US3464779A - Methods for dyeing pile fabrics and colored fabrics obtained thereby - Google Patents

Methods for dyeing pile fabrics and colored fabrics obtained thereby Download PDF

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Publication number
US3464779A
US3464779A US532075A US3464779DA US3464779A US 3464779 A US3464779 A US 3464779A US 532075 A US532075 A US 532075A US 3464779D A US3464779D A US 3464779DA US 3464779 A US3464779 A US 3464779A
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United States
Prior art keywords
pile
fabrics
fibres
fabric
methods
Prior art date
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Expired - Lifetime
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US532075A
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English (en)
Inventor
Louis Collez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Peltex SA
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Peltex SA
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Publication date
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Publication of US3464779A publication Critical patent/US3464779A/en
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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0096Multicolour dyeing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0044Dyeing with a dye in volatilised form
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92Synthetic fiber dyeing
    • Y10S8/921Cellulose ester or ether
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92Synthetic fiber dyeing
    • Y10S8/922Polyester fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92Synthetic fiber dyeing
    • Y10S8/924Polyamide fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92Synthetic fiber dyeing
    • Y10S8/927Polyacrylonitrile fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/929Carpet dyeing

Definitions

  • the present invention has for its object the dyeing of pile fabrics, chiefly of imitation fur fabrics, the pile of which is constituted by synthetic or artificial fibres.
  • the migration may be complete in as much as a fraction of the fibres on which the dyestuif has been applied loses its dye and the intensity of the migration is gradual; in other words the intensity of coloration along the fibre starting from the point of application of the dyestuff is shaded off.
  • the present invention has for its object to resort to this dyestulf subliming or diffusing phenomenon with a view to providing novel colored effects on pile fabrics and to obtaining, chiefly in the case of imitation fur, a coloration which varies throughout the depth of the pile, that is along the different fibres forming the pile so as to imitate certain effects of natural furs.
  • the present invention covers thus a method which consists in coloring a pile fabric and chiefly an imitation fur of which the pile is made of artificial or synthetic fibres, said coloring being obtained by applying in a uniform manner or otherwise on the ends of the fibres forming the pile a dispersed dyestuif and by subjecting the fabric to a heating at a temperature and for a duration which depend on the speed of migration or so-called sublimation speed of the dyestuif resorted to with a view to obtaining a coloration shaded olf throughout the depth of the pile.
  • Said method is applicable with a single dyestulf and, in such a case, only the shading off phenomenon is resorted to which is ascribable to the diffusion and, if desired, the complete migration of the dyestuif.
  • the dyestutf which shows both the highest speed of migration and the highest maximum diffusion appears at a point furthest from the point of application of the dyestuif; in other words, it enters more deeply inside the pile of the imitation fur and, when points nearer and nearer the ends of the fibres are considered, there is found a mixture of two and then of three dyestuffs and so on until a mixture of all the basic dystulfs is found at the tips of the fibres, while possibly one or more dyestulfs which have migrated completely off the point of application of the dyestuif are no longer present at said point of application.
  • the dyestuff may be applied in a wet phase by means of a brush or of a gun or else in a dry phase by sprinkling over the free ends of the pile fibres of the fabric. It may be executed throughout the fabric so as to obtain a uniform effect over its entire surface or else it may be executed by printing within a frame, by printing in a wet phase by means of .a brush or a gun with a cut out mask or else by printing in a dry phase under a suitably cut mask with the possible application of an electrostatic field.
  • the heat treatment may be executed by causing the fabric to pass underneath infrared rays, inside a tunnel kiln or in an oven at temperatures ranging between about and 200 C.
  • the invention has also for its object the novel article of manufacture constituted by pile fabrics and imitation furs showing shaded off colors as obtained by the method forming the object of the invention.
  • Example 1 There is applied, over a piece of fabric forming an imitation fur and the pile of which is constituted by acrylic fibres of 25 deniers of a white color and of an average length of 70 mm., a suspension in water of dispersed dyestuif projected by a gun. To this end, there is added to one litre of water at 40 C. or thereabouts and incorporating 2 gr. of a dispersing reagent the following dyestuffs under energetic stirring conditions.
  • Acetoquinone Yellow SJZ (Chemical Index No. 14)- Cibacete Blue F3R (Chemical Index No. 3) 8 Cibacete Brown RBN (a heterogeneous dyestuff having no color index number) 32 Cibacete Red 3B (Chemical Index No. 15)
  • S Acetoquinone Yellow (a product of the French Francolor Cy) is a dyestuff which is energetically diffused while the Brown and the Red are diifused to a medium extent and the Blue diffuses but little (these Cibacetes being products of the Swiss Ciba Cy). Consequently the free end of the pile, will be very dark (brown plus blue).
  • the middle of the fibres will be of .a shaded off reddish brown and the bottom will be slightly colored in yellow, the passage between the different hues being obtained in a gradual manner.
  • the application of said dyestutf dispersion by means of a gun onto the fabric should be executed through a number of passes so as to make the hues more uniform.
  • the fabric is then caused to dry in a stream of hot air after which the dyestulf is fixed and caused to diffuse under the action of a battery of infra-red lamps of a sufiicient power, of say about to kilowatts per square meter, during one minute.
  • the whole arrangement is then allowed to cool and the dyed fabric is washed in a succession of baths of tepid water at about 30 to C., incorporating a few drops of a dispersing reagent.
  • the imitation fur is then rinsed with pure water and dried in hot air.
  • a subsequent brushing causes the fibres to return into parallelism and it is then possible to subject the dry imitation fur to be conventional finishing operations.
  • a method for dyeing pile fabrics to produce a material such as imitation fur comprising synthetic polymer fibres, consisting essentially in applying to only the free ends of the pile fibers dispersed tdyestuif, and thereafter heating the fabric during a predetermined time at a predetermined temperature Within the thermofixing range for the dyestuif to obtain a migration of the dyestuff along the length of the fibres and thereby ashaded off coloration of the latter.
  • a method as claimed in claim 1 consisting in applying to the free ends of the pile fibres a pure dyestuff adapted to diffuse along the fibres in a uniform manner.
  • a method as claimed in claim 1 consisting in applying to the free ends of the pile fibres a mixture of dyestuifs having predetermined speeds of migration and predetermined maximum diffusion distances.
  • a method as claimed in claim 1 consisting in applying the dyestutf in a dry phase by sprinkling it over the free ends of the pile fibres.
  • a method as claimed in claim 1 consisting in applying the dyestuff uniformly throughout the extent of the fabric.
  • a method as claimed in claim 1 consisting in applying the dyestuff selectively over fractions of the fabric.
  • a method as claimed in claim 1 consisting in executing the heating step at a temperature ranging between about and 200 C.
  • a pile fabric chiefly an imitation fur including fibers showing a longitudinally shaded off coloration.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
US532075A 1965-03-10 1966-03-07 Methods for dyeing pile fabrics and colored fabrics obtained thereby Expired - Lifetime US3464779A (en)

Applications Claiming Priority (1)

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FR8682 1965-03-10

Publications (1)

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US3464779A true US3464779A (en) 1969-09-02

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US (1) US3464779A (US20110009641A1-20110113-C00185.png)
BE (1) BE677137A (US20110009641A1-20110113-C00185.png)
GB (1) GB1121886A (US20110009641A1-20110113-C00185.png)
NL (1) NL6603136A (US20110009641A1-20110113-C00185.png)
SE (1) SE313037B (US20110009641A1-20110113-C00185.png)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3751284A (en) * 1971-07-02 1973-08-07 United Merchants & Mfg Tone-on-tone resin bonded pigmenting of flock printed fabric with low temperature air drying
US3888623A (en) * 1972-12-08 1975-06-10 Ici Ltd Transfer materials
US3915629A (en) * 1972-01-05 1975-10-28 Georges Pouille Plush fabric having a long pile
US3966396A (en) * 1974-12-18 1976-06-29 F P Licensing Co Inc Textile printing process and transfer medium
US3986235A (en) * 1975-06-26 1976-10-19 Champion International Corporation Space dyeing of textile strands
US4163642A (en) * 1977-07-07 1979-08-07 Collins & Aikman Corporation Process for the sublimation transfer dyeing of textile materials including subsequent conductive heading
US4242092A (en) * 1970-11-12 1980-12-30 Glover Richard D Method of sublimatic printing on sheet structures
US4541340A (en) * 1982-07-02 1985-09-17 Markem Corporation Process for forming permanent images using carrier supported inks containing sublimable dyes
US6634070B2 (en) * 2001-08-03 2003-10-21 Milliken & Company Multi-colored materials and method of making same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU6373480A (en) * 1979-10-30 1981-05-07 Unilever Ltd. Dyeing textile products

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2816811A (en) * 1955-05-12 1957-12-17 Deep Dye Ind Inc Printing and dyeing of pile carpeting
US3118723A (en) * 1961-02-08 1964-01-21 Arthur J I Harding Process for dyeing nylon to produce multi-colored dyeings
US3181749A (en) * 1960-12-23 1965-05-04 Pegg S & Son Ltd Dyeboarding method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2816811A (en) * 1955-05-12 1957-12-17 Deep Dye Ind Inc Printing and dyeing of pile carpeting
US3181749A (en) * 1960-12-23 1965-05-04 Pegg S & Son Ltd Dyeboarding method
US3118723A (en) * 1961-02-08 1964-01-21 Arthur J I Harding Process for dyeing nylon to produce multi-colored dyeings

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4242092A (en) * 1970-11-12 1980-12-30 Glover Richard D Method of sublimatic printing on sheet structures
US3751284A (en) * 1971-07-02 1973-08-07 United Merchants & Mfg Tone-on-tone resin bonded pigmenting of flock printed fabric with low temperature air drying
US3915629A (en) * 1972-01-05 1975-10-28 Georges Pouille Plush fabric having a long pile
US3888623A (en) * 1972-12-08 1975-06-10 Ici Ltd Transfer materials
US3966396A (en) * 1974-12-18 1976-06-29 F P Licensing Co Inc Textile printing process and transfer medium
US3986235A (en) * 1975-06-26 1976-10-19 Champion International Corporation Space dyeing of textile strands
US4163642A (en) * 1977-07-07 1979-08-07 Collins & Aikman Corporation Process for the sublimation transfer dyeing of textile materials including subsequent conductive heading
US4541340A (en) * 1982-07-02 1985-09-17 Markem Corporation Process for forming permanent images using carrier supported inks containing sublimable dyes
US6634070B2 (en) * 2001-08-03 2003-10-21 Milliken & Company Multi-colored materials and method of making same

Also Published As

Publication number Publication date
DE1519504A1 (de) 1970-07-23
SE313037B (US20110009641A1-20110113-C00185.png) 1969-08-04
NL6603136A (US20110009641A1-20110113-C00185.png) 1966-09-12
BE677137A (US20110009641A1-20110113-C00185.png) 1966-07-18
GB1121886A (en) 1968-07-31

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