US3404687A - Cigarette paper - Google Patents

Cigarette paper Download PDF

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Publication number
US3404687A
US3404687A US604178A US60417866A US3404687A US 3404687 A US3404687 A US 3404687A US 604178 A US604178 A US 604178A US 60417866 A US60417866 A US 60417866A US 3404687 A US3404687 A US 3404687A
Authority
US
United States
Prior art keywords
paper
perforations
cigarette
porosity
smoke
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US604178A
Other languages
English (en)
Inventor
James C Rickards
Jr William F Owens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ECYSTA Corp A CORP OF DE
Original Assignee
Olin Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Olin Corp filed Critical Olin Corp
Priority to US604178A priority Critical patent/US3404687A/en
Priority to GB55438/67A priority patent/GB1137460A/en
Priority to NL676716912A priority patent/NL151758B/nl
Priority to SE17609/67A priority patent/SE341977B/xx
Application granted granted Critical
Publication of US3404687A publication Critical patent/US3404687A/en
Assigned to ECYSTA CORPORATION, A CORP OF DE. reassignment ECYSTA CORPORATION, A CORP OF DE. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: OLIN CORPORATION, A CORP OF VA.
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/02Cigars; Cigarettes with special covers
    • A24D1/027Cigars; Cigarettes with special covers with ventilating means, e.g. perforations
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00Special paper or cardboard not otherwise provided for
    • D21H5/12Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials
    • D21H5/14Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of cellulose fibres only
    • D21H5/16Tobacco or cigarette paper

Definitions

  • This invention provides improved cigarette paper of high porosity to serve as Wrapper for a cigarette tobacco column, which effects a significantly greater reduction of the vapor phase constituents of cigarette smoke than of the particulate constituents.
  • Very high porosity is imparted to the paper by the provision of perforations having length and width dimensions between about 0.001 to 0.015 inch, the size and number being such as to impart to the paper an absolute Greiner porosity index value in the unprecedented low range of about 1 to 3.
  • the perforations are symmetrically arranged with respect to the length and width of the paper, and preferably are arranged in the form of two or three longitudinal rows.
  • This invention relates to improved paper wrappers for cigarettes and like smoking devices and, more particularly, to improved cigarette paper which is provided with .a plurality of perforations, preferably aligned in rows, said perforations being symmetrically spaced with respect to the length and width of the said paper.
  • the arrangement of the perforations is such that when a cigarette tobacco 3,404,687 Patented Oct. 8, 1968 and in U.S. Patent 3,046,994 issued on July 31, 1962.
  • a selectivereduction of vapor phase constituents in cigarette smoke can be effected by the provision of paper wrappers having much higher porosities, in the range of absolute Greiner porosity index values of about 1 to 3, wherein the porosity is imparted to the wrapper through the provision of symmetrically distributed spaced perforations having length and width dimensions of 0.001 to 0.015 inch.
  • perforations are provided as two or three longitudinal rows, both the perforations and the rows being equally spaced from the adjacent ones in the assembled cigarette.
  • the use of such paper wrappers provides a substantially greater reduction of vapor phase constituents of the cigarette smoke than of the particulate matter, the ratio of percentage reductions generally being about 1.5, and within the range of 1.1 to 2.
  • cigarette papers perforated in accordance with this invention display a selective reduction of vapor phase constituents of cigarette smoke.
  • the spaced perforations provided in the paper have smoke divided by the percentage reduction of the parlength and width dimensions between about 0.001 to 0.015 r ticulate constituents. inch, the size and number being so coordinated as to im-
  • the perforations are provided in longitudinal alignpaper characterized by an absolute Greiner porosity index ment, desirably in two or three rows.
  • n T bl I and II characterizing, respectively, the ad- Typical examples were discussed and referred to i the vantageous performance in accordance with this invention article
  • the Design of Low Yield Cigarettes by Schur as contrasted with the confirmation of what might have and Rickards, Tobacco Science, vol. 4, pp. 69-77 (1960) been expected from the prior art.
  • test cigarettes of these two tables were prepared by wrapping the tobacco column of the same popular commercial brand of cigarette in wrappers of the same paper, which differed only as indicated with respect to the porosity value and the manner of imparting porosity.
  • Example 1 to 6 of Table I the macroscopic perforations were produced by means of apparatus as shown in US. Patent 2,699,208 issued Jan. 11, 1955, to Milton 0. Schur to provide two longitudinal rows of perforations, symmetrically spaced apart so that in the wrapped cigarette the rows of perforations are equally spaced from each other.
  • Examples 1 and 2 there were 30 perforations per inch along each row, produced by rectangular perforating teeth which were initially 0.010 inch in length and 0.001 inch in width.
  • the lower porosity of Example 2 could be produced by the use of lower perforating pressures or of somewhat worn perforating rolls.
  • Examples 3 and 4 there were 16 perforations per inch along each row, produced by perforating teeth which were initially 0.005 inch by 0.005 inch.
  • Examples 5 and 6 there were 8 perforations per inch along each row, produced by rectangular perforating teeth which were initially 0.010 inch in length and 0.0025 inch in width.
  • the resulting perforations may be characterized as macroscopic in that they are visible without magnification at normal reading distances.
  • the porosity index values were measured with the use of a Greiner porosity tester, an instrument long used in the paper industry. The measurement is of the time in seconds for 50 ml. of air to be drawn through a test area of paper one inch in diameter under the influence of a varying suction head corresponding to a column of water averaging about 4 /2 inches in height. The readings have been corrected to absolute values by deducting the time, close to 4 seconds, required for a blank determination, without any paper sample in the instrument. For increased accuracy, the time measurements were carried out automatically by the use of a light absorbing solution and a photo-electric circuit in the apparatus.
  • the smoking tests reported herein were carried out in conventional manner, a 35 ml. puff being taken over a two second interval once per minute. In every case, 47 mm. of each cigarette was smoked, using cigarettes which had been conditioned for at least 48 hours at 72 F. and relative humidity of 63%. The cigarettes were selected by weight to be within :2% of the average weight of the group under test.
  • Particulate matter was removed from the smoke by means of a Cambridge Absolute Filter and weighed.
  • Table III The smoke analysis results in Table III were obtained on cigarettes prepared by wrapping the tobacco column of a popular commercial brand of cigarettes (not the same as used in the preceding tables) in a standard cigarette paper. Testing was carried out both with cigarettes having unperforated wrappers and having wrappers performated as in Example 4 above (two lines of 0.005 x 0.005 inch perforations, 16 per inch).
  • Methyl ethyl ketone 0. 119 0. 084 29. 4 1. 26 Furan 0. 038 0. 025 34. 2 1. 47 Propionaldehyde- 0 076 0. 043 43. 4 1. 87 crolein 0. 122 0. 065 46. 7 2. [)1 Methyl acetate 016 0. 009 43. 8 1. 88 Isobutyraldehyde... 0 032 0. 021 34. 4 1. 47
  • the average selectivity ratio of 1.54 confirms the selective reduction of vapor phase constituents in accordance with the invention.
  • the non-selectivity found with respect to methanol occurs occasionally with respect to one or several constituents and is believed to be characteristic of the particular tobacco blend.
  • the macroscopic perforations must be symmetrically arranged, in addition to being suflicient in size and number to impart a porosity in the effective critical range. Departures from symmetry in the arrangement of the perforations tends to decrease significantly the selectivity effect.
  • Microporousd0 vanishes Also, at values less than 0.5, difiiculties arise in easily lighting the cigarette.
  • the macroscopic perforations should have a length and width dimensions within the range of 0.001 to 0.015 inch. Larger openings are undesirable as tending to weaken the paper or tending to detract from the appearance,
  • the shape of the perforations may be varied as desired, provided that the area of the openings is within the specified macroscopic range. Thus, circular, elliptical, crescent, or partially circular, as well as triangular, rectangular or other polygonal shapes are suitable.
  • the perforating method and apparatus issued is as shown in US. Patent 2,699,208, the perforations should be square or rectangular.
  • other methods of perforation may be employed, for example as set forth in U.S. Patents 3,074,303 or 3,021,732. The provision of two or three lines of regularly spaced perforations is preferred as an eifective product can thus be made readily and efiiciently at high production rates.
  • the selective reduction of vapor phase constituents in accordance with this invention may be applied advantageously to any type of cigarette, including cigarettes provided with any of the available types of filters.
  • Particular advantages may be derived in filter cigarettes combining macroporous paper wrappers as defined herein with a specialized filter tip adapted to remove certain components from the smoke or to supply flavoring ingredients to the smoke.
  • a cigarette paper adapted to serve as wrapper for 25 a tobacco column
  • said paper being provided with a plurality of macroscopic perforations aligned longitudinally 'in lines containing about 8 to 30 perforations per inch arranged symmetrically about the center of said paper, said perforations having length and width dimensions between .001 and .015 inch and imparting to said paper an absolute Greiner porosity index of about 1 to 3, p whereby smoke drawn from a cigarette tobacco column wrapped with said paper is attenuated by a plurality of substantially symmetrically disposed jets of air directed inwardly through said column, thereby effecting a significant reduction both .of vapor phase and particulate constituents of said smoke with selective reduction of said vapor phase constituents.

Landscapes

  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
US604178A 1966-12-23 1966-12-23 Cigarette paper Expired - Lifetime US3404687A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US604178A US3404687A (en) 1966-12-23 1966-12-23 Cigarette paper
GB55438/67A GB1137460A (en) 1966-12-23 1967-12-06 Cigarette paper
NL676716912A NL151758B (nl) 1966-12-23 1967-12-12 Sigarettenpapier met macroscopische perforaties.
SE17609/67A SE341977B (nl) 1966-12-23 1967-12-21

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US604178A US3404687A (en) 1966-12-23 1966-12-23 Cigarette paper

Publications (1)

Publication Number Publication Date
US3404687A true US3404687A (en) 1968-10-08

Family

ID=24418512

Family Applications (1)

Application Number Title Priority Date Filing Date
US604178A Expired - Lifetime US3404687A (en) 1966-12-23 1966-12-23 Cigarette paper

Country Status (4)

Country Link
US (1) US3404687A (nl)
GB (1) GB1137460A (nl)
NL (1) NL151758B (nl)
SE (1) SE341977B (nl)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3656489A (en) * 1969-08-26 1972-04-18 Eldon Stahly Method of treating tobacco smoke to eliminate metal carbonyl content thereof
US3884220A (en) * 1972-07-05 1975-05-20 Leo J Hartnett Method for injecting X-ray contrast media for venography of the female pelvis
US4447709A (en) * 1976-05-25 1984-05-08 Olin Corporation Method for electrically perforating dielectric webs
US4590955A (en) * 1984-07-11 1986-05-27 Olin Corporation Cigarette paper with reduced CO on burning

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR998557A (fr) * 1945-10-29 1952-01-21 Papeteries De Mauduit Sa Des Feuille de papier à cigarettes et cigarette obtenue au moyen de cette feuille
US3046994A (en) * 1959-07-02 1962-07-31 Olin Mathieson Ventilated cigarette
CA683748A (en) * 1964-04-07 O. Jones Samuel Smoking article

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA683748A (en) * 1964-04-07 O. Jones Samuel Smoking article
FR998557A (fr) * 1945-10-29 1952-01-21 Papeteries De Mauduit Sa Des Feuille de papier à cigarettes et cigarette obtenue au moyen de cette feuille
US3046994A (en) * 1959-07-02 1962-07-31 Olin Mathieson Ventilated cigarette

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3656489A (en) * 1969-08-26 1972-04-18 Eldon Stahly Method of treating tobacco smoke to eliminate metal carbonyl content thereof
US3884220A (en) * 1972-07-05 1975-05-20 Leo J Hartnett Method for injecting X-ray contrast media for venography of the female pelvis
US4447709A (en) * 1976-05-25 1984-05-08 Olin Corporation Method for electrically perforating dielectric webs
US4590955A (en) * 1984-07-11 1986-05-27 Olin Corporation Cigarette paper with reduced CO on burning

Also Published As

Publication number Publication date
NL6716912A (nl) 1968-06-24
NL151758B (nl) 1976-12-15
GB1137460A (en) 1968-12-18
SE341977B (nl) 1972-01-24

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AS Assignment

Owner name: ECYSTA CORPORATION, A CORP OF DE.

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:OLIN CORPORATION, A CORP OF VA.;REEL/FRAME:004446/0525

Effective date: 19850724