US3310397A - Method of inoculating molten cast iron - Google Patents

Method of inoculating molten cast iron Download PDF

Info

Publication number
US3310397A
US3310397A US296119A US29611963A US3310397A US 3310397 A US3310397 A US 3310397A US 296119 A US296119 A US 296119A US 29611963 A US29611963 A US 29611963A US 3310397 A US3310397 A US 3310397A
Authority
US
United States
Prior art keywords
cast iron
molten cast
naphthalene
molten
spheroidal graphite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US296119A
Inventor
Gorshkov Andrei Andreevich
Voloshchenko Mikha Vasiljevich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INST LITEINOGO PROISVODSTVA
INSTITUTE LITEINOGO PROISVODSTVA
Original Assignee
INST LITEINOGO PROISVODSTVA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by INST LITEINOGO PROISVODSTVA filed Critical INST LITEINOGO PROISVODSTVA
Priority to US296119A priority Critical patent/US3310397A/en
Application granted granted Critical
Publication of US3310397A publication Critical patent/US3310397A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00Refining of pig-iron; Cast iron
    • C21C1/08Manufacture of cast-iron

Definitions

  • castings should be subject to heat treatment (malleablizing) in an oxidizing or neutral atmosphere in order to form a spheroidal graphite in malleable cast iron.
  • heat treatment malleablizing
  • the carbon present in the cast iron in the form of cementite is converted into graphite having the shape of round particles.
  • this method of heat treatment of cast iron complicates its process of manufacture.
  • naphthalene to the molten cast iron with the subsequent removal of primary and eutectic carbides by adding silicocalcium to the cast iron melt thus forming spheroidal graphite in the therebyproduced malleable cast iron.
  • One of the aims of this invention is to improve the processing of cast iron manufacture by reducing its treatment cycle.
  • Naphthalene can be added to the molten cast iron by various methods. For example, during experimental checking of the proposed method naphthalene was injected into the molten cast iron by means of steel tubes provided with openings.
  • the amount of added naphthalene is 0.1-0.3 percent of the weight of the molten cast iron.
  • the solid naphthalene is gasified under the conditions of molten cast iron, which facilitates the formation of spheroidal graphite particles 3,310,397 Patented Mar. 21, 1967 in the cast iron castings.
  • 0.3-0.6 percent by weight of silicocalcium is added, also contributing to the formation of spheroidal graphite by eliminating primary and eutectic carbides in the castings of malleable cast iron.
  • the amount of silicocalcium being added depends on the thickness of the casting walls. The thinner are the walls, the more silicocalcium is added.
  • a method for producing spheroidal graphite in cast iron comprising adding 0.1-0.3 percent naphthalene to molten cast iron.
  • a method for producing spheroidal graphite in cast iron comprising adding 0.1-0.3 percent naphthalene to molten cast iron and t-hen adding 0.3-0.6 percent of silicocalcium whereby the primary and eutectic carbides are eliminated as a result of the decomposition of the naphthalene.

Description

United States Patent 3,310,397 METHOD OF IN OCULATING MOLTEN CAST IRON Andrei Andreevich Gorshkov and Mikhail Vasiljevich Voloshchenko, Kiev, U.S.S.R., assignors to Institute Liteinogo Proisvodstva No Drawing. Filed July 18, 1963, Ser. No. 296,119 2 Claims. (Cl. 75-130) The invention relates to the methods of inoculating molten cast type iron with chemical reagents.
The problem concerning treatment of cast type iron by forming in it a spheroidal graphite of globular shape without any further heat treatment, by inoculating it with chemical reagents, for instance, with silicocalcium has not yet been solved satisfactorily.
It is will known that castings should be subject to heat treatment (malleablizing) in an oxidizing or neutral atmosphere in order to form a spheroidal graphite in malleable cast iron. At the same time, the carbon present in the cast iron in the form of cementite is converted into graphite having the shape of round particles. However, the application of this method of heat treatment of cast iron complicates its process of manufacture.
In order to eliminate various drawbacks it is advisable to add naphthalene to the molten cast iron with the subsequent removal of primary and eutectic carbides by adding silicocalcium to the cast iron melt thus forming spheroidal graphite in the therebyproduced malleable cast iron.
One of the aims of this invention is to improve the processing of cast iron manufacture by reducing its treatment cycle.
Naphthalene can be added to the molten cast iron by various methods. For example, during experimental checking of the proposed method naphthalene was injected into the molten cast iron by means of steel tubes provided with openings.
The amount of added naphthalene is 0.1-0.3 percent of the weight of the molten cast iron. The solid naphthalene is gasified under the conditions of molten cast iron, which facilitates the formation of spheroidal graphite particles 3,310,397 Patented Mar. 21, 1967 in the cast iron castings. Then 0.3-0.6 percent by weight of silicocalcium is added, also contributing to the formation of spheroidal graphite by eliminating primary and eutectic carbides in the castings of malleable cast iron. The amount of silicocalcium being added depends on the thickness of the casting walls. The thinner are the walls, the more silicocalcium is added.
Test results show that the castings made of malleable cast iron without further heat treatment by adding the said amount of naphthalene to the molten iron acquire the following mechanical properties:
Tensile strength in kg./cm.'-=5565 kg. per sq. cm.
Relative elongation=1.03.0 percent Although the given invention has been described in conformity with the preferable method of realization, it is self evident that modifications and variations may be introduced without diverging from the idea and the scope .of this invention. Such modifications and variations are considered to be within the scope of the invention and the claims enclosed.
What we claim is:
1. A method for producing spheroidal graphite in cast iron comprising adding 0.1-0.3 percent naphthalene to molten cast iron.
2. A method for producing spheroidal graphite in cast iron comprising adding 0.1-0.3 percent naphthalene to molten cast iron and t-hen adding 0.3-0.6 percent of silicocalcium whereby the primary and eutectic carbides are eliminated as a result of the decomposition of the naphthalene.
References Cited by the Examiner UNITED STATES PATENTS 1,790,552 1/1931 Meehan -130 2,863,755 12/1958 Kurzinski 75-130 X 3,155,498 11/1964 Jandras 75-130 DAVID L. RECK, Primary Examiner.
H. W. TARRING, Assistant Examiner.

Claims (1)

1. A METHOD FOR PRODUCING SPHEROIDAL GRAPHITE IN CAST IRON COMPRISING ADDING 0.1-0.3 PERCENT NAPHTHALENE TO MOLTEN CAST IRON.
US296119A 1963-07-18 1963-07-18 Method of inoculating molten cast iron Expired - Lifetime US3310397A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US296119A US3310397A (en) 1963-07-18 1963-07-18 Method of inoculating molten cast iron

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US296119A US3310397A (en) 1963-07-18 1963-07-18 Method of inoculating molten cast iron

Publications (1)

Publication Number Publication Date
US3310397A true US3310397A (en) 1967-03-21

Family

ID=23140699

Family Applications (1)

Application Number Title Priority Date Filing Date
US296119A Expired - Lifetime US3310397A (en) 1963-07-18 1963-07-18 Method of inoculating molten cast iron

Country Status (1)

Country Link
US (1) US3310397A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1790552A (en) * 1931-01-27 Nesses
US2863755A (en) * 1957-04-22 1958-12-09 Union Carbide Corp Oil-treated calcium carbide for desulfurization of iron
US3155498A (en) * 1961-12-27 1964-11-03 Bethlehem Steel Corp Ductile iron and method of making same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1790552A (en) * 1931-01-27 Nesses
US2863755A (en) * 1957-04-22 1958-12-09 Union Carbide Corp Oil-treated calcium carbide for desulfurization of iron
US3155498A (en) * 1961-12-27 1964-11-03 Bethlehem Steel Corp Ductile iron and method of making same

Similar Documents

Publication Publication Date Title
US2485761A (en) Gray cast iron having improved properties
US3768999A (en) Coated wire feeding technique for making addition of components to molten metals
US2485760A (en) Cast ferrous alloy
SU587872A3 (en) Method of preparing iron with spherical graphite
US2750284A (en) Process for producing nodular graphite iron
US3765875A (en) Inoculating alloy for cast irons
US3080228A (en) Process for the production of cast iron
US3459541A (en) Process for making nodular iron
US3310397A (en) Method of inoculating molten cast iron
US3055756A (en) Yttrium containing ferrous products and methods for preparing same
JPH01136920A (en) Production of spheroidal graphite cast iron
US3336118A (en) Magnesium alloy for cast iron
US3000770A (en) Malleable white cast iron alloys
US2610912A (en) Steel-like alloy containing spheroidal graphite
US2749238A (en) Method for producing cast ferrous alloy
US3600159A (en) Nodular cast iron containing silicon and vanadium
US2578794A (en) Magnesium-treated malleable iron
US3033676A (en) Nickel-containing inoculant
US2973564A (en) Method of graphitizing cast iron
US3871868A (en) Method of preparing a corrosion-resistant and ductile iron alloy with a high aluminum content
US3328164A (en) Prealloy for the treatment of iron and steel melts
US2494238A (en) Method of making gray cast iron
US2529346A (en) Method for the production of cast iron and alloy addition agent used in method
US2809888A (en) Cast iron with high creep resistance and method for making same
US3661566A (en) Process for the treatment of nodular cast iron