US3397033A - Textile bleaching process - Google Patents

Textile bleaching process Download PDF

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Publication number
US3397033A
US3397033A US445696A US44569665A US3397033A US 3397033 A US3397033 A US 3397033A US 445696 A US445696 A US 445696A US 44569665 A US44569665 A US 44569665A US 3397033 A US3397033 A US 3397033A
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US
United States
Prior art keywords
goods
bleaching
bleaching solution
textile
impregnated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US445696A
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English (en)
Inventor
Ney Peter
Kuhnmunch Walter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH filed Critical Degussa GmbH
Application granted granted Critical
Publication of US3397033A publication Critical patent/US3397033A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen

Definitions

  • the present invention relates to an improved process for bleachingfibers, especially, cellulosic fibers, either as such or in the form of yarns, woven fabrics or knit goods, in which the goods to be bleached are impregnated with an aqueous bleaching solution, the excess bleaching solution is removed by squeezing or centrifug" ing and the goods are then subjected to a heat treatment followed by washing which simplifies and reduces the time required for the bleaching.
  • the object of the present invention is to provide a process in which the time the bleaching agent acts on the goods could be shortened substantially while at the same time attaining a higher degree of whiteness.
  • the results of a bleaching treatment with regard to the degree of whiteness, as well as wettability could be substantially improved while effecting a saving in steam Patented Aug. 13, 1968 and heat energy if, according to the invention, the goods to be bleached are impregnated with the aqueous bleaching solution, such impregnated goods are stored at room or moderately raised temperatures, for instance up to about 40 C. for several hours, for example, 3 to 10 hours, in a tightly packed state, and after such storage are treated in a pressure steamer at temperatures between and 200 C. for 15 to 120 seconds.
  • a pressure steaming treatment is effected at temperatures between and 150 C. at corresponding pressures for 30 to 60 seconds.
  • Peroxidic textile bleaching solutions such as, for example, those of hydrogen peroxide, sodium peroxide or sodium perborate, are especially suited for the process according to the invention.
  • the process for instance,
  • the textile goods to be bleached can be carried out by impregnating the textile goods to be bleached with, for example, an alkaline hydrogen peroxide containing bleaching solution, removing the excess solution to provideabout a 100% to 150% take up by the goods. Thereupon the goods are folded up or rolled up and left to be acted on by the bleaching solution contained therein for several hours at room temperature. Thereafter, the goods are introduced into a pressure steamer without repeating the impregnation or an intervening Wash and treated in such pressure steamer at the temperatures indicated for a short time and then given the usual rinse.
  • an alkaline hydrogen peroxide containing bleaching solution removing the excess solution to provideabout a 100% to 150% take up by the goods.
  • the goods are folded up or rolled up and left to be acted on by the bleaching solution contained therein for several hours at room temperature. Thereafter, the goods are introduced into a pressure steamer without repeating the impregnation or an intervening Wash and treated in such pressure steamer at the temperatures indicated
  • the total time required for the treatment of the goods to be bleached can be shortened substantially while at the same time a higher degree of whiteness and a better removal of seed shells in theicase of cotton fabrics can be attained. Furthermore, the wettability of the goods bleached according to the invention is considerably improved.
  • the nettle cloth was impregnated with an aqueous bleaching solution which per liter contained Water glass 38/40 B. "ml-.. 30 NaOH g 10 H 0 (35% by weight) ml 40 Lamepon A (condensation product of oleic acid chloride and sodium lysalbinate) g 2 Wetting agent (lauryl sulfate) g 2
  • Wetting agent laauryl sulfate
  • the steam was at a temperature of 130 C. which corresponds to a gauge pressure between 2.8 to 3.2.
  • the cloth samples were each rinsed successively with hot, warm and cold tap water.
  • the degree of whiteness, the time required for submerging when placed on water and the degree of seed shell removal was determined for each bleached sample. The results are given in the following table:
  • tests 2 and 3 which were according to the invention, resulted in goods which were seed shell free, and had good wettability and a higher degree of whiteness than were obtained in tests 1, 2a and 3a.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Detergent Compositions (AREA)
  • Paper (AREA)
US445696A 1964-04-09 1965-04-05 Textile bleaching process Expired - Lifetime US3397033A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED44106A DE1301996B (de) 1964-04-09 1964-04-09 Verfahren zum Bleichen

Publications (1)

Publication Number Publication Date
US3397033A true US3397033A (en) 1968-08-13

Family

ID=7048088

Family Applications (1)

Application Number Title Priority Date Filing Date
US445696A Expired - Lifetime US3397033A (en) 1964-04-09 1965-04-05 Textile bleaching process

Country Status (2)

Country Link
US (1) US3397033A (de)
DE (1) DE1301996B (de)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4139697A (en) * 1977-04-06 1979-02-13 Tenneco Chemicals, Inc. Color stabilization of vinyl chloride resins
US4220754A (en) * 1976-05-25 1980-09-02 Tenneco Chemicals, Inc. Process for the purification of polyvinyl chloride with oxidizing agents
FR2478152A1 (fr) * 1980-03-15 1981-09-18 Kuesters Eduard Procede continu de blanchiment avec des peroxydes
US4734098A (en) * 1985-11-22 1988-03-29 Crucible Chemical Company Method for bleaching cotton

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA539280A (en) * 1957-04-09 A. Simon Simon Bleaching process
CA577546A (en) * 1959-06-09 F. Coleman Walter Textile bleaching process
CA589916A (en) * 1959-12-29 L. Potter Howard Bleaching cotton
GB844699A (en) * 1956-12-17 1960-08-17 Montedison Spa An improved method of purifying and bleaching cotton
FR1276635A (fr) * 1960-03-02 1961-11-17 Columbia Southern Chem Corp Procédé pour blanchir des articles de coton

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA539280A (en) * 1957-04-09 A. Simon Simon Bleaching process
CA577546A (en) * 1959-06-09 F. Coleman Walter Textile bleaching process
CA589916A (en) * 1959-12-29 L. Potter Howard Bleaching cotton
GB844699A (en) * 1956-12-17 1960-08-17 Montedison Spa An improved method of purifying and bleaching cotton
FR1276635A (fr) * 1960-03-02 1961-11-17 Columbia Southern Chem Corp Procédé pour blanchir des articles de coton

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4220754A (en) * 1976-05-25 1980-09-02 Tenneco Chemicals, Inc. Process for the purification of polyvinyl chloride with oxidizing agents
US4139697A (en) * 1977-04-06 1979-02-13 Tenneco Chemicals, Inc. Color stabilization of vinyl chloride resins
FR2478152A1 (fr) * 1980-03-15 1981-09-18 Kuesters Eduard Procede continu de blanchiment avec des peroxydes
US4734098A (en) * 1985-11-22 1988-03-29 Crucible Chemical Company Method for bleaching cotton

Also Published As

Publication number Publication date
DE1301996B (de) 1969-09-25

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