US3415605A - Combustion flash bulbs - Google Patents
Combustion flash bulbs Download PDFInfo
- Publication number
- US3415605A US3415605A US638631A US63863167A US3415605A US 3415605 A US3415605 A US 3415605A US 638631 A US638631 A US 638631A US 63863167 A US63863167 A US 63863167A US 3415605 A US3415605 A US 3415605A
- Authority
- US
- United States
- Prior art keywords
- oxygen
- gas
- bulb
- flash
- flash bulbs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000002485 combustion reaction Methods 0.000 title description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 24
- 229910052760 oxygen Inorganic materials 0.000 description 24
- 239000001301 oxygen Substances 0.000 description 24
- 239000007789 gas Substances 0.000 description 21
- GVGCUCJTUSOZKP-UHFFFAOYSA-N nitrogen trifluoride Chemical compound FN(F)F GVGCUCJTUSOZKP-UHFFFAOYSA-N 0.000 description 13
- 239000007787 solid Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 150000002222 fluorine compounds Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical compound FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- UOBPHQJGWSVXFS-UHFFFAOYSA-N [O].[F] Chemical compound [O].[F] UOBPHQJGWSVXFS-UHFFFAOYSA-N 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
- F21K5/00—Light sources using charges of combustible material, e.g. illuminating flash devices
- F21K5/02—Light sources using charges of combustible material, e.g. illuminating flash devices ignited in a non-disrupting container, e.g. photo-flash bulb
Definitions
- Suitable fluorine compounds are: oxygen fluoride (OF and nitrogen fluorides (e.g. NF N F Oxygen fluoride has the disadvantage that it is toxic. Therefore, the large-scale use of said gas in flash bulbs seems hardly possible without taking special steps.
- oxygen fluoride OF
- nitrogen fluorides e.g. NF N F Oxygen fluoride has the disadvantage that it is toxic. Therefore, the large-scale use of said gas in flash bulbs seems hardly possible without taking special steps.
- auxiliary gas having a braking effect on the combustion.
- suitable auxiliary gases are volatile halogen-containing compounds of boron, carbon, silicon, titanium, germanium or .tin having a combustion heat smaller than 200 kcaL/mol. Under the conditions prevailing in the bulb, these compounds do not react with oxygen or with the solid substance.
- the flash bulb according to the invention is characterized in that the bulb contains a mixture of oxygen and nitrogen fluoride.
- Table I which relates to a flash bulb having a volume of approximately 1.2 crn. and which contains 22 mgs. of zirconium in the form of a metal wool
- the relative pressures in a gas mixture of oxygen and N1 are stated in the first and second columns; the third column indicates the ratio between oxygen and NE, in the gas mixture, expressed in equivalent quantities.
- the fourth and fifth columns indicate the light output in lumenseconds and in lumenseconds per mg. of zirconium, respectively.
- the sixth column indicates the maximum time.
- the stated values are invariably the average values of measurements on five flash bulbs.
- the table also includes measurements relating to bulbs solely containing oxygen and NF respectively.
- tween 21 solid substance in said bulb and a gas in said bulb
- the improvement which comprises employing as said gas a mixture of oxygen and nitrogen fluoride, the ratio of oxygen and nitrogen fluoride, expressed in equivalent quantities being between 3:1 to 1:1 and wherein the total amount of oxygen and nitrogen fluoride is sulficient to convert all of said solid substance present in the bulb to the corresponding saturated oxide and fluoride.
- a combustion flash bulb as claimed in claim 1 characterized in that the ratio between oxygen and nitrogen fluoride in the gas mixture, expressed in equivalent quantities, is approximately 1:1.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Discharge Lamp (AREA)
- Vessels And Coating Films For Discharge Lamps (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6606713A NL6606713A (ref) | 1966-05-17 | 1966-05-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3415605A true US3415605A (en) | 1968-12-10 |
Family
ID=19796620
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US638631A Expired - Lifetime US3415605A (en) | 1966-05-17 | 1967-05-15 | Combustion flash bulbs |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3415605A (ref) |
| AT (1) | AT273670B (ref) |
| BE (1) | BE698543A (ref) |
| CH (1) | CH459755A (ref) |
| GB (1) | GB1114173A (ref) |
| NL (1) | NL6606713A (ref) |
| SE (1) | SE314896B (ref) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3765821A (en) * | 1971-10-14 | 1973-10-16 | Gte Laboratories Inc | Flash lamp |
| US3807935A (en) * | 1971-10-14 | 1974-04-30 | Gte Laboratories Inc | Flash lamp |
-
1966
- 1966-05-17 NL NL6606713A patent/NL6606713A/xx unknown
-
1967
- 1967-05-12 AT AT448167A patent/AT273670B/de active
- 1967-05-15 US US638631A patent/US3415605A/en not_active Expired - Lifetime
- 1967-05-15 GB GB22335/67A patent/GB1114173A/en not_active Expired
- 1967-05-16 CH CH688067A patent/CH459755A/de unknown
- 1967-05-16 SE SE6818/67A patent/SE314896B/xx unknown
- 1967-05-16 BE BE698543D patent/BE698543A/xx unknown
Non-Patent Citations (1)
| Title |
|---|
| None * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3765821A (en) * | 1971-10-14 | 1973-10-16 | Gte Laboratories Inc | Flash lamp |
| US3807935A (en) * | 1971-10-14 | 1974-04-30 | Gte Laboratories Inc | Flash lamp |
Also Published As
| Publication number | Publication date |
|---|---|
| SE314896B (ref) | 1969-09-15 |
| DE1597715A1 (de) | 1970-06-04 |
| NL6606713A (ref) | 1967-11-20 |
| GB1114173A (en) | 1968-05-15 |
| AT273670B (de) | 1969-08-25 |
| BE698543A (ref) | 1967-11-16 |
| DE1597715B2 (de) | 1975-09-25 |
| CH459755A (de) | 1968-07-15 |
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