US3511652A - Process for the reproduction of information by short-duration,high-intensity exposure of a heat-sensitive material to visible light - Google Patents
Process for the reproduction of information by short-duration,high-intensity exposure of a heat-sensitive material to visible light Download PDFInfo
- Publication number
- US3511652A US3511652A US557259A US3511652DA US3511652A US 3511652 A US3511652 A US 3511652A US 557259 A US557259 A US 557259A US 3511652D A US3511652D A US 3511652DA US 3511652 A US3511652 A US 3511652A
- Authority
- US
- United States
- Prior art keywords
- heat
- radiation
- exposure
- visible light
- sensitive material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title description 38
- 238000000034 method Methods 0.000 title description 15
- 230000008569 process Effects 0.000 title description 12
- 230000005855 radiation Effects 0.000 description 36
- 108010010803 Gelatin Proteins 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 229920000159 gelatin Polymers 0.000 description 8
- 239000008273 gelatin Substances 0.000 description 8
- 235000019322 gelatine Nutrition 0.000 description 8
- 235000011852 gelatine desserts Nutrition 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 239000003086 colorant Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920002284 Cellulose triacetate Polymers 0.000 description 4
- 244000287680 Garcinia dulcis Species 0.000 description 4
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 3
- 229960003351 prussian blue Drugs 0.000 description 3
- 239000013225 prussian blue Substances 0.000 description 3
- 230000011514 reflex Effects 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 230000005670 electromagnetic radiation Effects 0.000 description 2
- 238000007687 exposure technique Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- SYXUBXTYGFJFEH-UHFFFAOYSA-N oat triterpenoid saponin Chemical compound CNC1=CC=CC=C1C(=O)OC1C(C=O)(C)CC2C3(C(O3)CC3C4(CCC5C(C)(CO)C(OC6C(C(O)C(OC7C(C(O)C(O)C(CO)O7)O)CO6)OC6C(C(O)C(O)C(CO)O6)O)CCC53C)C)C4(C)CC(O)C2(C)C1 SYXUBXTYGFJFEH-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 241001479434 Agfa Species 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- -1 poly(ethylene) Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- FVEFRICMTUKAML-UHFFFAOYSA-M sodium tetradecyl sulfate Chemical compound [Na+].CCCCC(CC)CCC(CC(C)C)OS([O-])(=O)=O FVEFRICMTUKAML-UHFFFAOYSA-M 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/46—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by the light-to-heat converting means; characterised by the heat or radiation filtering or absorbing means or layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/36—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties
- B41M5/368—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties involving the creation of a soluble/insoluble or hydrophilic/hydrophobic permeability pattern; Peel development
Definitions
- the present invention relates to a process for the production of copies by a brief intensive exposure, especially by reflex exposure, the copying material being exposed to light comprising substantially no infrared radiation.
- Suitable copying materials for use in the flash exposure technique are described in Belgian patent specifications 656,713 and 674,869 respetcively and in the specification of Marcel Nicholas Vrancken et al., US. application Ser. No. 550,834, filed May 17, 1966.
- Suitable materials according to the latter Belgian patent specification comprise a recording layer wherein an imagewise change in solubility or permeability for water or aqueous solutions is obtained by heating.
- G 10% aqueous solution of gelatin 5O 40% aqueous dispersion of poly(ethylene) having a particle size of 0.1a and an average molecular weight between 15,000 and 30,000 Water 320 60% aqueous dispersion of carbon 4 5% aqueous solution of sodium tetradecylsulphate 40 The material is then dried with an air-stream. at 30 C.
- the heat-sensitive copying material 30 is exposed reflectographically to an original 34 comprising coloured image parts by means of a xenon gas discharge lamp 35.
- the exposed material is slightly Wetted with water and then with its heat-sensitive layer 33 pressed against a receiving paper.
- the material and the receiving paper are conducted between two pressure rollers at a travelling speed of approximately 10 cm./sec., one of the rollers being heated to 35 C. When emerging from between the rollers, both materials are immediately peeled apart.
- a thin stratum of the heat-sensitive layer 33 is transferred image-wise to the receiving paper so as to form a legible print in accordance with the original 34.
- EXAMPLE 2 Production of the infrared filter A composition consisting of 50 g. of gelatin, 8 g. of Prussian blue, and 450 g. of water is applied to a gelatincoated cellulose triacetate support pro rate of 50 g. per sq. m. The resulting material is dried.
- the absorption curve of the material is represented by the curve B in FIG. 1, the ordinate indicating the absorption and the abscissa indicating the wavelengths.
- the filter is used in the same manner as described in Example 1 and yields a same improvement.
- EXAMPLE 3 Production of a heat-sensitive material with built-in infrared material A composition consisting of 10 g. of a dispersion of 13 g. of Prussian blue in 300 g. of a 4.5% aqueous gelatin solution, 10 g. of a 12% aqueous solution of saponine, and 10 g. of a 2.5% aqueous solution of the sodium salt of the condensation product from oleic acid and methyl-- taurine is applied to a gelatin-coated cellulose triacetate support pro rata of 130 g. per sq. 111.
- the resulting material is coated with a second layer pro rata of 36 g. per sq. m. from the following composition:
- the material is then dried with an air-stream at 30 C.
- An air-stream at 30 C.
- EXAMPLE 4 A heat-sensitive material as described in the abovementioned Belgian patent specification 657,5 2, filed Dec. 23, 1964 by Agfa A.G. is processed as defined therein.
- the original is a copy that comprises red image areas absorbing almost no infrared radiation and black image areas absorbing the infrared radiation very well.
- the glass cylinder of the exposure apparatus is changed in such a way that the infrared radiation in the copying light is absorbed essentially, a true copy is obtained without diificulties.
- the following alterations may be introduced in the glass cylinder of the exposure apparatus:
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEA49469A DE1242247B (de) | 1965-06-12 | 1965-06-12 | Verfahren zur Herstellung von Kopien durch Blitzbelichtung |
Publications (1)
Publication Number | Publication Date |
---|---|
US3511652A true US3511652A (en) | 1970-05-12 |
Family
ID=6936889
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US557259A Expired - Lifetime US3511652A (en) | 1965-06-12 | 1966-06-13 | Process for the reproduction of information by short-duration,high-intensity exposure of a heat-sensitive material to visible light |
Country Status (6)
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3619157A (en) * | 1966-10-24 | 1971-11-09 | Agfa Gevaert Nv | Thermo recording |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0373814A (ja) * | 1989-08-15 | 1991-03-28 | Jujo Paper Co Ltd | 光出力、主波長識別方法 |
US5151595A (en) * | 1990-10-16 | 1992-09-29 | Simon Marketing, Inc. | Imaging device and method for developing, duplicating and printing graphic media |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3121162A (en) * | 1960-04-16 | 1964-02-11 | Eastman Kodak Co | Thermographic colloid transfer process |
US3298833A (en) * | 1960-12-30 | 1967-01-17 | Gen Electric | Method for storing information |
-
1965
- 1965-06-12 DE DEA49469A patent/DE1242247B/de active Pending
-
1966
- 1966-05-27 CH CH778766A patent/CH464249A/de unknown
- 1966-06-13 NL NL6608150A patent/NL6608150A/xx unknown
- 1966-06-13 US US557259A patent/US3511652A/en not_active Expired - Lifetime
- 1966-06-13 GB GB26184/66A patent/GB1160225A/en not_active Expired
- 1966-06-13 BE BE682428D patent/BE682428A/xx unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3121162A (en) * | 1960-04-16 | 1964-02-11 | Eastman Kodak Co | Thermographic colloid transfer process |
US3298833A (en) * | 1960-12-30 | 1967-01-17 | Gen Electric | Method for storing information |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3619157A (en) * | 1966-10-24 | 1971-11-09 | Agfa Gevaert Nv | Thermo recording |
Also Published As
Publication number | Publication date |
---|---|
DE1242247B (de) | 1967-06-15 |
BE682428A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1966-12-13 |
CH464249A (de) | 1968-10-31 |
NL6608150A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1966-11-25 |
GB1160225A (en) | 1969-08-06 |
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