Classifications

• • D—TEXTILES; PAPER
  • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
  • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
  • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
  • D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
  • D02J1/227—Control of the stretching tension; Localisation of the stretching neck; Draw-pins
• • D—TEXTILES; PAPER
  • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
  • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
  • D01D5/00—Formation of filaments, threads, or the like
  • D01D5/20—Formation of filaments, threads, or the like with varying denier along their length

Definitions

• this invention relates to a method for the manufacture of a yarn having denier fluctuations or variations of random size and placement along the length of the yarn, and the invention also provides a novel yarn having such random denier fluctuations and textile products made therefrom.
• a number of methods have been suggested for producing yarn or threads with a fluctuating denier, i.e., with lengthwise portions of the yarn or threads having different diameters. For example, this has been accomplished by a controlled irregularity in the feed rate of the fiberforming mass to the spinning nozzles. The pressure variations resulting from these controlled changes of the feed rate cause corresponding changes in the thickness of the resulting thread.
• the filaments or threads are drawn off from the spinning nozzles at a variable or changing velocity, e.g., the drawing spool is operated in such a manner that it stands 'still at irregular intervals, thereby forming nodules, hubs or burls.
• Another object of the invention is to provide novel polyester yarns having 'an extremely high number of relatively short and thick nodules per unit length of the yarn.
• Still another object of the invention is to provide a method of producing random denier fluctuations in a polyester yarn in an economical manner and with easily controlled or regulated conditions and apparatus.
• these essential conditions include the following:
• the stretching pin must be maintained at a temperature of 60 C. to 105 C., preferably 65 C. to 85 C.;
• the stretching ratio must be about 60 to preferably 66 to 74%, of the normal stretching ratio which is defined herein as the ratio of the unstretched length of yarn to its stretched length with reference to an initial yarn of the same denier which has been uniformly stretched to a breaking elongation of 20%;
• the thread tension after the stretching pin i.e., in the length of yarn following this pin, must correspond to a value of about 0.2 to 1.1 grams/ denier, preferably about 0.45 to 0.9 gram/denier;
• the ratio of thread tension after the stretching pin to the thread tension before the pin should fall within limits of about 1:15 to 1:4, preferably about 1:19 to 1:2.6.
• the best stretching ratio for purposes of the present invention is between about 122.2 and 1:3.4.
• a higher or lower spinning ratio can be used, depending upon the extent 6 to which one deviates from conventional melt-spinning conditions.
• the pin diameter, pin surface, pin temperature, stretching velocity, thread tension and stretch ratio all influence the desired effect in forming the nodules or thickened portions of the yarn to different degrees and quite considerably in some instances.
• the pin should of course have a reasonably smooth surface to avoid snagging, and one preferably employs a pin having a high gloss or dull chrome finish with a diameter of about to 60 mm., preferably to 40 mm. Above or below this range of the diameter, the effect on the thread vanishes. If the pin diameter is increased beyond this range, the resulting yarn has undesirable completely unstretched portions and proportionately long partly stretched portions. With a decreasing pin diameter, the desired effect is gradually reduced and finally vanishes completely.
• the best stretch ratio for purposes of the invention is particularly dependent upon the spinning velocity or spindraw with its related pre-orientation of the filaments during the melt-spinning process. For this reason, it is preferable to define the essential conditions of the process in terms of a percentage of the normal stretch ratio providing a 20% breaking elongation, since this parameter can also be further qualified so as to require the yarn to be drawn for purposes of the invention to provide an elongation value of to 80%, preferably to 65%, in the finished product.
• the above-noted values of stretching ratio i.e., 1:2.2 to 123.4 and preferably 1:2.5 to 123.1, represent the limits for an initial unstretched polyester yarn which has been melt-spun at a drawing-off velocity of about 1200 to 800 meters/minute. Variations in the spinning or drawing-off velocity from these usual meltspinning conditions naturally require a corresponding adjustment of the stretch ratio.
• the finished yarn product of the stretching method of this invention has a number of novel and advantageous properties.
• the yarn exhibits a very high number of about 15 to 35, preferably 20 to 30, nodules or partly stretched thickened portions per meter length of the yarn, and these nodules are randomly spaced from one another at intervals ranging from about 0.5 to 8 centimeters, preferably about 0.8 to 6 centimeters.
• the yarn also exhibits a breaking elongation of about 30 to 80%, preferably 35 to 65%, and a shrinkage capacity in boiling water, i.e., at 100 C., of about 20 to 50%.
• the yarns or threads of the invention are especially adapted to be processed into woven or knitted textile fabrics, either alone or in combination with other types of threads, and these fabrics can then be dyed with any known dyestuif for polyester fibers which is capable of yielding a different strength of dyeing as between the thicker and thinner portions of the special yarn of the invention.
• any known dyestuif for polyester fibers which is capable of yielding a different strength of dyeing as between the thicker and thinner portions of the special yarn of the invention.
• basic dyesand dispersion dyes available for this purpose, i.e., which are recognized dyes which will enhance rather than cover the variable dyeability of yarns with denier fluctuations.
• a fabric composed of the yarn of the present invention has a texture as well as a completely random pattern quite similar to so-called Honan silk.
• the variations in d ameter of the yarn according to the invention are also completely irregular, and the ratio of maximum to minimum denier generally falls in a range of about 1.2:1 to 28:1.
• a cross-section at any particular point exhibits a degree of stretching some place between a completely unstretched thread and a completely stretched thread, the enlarged or thickened portions of the yarn naturally exhibiting less stretching than the thinner portions.
• completely unstretched portions of the thread or yarn are quite minimal.
• One of the most important advantages of the yarn produced according to the invention resides in this completely irregular or random size of the nodule diameter as well as random nodule length and spacing, because textile fabrics or knitted goods produced from this yarn have an ideal texture without any danger of exhibiting so-called pictures, patterns or designs on the surface of the finished textile product.
• Polyethylene terephthalate is the most common thermoplastic polymer employed for melt-spinning fiber-forming filaments and is therefore preferred for purposes of the present invention.
• other fiber-forming polyesters are equally suitable whether modified forms of polyethylene terephthalate or other well-known polyalkylene terephthalates of about 2 to 10 carbon atoms in the alkylene chain.
• These polyesters are produced according to wellknown processes, e.g. as described in Artificial Fibres by Moncrieif, John Wiley & Sons, Inc., New York (1954), pp. 264-277, and as first developed according to the Whinfield and Dickson patent, U.S. 2,465,319.
• melt-spinning such polymers is likewise conventional as well as the type of equipment or apparatus required.
• filaments which are meltspun with diameters of approximately 25 my to 46 my. When stretched to a uniform denier with an elongation value of 20%, these filaments have an individual denier of 1.5 to 5.0
• the heated stretching pin is the only device which requires a change from the conventional diameter to a larger diameter.
• the polyester melt is spun from the usual spinneret or spinning nozzles and preferably drawn at a conventional spinning velocity while solidifying into unstretched filaments. These filaments as a thread or yarn are then collected on the usual take-up spool or they can be directed immediately to the stretching method of the invention.
• the apparatus for this stretching method is quite simple and inexpensive because the yarn is merely directed from a feed roll to a draw roll with the heated stretching pin interposed therebetween, the yarn preferably being wound approximately once around this pin.
• Conventional means can be used to heat this pin and to provide the required stretching velocity, stretch ratio and thread tension by using regulatable means of rotating the feed and draw rolls.
• the tension on the thread is best regulated by a slight variation of surface contact of the yarn with the circumference of the stretching pin.
• the processing or. fabrication of the novel yarn into textile products can be carried out with any conventional apparatus using known weaving or knitting techniques.
• the novel yarn can be used either as the warp or weft thread in combination with other natural or synthetic threads.
• the effect of denier fluctuations is especially enhanced by using the novel yarn in both warp and weft threads.
• Dyeing of the textile fabric is quite conventional, but again the desired effect is enhanced by avoiding the use of dyes which cover or mask the denier variations.
• EXAMPLE 1 Polyethylene terephthalate was melt-spun at a spinning velocity of 1000 meters/ minute into a yarn of a nominal titer of 68 denier (measured as yarn stretched to a uniform denier having an elongation at break of 20%). The unstretched yarn was then processed at an average stretch velocity of 450 meters/minute on a stretching pin of 32 mm. diameter and having a dull chrome surface heated to a temperature of 65 C., the yarn being wrapped once around the pin and drawn at a stretch ratio of 1:28. The resulting yarn exhibited very pronounced denier variations. There were approximately 20 to 25 thick nubs or nodules per meter and distance between adjacent nodules fluctuated in a range of 1 to 5 centimeters. The variations in cross-sectional diameter of the individual nodules were in an area of about 1228 as the ratio of thinner diameter to the nodule diameter, and substantially no completely unstretched portions existed in the yarn.
• EXAMPLE 2 A series of tests were carried out to obtain polyethylene terephthalate yarns with denier fluctuations similar'to that produced in Example 1 but using various stretch ratios in order to observe their effect on other characteristics of the finished yarn. These tests are summarized in the following table.
• a method of producing a polyester yarn with random denier fluctuations comprising stretch ing a previously unstretched polyester yarn on a stationary heated stretching pin having a diameter of 15 to 60 mm. at a pin temperature of 60 to 105 (3., said yarn being drawn at a stretching ratio of 60 to 80% of the normal stretching ratio at which an elongation value of is achieved while placing the yarn under a thread tension following the stretching pin of 0.2 to 1.1 grams/ denier with a ratio of the thread tension after the stretching pin to the thread tension before the stretching pin of about 1:1.5 to 1:4.
• While the desired dyeing effect is thus somewhat dependent upon the nominal denier of the yarn being subjected to the method of the invention, one can select suitable stretching conditions within the critical limits of the invention so as to produce denier fluctuations which are capable of giving a desirable textured effect.
• suitable stretching conditions within the critical limits of the invention so as to produce denier fluctuations which are capable of giving a desirable textured effect.
• disperse azo dyes commonly used for dyeing polyethylene terephthalate
• various pleasing effects can be obtained, e.g. by pre-dyeing the individual threads which is also advantageous because of the shrinkage values of the novel yarn.
• the texture is also brought out in an advantageous manner by dyeing the fabric in one piece even when consisting solely of threads produced according to the invention.
• the number and size as well as the spacing of the denier fluctuations can be varied as desired without any difficulty in reproducing the specific effect desired in any given case. Also, the method of the invention achieves this result at considerably lower effort and expense as compared to prior attempts of achieving random denier fluctuations.
• the novel yarn of the invention is therefore stretching ratio is about 1:2.2 to 1:3.4.

Landscapes

• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Mechanical Engineering (AREA)
• Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
• Artificial Filaments (AREA)

Applications Claiming Priority (2)

Publications (1)

Family

ID=26001456

Family Applications (1)

Country Status (9)

Cited By (4)

Citations (5)

• 1967
  • 1967-03-13 BE BE695390D patent/BE695390A/xx not_active IP Right Cessation
  • 1967-03-17 CH CH942167D patent/CH942167A4/xx unknown
  • 1967-03-31 DK DK180767AA patent/DK128612B/da unknown
  • 1967-04-03 NL NL6704702A patent/NL6704702A/xx unknown
  • 1967-04-06 AT AT328667A patent/AT325191B/de not_active IP Right Cessation
  • 1967-04-06 LU LU53369D patent/LU53369A1/xx unknown
  • 1967-04-11 GB GB06587/67A patent/GB1188654A/en not_active Expired
  • 1967-04-14 US US630819A patent/US3478143A/en not_active Expired - Lifetime
  • 1967-04-27 SE SE6001/67A patent/SE306802B/xx unknown

Patent Citations (5)

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