US3442673A - Mineral grinding aids - Google Patents
Mineral grinding aids Download PDFInfo
- Publication number
- US3442673A US3442673A US554699A US3442673DA US3442673A US 3442673 A US3442673 A US 3442673A US 554699 A US554699 A US 554699A US 3442673D A US3442673D A US 3442673DA US 3442673 A US3442673 A US 3442673A
- Authority
- US
- United States
- Prior art keywords
- additive
- grinding
- minerals
- mineral
- pack set
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052500 inorganic mineral Inorganic materials 0.000 title description 30
- 239000011707 mineral Substances 0.000 title description 29
- 239000000654 additive Substances 0.000 description 28
- 230000000996 additive effect Effects 0.000 description 22
- 239000007787 solid Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000011343 solid material Substances 0.000 description 8
- MGAXYKDBRBNWKT-UHFFFAOYSA-N (5-oxooxolan-2-yl)methyl 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)OCC1OC(=O)CC1 MGAXYKDBRBNWKT-UHFFFAOYSA-N 0.000 description 7
- 239000011398 Portland cement Substances 0.000 description 7
- 239000004568 cement Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- -1 alkyl radical Chemical group 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 235000019738 Limestone Nutrition 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002367 phosphate rock Substances 0.000 description 2
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000005840 aryl radicals Chemical group 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011396 hydraulic cement Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/02—Alcohols; Phenols; Ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/06—Selection or use of additives to aid disintegrating
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/52—Grinding aids; Additives added during grinding
Description
United States Patent US. Cl. 10690 8 Claims ABSTRACT OF THE DISCLOSURE Portland cement and minerals are ground with a grinding aid having the formula R--OX wherein'R is alkyl of 1 to 20 carbon atoms, phenyl or naphthyl and X is a metal above hydrogen in the electromotive series.
This invention relates to grinding minerals and more particularly to the use of an additive for improving the grinding efficiency and pack set characteristics of minerals.
In the processing of minerals, a grinding operation is generally employed either in the unprocessed or semiprocessed state to reduce the particular mineral to relatively small particle size. It is desirable in this grinding step to have as efficient an operation as possible, that is, to reduce the particular mineral to the desired particle size at a relatively rapid rate.
A grinding aid is frequently employed in such a grinding operation to assist in the grinding of the minerals either by increasing the rate of production or by increasing the fineness of the particles at the same rate of production without having adverse effects or any of the properties of the ground product.
Cleavage of the particles during grinding of the minerals exposes fresh or nacent surfaces which have high energy due probably to the breaking of ionic bonds. The surface forces of the ground particles persist for some time after grinding and lead to compaction or pack set and/ or poor fluidity if they are not reduced. Mineral particles when compacted by vibration, e.g., when transported in a hopper car often become semi-rigid and will not flow until considerable mechanical effort has been applied to break up the compaction. Therefore, it is also desirable that a material be employed to reduce the above-described adhesion of the particles.
The term pack set as used herein is intended to refer to the agglomeration or adhesion of particles by, for example, storing or transporting in bulk. Adhesion results from surface forces, the majority of which are believed to be created during the grinding of the minerals. Pack set index is a relative term which indicates numerically how prone a particular material is to start flowing after it is stored or transported in bulk. Pack set index ratio is the relative pack set index of the untreated sample compared to the treated sample. This ratio is used to permit comparison between different samples of the mineral.
The pack set index is determined in the following manner:
One hundred grams of the mineral are placed in a 250 milliliter Erhlenmeyer flask set on top of a variable vibrator. The flask containing the mineral is vibrated 15 seconds after which it is removed from the vibrator and set into a jig with the axis of the flask lying horizontally. The flask is then rotated around its axis until the mineral which is compacted in the bottom of the flask collapses. The flask is twisted at 180 angles at approximately 100 twists per minute. The number of 180 twists required for the mineral sample to collapse establishes the pack set index. Thus, the greater the energy required to break up the bed, the higher will be the pack set index.
A novel additive has now been found which will function as a grinding aid and a pack set inhibitor for minerals. The novel additive of the present invention is a compound of the formula wherein R is an alkyl radical or an aryl radical and X is a metal above hydrogen in the electromotive series wherein hydrogen is in its standard state and has an electrode potential of 0.
The term alkyl as used herein is intended to refer to branched as well as straight chain alkyl radicals. Preferably the alkyl group contains 1 to 20 carbons, more preferably, 1 to 4 carbons. In a particularly preferred embodiment, it is a methyl group. The term aryl as used herein is intended to refer to a phenyl or naphthyl radical. It should be understood that the alkyl and aryl group may be substituted by, e.g., nitro, halogen, preferably chlorine; alkyl, preferably a 1 to 5 carbon group, more preferably methyl; aryl, hydroxyl, amino, and alkoxy, preferably a l to 5 carbon alkoxy group.
The metal represented by X is a metal above hydrogen in the electromotive series, preferably an alkali metal or an alkaline earth metal. Particularly preferred are sodium and calcium, as illustrative of additives within the scope of the present invention, mention may be made of the following:
Sodium methoxide Sodium phenoxide Calcium phenoxide Calcium butoxide Aluminum ethoxide Magnesium methoxide Aluminum methoxide Aluminum isopropoxide Aluminum-T-butoxide Potassium O-methylphenoxide The additives within the scope of the present invention are prepared by conventional means known to the art. For example, the metal hydroxide is reacted with a compound of the formula ROH wherein R is aryl as defined above or the metal is reacted with a compound of the formula ROH wherein R is alkyl as defined above.
The additive is interground with the mineral in the grinding mill to provide increased grinding efficiency as well as other advantageous results, e.g., inhibiting pack set of bulk stored materials. It has also been found that the novel additive of the present invention serves to provide fluidity to the ground minerals when they are being transported by conveying systems, particularly by pneumatic air systems.
The term mineral as used herein is intended to refer to naturally occurring inorganic minerals such as phosphate rock, partially processed minerals such as concentrated iron ore, and mixtures of minerals such as cement clinker or ceramics. As examples of such minerals that can be processed with the additive of the present invention, mention may be made of beryllium oxide, limestone, gypsum, clays and bauxite.
The grinding aids of the present invention are particularly preferred for use with cement, particularly portland cement.
Portland cement represents a class of hydraulic cements and is comprised essentially of two calcium silicates and a lesser amount of calcium aluminate. These cements are produced by heating an intimate mixture of finely divided calcareous material (limestone) and argillaceous material (clay) to form a clinker, The clinker is ground with the addition of about 5 percent gypsum, or some other form of calcium sulfate, to obtain the desired setting qualities in the finished cement. It is to the clinker that the novel additive of this invention is preferably added to increase grinding efliciency and to inhibit subsequent pack set in the finished cement.
The additives of the present invention are employed in either dry or liquid form. For convenience, the additive is in water solution to permit accurate metering into the mill stream. In instances where the additive is not very soluble in water, it can be utilized in liquid form by emulsifying with a suitable wetting agent, for example, sodium dodecyl benzene sulfonate. The addition is accomplished either prior to the grinding or the additive is introduced into the grinding mill simultaneously with the mineral. If the additive is employed merely for the reduction of pack set or for fiuidizing purposes, it is added at any convenient point in the processing.
The additive is employed effectively over a relatively wide range. The preferred range is about 0.001 to 1 percent based on the weight of the mineral, i.e., the weight of additive solids based on the weight of the mineral solids (herein referred to as solids on solids). In a particularly preferred embodiment, the amount of additive employed is about .005 to .04 percent. Higher levels are employed if grinding to a relatively high surface area and the amount of additive is limited solely by the desired surface area and the degree of fluidity desired.
In Table l, the effectiveness of the additives of the present invention is recorded as well as data on pack set characteristics, The data was collected on Type 1 portland cement ground in a laboratory steel ball mill for 5,216 revolutions at 210 F.
TAB LE 1 Amount of additive Blaine Percent (percent surface increase solids on area, over Pack set Additive solids) emf/g. blank index Blank 3114 57. 7 Sodium phenoXide 0. 033 3373 8. 30 34. 7 Sodium methoxide 0. 015 3259 4. 66 Sodium phenoxide 0. 060 3473 11. 52 14.
In Table 2, the air-entertainment data and setting time data are reported. The percent air entrained was determined by the ASTM C185 Air Entrainment Test and the setting time by the ASTM C191 Vicat Setting Time Test. The water/cement ratio was 0.67.
TABLE 2 Amount of additive (percent solids on Setting time, Additive solids) Percent air hourszmin.
13. 3 2:00 11. 0 1:50 10.8 1:40 Sodium phenoxide 0. 060 10. 8 1 :25
additive (per- Compressive strength, p.51. cent solids on Additive solids) 1 day 7 days Blank 883 347 Sodium phenoxlde 0. 033 1103 3905 Sodium methox1de 0. 015 1043 3530 Sodium phenoxide 0. 060 1267 4403 The additive of the present invention is employed preferably as the sole grinding aid but it should be understood that it can also be employed with a mixture of one or more grinding aids or in admixture with other additives.
The additives of the present invention are also employed with satisfactory results in grinding other minerals in addition to cement, such as phosphate rock and iron ore.
Since changes may be made in the above products and processes without departing from the scope of the invention, it is intended that all matter contained in the above description shall be interpreted as illustrative and not in a limiting sense.
What is claimed is:
1. A novel composition comprising a solid material selected from the group consisting of minerals and portland cement and, intimately admixed therewith, from about 0.001 to 1 percent by weight based on the weight of said solid material of a compound of the formula wherein R is selected from the group consisting of alkyl of 1-20 carbon atoms, phenyl and naphthyl radicals and X is a metal above hydrogen in the electromotive series.
2. The composition as defined in claim 1 wherein said compound is sodium phenoxide.
3. A composition as defined in claim 1 wherein said compound is sodium methoxide.
4. A composition as defined in claim 2 wherein sodium phenoxide is present at a level of 0.060 percent based on the weight of the solid material.
5. The composition as defined in claim 1 wherein said solid material is portland cement.
6. The method which comprises intergrinding a solid material selected from the group consisting of minerals and portland cement with from about 0.001 to 1 percent by weight based on the weight of said solid material of a compound of the formula wherein R is selected from the group consisting of alkyl of 1-20 carbon atoms, phenyl and naphthyl radicals and X is a metal above hydrogen in the electromotive series.
7. The method as defined in claim 6 wherein said compound is added to the solid material prior to introducing the solid material into the grinding zone.
8. The method as defined in claim 6 wherein said compound is sodium phenoxide,
References Cited UNITED STATES PATENTS 2,225,147 12/1940 Bechtold 24116 2,364,555 12/1944 Scripture 241-16 2,857,286 10/1958 Striker 106102 3,068,110 12/1962 Fagerholt 106-107 3,325,105 6/1967 Veltman 106102 TOBIAS E. LEVOW, Primary Examiner.
S. E. MOTT, Assistant Examiner.
U.S. Cl. X.R.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55469966A | 1966-06-02 | 1966-06-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3442673A true US3442673A (en) | 1969-05-06 |
Family
ID=24214366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US554699A Expired - Lifetime US3442673A (en) | 1966-06-02 | 1966-06-02 | Mineral grinding aids |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US3442673A (en) |
| GB (1) | GB1151024A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3950182A (en) * | 1973-11-20 | 1976-04-13 | Imperial Chemical Industries Limited | Treatment process |
| US5298071A (en) * | 1990-03-23 | 1994-03-29 | Vontech International Corporation | Interground fiber cement |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2225147A (en) * | 1938-03-18 | 1940-12-17 | California Portland Cement Co | Portland cement manufacture |
| US2364555A (en) * | 1942-07-17 | 1944-12-05 | Jr Edward W Scripture | Cement composition and method of making same |
| US2857286A (en) * | 1955-11-23 | 1958-10-21 | Missouri Portland Cement Compa | Manufacture of portland cement |
| US3068110A (en) * | 1959-04-22 | 1962-12-11 | Smidth & Co As F L | Method of grinding portland cement using a phenolic compound as a grinding aid |
| US3325105A (en) * | 1964-07-17 | 1967-06-13 | Grace W R & Co | Mineral grinding aids and process of grinding |
-
1966
- 1966-06-02 US US554699A patent/US3442673A/en not_active Expired - Lifetime
-
1967
- 1967-06-01 GB GB25404/67A patent/GB1151024A/en not_active Expired
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2225147A (en) * | 1938-03-18 | 1940-12-17 | California Portland Cement Co | Portland cement manufacture |
| US2364555A (en) * | 1942-07-17 | 1944-12-05 | Jr Edward W Scripture | Cement composition and method of making same |
| US2857286A (en) * | 1955-11-23 | 1958-10-21 | Missouri Portland Cement Compa | Manufacture of portland cement |
| US3068110A (en) * | 1959-04-22 | 1962-12-11 | Smidth & Co As F L | Method of grinding portland cement using a phenolic compound as a grinding aid |
| US3325105A (en) * | 1964-07-17 | 1967-06-13 | Grace W R & Co | Mineral grinding aids and process of grinding |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3950182A (en) * | 1973-11-20 | 1976-04-13 | Imperial Chemical Industries Limited | Treatment process |
| US5298071A (en) * | 1990-03-23 | 1994-03-29 | Vontech International Corporation | Interground fiber cement |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1151024A (en) | 1969-05-07 |
| DE1667064B2 (en) | 1975-08-28 |
| DE1667064A1 (en) | 1971-06-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3607326A (en) | Mineral grinding aids | |
| KR900002819B1 (en) | Hydraulic material composition having high strengh | |
| EP1183217B1 (en) | Improved cement-based compositions | |
| US20010013302A1 (en) | Manufacture of improved metakaolin by grinding and use in cement-based composites and alkali-activated systems | |
| US3329517A (en) | Cement additives composed of ethanolamine salts | |
| JPS5910280B2 (en) | Fixation method for waste liquid or sludge | |
| GB2131409A (en) | Concrete additive admixture containing microsilica and concrete produced therewith | |
| CN106587695A (en) | Method for preparing cement mixture from waste phosphorus dregs through wet-milling method | |
| US20090064899A9 (en) | Microsilica materials with improved pozzolanic activity | |
| JP5925790B2 (en) | Clay-containing artificial sand for hydratable cementitious compositions | |
| US3443976A (en) | Mineral grinding aids | |
| US3325105A (en) | Mineral grinding aids and process of grinding | |
| JPH07267697A (en) | Hydraulic composition | |
| US3442673A (en) | Mineral grinding aids | |
| US3459570A (en) | Amide grinding aid | |
| JPH06100338A (en) | Highly fluid cement | |
| EP0498815B1 (en) | Process for producing an active fine aggregate for the preparation of concrete | |
| US3420687A (en) | Method of increasing the grinding efficiencies of minerals and cement | |
| CH509939A (en) | Powdered mineral or powdered mineral substance with a reduced tendency to cake and process for its production | |
| US3443975A (en) | Vinyl acetate grinding aid | |
| JPH04228462A (en) | Masonry cement additive agent | |
| JP2618366B2 (en) | Method for producing hydraulically cured product | |
| US3420686A (en) | Aromatic acetates as grinding aids | |
| US3183105A (en) | Cement additive composed of a mixture of methyl acetate and methyl alcohol | |
| US4491480A (en) | Grinding aid and mineral mixture containing it |