US3411182A - Apparatus for extruding helical webs on conductors - Google Patents

Apparatus for extruding helical webs on conductors Download PDF

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Publication number
US3411182A
US3411182A US582702A US58270266A US3411182A US 3411182 A US3411182 A US 3411182A US 582702 A US582702 A US 582702A US 58270266 A US58270266 A US 58270266A US 3411182 A US3411182 A US 3411182A
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US
United States
Prior art keywords
die
conductor
orifice
web
extrusion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US582702A
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English (en)
Inventor
John J Nevin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phelps Dodge Copper Products Corp
Original Assignee
Phelps Dodge Copper Products Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phelps Dodge Copper Products Corp filed Critical Phelps Dodge Copper Products Corp
Priority to US582702A priority Critical patent/US3411182A/en
Priority to BE704063D priority patent/BE704063A/xx
Priority to DE19671729315 priority patent/DE1729315C/de
Priority to NL676712871A priority patent/NL149424B/xx
Priority to AT858967A priority patent/AT283482B/de
Priority to CH1320767A priority patent/CH468251A/fr
Priority to SE13062/67A priority patent/SE336459B/xx
Priority to GR670134665A priority patent/GR34665B/el
Priority to GB43343/67A priority patent/GB1150517A/en
Priority to ES345450A priority patent/ES345450A1/es
Priority to FI672585A priority patent/FI47820C/fi
Priority to DK482967AA priority patent/DK119117B/da
Application granted granted Critical
Publication of US3411182A publication Critical patent/US3411182A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06Insulating conductors or cables
    • H01B13/14Insulating conductors or cables by extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/06Rod-shaped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/131Curved articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/32Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
    • B29C48/33Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles with parts rotatable relative to each other
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/32Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
    • B29C48/34Cross-head annular extrusion nozzles, i.e. for simultaneously receiving moulding material and the preform to be coated
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06Insulating conductors or cables
    • H01B13/18Applying discontinuous insulation, e.g. discs, beads
    • H01B13/20Applying discontinuous insulation, e.g. discs, beads for concentric or coaxial cables
    • H01B13/206Applying discontinuous insulation, e.g. discs, beads for concentric or coaxial cables by forming a helical web
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/05Filamentary, e.g. strands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films

Definitions

  • ABSTRACT OF THE DISCLOSURE The electrical conductor is passed through the main orifice of an extrusion die having an exit end through which the main orifice opens and also having a sub-orifice intersecting the main orifice and extending generally radially outward therefrom, the sub-orifice opening through the exit end of the die with the radially outer portion of the sub-orifice terminating short of the outer periphery of the die.
  • the die is supported for rotation about the conductor and is provided with an inlet to which a plasticized resinous material is supplied under pressure in all rotational positions of the die, to cause the material to be extruded continuously through the exit opening of the suborifice in the form of a generally radial web on the conductor.
  • Driving means are provided to rotate the die so as to spiral the web in a helix about the conductor, the pitch of the helical web being determined by the rotational speed of the die relative to the speed at which the conductor is moved lengthwise through the die by a transport means.
  • This invention relates to extrusion apparatus and more particularly to apparatus for extruding a helical web around and along the length of an electrical conductor.
  • a conductor having a web formed in accordance with this invention is useful as a component of electrical cable, such as coaxial cable wherein the helical web serves to maintain the conductor in concentrically spaced relation to a surrounding outer conductor.
  • a second known type of apparatus for forming a helical web about an electrical conductor, comprises a rotatable die having a cavity wiih the configuration of the helix and through which the electrical conductor passes.
  • the uniformity of the resulting helix is dependent upon the accuracy with which the die cavity is machined.
  • An apparatus of this type may be seen in United States Patent No. 2,834,047.
  • Another object of this invention is to provide an extru- 3,411,182 Patented Nov. 19, 1968 sion apparatus having sufficient operation flexibility to permit variation in helix pitch without replacement .of the extrusion die.
  • FIGURE 1 is a partially cutaway perspective view of an electrical coaxial cable produced by apparatus in accordance with this invention
  • FIGURE 2 is a schematic illustration of an extrusion system, including control circuitry, made in accordance with this invention
  • FIGURE 3 is a vertical, longitudinal sectional view of the extrusion apparatus of the system of FIGURE 2, and
  • FIGURE 4 is a sectional view taken along line 44 in FIGURE 3.
  • this invention in one form comprises an extrusion apparatus including a feeding means, which may be conventional, for directing a plasticized resinous material under pressure to an extrusion die.
  • the extrusion die is formed with a main orifice adapted to accommodate passage of the conductor on which the web is to be formed. Intersecting this main orifice and extending radially outwardly from it is a sub-orifice through which the resinous material is extruded.
  • This sub-orifice at least where it opens through the exit end of the die, has the shape of the desired cross-section of the helical web, preferably rectangular, with its radially outermost portion terminating short of the outer periphery of the die, so that the sub-orifice is completely contained within and defined by the die.
  • the extrusion die is held in a die carrier which is mounted for rotation about the conductor in the main on'fice, and driving means are provide-d to rotate the die carrier and hence the extrusion die.
  • the main orifice of the die is provided with a diameter which exceeds the conductor diameter by twice the desired thickness of the film. Otherwise, the diameter of the main orifice is essentially the diameter of the conductor.
  • the conductor is fed continuously lengthwise to the extrusion die and through its main orifice by suitable transport means.
  • the resinous material is extruded through the sub-orifice and the extrusion die is rotated during this lengthwise movement of the conductor.
  • the pitch of the resulting helical web is determined by the rotational speed of the die relative to the linear speed at which the transport means passes the conductor through the die, and the pitch can be varied as desired by varying the ratio of these two speeds. Because the conductor is supported so that its central axis coincides with that of the main orifice in the die, and because the sub-orifice is completely defined by the die, the helical web will be concentric to the conductor axis and uniform throughout.
  • an air dielectric electrical coaxial cable 8 including an electrical conductor 10 having a helical web 12 extending radially therefrom and formed by the apparatus of this invention.
  • the web serves as a dielectric support to hold the inner conductor 10 concentrically within an outer conductor 14.
  • conductor refers to an electrical conductor of any conventional material having high conductivity, such as copper or aluminum.
  • the system as shown in FIGURE 2 includes a payoff reel 18 rotatably supported by any conventional means, such as jackstands 20, which permits free rotation of the reel as the conductor is pulled by an appropriate transport mechanism described below.
  • the electrical conductor is passed through an extrusion apparatus 22 wherein the helical web 12 is extruded onto the conductor 10.
  • the conductor and web combination is then passed through a conventional cooling apparatus, such as a water trough 24, wherein the web acquires its final solid state.
  • Any conventional transport mechanism 26, such as a tractor capstan, may be employed.
  • the transport mechanism 26 feeds the webbed conductor to a take-up reel 28.
  • a coordinating speed control 30 which controls the speeds of the transport mechanism 26 and the extrusion apparatus 22.
  • the control 30 is of the known type which, in response to any increase or decrease in the speed of one, results in a corresponding change in the speed of the other, so that the relative speeds are maintained essentially constant. If desired, however, the control 30 may be adjusted to maintain a different ratio of the speeds and thus provide a uniform helical web of different pitch. This adjustment may be effected automatically according to a predetermined pattern, when it is desired to vary the pitch of the helical web from time to time during a continuous run.
  • FIGURES 3 and 4 illustrate in detail the extrusion apparatus which forms the helical web 12.
  • the apparatus includes a block 32 containing a cylindrical member 33 and forming therewith an annular cavity 34 for receiving a plasticized resinous material to be extruded. Any conventional, nonconductive, thermoplastic or thermosetting material can be used.
  • the material is supplied by a standard feeding means, such as a feed screw 36, which forces the material through the cavity 34 and into the adjacent entrance end of an extension die 38.
  • the die 38 is formed with a central orifice 40 which, as shown, receives the conductor 10 with a close sliding fit. Extending radially outwardly from the central orifice 40 is a rectangular sub-orifice 42 through which the res inous material is extruded. The radial dimension of the sub-orifice 42 is slightly larger than the desired Web height in order to allow for shrinkage when the web 12 cools and solidifies.
  • the extrusion die 38 is supported within a die carrier 44 and is adapted to be rotated with this carrier, as through a key 45.
  • the die carrier 44 is located in a cavity 46 formed in an extension of the stationary block 32 and is supported for rotation therein by bearings 48.
  • a drive sprocket 50 is secured to the die carrier by any conventional means, such as bolts 52.
  • the drive sprocket is adapted to be driven by a variable speed motor 53 through a suitable connection 54.
  • the electrical conductor 10 is fed through a guide 56 centrally located within the cylindrical member 33 and passes from this guide through the central orifice 40 in the extrusion die 38.
  • the die 38 has a conical cavity 39 tapering from the entrance end of the die toward its exit end and forming an inlet to the orifices 40 and 42.
  • the guide 56 has a similarly tapered end 57 centrally located in the die cavity 39, so that the extrusion material is forced from the annular cavity 34 through the tapering annular passage surrounding the guide end 57, and thence through the sub-orifice 42.
  • the conductor 10 is pulled lengthwise through the extrusion die 38 by means of the transport mechanism 26. Simultaneously, the resinous material is fed by a screw 36 to the extrusion die 38 and is extruded through the sub-orifice 42 in the form of a radial web having its inner edge in contact with the conductor, since this sub-orifice intersects the main orifice 40 through which the conductor passes. At the same time, the extrusion die 38 is rotated by the variable speed motor 53, resulting in the formation of a uniform extruded web 12 spiralling about the conductor 10 along its length.
  • the spacing of the convolutions of the helix is determined by the speed at which the conductor 10 is moved through the die 38 and the speed at which the die is rotated. With a fixed speed of conductor movement, an increase in rotational speed of the die decreases the helix pitch. Conversely, with a fixed rotational speed of the die, an increase in speed of conductor movement increases the helix pitch. Accordingly, the coordinating speed control means 30 can be programed to provide any desired pitch by merely adjusting the relative speeds of the transport mechanism 26 and motor 53. It is also necessary to control the rate of material feed in order to insure uniformity in web thickness.
  • the speed control of the feed screw 36 is coordinated with the operation of the transport mechanism 26 and variable speed motor 53 by means of the speed control means 30.
  • any desired web shape can be provided by merely varying the cross-sectional shape of the extrusion orifice 42.
  • various size conductors can be accommodated by interchanging the extrusion die 38. This is accomplished by merely removing the die carrier 44 from the block 32 and replacing the extrusion die 38 with the appropriate die. The die and carrier assembly are then reinserted in the cavity 46. i
  • the extrusion is effected through an orifice 42 extending radially outward from the main orifice 40 but terminating short of the outer periphery of the die 38, so that the extrusion orifice 42 is defined entirely by the die and the conductor 10 passing through the main orifice. Consequently, it is unnecessary to center the extrusion die 38 with any other element of the apparatus, in order to form a uniform helical web 12 which is perfectly concentric to the conductor 10.
  • the present apparatus is entirely self-centering for the purpose of maintaining the helical web concentric to the conductor.
  • the helical web is formed without resort to a helical die cavity, which requires accurate and difiicult machining and limits the helix to a predetermined pitch.
  • the extrusion material supplied by the feed screw 36 may be any of the polyolefins, cross-linked or not, such as polyethylene, polysulfone or Teflon.
  • the cooling apparatus 24 serves to solidify the extruded material before it is engaged by the transport mechanism 26 which pulls the conductor from the extrusion die.
  • Apparatus for extruding a helical web along the length of an electrical conductor comprising (a) an extrusion die formed with a main orifice through which said conductor is adapted to pass, the die having an outer periphery and also having an exit end through which said main orifice opens, the die also being formed with a sub-orifice intersecting said main orifice and extending generally radially outward from said main orifice, said sub-orifice opening through said exit end of the die with the radially outer portion of the sub-orifice terminating short of said outer periphery, the die forming an inlet to said sub-orifice,
  • the apparatus comprising also a stationary guide member having a conical end disposed in said cavity in spaced relation to the die and tapering toward said exit end, said member having a passage for guiding the conductor to the die and opening through said tapered end, said material supplying means forming an annular supply passage surrounding the guide member and opening into said cavity at the end of the die remote from said exit end.
  • Apparatus as defined in claim 1, comprising also control means operatively connected to said driving means and said transport means for maintaining a predetermined ratio of the rotational speed of the die and said lengthwise speed of the conductor.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
US582702A 1966-09-28 1966-09-28 Apparatus for extruding helical webs on conductors Expired - Lifetime US3411182A (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
US582702A US3411182A (en) 1966-09-28 1966-09-28 Apparatus for extruding helical webs on conductors
BE704063D BE704063A (es) 1966-09-28 1967-09-19
DE19671729315 DE1729315C (de) 1966-09-28 1967-09-20 Vorrichtung zum Strangpressen einer Wendel aus plastizierbarem Stoff längs eines zylindrischen Drahtes
AT858967A AT283482B (de) 1966-09-28 1967-09-21 Vorrichtung zum Extrudieren einer Wendel um und längs eines zylindrischen Körpers, wie z.B. eines elektrischen Leiters
CH1320767A CH468251A (fr) 1966-09-28 1967-09-21 Appareil pour extruder une nervure hélicoïdale autour et le long d'un élément cylindrique
NL676712871A NL149424B (nl) 1966-09-28 1967-09-21 Inrichting voor het schroeflijnvormig om een draadkern extruderen van een strook uit een plastificeerbare kunststof.
SE13062/67A SE336459B (es) 1966-09-28 1967-09-22
GR670134665A GR34665B (el) 1966-09-28 1967-09-22 Συσκευη δια την εξωθησιν ελικοειδων μεμβρανων επιηλεκτρικων αγωγων.
GB43343/67A GB1150517A (en) 1966-09-28 1967-09-22 Apparatus for Extruding Helical Webs on Cylindrical Members
ES345450A ES345450A1 (es) 1966-09-28 1967-09-25 Un aparato que sirve para extruir o moldear por inyeccion una aleta o nervadura helicoidal alrededor y a lo largo de un elemento cilindrico.
FI672585A FI47820C (fi) 1966-09-28 1967-09-27 Laite ruuvinmuotoisen laipan suulakepuristamiseksi lieriömäisen elemen tin ympärille
DK482967AA DK119117B (da) 1966-09-28 1967-09-28 Apparat til ekstrudering af en skrueformet fane rundt omkring og langs med en elektrisk leder.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US582702A US3411182A (en) 1966-09-28 1966-09-28 Apparatus for extruding helical webs on conductors

Publications (1)

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US3411182A true US3411182A (en) 1968-11-19

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Application Number Title Priority Date Filing Date
US582702A Expired - Lifetime US3411182A (en) 1966-09-28 1966-09-28 Apparatus for extruding helical webs on conductors

Country Status (11)

Country Link
US (1) US3411182A (es)
AT (1) AT283482B (es)
BE (1) BE704063A (es)
CH (1) CH468251A (es)
DK (1) DK119117B (es)
ES (1) ES345450A1 (es)
FI (1) FI47820C (es)
GB (1) GB1150517A (es)
GR (1) GR34665B (es)
NL (1) NL149424B (es)
SE (1) SE336459B (es)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3710440A (en) * 1970-01-16 1973-01-16 Phelps Dodge Copper Prod Manufacture of coaxial cable
DE2820987A1 (de) * 1977-05-17 1978-11-23 Sumitomo Electric Industries Vorrichtung zur herstellung einer wendelrippe aus isoliermaterial bei einem koaxialkabel
US4285899A (en) * 1978-05-17 1981-08-25 Nortene Method and apparatus for making helical plastic members, and the members produced
US5834034A (en) * 1995-02-28 1998-11-10 Toyox Co., Ltd. Apparatus for producing ribbed hose

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL191065C (nl) * 1982-09-01 1995-01-02 Cable Belt Ltd Kabel, gevormd uit een of meer lagen, alsmede werkwijze voor het vervaardigen van deze kabel.
GB8415310D0 (en) * 1984-06-15 1984-07-18 Delta Enfield Cables Ltd Electric cables
DE102017004477A1 (de) * 2017-05-10 2018-11-15 Gemo D.G. Moritz GmbH & Co. Kommanditgesellschaft Verfahren zur Herstellung eines Steigungskabels und Extruder zu seiner Durchführung

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2446057A (en) * 1944-04-25 1948-07-27 Davis Marinsky Plastic casting machine
US2805179A (en) * 1952-05-12 1957-09-03 British Insulated Callenders Electric cable
US2834047A (en) * 1954-01-15 1958-05-13 Louis H Morin Apparatus for making extruded spiral coaxial cable

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2446057A (en) * 1944-04-25 1948-07-27 Davis Marinsky Plastic casting machine
US2805179A (en) * 1952-05-12 1957-09-03 British Insulated Callenders Electric cable
US2834047A (en) * 1954-01-15 1958-05-13 Louis H Morin Apparatus for making extruded spiral coaxial cable

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3710440A (en) * 1970-01-16 1973-01-16 Phelps Dodge Copper Prod Manufacture of coaxial cable
DE2820987A1 (de) * 1977-05-17 1978-11-23 Sumitomo Electric Industries Vorrichtung zur herstellung einer wendelrippe aus isoliermaterial bei einem koaxialkabel
US4181486A (en) * 1977-05-17 1980-01-01 Sumitomo Electric Industries, Ltd. Apparatus for producing the insulating layer of a coaxial cable
US4285899A (en) * 1978-05-17 1981-08-25 Nortene Method and apparatus for making helical plastic members, and the members produced
US5834034A (en) * 1995-02-28 1998-11-10 Toyox Co., Ltd. Apparatus for producing ribbed hose

Also Published As

Publication number Publication date
NL149424B (nl) 1976-05-17
GB1150517A (en) 1969-04-30
SE336459B (es) 1971-07-05
FI47820B (es) 1973-11-30
FI47820C (fi) 1974-03-11
AT283482B (de) 1970-08-10
CH468251A (fr) 1969-02-15
GR34665B (el) 1968-06-05
BE704063A (es) 1968-03-19
NL6712871A (es) 1968-03-29
DE1729315B2 (es) 1972-11-16
DE1729315A1 (de) 1972-03-02
DK119117B (da) 1970-11-16
ES345450A1 (es) 1968-11-16

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