US3314868A - Acid nickel electroplating baths and processes - Google Patents
Acid nickel electroplating baths and processes Download PDFInfo
- Publication number
- US3314868A US3314868A US340787A US34078764A US3314868A US 3314868 A US3314868 A US 3314868A US 340787 A US340787 A US 340787A US 34078764 A US34078764 A US 34078764A US 3314868 A US3314868 A US 3314868A
- Authority
- US
- United States
- Prior art keywords
- betaine
- nickel
- group
- nickel electroplating
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
- C25D3/14—Electroplating: Baths therefor from solutions of nickel or cobalt from baths containing acetylenic or heterocyclic compounds
- C25D3/18—Heterocyclic compounds
Definitions
- reaction products of hetero cyclic nitrogen bases of the aromatic type with sultones as leveling agents in nickel electroplating baths.
- these products are inner salts of amino-alkane-sulfonic acids, so-called sulfobetaines.
- the leveling effect of these products is entirely effect may be adversely affected.
- Another object is nickel electroplating which produces an improved leveling effect and leveling depth distribution.
- organic betaine additives of the general formula wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom.
- R, R and R represent the substituents CH C H or another alkyl substituent, which may also be omitted.
- R is an alkylene radical with l to 12 carbon atoms phosphoric acid ester radical wherein at least one -R X radical is present in the molecule attached to a nitrogen atom.
- the betaine compounds according to the present in- The betaine compounds may also be derived from heterocyclic nitrogen bases which comprise two or more ring system, which may be, for exmple, pyridazine, pyrimidine, pyrazine, phthalazine, quinazoline, quinoxaline, phenazine, and the like, where 3,314,868 Patented Apr. 18, 1967 the acid alkanic acid ester radical (-R -X*) may also be present on several ring nitrogen atoms.
- the additives may be used in nickel electroplating baths, for example, a Watts type nickel plating bath.
- the baths products according to the present inven- the nickel electroplating baths may be modified with customary brightening agents well known in the art, such as benzene-m-disulfonic acid, diaryldisulfimides, sulfonamides and the like, and also with other known agents, such as wetting agents.
- Example I The leveling agent according to the may be prepared by pyridine were added present invention the following method. 85.7 gm. of dropwise at to -C. over the over the course Subsequently, the mixture was heated to 40 C. in the course of 60 minutes, then stirred for one hour. Nitrogen was then passed therethrough for two hours to drive oil the hydrogen chloride formed by heating, and then the mixture was stirred for two additional vhours at 35 to 40 C.
- the solid substance Example II A nickel bath of the Watts-type was modified with 2 gm./l. of o-toluene-disulfonimide as a brightening agent,
- Example I In the nickel bath described in Example I the leveling agent was replaced by an equal amount of pyridinium- (decy-lsulfate-) betaine. An equally good leveling effect of the nickel electrodeposits was achieved even down to a current density range of 0.1 amp/dm.
- This bath furnished full bright, ductile and well-leveled nickel electrodeposits at an operating temperature of 50 to 60 C. in a current density range of 0.25 to 7 amp/drnfl.
- Example V In the nickel bath of Example IV the pyridinium-(ethylphosphate-2) betaine was replaced by the same amount of w-picolinium-ethylsulfate-Z) betaine as a leveling agent. Nickel electrodeposits of equally good quality were obtained.
- Example VI A nickel bath of the Watts-type was modified with 1.5 gm./l. of N-(benzene-sulfonyl)acct-amide as a brightening agent, 0.5 gm./l. of sodium dodecylsulfate as a wetting agent and 0.3 gm./l. of pyridinium-(3,-dioxaoctylsulfate-8) betaine as a leveling agent. Full bright, ductile and high-level nickel electrodeposits were obtained at a bath temperature of 50 to 60 C.
- An aqueous acid nickel electroplating bath for obtaining level nickel electrodeposits which comprises an organic betaine additive compound of the general formula wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom,
- An aqueous acid nickel electroplating bath which comprises an organic betaine additive compound of the general formula wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom,
- R, R and R are selected from the group consisting of hydrogen and alkyl groups
- R is an aliphatic radical with 1 to 12 carbon atoms
- X is selected from the group consisting of an acid sulfuric acid ester radical and an acid phosphoric acid ester radical
- a radical -R X is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said additive being added in an amount from about 0.05 to 3 gm./l.
- An aqueous acid nickel electroplating bath which comprises an organic betaine additive compound of the general formula wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom,
- R, R and R are selected from the group consisting of hydrogen and alkyl groups
- R is an aliphatic radical with 1 to 12 carbon atoms
- X is selected from the group consisting of an acid sulfuric acid ester radical and an acid phosphoric acid ester radical
- a radical R X" is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said additive being added in an amount from about 0.01 to 0.05 gm./l.
- An aqueous acid nickel electroplating bath comprising as an additive compound from about 0.05 to 3 gm./l. of pyridinium-(ethylsulfate-2) betaine.
- An aqueous acid nickel electroplating bath comprising as an additive compound from about 0.05 to 3 gm./l.v of pyridinium-(decylsulfate-lO) betaine.
- An aqueous acid nickel electroplating bath comprisas an additive compound from about 0.05 to 3 gm./1. of
- R, R and R are selected from the group consisting of hydrogen and alkyl groups
- R is an aliphatic radical with 1 to 12 carbon atoms
- X is selected from the group consisting of an acid sulfuric acid ester radical and an acid phosphoric acid ester radical
- a radical -R -X is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said compound being added in sufiicient amount to obtain said level nickel electrodeposits.
- a method for producing level nickel electrodeposits which comprises forming said electrodeposits in an aqueous acid nickel electroplating bath to which has been added a betaine compound of the general formula wherein represents a member selected from the group consisting of monoand polynuclear heterocyclic nitrogen base groups having at least one nitrogen atom,
- a radical -R -X is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said additive being added in an amount from 0.05 to 3 gm./l.
- a method for producing level nickel electrodeposits which comprises forming said electrodeposits in an aque- 6 ous acid nickel electroplating bath to which has been added a betaine compound of the general formula 2 wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom,
- R, R and R are selected from the group consisting of hydrogen and alkyl groups
- R is an aliphatic radical with 1 to 12 carbon atoms
- X is selected from the group consisting of an acid sulfuric acid ester radical and an acid phosphoric acid ester radical
- a radical -R -X-' is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said additive being added in an amount from about 0.01 to 0.05 gm./l.
Description
United States Patent Ofifice 3,314 868 ACID NICKEL ELECT ROPLATING BATHS AND PROCESSES Wolf-Dieter Willmund and Wennemar Strauss, Dusseldorf-Holthausen, Germany, assignors to Dehydag Deutsche Hydrierwerke G.m.b.H., Dusseldorf, Germany, a corporation of Germany Drawing. Filed Jan. 28, 1964, Ser. No. 340,787 Claims priority, application Germany, May 15, 1963, D 41,559 20 Claims. (Cl. 204-49) This invention relates to a process for nickel electroplating and to a nickel electroplating bath containing additive compounds. It more specifically relates to the use of aromatic nitrogen compounds as leveling additives for nickel electroplating baths.
It is already known to use reaction products of hetero cyclic nitrogen bases of the aromatic type with sultones as leveling agents in nickel electroplating baths. Accord ing to their chemical structure, these products are inner salts of amino-alkane-sulfonic acids, so-called sulfobetaines. The leveling effect of these products is entirely effect may be adversely affected.
It is, therefore, an object of this invention to provide a during operation of the electroplating process.
Another object is nickel electroplating which produces an improved leveling effect and leveling depth distribution.
These and other objects of our invention will become apparent as the description thereof proceeds.
It has now been found that the objects of the invention may be attained and the disadvantages of the prior art overcome by use of organic betaine additives of the general formula wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom.
R, R and R represent the substituents CH C H or another alkyl substituent, which may also be omitted. R is an alkylene radical with l to 12 carbon atoms phosphoric acid ester radical wherein at least one -R X radical is present in the molecule attached to a nitrogen atom.
The betaine compounds according to the present in- The betaine compounds may also be derived from heterocyclic nitrogen bases which comprise two or more ring system, which may be, for exmple, pyridazine, pyrimidine, pyrazine, phthalazine, quinazoline, quinoxaline, phenazine, and the like, where 3,314,868 Patented Apr. 18, 1967 the acid alkanic acid ester radical (-R -X*) may also be present on several ring nitrogen atoms.
The additives may be used in nickel electroplating baths, for example, a Watts type nickel plating bath. The baths products according to the present inven- In addition to the leveling agents according to the present invention, the nickel electroplating baths may be modified with customary brightening agents well known in the art, such as benzene-m-disulfonic acid, diaryldisulfimides, sulfonamides and the like, and also with other known agents, such as wetting agents.
Example I The leveling agent according to the may be prepared by pyridine were added present invention the following method. 85.7 gm. of dropwise at to -C. over the over the course Subsequently, the mixture was heated to 40 C. in the course of 60 minutes, then stirred for one hour. Nitrogen was then passed therethrough for two hours to drive oil the hydrogen chloride formed by heating, and then the mixture was stirred for two additional vhours at 35 to 40 C. The solid substance Example II A nickel bath of the Watts-type was modified with 2 gm./l. of o-toluene-disulfonimide as a brightening agent,
In the nickel bath described in Example I the leveling agent was replaced by an equal amount of pyridinium- (decy-lsulfate-) betaine. An equally good leveling effect of the nickel electrodeposits was achieved even down to a current density range of 0.1 amp/dm.
Example IV In a nickel bath of the Watts-type, 3 gm./l. of N (benzene'sulfonyl)=benzoylarnide were dissolved as a brightening agent, 0.5 gm./l. of sodium dodecylsulfate as a wetting agent and 0.2 gm./l. of .py-ridinium(ethylphosphate-Z) betaine as a leveling agent. This bath furnished full bright, ductile and well-leveled nickel electrodeposits at an operating temperature of 50 to 60 C. in a current density range of 0.25 to 7 amp/drnfl.
Example V In the nickel bath of Example IV the pyridinium-(ethylphosphate-2) betaine was replaced by the same amount of w-picolinium-ethylsulfate-Z) betaine as a leveling agent. Nickel electrodeposits of equally good quality were obtained.
Example VI A nickel bath of the Watts-type was modified with 1.5 gm./l. of N-(benzene-sulfonyl)acct-amide as a brightening agent, 0.5 gm./l. of sodium dodecylsulfate as a wetting agent and 0.3 gm./l. of pyridinium-(3,-dioxaoctylsulfate-8) betaine as a leveling agent. Full bright, ductile and high-level nickel electrodeposits were obtained at a bath temperature of 50 to 60 C. in a current density range of 0.5 to 8 amp/dnm While certain specific examples and preferred modes of practice of the invention has been set forth it will be understood that this is solely for the purpose of illustration and that various changes and modifications may be made without departing from :the spirit of the disclosure and the scope of the appended claims.
We claim:
1. An aqueous acid nickel electroplating bath for obtaining level nickel electrodeposits, which comprises an organic betaine additive compound of the general formula wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom,
wherein a radical -R -X- is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said additive being added in sufficient amount to obtain said level nickel deposits.
4 2. An aqueous acid nickel electroplating bath, which comprises an organic betaine additive compound of the general formula wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom,
R, R and R are selected from the group consisting of hydrogen and alkyl groups,
R is an aliphatic radical with 1 to 12 carbon atoms,
and
X is selected from the group consisting of an acid sulfuric acid ester radical and an acid phosphoric acid ester radical,
wherein a radical -R X is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said additive being added in an amount from about 0.05 to 3 gm./l.
3. An aqueous acid nickel electroplating bath, which comprises an organic betaine additive compound of the general formula wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom,
R, R and R are selected from the group consisting of hydrogen and alkyl groups,
R is an aliphatic radical with 1 to 12 carbon atoms,
and
X is selected from the group consisting of an acid sulfuric acid ester radical and an acid phosphoric acid ester radical,
wherein a radical R X" is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said additive being added in an amount from about 0.01 to 0.05 gm./l.
4. The bath of claim 1 wherein said additive is a pyridiniumalkane sulfate betaine.
5. The bath of claim 1 wherein said additive is a pyridiniumalkane phosphate betaine.
6. An aqueous acid nickel electroplating bath comprising as an additive compound from about 0.05 to 3 gm./l. of pyridinium-(ethylsulfate-2) betaine.
7. An aqueous acid nickel electroplating bath comprising as an additive compound from about 0.05 to 3 gm./l.v of pyridinium-(decylsulfate-lO) betaine.
8. An aqueous acid nickel electroplating bath comprisas an additive compound from about 0.05 to 3 gm./1. of
wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom,
R, R and R are selected from the group consisting of hydrogen and alkyl groups,
R is an aliphatic radical with 1 to 12 carbon atoms,
X is selected from the group consisting of an acid sulfuric acid ester radical and an acid phosphoric acid ester radical,
wherein a radical -R -X is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said compound being added in sufiicient amount to obtain said level nickel electrodeposits.
12. A method for producing level nickel electrodeposits which comprises forming said electrodeposits in an aqueous acid nickel electroplating bath to which has been added a betaine compound of the general formula wherein represents a member selected from the group consisting of monoand polynuclear heterocyclic nitrogen base groups having at least one nitrogen atom,
wherein a radical -R -X is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said additive being added in an amount from 0.05 to 3 gm./l.
13. A method for producing level nickel electrodeposits which comprises forming said electrodeposits in an aque- 6 ous acid nickel electroplating bath to which has been added a betaine compound of the general formula 2 wherein represents a member selected from the group consisting of monoand polynuclear aromatic heterocyclic nitrogen base groups having at least one nitrogen atom,
R, R and R are selected from the group consisting of hydrogen and alkyl groups,
R is an aliphatic radical with 1 to 12 carbon atoms,
and
X is selected from the group consisting of an acid sulfuric acid ester radical and an acid phosphoric acid ester radical,
wherein a radical -R -X-' is attached to at least one nitrogen atom of said aromatic heterocyclic base group, said additive being added in an amount from about 0.01 to 0.05 gm./l.
14. The process of claim 11 wherein said additive is a pyridinium-alkane sulfate betaine.
15. The process of claim 11 wherein said additive is a pyridinium-alkane phosphate betaine.
16. The process of claim 11 comprising as said additive compound from about 0.05 to 3 gm./l. of pyridinium- (ethylsulfate-Z) betaine.
17. The process of claim 11 comprising as said additive compound from about 0.05 to 3 gm./l. of pyridinium- (decylsulfate-IO) betaine.
18. The process of claim 11 comprising as said additive compound from about 0.05 to 3 gm./l. of pyridnium- (ethylphosphate-Z) betaine.
19. The process of claim 11 comprising as said additive compound from about 0.05 to 3 gm./l. of 'y-picolinium-(ethylsulfate-2) betaine.
20. The process of claim 11 comprising as said additive compound from about 0.05 to 3 gm./l.. of pyridinium-(3,6-dioxaoctylsulfate-8) betaine.
References Cited by the Examiner UNITED STATES PATENTS JOHN H. MACK, Primary Examiner. MURRAY TILLMAN, Examiner. G. KAPLAN, Assistant Examiner.
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3,314,868 April 18, 1967 WolfDieter Willmund et al.
at error appears in the above numbered pat- It is hereby certified bh tters Patent should read as ent requiring correction and that the said Le correctedbelow.
Column 4, line 67, for "compris-" read comprising llne 71, for "pyridinium" read y picolinium Signed and sealed this 14th day of November 1967.
(SEAL) Attest:
EDWARD J. BRENNER Edward M. Fletcher, Jr.
Commissioner of Patents Attesting Officer
Claims (1)
1. AN AQUEOUS ACID NICKLE ELECTROPLATING BATH FOR OBTAINING LEVEL NICKEL ELECTRODEPOSITS, WHICH COMPRISES AN ORGANIC BETAINE ADDITIVE COMPOUND OF THE GENERAL FORMULA
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED41559A DE1191652B (en) | 1963-05-15 | 1963-05-15 | Acid galvanic nickel bath |
Publications (1)
Publication Number | Publication Date |
---|---|
US3314868A true US3314868A (en) | 1967-04-18 |
Family
ID=7046187
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US340787A Expired - Lifetime US3314868A (en) | 1963-05-15 | 1964-01-28 | Acid nickel electroplating baths and processes |
Country Status (3)
Country | Link |
---|---|
US (1) | US3314868A (en) |
DE (1) | DE1191652B (en) |
GB (1) | GB998370A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3444056A (en) * | 1966-06-24 | 1969-05-13 | Cilag Chemie | Nickel electroplating electrolyte |
US3862019A (en) * | 1974-04-26 | 1975-01-21 | R O Hull & Company Inc | Composition of electroplating bath for the electrodeposition of bright nickel |
US4212709A (en) * | 1978-06-14 | 1980-07-15 | Basf Aktiengesellschaft | Acidic nickel electroplating bath containing sulfobetaines as brighteners and levelling agents |
US4270987A (en) * | 1978-08-21 | 1981-06-02 | Henkel Kommanditgesellschaft Auf Aktien | Acid galvanic nickel baths containing N-(2,3-dihydroxypropyl)-pyridinium sulfates |
US4430171A (en) | 1981-08-24 | 1984-02-07 | M&T Chemicals Inc. | Electroplating baths for nickel, iron, cobalt and alloys thereof |
EP0264089A2 (en) * | 1986-10-16 | 1988-04-20 | BASF Aktiengesellschaft | Process for the preparation of sulphatobetaines |
US5024736A (en) * | 1988-05-25 | 1991-06-18 | Raschig Ag | Process for electroplating utilizing disubstituted ethane sulfonic compounds as electroplating auxiliaries and electroplating auxiliaries containing same |
US5417840A (en) * | 1993-10-21 | 1995-05-23 | Mcgean-Rohco, Inc. | Alkaline zinc-nickel alloy plating baths |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4135710A1 (en) * | 1991-10-30 | 1993-05-06 | Basf Ag, 6700 Ludwigshafen, De | CYCLIC AMMONIUM COMPOUNDS AND THE USE THEREOF AS A GLOSS AGENT FOR AQUEOUS-ACID GALVANIC NICKEL BATHS |
EP0621908B1 (en) * | 1992-01-25 | 1995-09-06 | BASF Aktiengesellschaft | Process for producing nickel-plated mouldings |
DE4211140A1 (en) * | 1992-04-03 | 1993-10-07 | Basf Ag | Phosphonium salts and their use as brighteners for aqueous acidic galvanic nickel baths |
DE4242194A1 (en) * | 1992-12-15 | 1994-06-16 | Basf Ag | Use of thiuronium salts as a brightener for aqueous-acidic galvanic nickel baths |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2647866A (en) * | 1950-07-17 | 1953-08-04 | Udylite Corp | Electroplating of nickel |
US2749349A (en) * | 1956-02-02 | 1956-06-05 | Reilly Tar & Chem Corp | Vinylpyridine-nu-oxides and process of making them |
US2782153A (en) * | 1954-02-16 | 1957-02-19 | Harshaw Chem Corp | Nickel electrodeposition |
US2848392A (en) * | 1956-10-10 | 1958-08-19 | Harshaw Chem Corp | Electrodeposition of nickel and electrolytes therefor |
US2876177A (en) * | 1955-03-16 | 1959-03-03 | Dehydag Gmbh | Additives for nickel electroplating baths |
US2938033A (en) * | 1960-05-24 | Stabilization of vinylpyridines | ||
DE1092744B (en) * | 1958-12-17 | 1960-11-10 | Dehydag Gmbh | Acid galvanic nickel bath |
US3170854A (en) * | 1963-03-18 | 1965-02-23 | Sarki Res And Dev Corp | Bright nickel plating bath containing a pyridinium or quinolinium phosphate brightener and method of electroplating therewith |
-
1963
- 1963-05-15 DE DED41559A patent/DE1191652B/en active Pending
-
1964
- 1964-01-28 US US340787A patent/US3314868A/en not_active Expired - Lifetime
- 1964-02-27 GB GB8102/64A patent/GB998370A/en not_active Expired
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2938033A (en) * | 1960-05-24 | Stabilization of vinylpyridines | ||
US2647866A (en) * | 1950-07-17 | 1953-08-04 | Udylite Corp | Electroplating of nickel |
US2782153A (en) * | 1954-02-16 | 1957-02-19 | Harshaw Chem Corp | Nickel electrodeposition |
US2876177A (en) * | 1955-03-16 | 1959-03-03 | Dehydag Gmbh | Additives for nickel electroplating baths |
US2749349A (en) * | 1956-02-02 | 1956-06-05 | Reilly Tar & Chem Corp | Vinylpyridine-nu-oxides and process of making them |
US2848392A (en) * | 1956-10-10 | 1958-08-19 | Harshaw Chem Corp | Electrodeposition of nickel and electrolytes therefor |
DE1092744B (en) * | 1958-12-17 | 1960-11-10 | Dehydag Gmbh | Acid galvanic nickel bath |
US3170854A (en) * | 1963-03-18 | 1965-02-23 | Sarki Res And Dev Corp | Bright nickel plating bath containing a pyridinium or quinolinium phosphate brightener and method of electroplating therewith |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3444056A (en) * | 1966-06-24 | 1969-05-13 | Cilag Chemie | Nickel electroplating electrolyte |
US3862019A (en) * | 1974-04-26 | 1975-01-21 | R O Hull & Company Inc | Composition of electroplating bath for the electrodeposition of bright nickel |
US4212709A (en) * | 1978-06-14 | 1980-07-15 | Basf Aktiengesellschaft | Acidic nickel electroplating bath containing sulfobetaines as brighteners and levelling agents |
US4270987A (en) * | 1978-08-21 | 1981-06-02 | Henkel Kommanditgesellschaft Auf Aktien | Acid galvanic nickel baths containing N-(2,3-dihydroxypropyl)-pyridinium sulfates |
US4430171A (en) | 1981-08-24 | 1984-02-07 | M&T Chemicals Inc. | Electroplating baths for nickel, iron, cobalt and alloys thereof |
EP0264089A2 (en) * | 1986-10-16 | 1988-04-20 | BASF Aktiengesellschaft | Process for the preparation of sulphatobetaines |
EP0264089A3 (en) * | 1986-10-16 | 1989-12-27 | Basf Aktiengesellschaft | Process for the preparation of sulphatobetaines |
US5024736A (en) * | 1988-05-25 | 1991-06-18 | Raschig Ag | Process for electroplating utilizing disubstituted ethane sulfonic compounds as electroplating auxiliaries and electroplating auxiliaries containing same |
US5417840A (en) * | 1993-10-21 | 1995-05-23 | Mcgean-Rohco, Inc. | Alkaline zinc-nickel alloy plating baths |
Also Published As
Publication number | Publication date |
---|---|
DE1191652B (en) | 1965-04-22 |
GB998370A (en) | 1965-07-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3314868A (en) | Acid nickel electroplating baths and processes | |
US2837472A (en) | Brighteners for electroplating baths | |
DE1053274B (en) | Bath for the production of galvanic metal coatings | |
US3054733A (en) | Composition for the electrolytic deposition of well levelled and ductile nickel coatings of mirror-like luster | |
US2876177A (en) | Additives for nickel electroplating baths | |
US3276979A (en) | Baths and processes for the production of metal electroplates | |
US3081240A (en) | Acid copper electroplating baths | |
US3798138A (en) | Electrodeposition of copper | |
US2550449A (en) | Electrodeposition of nickel from an acid bath | |
US3528894A (en) | Method of electrodepositing corrosion resistant coating | |
US3432408A (en) | Chromium plating electrolyte and method for preventing mist therein | |
US3953304A (en) | Electroplating baths for nickel and brightener-leveler compositions therefor | |
US3414493A (en) | Electrodeposition of copper | |
US3203878A (en) | Acid metal electroplating bath containing an organic sulfonic acid-thioureadithiocarbamic acid reaction product | |
US3218244A (en) | Nickel electroplating bath containing a 1, 2-dichloropropene pyridinium or quinolinium brightener | |
US3413295A (en) | Certain 1, 2-dichloro-propene pyridinium and quinolinium halide derivatives | |
EP0610236B1 (en) | Process for making nickel-plated castings | |
US3023151A (en) | Nickel electroplating baths | |
EP0675975B1 (en) | Use of thiourea salts as brighteners for aqueous-acid galvanic nickel baths | |
US3023152A (en) | Copper electroplating baths | |
US3282811A (en) | Acid nickel electroplating baths and processes | |
US3432509A (en) | Certain quaternary n-propargyl pyridinium salts | |
US3367854A (en) | Nickel plating | |
US3423296A (en) | Nickel electrodepositing baths,process,and additive composition comprising levelling agent therefor | |
US2758076A (en) | Bright acid copper plating |