US3395910A - Metallurgical tuyere - Google Patents

Metallurgical tuyere Download PDF

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Publication number
US3395910A
US3395910A US510772A US51077265A US3395910A US 3395910 A US3395910 A US 3395910A US 510772 A US510772 A US 510772A US 51077265 A US51077265 A US 51077265A US 3395910 A US3395910 A US 3395910A
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United States
Prior art keywords
tuyere
nozzle
molten metal
refractory
central conduit
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US510772A
Inventor
Ronald L W Holmes
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Union Carbide Corp
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Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Priority to US510772A priority Critical patent/US3395910A/en
Priority to BE690348D priority patent/BE690348A/xx
Priority to FR85470A priority patent/FR1503078A/en
Priority to DE19661508282 priority patent/DE1508282B1/en
Priority to GB53603/66A priority patent/GB1133359A/en
Application granted granted Critical
Publication of US3395910A publication Critical patent/US3395910A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/05Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • B22D1/002Treatment with gases
    • B22D1/005Injection assemblies therefor
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/42Constructional features of converters
    • C21C5/46Details or accessories
    • C21C5/4606Lances or injectors
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0037Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material

Definitions

  • This invention relates to a metallurgical tuyere and more particularly to a submerged tuyere for injecting a gas below the surface of a molten metal bath.
  • the main object of the invention is to provide a tuyere which will exhibit a relatively long life when exposed to a high temperature bath of molten metal such as steel, even though such tuyere is not water cooled.
  • Another object is to provide a tuyere which will not readily become plugged with molten metal during its operation.
  • Still another object is to provide a tuyere which in addition to satisfying the foregoing -objects will also enable the gas to be discharged at about its critical velocity.
  • FIGURE 1 is a sectional view of the tuyere of the inventi-0n when in operative position below the surface of a molten metal bath in a degassing vessel, and
  • FIGURE 2 is an isometric view of a portion of the injection tuyere shown in FIGURE l.
  • the apparatus of the invention consists of a central conduit for conduct-ing a ow of gas, e.g. argon, from a source of gas supply, such conduit having an inlet end and a discharge end. Connected to the discharge end of this conduit is a nozzle of smaller diameter than the central conduit. The nozzle is sized so that the gas will be discharged at critical velocity at the flow rate of gas expected to be injected into the molten metal.
  • a ow of gas e.g. argon
  • a sheath of refractory surrounding the nozzle is utilized to protect the nozzle from actually coming into contact with the molten metal.
  • a highly conductive metal stopper member is disposed within the central conduit adjacent its inlet end. In the event there is a sudden failure in the gas supply pressure and molten metal enters the nozzle and central conduit, this stopper member will prevent the molten metal from flowing into the gas supply lines. Another advantage of this stopper member is that its removal enables one to insert a cleaning tool axially through the central conduit and nozzle in order to clean same if it becomes partially plugged.
  • this pipe' should be greater than the anticipated height of molten metal in the de- Vgassing vessel so that the gravity effect will be neutralized and molten metal will not be able toenter the gas supply system.
  • the tuyere 10 of the invention is shownpositioned at the bottom ofa degassing vessel 11 having a lining 12.
  • the tuyere consists of a centralA conduit 15 having an inlet end 16 and a discharge end 17.
  • the inlet end -16 is connected to an upwardly ex- Y tending length of heavy pipe 18.
  • the lengthA of pipe 18 is' preferably greater than the expected head of molten met'- al in the degassing vessel.
  • the upper end of pipe '18 is connected via conduit 19 to a gaseous supply means such as "a tank-of pressurized gas.
  • the discharge end"'17l of central conduit 15 has a tuyereV nozzle 20 connected thereto.
  • the diameter of tuyere nozzle 20 is sized so as to provide'critical flow at the flow rates anticipated which will be required for a particular degassing process.
  • the nozzle 20, along with the exposedportion o f central conduit 15, is encased with a sheath of low grade refractory cement 21 which in turn is su-rrounded by a sheath of high grade refractory brick 22.
  • the refractory brick 22 is secured to the side of the vessel lining by a refractory fillet 23.
  • the refractory cement 21 When the refractory cement 21 is applied it is molded so as to provide a discharge passage 24 extending axially from the discharge end of nozzle 20.
  • the diameter of this discharge passage is also preferably of the same diameter as the diameter of nozzle 20.
  • the overall sheath of refractory serves to prevent molten metal from coming into contact with the exposed surfaces of the tuyere, thereby prolonging the life of the tuyere, though it is not water cooled.
  • the refractory sheath is usually replaced after every heat.
  • the refractory sheath as well as the pressure of the gas discharged from the tuyere prevent molten metal from entering or otherwise contacting the metal surfaces of the tuyere.
  • the gas between the shut-off valve (not shown) and the tuyere nozzle 20 escapes into the molten metal until the pressure in the tuyere is equal to the ferrostatic pressure.
  • some of the metal freezes at the face of the nozzle 20'. In most cases, however, the metal freezes in the molded port 24, just short of the tuyere nozzle, and thus only the refractory sheath would be replaced between heats.
  • a high conductive stopper rod member 26 is positioned adjacent the inlet end of central conduit 15 so as to cause the molten metal to freeze at this point and prevent it from entering the gas supply lines.
  • the stopper rod member 26 may be formed of copper or other highly heat conductive material.
  • the stopper rod member 26 is also positioned axially of the central conduit 15 so that when the rod is removed it will enable one to insert a cleaning tool to remove a partially plugged up tuyere tube or nozzle.
  • a length of heavy pipe 18 is positioned vertically between the inlet end of conduit 15 and the tubing 19 leading to the gas supply, the length of such pipe being preferably slightly greater than the anticipated height of molten metal to be held within the degassing vessel.
  • a tuyere having a central conduit 15 of 1/2 inch inside diameter, with a tuyere nozzle 20 of 0,220 inch inside diameter was successfully operated at a flow rate of 4,000 s.c.f.h. of argon.
  • the low grade refractory cement 21 consisted essentially of about 30% alumina and 70% 3 silica.
  • the high grade refractory 22 consisted essentially of an 80% alumina ramming refractory, balance silica.
  • the tuyere was positioned about three feet beneath the surface of a molten steel bath in a degassing vessel having a capacity of about 90 cubic feet.
  • a metallurgical tuyere for submerged injection of inert gas into a molten metal bath which comprises: a central conduit having an inlet end and a discharge end, a metal nozzle connected to said discharge end of said central conduit, said nozzle having a diameter which is smaller than the diameter of said central conduit, and a protective sheath of refractory material surrounding said nozzle and the immersed portion of said central conduit, said sheath of refractory material additionally forming a discharge passage extending axially from the discharge end of said nozzle for passing gas from said nozzle into said bath, whereby said sheath of refractory material prevents molten metal from coming into contact with said nozzle.
  • a metallurgical tuyere asclaimed in claim 1 ncluding a highly heat conductive metal stopper member positioned adjacent the inlet end of said central conduit and extending thereinto.
  • a metallurgical tuyere as claimed in claim 1 including an upwardly extending length of pipe connected to the inlet end of said central conduit, the length of said pipe being slightly greater than the anticipated head of molten metal to be treated by said tuyere in a givenheat.

Description

Aug. 6, 1968 R. 1 w. HOLMES METAL-LURG I CAL TUYERE Filed DSC. l, 1965 ATTORNEY United States Patent* O v f 3,395,910- f METALLURGICAL TUYERE Ronald L. W. Holmes, New Providence, NJ., assignor to Union Carbide, Corporation, a corporation 4of 4New York Filed Dec. 1, 1965, Ser. No. 510,772
5 Claims. (Cl. `26E-41) l nozzle into the bath, whereby the refractory material serves to prevent molten material from coming into contact with the metal parts of the tuyere.
This invention relates to a metallurgical tuyere and more particularly to a submerged tuyere for injecting a gas below the surface of a molten metal bath.
The main object of the invention is to provide a tuyere which will exhibit a relatively long life when exposed to a high temperature bath of molten metal such as steel, even though such tuyere is not water cooled.
Another object is to provide a tuyere which will not readily become plugged with molten metal during its operation.
Still another object is to provide a tuyere which in addition to satisfying the foregoing -objects will also enable the gas to be discharged at about its critical velocity.
Other objects and advantages of the invention will suggest themselves from the remaining disclosure, drawing and appended claims.
In the drawing:
FIGURE 1 is a sectional view of the tuyere of the inventi-0n when in operative position below the surface of a molten metal bath in a degassing vessel, and
FIGURE 2 is an isometric view of a portion of the injection tuyere shown in FIGURE l.
In brief, the apparatus of the invention consists of a central conduit for conduct-ing a ow of gas, e.g. argon, from a source of gas supply, such conduit having an inlet end and a discharge end. Connected to the discharge end of this conduit is a nozzle of smaller diameter than the central conduit. The nozzle is sized so that the gas will be discharged at critical velocity at the flow rate of gas expected to be injected into the molten metal.
A sheath of refractory surrounding the nozzle is utilized to protect the nozzle from actually coming into contact with the molten metal.
Preferably, a highly conductive metal stopper member is disposed within the central conduit adjacent its inlet end. In the event there is a sudden failure in the gas supply pressure and molten metal enters the nozzle and central conduit, this stopper member will prevent the molten metal from flowing into the gas supply lines. Another advantage of this stopper member is that its removal enables one to insert a cleaning tool axially through the central conduit and nozzle in order to clean same if it becomes partially plugged.
As a still further safety measure, it is preferable to employ a length of heavy pipe extending upwardly be- Patented Aug. 6,1968
tween vthe inlet end of the central conduit and the gas supply means. The length of this pipe' should be greater than the anticipated height of molten metal in the de- Vgassing vessel so that the gravity effect will be neutralized and molten metal will not be able toenter the gas supply system. l
Referring tov the drawing, the tuyere 10 of the invention is shownpositioned at the bottom ofa degassing vessel 11 having a lining 12. The tuyere consists of a centralA conduit 15 having an inlet end 16 and a discharge end 17. The inlet end -16 is connected to an upwardly ex- Y tending length of heavy pipe 18. The lengthA of pipe 18 is' preferably greater than the expected head of molten met'- al in the degassing vessel. The upper end of pipe '18 is connected via conduit 19 to a gaseous supply means such as "a tank-of pressurized gas. The discharge end"'17l of central conduit 15 has a tuyereV nozzle 20 connected thereto. The diameter of tuyere nozzle 20 is sized so as to provide'critical flow at the flow rates anticipated which will be required for a particular degassing process. The nozzle 20, along with the exposedportion o f central conduit 15, is encased with a sheath of low grade refractory cement 21 which in turn is su-rrounded by a sheath of high grade refractory brick 22. The refractory brick 22 is secured to the side of the vessel lining by a refractory fillet 23. When the refractory cement 21 is applied it is molded so as to provide a discharge passage 24 extending axially from the discharge end of nozzle 20. The diameter of this discharge passage is also preferably of the same diameter as the diameter of nozzle 20. The overall sheath of refractory serves to prevent molten metal from coming into contact with the exposed surfaces of the tuyere, thereby prolonging the life of the tuyere, though it is not water cooled. The refractory sheath, however, is usually replaced after every heat.
In operation, the refractory sheath as well as the pressure of the gas discharged from the tuyere prevent molten metal from entering or otherwise contacting the metal surfaces of the tuyere. When the ow of gas is stopped, the gas between the shut-off valve (not shown) and the tuyere nozzle 20 escapes into the molten metal until the pressure in the tuyere is equal to the ferrostatic pressure. Within a few seconds thereafter, some of the metal freezes at the face of the nozzle 20'. In most cases, however, the metal freezes in the molded port 24, just short of the tuyere nozzle, and thus only the refractory sheath would be replaced between heats.
In the event of a sudden loss of gas pressure, molten metal would enter the metal portions of the tuyere. As a safety precaution, a high conductive stopper rod member 26 is positioned adjacent the inlet end of central conduit 15 so as to cause the molten metal to freeze at this point and prevent it from entering the gas supply lines. The stopper rod member 26 may be formed of copper or other highly heat conductive material.
The stopper rod member 26 is also positioned axially of the central conduit 15 so that when the rod is removed it will enable one to insert a cleaning tool to remove a partially plugged up tuyere tube or nozzle.
As a still further safety precaution, a length of heavy pipe 18 is positioned vertically between the inlet end of conduit 15 and the tubing 19 leading to the gas supply, the length of such pipe being preferably slightly greater than the anticipated height of molten metal to be held within the degassing vessel.
To provide an indication of the relative dimensions of the tuyere in a typical situation according to the invention, a tuyere having a central conduit 15 of 1/2 inch inside diameter, with a tuyere nozzle 20 of 0,220 inch inside diameter was successfully operated at a flow rate of 4,000 s.c.f.h. of argon. The low grade refractory cement 21 consisted essentially of about 30% alumina and 70% 3 silica. The high grade refractory 22 consisted essentially of an 80% alumina ramming refractory, balance silica. The tuyere was positioned about three feet beneath the surface of a molten steel bath in a degassing vessel having a capacity of about 90 cubic feet.
What is claimed is:
1. A metallurgical tuyere for submerged injection of inert gas into a molten metal bath, which comprises: a central conduit having an inlet end and a discharge end, a metal nozzle connected to said discharge end of said central conduit, said nozzle having a diameter which is smaller than the diameter of said central conduit, and a protective sheath of refractory material surrounding said nozzle and the immersed portion of said central conduit, said sheath of refractory material additionally forming a discharge passage extending axially from the discharge end of said nozzle for passing gas from said nozzle into said bath, whereby said sheath of refractory material prevents molten metal from coming into contact with said nozzle.
2. A metallurgical tuyere as claimed in claim 1 wherein said sheath of refractory surrounding said nozzle consists of a layer of low grade refractory cement in contact with said nozzle and a second layer of high grade refractory surrounding said refractory cement.
3. A metallurgical tuyere as claimed in claim 1 wherein the diameter of the discharge passage formed by said sheath of refractory material is substantially the same as the diameter of said nozzle. Y
4. A metallurgical tuyere asclaimed in claim 1 ncluding a highly heat conductive metal stopper member positioned adjacent the inlet end of said central conduit and extending thereinto.
5. A metallurgical tuyere as claimed in claim 1 including an upwardly extending length of pipe connected to the inlet end of said central conduit, the length of said pipe being slightly greater than the anticipated head of molten metal to be treated by said tuyere in a givenheat.
References Cited UNITED STATES PATENTS 2,294,162 8/ 1942 Dobscha 266-42 3,236,629 2/1966 Agarwal et al. 266-41 X 3,264,874 8/1966 Fischer 266-42 X I. SPENCER OVERHOLSER, Primary Examiner. E. MAR, Assistant Examiner.
US510772A 1965-12-01 1965-12-01 Metallurgical tuyere Expired - Lifetime US3395910A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US510772A US3395910A (en) 1965-12-01 1965-12-01 Metallurgical tuyere
BE690348D BE690348A (en) 1965-12-01 1966-11-28
FR85470A FR1503078A (en) 1965-12-01 1966-11-29 Metallurgical lance
DE19661508282 DE1508282B1 (en) 1965-12-01 1966-11-30 Metallurgical nozzle
GB53603/66A GB1133359A (en) 1965-12-01 1966-11-30 Tuyeres

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Application Number Priority Date Filing Date Title
US510772A US3395910A (en) 1965-12-01 1965-12-01 Metallurgical tuyere

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US3395910A true US3395910A (en) 1968-08-06

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BE (1) BE690348A (en)
DE (1) DE1508282B1 (en)
FR (1) FR1503078A (en)
GB (1) GB1133359A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3608881A (en) * 1967-03-24 1971-09-28 Za Zvetni Metali K Tuyere apparatus for using liquid fuel in the fuming process
US4572482A (en) * 1984-11-19 1986-02-25 Corcliff Corporation Fluid-cooled metallurgical tuyere
EP0181853A1 (en) * 1984-09-18 1986-05-21 Radex Austria Aktiengesellschaft für feuerfeste Erzeugnisse Gas flushing plug for metallurgical furnaces and vessels
US4721287A (en) * 1985-02-20 1988-01-26 Didier-Werke Ag Sleeve for blowing solid materials into a molten metal bath and method for use thereof
WO2016131090A1 (en) * 2015-02-17 2016-08-25 Technological Resources Pty. Limited Solids injection lance and conveying system maintenance without slag drain

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1141174A (en) * 1979-10-31 1983-02-15 Guy Savard Homogenization of metal using gas
DE3003884C2 (en) * 1980-02-02 1983-02-10 Didier-Werke Ag, 6200 Wiesbaden Method for installing and replacing a gas-permeable refractory insert in the wall of a container containing a melt for introducing gases into the container and arrangement for carrying out this method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2294162A (en) * 1942-08-25 Blast furnace cinder notch stopper
US3236629A (en) * 1962-12-19 1966-02-22 United States Steel Corp Method of introducing fluid fuel into a blast furnace
US3264874A (en) * 1962-05-30 1966-08-09 Max Planck Inst Eisenforschung Apparatus for measuring temperatures of iron and steel melts

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU31885A1 (en) * 1951-12-24

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2294162A (en) * 1942-08-25 Blast furnace cinder notch stopper
US3264874A (en) * 1962-05-30 1966-08-09 Max Planck Inst Eisenforschung Apparatus for measuring temperatures of iron and steel melts
US3236629A (en) * 1962-12-19 1966-02-22 United States Steel Corp Method of introducing fluid fuel into a blast furnace

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3608881A (en) * 1967-03-24 1971-09-28 Za Zvetni Metali K Tuyere apparatus for using liquid fuel in the fuming process
EP0181853A1 (en) * 1984-09-18 1986-05-21 Radex Austria Aktiengesellschaft für feuerfeste Erzeugnisse Gas flushing plug for metallurgical furnaces and vessels
US4572482A (en) * 1984-11-19 1986-02-25 Corcliff Corporation Fluid-cooled metallurgical tuyere
US4721287A (en) * 1985-02-20 1988-01-26 Didier-Werke Ag Sleeve for blowing solid materials into a molten metal bath and method for use thereof
WO2016131090A1 (en) * 2015-02-17 2016-08-25 Technological Resources Pty. Limited Solids injection lance and conveying system maintenance without slag drain
CN107429305A (en) * 2015-02-17 2017-12-01 技术资源有限公司 Solid injection spray gun and induction system without slag discharge are safeguarded

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Publication number Publication date
BE690348A (en) 1967-05-29
FR1503078A (en) 1967-11-24
GB1133359A (en) 1968-11-13
DE1508282B1 (en) 1970-08-27

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