US3362812A - Alloy steel and method - Google Patents
Alloy steel and method Download PDFInfo
- Publication number
- US3362812A US3362812A US469577A US46957765A US3362812A US 3362812 A US3362812 A US 3362812A US 469577 A US469577 A US 469577A US 46957765 A US46957765 A US 46957765A US 3362812 A US3362812 A US 3362812A
- Authority
- US
- United States
- Prior art keywords
- vanadium
- chromium
- alloy
- manganese
- steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 14
- 229910000851 Alloy steel Inorganic materials 0.000 title description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 28
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 28
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 16
- 229910052804 chromium Inorganic materials 0.000 claims description 16
- 239000011651 chromium Substances 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 229910000617 Mangalloy Inorganic materials 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 239000005864 Sulphur Substances 0.000 claims description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 1
- 238000005266 casting Methods 0.000 description 12
- 239000000956 alloy Substances 0.000 description 10
- 229910045601 alloy Inorganic materials 0.000 description 9
- 229910000831 Steel Inorganic materials 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910000914 Mn alloy Inorganic materials 0.000 description 2
- 229910000756 V alloy Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 229910000628 Ferrovanadium Inorganic materials 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- HBXWYZMULLEJSG-UHFFFAOYSA-N chromium vanadium Chemical compound [V][Cr][V][Cr] HBXWYZMULLEJSG-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- PNXOJQQRXBVKEX-UHFFFAOYSA-N iron vanadium Chemical compound [V].[Fe] PNXOJQQRXBVKEX-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T82/00—Turning
- Y10T82/25—Lathe
- Y10T82/2568—Center
Definitions
- austenitic manganese steel carbon about 1%, manganese can he Observed in the grain boundaries Or in the ma x l0-l4%) which, although soft in the heated treated conof the Steel- However, even When little as 25% dition, becomes surface-hardened through cold working.
- Example it was intended to have 1.50% vanadium (based upon the amount of vanadium added to the melt) with run 1 in- Casting l for a X Cedar Rapids efllshcluding additionally 1.50% chromium.
- run 1 in- Casting l for a X Cedar Rapids efllshcluding additionally 1.50% chromium.
- Chromium 1:50 Likewise, in runs 2, 4, 6, 8 and 10, it was intended to Silicon -38 have no chromium. The analyses subsequent to casting Manganese 12.85 are those reported. Further, in the various runs, the Vanadium 0-98 amount of vanadium was decreased, i.e., for runs 1 and Carbon 2 a target of 1.50%, for runs 3 and 4 a target of 1.25%, Iron (usual impurities) Remaihdeffor runs 5 and 6 a target of 1.00%, for runs 7 and 8 a The casting procedure included adding the vanadium in target of 050%, and for runs 9 and 10 a target of 025% the form of Carvan, a high carbon ferrovanadium marketed by Union Carbide. After casting, the jaws were vanadium. Runs E and 12 correspond to the formulations used in the 18,000 lb. and 6000 lb. life jaws, respectively.
- the vanadium target is set dependent upon the combination of physical characteristics sought, it being appreciated that the remainder is iron with the usual impurities associated therewith. In this connection, I prefer to maintain sulfur and phosphorus each below a maximum of 0.04%.
- vanadium Relative to the amount of vanadium employed, I find useful percentages in the range of 0.600.80% where the casting is relatively unsupported as in the case of a crusher bowl liner. However, where ductility can be sacrificed in favor of increased wear life, as in a supported crusher jaw, the vanadium is set at the high end of the optimum range and may advantageously go to 1.25% for certain crusher jaws.
- Vanadium added in the amounts from .251.25% to an 11-14% austenitic manganese steel, with approximately 1.50% chromium, will give increased hardness to the alloy when the alloy is quenched in water in the normal manner for manganese alloys from a temperature greater than 1700 F.
- vanadium added to the base analysis of the chromium-bearing austenitic manganese steel is about .60-.80% since this providees the best combination of mechanical properties. However, if ductility can be sacrified for potential increased wear, then the vanadium may be increased to a value as high as 1.25
- An austenitic manganese steel useful in abrasive applications consisting essentially of from about 1.0% to about 2.0% chromium, from about 0.15% to about 0.70% silicon, from about 10.5% to about 14.5% manganese, from about 0.25% to about 1.5% vanadium, from about 0.90% to about 1.40% carbon with the balance iron including the usual impurities associated therewith, with a maximum of about 0.04% each of phosphorus and sulphur.
- An austenitic manganese steel useful in abrasive applications consisting essentially of from about 1.3% to about 1.6% chromium, from about 0.040% to about 0.60% silicon, from about 11.5% to about 13.5% manganese, from about 0.60% to about 1.50% vanadium, from about 1.20% to about 1.35% carbon with the balance iron including the usual impurities associated therewith, with a maximum of about 0.04% each of phosphorus with sulphur.
- a method of preparing an abrasion resistant alloy steel comprising casting a mixture of from about 1.3% to about 1.6% chromium, from 0.40% to about 0.60% silicon, from about 11.5% to about 13.5% manganese, from about 1.20% to about 1.35% carbon and an amount of vanadium in the range of about 0.60% to about 1.05% along with iron and water quenching the casting from above about 1700" F., the amount of vanadium employed being in the lower end of the above-mentioned range when the casting is employed in an environment where self-support is needed and being in the higher end of the range where the casting is substantially supported in operation.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Crushing And Grinding (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US469577A US3362812A (en) | 1965-07-06 | 1965-07-06 | Alloy steel and method |
BE707194D BE707194A (enrdf_load_stackoverflow) | 1965-07-06 | 1967-11-28 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US469577A US3362812A (en) | 1965-07-06 | 1965-07-06 | Alloy steel and method |
Publications (1)
Publication Number | Publication Date |
---|---|
US3362812A true US3362812A (en) | 1968-01-09 |
Family
ID=23864291
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US469577A Expired - Lifetime US3362812A (en) | 1965-07-06 | 1965-07-06 | Alloy steel and method |
Country Status (2)
Country | Link |
---|---|
US (1) | US3362812A (enrdf_load_stackoverflow) |
BE (1) | BE707194A (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50108118A (enrdf_load_stackoverflow) * | 1974-02-05 | 1975-08-26 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US436497A (en) * | 1890-09-16 | Robert iiadfield | ||
US1310528A (en) * | 1919-07-22 | Robert abbott hadfield | ||
US1435294A (en) * | 1916-07-15 | 1922-11-14 | Hadfield Robert Abbott | Manufacture of steel |
US2382651A (en) * | 1941-10-23 | 1945-08-14 | Bell Telephone Labor Inc | Magnetic materials |
US2865740A (en) * | 1954-06-23 | 1958-12-23 | United States Steel Corp | Precipitation-hardening nonmagneticferrous alloys |
-
1965
- 1965-07-06 US US469577A patent/US3362812A/en not_active Expired - Lifetime
-
1967
- 1967-11-28 BE BE707194D patent/BE707194A/xx unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US436497A (en) * | 1890-09-16 | Robert iiadfield | ||
US1310528A (en) * | 1919-07-22 | Robert abbott hadfield | ||
US1435294A (en) * | 1916-07-15 | 1922-11-14 | Hadfield Robert Abbott | Manufacture of steel |
US2382651A (en) * | 1941-10-23 | 1945-08-14 | Bell Telephone Labor Inc | Magnetic materials |
US2865740A (en) * | 1954-06-23 | 1958-12-23 | United States Steel Corp | Precipitation-hardening nonmagneticferrous alloys |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50108118A (enrdf_load_stackoverflow) * | 1974-02-05 | 1975-08-26 |
Also Published As
Publication number | Publication date |
---|---|
BE707194A (enrdf_load_stackoverflow) | 1968-04-01 |
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