US3448801A - Method for creating a permeable fragmented zone within an oil shale formation - Google Patents

Method for creating a permeable fragmented zone within an oil shale formation Download PDF

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US3448801A
US3448801A US653139A US3448801DA US3448801A US 3448801 A US3448801 A US 3448801A US 653139 A US653139 A US 653139A US 3448801D A US3448801D A US 3448801DA US 3448801 A US3448801 A US 3448801A
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oil shale
devices
shale formation
cavity
energy
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Philip J Closmann
Helmer Ode
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Shell USA Inc
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Shell Oil Co
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    • E—FIXED CONSTRUCTIONS
    • E21—EARTH OR ROCK DRILLING; MINING
    • E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/25—Methods for stimulating production
    • E21B43/26—Methods for stimulating production by forming crevices or fractures
    • E21B43/263—Methods for stimulating production by forming crevices or fractures using explosives
    • E21B43/2635—Methods for stimulating production by forming crevices or fractures using explosives by means of nuclear energy

Definitions

  • a very high energy explosive such as a nuclear device
  • a plurality of explosive devices of lesser energy, nuclear or non-nuclear, spaced radially from the high energy explosive are detonated between the time the initial cavity within the oil shale formation begins to expand radially outward as a result of the detonation of the high energy explosive, and the time at which a chimney of rubble of the fragmentsd oil shale formation is formed by the collapsing of the cavity roof of the oil shale formation.
  • the present invention relates to a process for creating a zone of relatively high permeability in an oil shale; more particularly, it relates to a process of utilizing high and low energy explosives, strategically placed, to cause the formation of a fragmented rubble zone of the oil shale formation alfected by systematically detonating the explosives.
  • thermonuclear explosives may become available for a fraction of a mill per kilowatt-hour equivalent has led to the realization that ultra-high energy explosives can be used in mining operations to break up formation and in the oil industry to increase or stimulate productivity by heating or raising the pressure of a reservoir.
  • the shock wave resulting from such nuclear explosions created a highly fractured region surrounding the chimney which may become many times larger in volume than the chimney itself.
  • the shale oil within the fragmented rubble zone including both the chimney and the surrounding fractured region can be recovered by known oil recovery means, such as in-situ retorting.
  • One recovery process would be to inject hot fluid into the zone so that the oil shale components 3,448,801 Patented June 10, 1969 ice SUMMARY OF THE INVENTION
  • the invention relates to a method for increasing the permeability in the rigion immediately surrounding the primary rubble zone of an oil shale formation.
  • a primary nuclear device is placed within a subterranean oil shale formation and is surrounded by a plurality of radially-placed devices of lesser explosive energy, nuclear or non-nuclear.
  • the radially- Iplaced devices are programmed to be detonated by either the main shock wave from the primary device or exploded by other means after the main shock wave has passed.
  • the lesser explosive energy devices are preferably detonated between the time the spherical cavity caused by the explosion of the primary device begins to expand radially outward and the time at which a chimney is formed by the collapse of the cavity roof.
  • FIGURE 1 shows a vertical cross-sectional view of an oil shale formation prior to detonating a plurality of explosive devices within the formation;
  • FIGURE 2 is a diagrammatic view of the cavities formed by detonating the explosive devices *within the oil shale formation of FIGURE 1 taken along a plane through the lines 2-2 of FIGURE 1;
  • FIGURE 3 is a vertical cross-sectional view of the oil shale formation of FIGURE 1 after the primary explosive device has been detonated;
  • FIGURE 4 is a vertical cross-sectional view of the final rubble zone created by detonating all of the explosive devices of FIGURE 1.
  • FIGURE 1 shows subterranean oil shale formation 11 having a primary explosive device 12 located within the formation 11.
  • Primary explosive device 12 is surrounded by a plurality of lesser energy explosive devices 13.
  • the device 12 can be either nuclear or non-nuclear; if a nuclear device is detonated in the subterranean oil shale formation 11, a strong shock wave from the nuclear device begins to move radially outwardly, vaporizing, melting, crushing, cracking and displacing the oil shale formation 11.
  • a generally spherical cavity i.e., the central cavity 14 in FIGURES 2 and 3 which continues to grow until the internal pressure is balanced by the lithostatic pressure.
  • the cavity 14 persists for a variable time depending on the composition of the oil shale formation 11 and then collapses to form a chimney 15 (FIGURE 4). Collapse progresses upwardly until the volume initially in the cavity is distributed between the fragments of the oil shale of formation 11.
  • the size of the cylindrical rubble zone i.e., the chimney formed by the collapse of the cavity 14 can be estimated from the fact that the initial cavity 14 expands to the pressure exerted by the overlying portions of earth formations 11 and 16.
  • a zone of permeability 17 within the fragmented oil shale formation is formed surrounding the chimney 15 as can be seen in FIGURE 4.
  • the permeability of this zone 17 can be increased by surrounding the primary explosive device which formed the central cavity with a plurality of devices 13 of lesser explosive energy.
  • a primary nuclear explosive device 12 is surrounded by explosive devices 13, equally spaced from each other and radially spaced from the primary explosive device 12.
  • These lesser energy devices :13 are preferably on substantially the same horizontal plane as the primary nuclear device (see FIGURE 1) and 500 to 1,000 feet from the nearest part of the outer wall of the central cavity 14 produced by the explosion of the high energy nuclear device 12.
  • the lesser energy devices 13 preferably have an energy yield no less than one-fourth of the primary high energy 12 nuclear device and can be either nuclear or non-nuclear.
  • the high energy device 12 could be non-nuclear and the lesser energy devices 13 could be greater in number as long as the total of the individual energy yield of the latter was approximately equal to the total combined energy yield of the primary explosive device.
  • Their individual energy yields i.e., the lesser energy devices 13 should be accordingly substantially equal to each other.
  • the lesser energy explosive devices 13 form cavities 18 (FIGURE 2) when detonated, surrounded by fractured zones 19 as can be seen in FIGURE 2.
  • the lesser energy devices 13 are preferably preset with detonating means adjusted to explode upon arival of the main shock wave from the explosion of the primary explosive device 12. Alternatively, the lesser energy devices 13 can be suitably delayed to explode after passage of the main shock wave.
  • another characteristic of the explosion of the primary explosive device 12 can be utilized to detonate the lesser energy devices 13, as, for example, changes in temperature or pressure as a result of the explosion of the primary explosive device.
  • the lesser energy explosives 13 are detonated substantially simultaneously with respect to each other so that the energies from the pluralities of the explosions are additively focused toward the cavity 14 formed by the central explosion of device .12.
  • the detonations of the satellite or lesser energy explosives 13 are actuated in response to the arrival of the pressure Wave from the detonation of centrally located nuclear explosive device 12 at a location spaced generally horizontally from the central explosion.
  • the time at which the lesser energy explosives 13 are detonated is preferably between about the time the shock wave arrives at the surrounding explosives and about the time the pressure in the central cavity 14 becomes as low as the pressure of overburden.
  • this time period lies between the period at which the spherical cavity 14 (FIGURE 3) formed by the central explosion begins to expand radially outwardly and the time at which a chimney 15 is formed by the collapse of the cavity roof 20.
  • the lesser energy explosives 13 are thus spaced from the central cavity 14 by sufficient distances so that the explosions from the satellite explosions are capable of causing rock to move into the void space within the central cavity 14 formed by the higher energy explosive 12.
  • the main shock wave from the higher energy explosive 12, in the case of a nuclear device travels at about five meters per millisecond and the initial spherical cavity 14 persists for times that vary with the composition of the shale oil formation 11.
  • the radius of the fractured zone outside the central cavity was approximately proportional to the radius of the central cavity 14.
  • This fractured zone 17 created as disclosed in this application, has been found to have a relatively high and uniform permeability.
  • Shale oil can be extracted from rubbled zones 15 and 17 by any known means, such as in situ retorting. Suitable materials and techniques for use in treating the fragmented oil shale 11 within the permeable zones 15 and 17 are disclosed in copen-ding applications, Ser. No. 632,006, filed Apr. 19, 1967 and Ser. No. 656,815, filed July 28, 1967.
  • a method of creating a zone of relatively high permeability within a subterranean oil shale formation com' prising the steps of:
  • step of placing a relatively high energy explosive device within the formation includes placing a nuclear device within the formation.
  • step of exploding the plurality of devices includes the step of programming the plurality of devices to be detonated as a result of a characteristic of the explosion of the high energy explosive device.
  • placing of a plurality of devices includes placing a number of such devices whose energy yield are substantially equal to each other, the total energy yield of the plurality of devices 5 being substantially equal to the energy yield of the high energy device.
  • placing of the plurality of devices comprises placing four such devices on the same horizontal plane as the high energy device and substantially equally spaced from the high energy explosive device and from each other.
  • placing of the plurality of devices includes placing such devices approximately 500 to 1,000 feet from the nearest part of the outer wall of the cavity to he formed within the oil shale formation.

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  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Description

June-10, 1969 P. J. CLOSMANN ETAL 3,448,801
METHOD FOR CREATING A PERMEABLE FRAGMENTED zoun WITHIN AN on. same: FORMATION Filed July-l5, 1967 Sheet of 2 INVENTORS'. v
PHILIP J. VCLOSMANN HELMER ODE BY: THEIR ATTORNEY June 10, 1969 P. J. CLOSMANN ET AL 3,448,801
' METHOD FOR CREATING A PERMEABLE FRAGMENTED ZONE WITHIN AN OIL SHALE FORMATION Filed July 15, 1967 Sheet 2 of 2 I NVENTORS:
PHILIP J. CLOSMANN HELMER oo BY: m THEIR ATTORNEY United States Patent 3,448,801 METHOD FOR CREATING A PERMEABLE FRAGMENTED ZONE WITHIN AN OIL SHALE FORMATION Philip J. Closmann, Houston, and Helmer Ode, Bellaire,
Tex., assignors to Shell Oil Company, New York, N.Y., a corporation of Delaware Filed July 13, 1967, Ser. No. 653,139 Int. Cl. E21h 43/25, 43/24 US. Cl. 166247 9 Claims ABSTRACT OF THE DISCLOSURE A method for creating a permeable zone in a subterranean oil shale formation by utilizing a plurality of strategically placed explosive devices of varying energy. A very high energy explosive, such as a nuclear device, is first exploded; then a plurality of explosive devices of lesser energy, nuclear or non-nuclear, spaced radially from the high energy explosive, are detonated between the time the initial cavity within the oil shale formation begins to expand radially outward as a result of the detonation of the high energy explosive, and the time at which a chimney of rubble of the fragmentsd oil shale formation is formed by the collapsing of the cavity roof of the oil shale formation.
BACKGROUND OF THE INVENTION Field 0 the invention The present invention relates to a process for creating a zone of relatively high permeability in an oil shale; more particularly, it relates to a process of utilizing high and low energy explosives, strategically placed, to cause the formation of a fragmented rubble zone of the oil shale formation alfected by systematically detonating the explosives.
Description of the prior art The fact that thermonuclear explosives may become available for a fraction of a mill per kilowatt-hour equivalent has led to the realization that ultra-high energy explosives can be used in mining operations to break up formation and in the oil industry to increase or stimulate productivity by heating or raising the pressure of a reservoir.
One of the chief uncertainties with regard to the effects of nuclear explosions within a subterranean oil shale formation is the permeability distribution surrounding the cavity and subsequent chimney produced by a detonation. In prior tests, nuclear devices have been detonated within various subterranean formations, and, at first, an almost spherical cavity filled with hot gases was formed. This cavity expanded until the pressure within the cavity equaled that of the overburden. On cooling, the roof of the cavity collapsed, since it could not support itself and a so-called chimney developed within the formation. Chimney growth ceased when the rock pile either filled the cavity or when a stable arch developed. Thus, the void space, or porosity of the broken rock in the chimney had approximately the same volume as the cavity before the roof began to fall in.
At the same time, the shock wave resulting from such nuclear explosions created a highly fractured region surrounding the chimney which may become many times larger in volume than the chimney itself. In an oil shale, the shale oil within the fragmented rubble zone including both the chimney and the surrounding fractured region can be recovered by known oil recovery means, such as in-situ retorting. One recovery process would be to inject hot fluid into the zone so that the oil shale components 3,448,801 Patented June 10, 1969 ice SUMMARY OF THE INVENTION The invention relates to a method for increasing the permeability in the rigion immediately surrounding the primary rubble zone of an oil shale formation. In a preferred embodiment, a primary nuclear device is placed within a subterranean oil shale formation and is surrounded by a plurality of radially-placed devices of lesser explosive energy, nuclear or non-nuclear. The radially- Iplaced devices are programmed to be detonated by either the main shock wave from the primary device or exploded by other means after the main shock wave has passed. The lesser explosive energy devices are preferably detonated between the time the spherical cavity caused by the explosion of the primary device begins to expand radially outward and the time at which a chimney is formed by the collapse of the cavity roof.
It is an object of this invention to increas the volume of a permeable zone of fragmented oil shale formation that is formed by detonating a high energy explosive device within the subterranean oil shale formation.
It is a further object to create a rubble zone of relatively high and uniform permeability within an oil shale formation.
Further objects of the invention will become apparent as the following description thereof proceeds in conjunction with the drawings.
BRIEF DESCRIPTION OF THE DRAWING FIGURE 1 shows a vertical cross-sectional view of an oil shale formation prior to detonating a plurality of explosive devices within the formation;
FIGURE 2 is a diagrammatic view of the cavities formed by detonating the explosive devices *within the oil shale formation of FIGURE 1 taken along a plane through the lines 2-2 of FIGURE 1;
FIGURE 3 is a vertical cross-sectional view of the oil shale formation of FIGURE 1 after the primary explosive device has been detonated; and
FIGURE 4 is a vertical cross-sectional view of the final rubble zone created by detonating all of the explosive devices of FIGURE 1.
DESCRIPTION OF THE PREFERRED EMBODIMENT FIGURE 1 shows subterranean oil shale formation 11 having a primary explosive device 12 located within the formation 11. Primary explosive device 12 is surrounded by a plurality of lesser energy explosive devices 13. The device 12 can be either nuclear or non-nuclear; if a nuclear device is detonated in the subterranean oil shale formation 11, a strong shock wave from the nuclear device begins to move radially outwardly, vaporizing, melting, crushing, cracking and displacing the oil shale formation 11. After the shock wave has passed, the high-pressure vaporized material expands, and a generally spherical cavity (i.e., the central cavity 14 in FIGURES 2 and 3) is formed which continues to grow until the internal pressure is balanced by the lithostatic pressure. The cavity 14 persists for a variable time depending on the composition of the oil shale formation 11 and then collapses to form a chimney 15 (FIGURE 4). Collapse progresses upwardly until the volume initially in the cavity is distributed between the fragments of the oil shale of formation 11. The size of the cylindrical rubble zone (i.e., the chimney formed by the collapse of the cavity 14 can be estimated from the fact that the initial cavity 14 expands to the pressure exerted by the overlying portions of earth formations 11 and 16.
A zone of permeability 17 within the fragmented oil shale formation is formed surrounding the chimney 15 as can be seen in FIGURE 4. The permeability of this zone 17 can be increased by surrounding the primary explosive device which formed the central cavity with a plurality of devices 13 of lesser explosive energy. For example, in FIGURE 1, a primary nuclear explosive device 12 is surrounded by explosive devices 13, equally spaced from each other and radially spaced from the primary explosive device 12. These lesser energy devices :13 are preferably on substantially the same horizontal plane as the primary nuclear device (see FIGURE 1) and 500 to 1,000 feet from the nearest part of the outer wall of the central cavity 14 produced by the explosion of the high energy nuclear device 12. The lesser energy devices 13 preferably have an energy yield no less than one-fourth of the primary high energy 12 nuclear device and can be either nuclear or non-nuclear. Of course, the high energy device 12 could be non-nuclear and the lesser energy devices 13 could be greater in number as long as the total of the individual energy yield of the latter was approximately equal to the total combined energy yield of the primary explosive device. Their individual energy yields (i.e., the lesser energy devices 13) should be accordingly substantially equal to each other.
The lesser energy explosive devices 13 form cavities 18 (FIGURE 2) when detonated, surrounded by fractured zones 19 as can be seen in FIGURE 2. The lesser energy devices 13 are preferably preset with detonating means adjusted to explode upon arival of the main shock wave from the explosion of the primary explosive device 12. Alternatively, the lesser energy devices 13 can be suitably delayed to explode after passage of the main shock wave. Of course, another characteristic of the explosion of the primary explosive device 12 can be utilized to detonate the lesser energy devices 13, as, for example, changes in temperature or pressure as a result of the explosion of the primary explosive device.
Because of this time delay, either detonating the lesser energy devices 13 upon arrival of the main shock wave or after the main shock wave has passed but before the central cavity 14 becomes filled with rubble due to the chimney collapse from above, the shock waves from the secondary explosions (that is, the explosions of the lesser energy devices 13) will cause spalling into the central cavity. The movement of rock towards the central cavity 14 due to the satellite explosions will enhance the permeability in the regions between these explosions and the central cavity 14, by allowing development of a greater void space in this region. This void space, indicated as a zone of increased permeability 17 in the drawings, has a high and uniform permeability in the fragmented oil shale formation 11.
It can be seen from the foregoing that the lesser energy explosives 13 are detonated substantially simultaneously with respect to each other so that the energies from the pluralities of the explosions are additively focused toward the cavity 14 formed by the central explosion of device .12. The detonations of the satellite or lesser energy explosives 13 are actuated in response to the arrival of the pressure Wave from the detonation of centrally located nuclear explosive device 12 at a location spaced generally horizontally from the central explosion. The time at which the lesser energy explosives 13 are detonated is preferably between about the time the shock wave arrives at the surrounding explosives and about the time the pressure in the central cavity 14 becomes as low as the pressure of overburden. Stated difierently, this time period lies between the period at which the spherical cavity 14 (FIGURE 3) formed by the central explosion begins to expand radially outwardly and the time at which a chimney 15 is formed by the collapse of the cavity roof 20. The lesser energy explosives 13 are thus spaced from the central cavity 14 by sufficient distances so that the explosions from the satellite explosions are capable of causing rock to move into the void space within the central cavity 14 formed by the higher energy explosive 12. The main shock wave from the higher energy explosive 12, in the case of a nuclear device, travels at about five meters per millisecond and the initial spherical cavity 14 persists for times that vary with the composition of the shale oil formation 11. Very little rock falls into this central cavity 14 until its pressure has decreased to about the pressure of the overburden. The decrease in the pressure of the central cavity 14 allows the weight of the overburden to stress the arch of rock that forms the roof 20 of the cavity, and this initiates, or at least accelerates, the relatively extensive collapsing that converts the spherical cavity 14 to rubblefilled chimney 15.
In the prior tests, the radius of the fractured zone outside the central cavity (the zone of increased permeability 17) was approximately proportional to the radius of the central cavity 14. This fractured zone 17, created as disclosed in this application, has been found to have a relatively high and uniform permeability. Shale oil can be extracted from rubbled zones 15 and 17 by any known means, such as in situ retorting. Suitable materials and techniques for use in treating the fragmented oil shale 11 within the permeable zones 15 and 17 are disclosed in copen-ding applications, Ser. No. 632,006, filed Apr. 19, 1967 and Ser. No. 656,815, filed July 28, 1967.
Various methods of carrying out the concepts of this invention may become apparent to one skilled in the art, and it is to be understood that such modifications fall within the spirit and scope of the appended claims- We claim as our invention:
1. A method of creating a zone of relatively high permeability within a subterranean oil shale formation com' prising the steps of:
placing a relatively high energy explosive device within the formation;
placing a plurality of devices of substantially lesser explosive energy within the formation;
spacing the plurality of devices such a distance from the relatively high energy device that the exploding of the plurality of devices can cause rubble from the oil shale formation to move into the area of the high energy explosive device;
exploding the relatively high energy explosive device Within the oil shale formation, thereby forming a cavity within the oil shale formation having a roof beneath the overburden which subsequently collapses to form a chimney of rubble within the oil shale formation; and exploding the plurality of devices between the time the initial cavity within the oil shale formation begins to expand radially outwardly as a result of the explosion of the high energy explosive device and the time at which the chimney of rubble of fragmented oil shale formation is formed by the collapsing of the cavity roof.
2. The method of claim 1 wherein the step of placing a relatively high energy explosive device within the formation includes placing a nuclear device within the formation.
3. The method of claim 1 wherein the step of exploding the plurality of devices includes the step of programming the plurality of devices to be detonated as a result of a characteristic of the explosion of the high energy explosive device.
4. The method of claim 1 wherein the placing of a plurality of devices includes placing a number of such devices whose energy yield are substantially equal to each other, the total energy yield of the plurality of devices 5 being substantially equal to the energy yield of the high energy device.
5. The method of claim 4 wherein the placing of the plurality of devices comprises placing four such devices on the same horizontal plane as the high energy device and substantially equally spaced from the high energy explosive device and from each other.
6. The method of claim 5 wherein the placing of the plurality of devices includes placing such devices approximately 500 to 1,000 feet from the nearest part of the outer wall of the cavity to he formed within the oil shale formation.
7. The method of claim 1 wherein the exploding of the plurality of devices includes exploding such devices after the main shock Wave from the high energy device has passed.
-8. The method of claim 1 wherein the exploding of the plurality of devices further includes exploding such de- References Cited UNITED STATES PATENTS 3,303,881 2/1967 Dixon 16636 3,342,257 9/1967 Jacobs et a1. 16636 FOREIGN PATENTS 1,147,517 11/1957 France.
1,278,435 10/ 1961 France.
STEPHEN I. NOVOSAD, Primary Examiner.
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3578080A (en) * 1968-06-10 1971-05-11 Shell Oil Co Method of producing shale oil from an oil shale formation
US3666014A (en) * 1969-12-29 1972-05-30 Shell Oil Co Method for the recovery of shale oil
US3677342A (en) * 1969-12-29 1972-07-18 Pan American Petroleum Corp Method of increasing size of underground nuclear chimney
US4025115A (en) * 1975-04-14 1977-05-24 Occidental Petroleum Corporation Method of enhancing recovery of oil from pillars adjacent in situ oil shaft retort
US4045085A (en) * 1975-04-14 1977-08-30 Occidental Oil Shale, Inc. Fracturing of pillars for enhancing recovery of oil from in situ oil shale retort
WO2013151603A1 (en) * 2012-01-13 2013-10-10 Los Alamos National Security, Llc Geologic fracturing method and resulting fractured geologic structure
US10246982B2 (en) 2013-07-15 2019-04-02 Triad National Security, Llc Casings for use in a system for fracturing rock within a bore
US10273792B2 (en) 2013-07-15 2019-04-30 Triad National Security, Llc Multi-stage geologic fracturing
US10294767B2 (en) 2013-07-15 2019-05-21 Triad National Security, Llc Fluid transport systems for use in a downhole explosive fracturing system
USD878163S1 (en) 2018-04-11 2020-03-17 Yeti Coolers, Llc Container

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FR1147517A (en) * 1955-03-01 1957-11-26 Deutsche Erdoel Ag Method of using underground deposits
FR1278435A (en) * 1961-01-23 1961-12-08 Method of using nuclear energy for the exploitation of underground mineral layers
US3303881A (en) * 1963-11-22 1967-02-14 Nuclear Proc Corp Underground nuclear detonations for treatment and production of hydrocarbons in situ
US3342257A (en) * 1963-12-30 1967-09-19 Standard Oil Co In situ retorting of oil shale using nuclear energy

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1147517A (en) * 1955-03-01 1957-11-26 Deutsche Erdoel Ag Method of using underground deposits
FR1278435A (en) * 1961-01-23 1961-12-08 Method of using nuclear energy for the exploitation of underground mineral layers
US3303881A (en) * 1963-11-22 1967-02-14 Nuclear Proc Corp Underground nuclear detonations for treatment and production of hydrocarbons in situ
US3342257A (en) * 1963-12-30 1967-09-19 Standard Oil Co In situ retorting of oil shale using nuclear energy

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3578080A (en) * 1968-06-10 1971-05-11 Shell Oil Co Method of producing shale oil from an oil shale formation
US3666014A (en) * 1969-12-29 1972-05-30 Shell Oil Co Method for the recovery of shale oil
US3677342A (en) * 1969-12-29 1972-07-18 Pan American Petroleum Corp Method of increasing size of underground nuclear chimney
US4025115A (en) * 1975-04-14 1977-05-24 Occidental Petroleum Corporation Method of enhancing recovery of oil from pillars adjacent in situ oil shaft retort
US4045085A (en) * 1975-04-14 1977-08-30 Occidental Oil Shale, Inc. Fracturing of pillars for enhancing recovery of oil from in situ oil shale retort
US9488456B2 (en) * 2012-01-13 2016-11-08 Los Alamos National Security, Llc Geologic fracturing method and resulting fractured geologic structure
US9835428B2 (en) 2012-01-13 2017-12-05 Los Alamos National Security, Llc Detonation command and control
US9181790B2 (en) 2012-01-13 2015-11-10 Los Alamos National Security, Llc Detonation command and control
US9354029B2 (en) 2012-01-13 2016-05-31 Los Alamos National Security, Llc Detonation command and control
US9476685B2 (en) 2012-01-13 2016-10-25 Los Alamos National Security, Llc Detonation control
WO2013151603A1 (en) * 2012-01-13 2013-10-10 Los Alamos National Security, Llc Geologic fracturing method and resulting fractured geologic structure
US9593924B2 (en) 2012-01-13 2017-03-14 Los Alamos National Security, Llc System for fracturing an underground geologic formation
US20140338894A1 (en) * 2012-01-13 2014-11-20 Los Alamos National Security, Llc Geologic fracturing method and resulting fractured geologic structure
US10184331B2 (en) 2012-01-13 2019-01-22 Los Alamos National Security, Llc Explosive assembly and method
US10436005B2 (en) 2012-01-13 2019-10-08 Triad National Security, Llc Detonation control
US10329890B2 (en) 2012-01-13 2019-06-25 Triad National Security, Llc System for fracturing an underground geologic formation
US10294767B2 (en) 2013-07-15 2019-05-21 Triad National Security, Llc Fluid transport systems for use in a downhole explosive fracturing system
US10273792B2 (en) 2013-07-15 2019-04-30 Triad National Security, Llc Multi-stage geologic fracturing
US10246982B2 (en) 2013-07-15 2019-04-02 Triad National Security, Llc Casings for use in a system for fracturing rock within a bore
USD878163S1 (en) 2018-04-11 2020-03-17 Yeti Coolers, Llc Container

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