en) * 1957-07-03 1960-06-14 None i red
US3316088A (en) * 1963-02-11 1967-04-25 Ibm Process of electrophotography based on electrophotolytic reactions and element therefor

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3768902A (en) * 1965-05-03 1973-10-30 Dorn W Van Manifold imaging
US3857707A (en) * 1965-11-30 1974-12-31 Xerox Corp Photoelectrophoretic imaging process using dry pigment coated substrate
US3661454A (en) * 1967-01-09 1972-05-09 Xerox Corp Combination of electrography and manifold imaging
US3723112A (en) * 1967-10-17 1973-03-27 Xerox Corp Manifold imaging method wherein the activator carries a plastic coating material
US3798030A (en) * 1967-11-01 1974-03-19 Xerox Corp Photoelectrosolographic imaging method utilizing powder particles
US3861910A (en) * 1969-01-13 1975-01-21 Xerox Corp Manifold imaging process
US3638567A (en) * 1969-05-13 1972-02-01 Xerox Corp Method of preparing and utilizing a gravure printing master
US3718462A (en) * 1969-06-03 1973-02-27 Xerox Corp Manifold electrification process
US3653892A (en) * 1969-07-01 1972-04-04 Xerox Corp Manifold imaging process wherein the imaged elements may be recombined and reused
US3653889A (en) * 1969-07-28 1972-04-04 Xerox Corp Method of fixing manifold images
US3839031A (en) * 1969-09-02 1974-10-01 Xerox Corp Electrode development migration imaging method
US3870517A (en) * 1969-10-18 1975-03-11 Matsushita Electric Ind Co Ltd Color image reproduction sheet employed in photoelectrophoretic imaging
US3837883A (en) * 1969-12-22 1974-09-24 Xerox Corp Image transfer process
US3658519A (en) * 1969-12-24 1972-04-25 Xerox Corp Image transfer process from conductive substrates
US4081273A (en) * 1970-01-02 1978-03-28 Xerox Corporation Migration imaging method
US3649117A (en) * 1970-01-02 1972-03-14 Xerox Corp Imaging process
US3918967A (en) * 1970-01-02 1975-11-11 Xerox Corp Contact reflex manifold imaging process
US4052208A (en) * 1973-05-04 1977-10-04 Martinelli Michael A Image recording medium employing photoconductive granules and a heat disintegrable layer
US3964904A (en) * 1974-08-22 1976-06-22 Xerox Corporation Manifold imaging member and process employing a dark charge injecting layer

Also Published As

Publication number Publication date
US3707368A (en) 1972-12-26
IL25681A (en) 1970-10-30
SE352752B (xx) 1973-01-08
NO124561B (xx) 1972-05-02
DE1522744C3 (de) 1974-04-25
FR1478172A (fr) 1967-04-21
CH481407A (fr) 1969-11-15
CH494989A (fr) 1970-08-15
DE1522744B2 (de) 1973-09-27
AT290985B (de) 1971-06-25
DE1522744A1 (de) 1969-10-16
SE360936B (xx) 1973-10-08
GB1150381A (en) 1969-04-30
JPS4832682B1 (xx) 1973-10-08

Similar Documents

Publication Publication Date Title
US3512968A (en) Method of proofing and screening color separations using the manifold imaging process
US3565612A (en) Duplicating masters by the manifold process
US3723113A (en) Polychromatic electrosolographic imaging process
US3692519A (en) Electrophotographic color process
US3573904A (en) Combination of electrography and manifold imaging
US3556783A (en) Color manifold imaging process
US4172721A (en) Dye-amplified imaging process
US3598581A (en) Manifold imaging method
US3737311A (en) Electrostatic particle transfer imaging process
US3912505A (en) Color imaging method employing a monolayer of beads
US3595771A (en) Method of removing accumulated charges in photoelectrophoretic imaging
US3723112A (en) Manifold imaging method wherein the activator carries a plastic coating material
US3681064A (en) Photoelectrophoretic imaging process employing multicomponent electrically photosensitive particles
US4524117A (en) Electrophotographic method for the formation of two-colored images
US3653892A (en) Manifold imaging process wherein the imaged elements may be recombined and reused
US4023968A (en) Photoelectrophoretic color imaging process in which back migration is eliminated
US3768902A (en) Manifold imaging
US3655372A (en) Image reversal in manifold imaging
US3681065A (en) Dye transfer color electrophotography
US3676313A (en) Removing undesired potential from the blocking electrode in a photoelectrophoretic imaging system
US3645883A (en) Photoelectrophoretic imaging apparatus employing photosensitive particles exhibiting fatigue characteristics
US3950167A (en) Imaging system
US3676116A (en) Image reversal in manifold imaging using an electrically conductive receiver sheet
US3661454A (en) Combination of electrography and manifold imaging
US3692518A (en) Manifold imaging process