US3423925A - Method of spinning fibers from a fluid suspension - Google Patents
Method of spinning fibers from a fluid suspension Download PDFInfo
- Publication number
- US3423925A US3423925A US406923A US3423925DA US3423925A US 3423925 A US3423925 A US 3423925A US 406923 A US406923 A US 406923A US 3423925D A US3423925D A US 3423925DA US 3423925 A US3423925 A US 3423925A
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- US
- United States
- Prior art keywords
- fibers
- suspension
- fluid
- fiber
- axis
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G13/00—Electrographic processes using a charge pattern
- G03G13/26—Electrographic processes using a charge pattern for the production of printing plates for non-xerographic printing processes
- G03G13/28—Planographic printing plates
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
- D01G99/00—Subject matter not provided for in other groups of this subclass
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
Definitions
- a method for spinning fibers comprising providing a fluid body containing fibrous materials suspended therein such as wood pulp or cellulose acetate, rotating the body of fluid relative to an axis while maintaining the body substantially stationary with respect to the length of the axis, whereupon a coherent strand containing aligned and twisted fibers is formed.
- This invention relates to a method of spinning fibers from a fluid suspension.
- the method of spinning fibers comprising: suspending fibers in a fluid; containing said suspension as a body; providing rotation of said body relative to an axis, while maintaining said body substantially stationary with respect to the length of said axis, whereby said fibers are concentrated along said axis in an aligned and twisted configuration; withdrawing said aligned and twisted fibers from said axis; replenishing said suspension with fresh fibers to replace the fibers withdrawn and with fresh fluid to replace any lost fluid.
- said axis comprises a rotating member immersed in said body, said relative rotation being provided only by the rotation of said member.
- said relative rotation is provided by rotating said body and in a still further aspect the rotation of the body is provided by mechanical stirring.
- said relative rotation is provided by propagating a gravity vortex in said body by allowing fluid to escape from the center of the bottom of said body While maintaining the height and volume of said body substantially constant by replenishing said body with fresh fluid introduced to said body other than at the center of its bottom.
- said fluid is a liquid and consequently the fibers as withdrawn from said body are wet with said liquid and are subjected to a drying step.
- Fresh liquid is introduced to said body to replace the liquid which is withdrawn with said fibers.
- the liquid comprise water.
- the fibers may be comprised of secondary cellulose acetate having an acetyl value of about 50 to 58% but preferably the wellknown secondary cellulose acetate of commerce having an acetyl value of about 53 to 55%, cellulose triacetate, i.e., acetylated cellulose having an acetyl value, calculated as combined acetic acid by weight, of at least 59% of a theoretical maximum of 62.5%, other cellulose esters such as cellulose propionate cellulose butyrate, cellulose acetate-propionate or cellulose acetate-butyrate and cellulose ethers such as ethyl or benzyl cellulose, and blends of such organic derivatives of cellulose with fibers of other materials such as regenerated cellulose, e.g., viscose rayon or cuprammonium rayon, polyamides such as nylon, e.g., the polyamide of hexamethylene diamine and adipic acid or of
- fibers comprising wood pulp, rayon, cellulose acetate or copolymers of at least 45% by weight of vinyldine cyanide with an ethylenically unsaturated comonomer.
- cellulose acetate generically denotes both secondary cellulose acetate and cellulose triacetate.
- An advantage of spinning fibers from a fluid suspension according to the present invention as contrasted with conventional spinning is that fibers of a substantially shorter average length may be spun according to the present method than can be spun according to conventional methods, Thus, according to the present invention, fibers having an average length of about one-eighth inch or less may be spun whereas the minimum average fiber length for conventional spinning is about one-half inch. The maximum average fiber lengths which can be spun, according to the present invention, are about one inch.
- the minimum weight concentration of fibers in the suspension necessary to obtain continuous spinning varies from fiber to fiber. However, generally it is found that a fiber concentration by weight of at least about 0.1 gram of fiber per litre of suspension is necessary to obtain continuous spinning. There is also a maximum concentration above which continuous spinning cannot be obtained. When the fiber concentration is too great, the fibers do not have enough freedom of motion to become mutually aligned and entangled in a strand and therefore continuous fiber structure cannot be formed. The maximum fiber concentration by weight varies somewhat from fiber to fiber but generally it is about 10 grams of fiber per litre of suspension.
- the fiber strands may be subjected to mechanical twisting as they are withdrawn from the suspension. Conventional twistingcollecting devices may be used such as the conventional down twisters or up twisters. Furthermore, in a subsequent operation, the fiber strand may be further compacted and strengthened by an additional twisting operation or treatment with resins, adhesives and other similar compositions with which conventionally spun fibers are often treated.
- the exact configuration of the apparatus Which is used is not critical.
- the suspension may be contained in substantially any container.
- any mechanical swirling or rotating technique may be used.
- a beaker may contain the suspension and the beaker may be equipped with a conventional magnetic stirrer and on a larger scale the suspension may be contained in a tank equipped with a paddle stirrer.
- the container may be rotated as a unit causing the suspension therein to swirl about.
- the suspension may be left undisturbed as a body and instead the member which is to gather the fibers from the suspension may be rotated at the center of the body of the suspension.
- the member may be a simple hook on a shaft; the shaft is rotated and the hook revolves in the suspension gathering together a longitudinal structure of fibers; the hook may then itself be used to withdraw the fibers simply by being drawn up from the suspension or if it is desired to continuously create a longer fiber structure the end of the fiber structure created at the hook may be withdrawn from the hook while leaving the hook immersed in the suspension and said end may be fixed to another take up means such as a godet roll.
- the strand collects at the hook continuously and from the hook is withdrawn by a take up means.
- the member may simply be an end of a fibrous strand which is being collected.
- the Withdrawing of the fibers from the suspension is a simple mechanical matter.
- a pair of tweezers may be used to grasp the upper end of the freshly formed fiber strand in the suspension; then, for example, the end maybe attached to a take up roll.
- Example I 5.5 denier per filament 3 inch viscose rayon staple fiber manner, there is slowly withdrawn from the suspension surface a strand of fibers several inches long.
- Example II Ion exchange fibers are made by cross-link carboxylating viscose rayon fibers; according to the method disclosed in US. Patent No. 3,017,237; the fibers have a cation exchange capacity of 0.58 milliequivalent per gram and are cut into /2 inch lengths.
- the fibers are suspended in water again at a concentration of 0.5 g./litre and formed into a strand with ease by swirling the suspension and withdrawing the strand at the center of the vortex.
- spun fiber structures made according to the present invention may be employed in all conventional textile applications. Furthermore, since fibers such as wood fibers can be spun by this technique whereas they cannot be spun by conventional techniques additional applications appear. Thus, for example, spun wood fibers may be used for backings of floor coverings, mats and the like.
- a method of spinning fibers comprising: suspending fibers in a fluid; containing said suspension as a body; providing relative rotation of said body relative to an axis, while maintaining said body substantially stationary with respect to the length of said axis, whereby said fibers are concentrated along said axis in an aligned and twisted configuration; withdrawing said aligned and twisted fibers from said axis; replenishing said suspension with fresh fibers to replace the fibers withdrawn and with fresh fluid to replace any lost fluid.
- said fibers comprise copolymers of at least 45% by weight of vinylidene cyanide with an ethylenically unsaturated comonomer.
- the concentration of said fibers suspended in said fluid is from about 0.1 to 10 grams of fiber per litre of fluid.
- said axis comprises a rotating member immersed in said body, said relative rotation being provided only by the rotation of said member.
Description
United States Patent ABSTRACT OF THE DISCLOSURE A method for spinning fibers comprising providing a fluid body containing fibrous materials suspended therein such as wood pulp or cellulose acetate, rotating the body of fluid relative to an axis while maintaining the body substantially stationary with respect to the length of the axis, whereupon a coherent strand containing aligned and twisted fibers is formed.
This invention relates to a method of spinning fibers from a fluid suspension.
In the prior art when it has been attempted to spin fibers from a fluid suspension it has been believed necessary to rotate the fluid while conducting it through a con duit. It was believed that the flow of fluid through the conduit was necessary to provide longitudinal alignment of the suspended fibers whereby they could become entangled in a continuous longitudinal structure. Such prior art is exemplified by U.S. Patent No. 2,700,866 and U.S. Patent No. 2,972,221.
It is an object of the present invention to spin fibers from a body of fluid in which the fibers are suspended by providing rotation of said body relative to an axis while maintaining said body substantially stationary with respect to said axis whereby said fibers are concentrated along said axis in an aligned and twisted configuration. This sharply contrasts with the prior art wherein axial motion of the fluid was a necessary condition.
Further objects will app-ear from the detailed description and claims which herein follow.
According to one embodiment of the present invention, there is provided the method of spinning fibers comprising: suspending fibers in a fluid; containing said suspension as a body; providing rotation of said body relative to an axis, while maintaining said body substantially stationary with respect to the length of said axis, whereby said fibers are concentrated along said axis in an aligned and twisted configuration; withdrawing said aligned and twisted fibers from said axis; replenishing said suspension with fresh fibers to replace the fibers withdrawn and with fresh fluid to replace any lost fluid.
In accordance with another aspect of the present invention, said axis comprises a rotating member immersed in said body, said relative rotation being provided only by the rotation of said member.
In accordance with a still further aspect of the present invention, said relative rotation is provided by rotating said body and in a still further aspect the rotation of the body is provided by mechanical stirring.
In yet a further aspect of the present invention said relative rotation is provided by propagating a gravity vortex in said body by allowing fluid to escape from the center of the bottom of said body While maintaining the height and volume of said body substantially constant by replenishing said body with fresh fluid introduced to said body other than at the center of its bottom.
Conveniently, said fluid is a liquid and consequently the fibers as withdrawn from said body are wet with said liquid and are subjected to a drying step. Fresh liquid is introduced to said body to replace the liquid which is withdrawn with said fibers. For economic reasons, it is preferred that the liquid comprise water.
Any fibrous material may be used. Thus, the fibers may be comprised of secondary cellulose acetate having an acetyl value of about 50 to 58% but preferably the wellknown secondary cellulose acetate of commerce having an acetyl value of about 53 to 55%, cellulose triacetate, i.e., acetylated cellulose having an acetyl value, calculated as combined acetic acid by weight, of at least 59% of a theoretical maximum of 62.5%, other cellulose esters such as cellulose propionate cellulose butyrate, cellulose acetate-propionate or cellulose acetate-butyrate and cellulose ethers such as ethyl or benzyl cellulose, and blends of such organic derivatives of cellulose with fibers of other materials such as regenerated cellulose, e.g., viscose rayon or cuprammonium rayon, polyamides such as nylon, e.g., the polyamide of hexamethylene diamine and adipic acid or of 6-aminocaproic acid, polyurethanes, acrylonitrile polymers and copolymers, polyesters such as polyethylene terephthalate, cotton and animal fibers such as wool, mohair and silk.
Particularly good results have been attained with fibers comprising wood pulp, rayon, cellulose acetate or copolymers of at least 45% by weight of vinyldine cyanide with an ethylenically unsaturated comonomer.
In the specification and claims the term cellulose acetate generically denotes both secondary cellulose acetate and cellulose triacetate.
An advantage of spinning fibers from a fluid suspension according to the present invention as contrasted with conventional spinning is that fibers of a substantially shorter average length may be spun according to the present method than can be spun according to conventional methods, Thus, according to the present invention, fibers having an average length of about one-eighth inch or less may be spun whereas the minimum average fiber length for conventional spinning is about one-half inch. The maximum average fiber lengths which can be spun, according to the present invention, are about one inch.
When wood fibers are spun from an aqueous suspension of wood pulp, it is found that the spinning is aided by the presence in the suspension of fibers other than wood fibers such as rayon fibers, cellulose acetate fibers or fibers of copolymers of at least 45% by weight of vinylidene cyanide with an ethylenically unsaturated comonomer; any other conventionally spinnable fiber will also sutfice. With such fiber addition the wood pulp fibers can be spun more rapidly. Also, it is observed that the spun wood fiber structures tend to disintegrate upon reimmersion in water. It is found, however, that a resinification reaction (such as by reaction of maleic anhydride and diepoxides) on the surface of the wood fibers greatly reduces the tendency of the spun wood fiber structures to disintegrate.
The minimum weight concentration of fibers in the suspension necessary to obtain continuous spinning varies from fiber to fiber. However, generally it is found that a fiber concentration by weight of at least about 0.1 gram of fiber per litre of suspension is necessary to obtain continuous spinning. There is also a maximum concentration above which continuous spinning cannot be obtained. When the fiber concentration is too great, the fibers do not have enough freedom of motion to become mutually aligned and entangled in a strand and therefore continuous fiber structure cannot be formed. The maximum fiber concentration by weight varies somewhat from fiber to fiber but generally it is about 10 grams of fiber per litre of suspension.
Spinning may be facilitated and the strength of the fiber strands increased by the addition of thickening agents or adhesives to the suspension. However, the results are somewhat unpredictable and sometimes a negative rather than a positive result will be achieved by these additions. The introduction of ion exchange groups in the fibers to be suspended is generally found to have a positive effect due to an improvement in interfiber bonding. The fiber strands may be subjected to mechanical twisting as they are withdrawn from the suspension. Conventional twistingcollecting devices may be used such as the conventional down twisters or up twisters. Furthermore, in a subsequent operation, the fiber strand may be further compacted and strengthened by an additional twisting operation or treatment with resins, adhesives and other similar compositions with which conventionally spun fibers are often treated.
The exact configuration of the apparatus Which is used is not critical. The suspension may be contained in substantially any container. In order to induce the accumulation of the fibers in a strand-like configuration along the center axis of the container any mechanical swirling or rotating technique may be used. Thus, for example, on a small scale, a beaker may contain the suspension and the beaker may be equipped with a conventional magnetic stirrer and on a larger scale the suspension may be contained in a tank equipped with a paddle stirrer. Or, the container may be rotated as a unit causing the suspension therein to swirl about. On the other hand, the suspension may be left undisturbed as a body and instead the member which is to gather the fibers from the suspension may be rotated at the center of the body of the suspension. Thus, for example, the member may be a simple hook on a shaft; the shaft is rotated and the hook revolves in the suspension gathering together a longitudinal structure of fibers; the hook may then itself be used to withdraw the fibers simply by being drawn up from the suspension or if it is desired to continuously create a longer fiber structure the end of the fiber structure created at the hook may be withdrawn from the hook while leaving the hook immersed in the suspension and said end may be fixed to another take up means such as a godet roll. Thus, the strand collects at the hook continuously and from the hook is withdrawn by a take up means. On the other hand, the member may simply be an end of a fibrous strand which is being collected.
It is found that particularly good results are achieved when a gravity vortex is created in the body of the suspension. This may be done simply by providing the container with an outlet at the center of its bottom. The flow of liquid therefrom creates a gravity vortex. The suspension may be continuously replenished thus maintaining the height and volume of the suspension in the container constant. At constant flow conditions the vortex is very stable and excellent accumulation and entanglement of fibers at the axis of the vortex is achieved.
It should be understood that the Withdrawing of the fibers from the suspension is a simple mechanical matter. Thus, for example, on a small scale a pair of tweezers may be used to grasp the upper end of the freshly formed fiber strand in the suspension; then, for example, the end maybe attached to a take up roll.
The following examples will further illustrate the present invention.
Example I 5.5 denier per filament 3 inch viscose rayon staple fiber manner, there is slowly withdrawn from the suspension surface a strand of fibers several inches long.
The same operation is carried out using inch viscose rayon fibers.
Example II Ion exchange fibers are made by cross-link carboxylating viscose rayon fibers; according to the method disclosed in US. Patent No. 3,017,237; the fibers have a cation exchange capacity of 0.58 milliequivalent per gram and are cut into /2 inch lengths. The fibers are suspended in water again at a concentration of 0.5 g./litre and formed into a strand with ease by swirling the suspension and withdrawing the strand at the center of the vortex.
The spun fiber structures made according to the present invention may be employed in all conventional textile applications. Furthermore, since fibers such as wood fibers can be spun by this technique whereas they cannot be spun by conventional techniques additional applications appear. Thus, for example, spun wood fibers may be used for backings of floor coverings, mats and the like.
The above detailed description is not meant to limit the scope of the present invention. Obvious variations and modifications are intended to be encompassed by the claims which follow.
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. A method of spinning fibers comprising: suspending fibers in a fluid; containing said suspension as a body; providing relative rotation of said body relative to an axis, while maintaining said body substantially stationary with respect to the length of said axis, whereby said fibers are concentrated along said axis in an aligned and twisted configuration; withdrawing said aligned and twisted fibers from said axis; replenishing said suspension with fresh fibers to replace the fibers withdrawn and with fresh fluid to replace any lost fluid.
2. The method defined in claim 1, wherein: said fluid is a liquid.
3. The method defined in claim 2, wherein: said withdrawn fibers are wet with said liquid and, consequently, are subjected to a drying step; and said fresh fluid is liquid which replaces the liquid withdrawn with said fibers.
4. The method defined in claim 3, wherein: said liquid comprises water.
5. The method defined in claim 3, wherein: have a length of from about /a to 1 inch.
6. The method defined in claim 5, wherein: comprise wood pulp.
7. The method defined in claim 5, wherein: comprise rayon.
8. The method defined in claim 5, wherein: comprise cellulose acetate.
9. The method defined in claim 5, wherein: said fibers comprise copolymers of at least 45% by weight of vinylidene cyanide with an ethylenically unsaturated comonomer.
10. The method defined in claim 5, wherein: said fibers have been surface modified through reaction with maleic anhydride and diepoxides.
11. The method defined in claim 5, wherein: the concentration of said fibers suspended in said fluid is from about 0.1 to 10 grams of fiber per litre of fluid.
12. The method defined in claim 1, wherein: said axis comprises a rotating member immersed in said body, said relative rotation being provided only by the rotation of said member.
13. The method defined in claim 1, wherein: said relative rotation is provided by rotating said body.
14. The method defined in claim 13, wherein: said body is rotated by mechanical stirring.
15. The method defined in claim 13, wherein: said body is rotated by propagating a gravity vortex in said body by allowing fluid to escape from the center of the said fibers said fibers said fibers said fibers 5 6 bottom of said body while maintaining the height and 2,451,504 10/1948 Mayo 5758.95 volume of said body substantially constant by replenish- 2,944,381 7/1960 Strang et al 57-58.91 ing said body with fresh fluid introduced to said body 3,038,294 6/1962 Pavek 5758.93 th that 12th t Of't 'b H m. 0 er na ecen er 1 s 0 o 5 FOREIGN PATENTS References Cited 880,963 10/1961 Great Britain.
UNITED STATE PATENTS s LEONARD D. CHRISTIAN, Primary Examiner.
2,241,405 5/1941 Hyde et al. 57-59 X I 5 04 0 43 Mayo 57 53 95 DONALD E. WATKINS, Assistant Examlner 2,700,866 2/1955 Strang 57-156 10 2,817,947 12/1957 Strang 57-12 2,972,221 2/1961 Wilke et al. 5758.49 X 57-5833, 156
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US40692364A | 1964-10-27 | 1964-10-27 |
Publications (1)
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US3423925A true US3423925A (en) | 1969-01-28 |
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US406923A Expired - Lifetime US3423925A (en) | 1964-10-27 | 1964-10-27 | Method of spinning fibers from a fluid suspension |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3943220A (en) * | 1969-09-30 | 1976-03-09 | Johns-Manville Corporation | Method of producing fiber strand |
US3997647A (en) * | 1973-10-01 | 1976-12-14 | Kimberly-Clark Corporation | Method of making filaments and webs of chemically modified cellulose fibers |
US4256111A (en) * | 1973-10-01 | 1981-03-17 | Kimberly-Clark Corporation | Filaments of chemically modified cellulose fibers and webs and products formed therefrom |
WO2016174306A1 (en) * | 2015-04-28 | 2016-11-03 | Spinnova Oy | Mechanical method and system for the manufacture of fibrous yarn and fibrous yarn |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2241405A (en) * | 1939-01-13 | 1941-05-13 | Owens Corning Fiberglass Corp | Apparatus for gathering fibers |
US2451504A (en) * | 1945-07-23 | 1948-10-19 | Marion S Mayo | Method of and apparatus for spinning cotton and other textile fibers |
US2700866A (en) * | 1953-07-24 | 1955-02-01 | Peter M Strang | Method of concatenating fibrous elements |
US2817947A (en) * | 1953-09-10 | 1957-12-31 | Peter M Strang | Preparation of textile strands comprising fibres having different characteristics |
US2944381A (en) * | 1955-05-27 | 1960-07-12 | Lawrence M Keeler | Apparatus for use in assembling and intertwining discrete fibers |
US2972221A (en) * | 1956-07-31 | 1961-02-21 | Rex Asbestwerke | Method of converting individual fibers into coherent fibrous bodies |
GB880963A (en) * | 1957-12-13 | 1961-10-25 | Sdruzeni Podniku Textilniho St | Improvements in or relating to continuous spinning of yarns directly from loose fibres |
US3038294A (en) * | 1959-01-09 | 1962-06-12 | Sdruzeni Podniku Textilniho St | Continuous spinning of yarns directly from loose fibres |
-
1964
- 1964-10-27 US US406923A patent/US3423925A/en not_active Expired - Lifetime
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2241405A (en) * | 1939-01-13 | 1941-05-13 | Owens Corning Fiberglass Corp | Apparatus for gathering fibers |
US2451504A (en) * | 1945-07-23 | 1948-10-19 | Marion S Mayo | Method of and apparatus for spinning cotton and other textile fibers |
US2700866A (en) * | 1953-07-24 | 1955-02-01 | Peter M Strang | Method of concatenating fibrous elements |
US2817947A (en) * | 1953-09-10 | 1957-12-31 | Peter M Strang | Preparation of textile strands comprising fibres having different characteristics |
US2944381A (en) * | 1955-05-27 | 1960-07-12 | Lawrence M Keeler | Apparatus for use in assembling and intertwining discrete fibers |
US2972221A (en) * | 1956-07-31 | 1961-02-21 | Rex Asbestwerke | Method of converting individual fibers into coherent fibrous bodies |
GB880963A (en) * | 1957-12-13 | 1961-10-25 | Sdruzeni Podniku Textilniho St | Improvements in or relating to continuous spinning of yarns directly from loose fibres |
US3038294A (en) * | 1959-01-09 | 1962-06-12 | Sdruzeni Podniku Textilniho St | Continuous spinning of yarns directly from loose fibres |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3943220A (en) * | 1969-09-30 | 1976-03-09 | Johns-Manville Corporation | Method of producing fiber strand |
US3997647A (en) * | 1973-10-01 | 1976-12-14 | Kimberly-Clark Corporation | Method of making filaments and webs of chemically modified cellulose fibers |
US4256111A (en) * | 1973-10-01 | 1981-03-17 | Kimberly-Clark Corporation | Filaments of chemically modified cellulose fibers and webs and products formed therefrom |
WO2016174306A1 (en) * | 2015-04-28 | 2016-11-03 | Spinnova Oy | Mechanical method and system for the manufacture of fibrous yarn and fibrous yarn |
US10544524B2 (en) | 2015-04-28 | 2020-01-28 | Spinnova Oy | Mechanical method and system for the manufacture of fibrous yarn and fibrous yarn |
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