US3275555A - Synthetic lubricant containing oxetane polymers - Google Patents
Synthetic lubricant containing oxetane polymers Download PDFInfo
- Publication number
- US3275555A US3275555A US277733A US27773363A US3275555A US 3275555 A US3275555 A US 3275555A US 277733 A US277733 A US 277733A US 27773363 A US27773363 A US 27773363A US 3275555 A US3275555 A US 3275555A
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- US
- United States
- Prior art keywords
- oxetane
- polymer
- acid
- ester
- units
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
- C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
- C07D305/04—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D305/06—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring atoms
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/16—Cyclic ethers having four or more ring atoms
- C08G65/18—Oxetanes
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/22—Acids obtained from polymerised unsaturated acids
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- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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- C10M2207/30—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids
- C10M2207/304—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids derived from the combination of monohydroxy compounds, dihydroxy compounds and dicarboxylic acids only and having no free hydroxy or carboxyl groups
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- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
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- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M2209/082—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
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- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2209/106—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only
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- C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
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- C10M2209/112—Complex polyesters having dihydric acid centres
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- C10M2211/042—Alcohols; Ethers; Aldehydes; Ketones
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- C10M2223/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
- C10N2040/13—Aircraft turbines
Definitions
- This invention relates to synthetic ester lubricants and more particularly to synthetic ester lubricants useful for lubrication over wide temperature ranges required in the lubrication of moving parts of combustion turbines such as in gas turbine engines and the like.
- ester bases particularly the diesters of aliphatic dicarboxylic acids and branchedchain aliphatic alcohols in the viscosity range of from about 2 to about 10 cs. at 210 F., preferably between 3 and 5 cs. at 210 F.
- Ester bases of this type have been fully described in such publications as the Industrial and Engineering Chemistry, 1947, 39, page 484 and 1950, 42, page 2421, and 1953, 45, page 1766 as well as ASTM Special Technical Publication No. 77 on Symposium on Synthetic Lubricants, and Gundersons text entitled, Synthetic lubricants, chapter 5, pages l51245.
- load and extreme pressure properties can be imparted to ester base lubricants by addition thereto of a minor amount of from about 0.5% to about preferably between about 1% and 5% by weight of a polymeric oxetane having at least one halogen atom in each oxetane unit and which halogen is at least one carbon atom removed from the oxygen atom in each of the oxetane units.
- the ester base which comprises the major portion of the lubricat consists of a diester of an aliphatic dicarboxylic acid containing from 6 to carbon atoms in the molecule and a branched-chain aliphatic monohydric alcohols containing from 6 to 12 carbon atoms in the molecule, or a blend of such esters and their free acids.
- dicarboxylic esters of the present invention are dinonyl sebacate, di(2-ethyl hexyl) sebacate, di-iso-octyl azelate, di( 3, 5, 5-tri-methylhexyl) adipate and the like. Mixtures of these esters an mixtures of the esters and the free acid may also be used. Such mixtures include: di-octyl sebacate and di-octyl azelate, di(2-ethyl hexyl) sebacate and sebacic acid (90%, 10%
- the viscosity of the above exemplified esters ranges between 3 and 4.7 cs. at 210 F.
- R is a residue from a monohydric 3,275,555 Patented Sept. 27, 1966 ICC aliphatic alcohol
- D is a residue from a dibasic acid
- G is a residue from a glycol HOR4OH which is either a simple glycol wherein R is a branched or unbranched alkylene radical or is a polyoxyalkylene glycol formed by the polymerization of ethylene or propylene oxides or a mixture of these compounds, in which case R is a divalent polyether radical and n is a number from 1 to 6.
- R in above cases is a residue from a branched-chain alcohol, e.g. 2-ethyl hexyl alcohol, 2,2, 4-trimethylpentan-1-ol and D is a residue from an aliphatic acid, e.g. sebasic acid, adipic acid, azelaic acid, glutaric acid.
- a branched-chain alcohol e.g. 2-ethyl hexyl alcohol, 2,2, 4-trimethylpentan-1-ol
- D is a residue from an aliphatic acid, e.g. sebasic acid, adipic acid, azelaic acid, glutaric acid.
- Polymers of class (1) can be exemplified by esters of acrylic or methacrylic acid and C valkanols and mixtures thereof such as octyl, lauryl or stearyl methacrylate polymers in the molecular weight range of from 1,000 to 45,000 preferably between 10,000 and 20,000 of which preferred are lauryl and/ or stearyl methacrylate having a molecular weight of from 5,000 to 15,000 as determined by the light scattering method.
- esters of acrylic or methacrylic acid and C valkanols and mixtures thereof such as octyl, lauryl or stearyl methacrylate polymers in the molecular weight range of from 1,000 to 45,000 preferably between 10,000 and 20,000 of which preferred are lauryl and/ or stearyl methacrylate having a molecular weight of from 5,000 to 15,000 as determined by the light scattering method.
- the thickeners of class (2) are the polyoxyalkylene glycols and their monoand di-ethers or esters having the general formula:
- R and R each represent a hydrogen atom, a non-aromatic hydrocarbon radical or an. acyl group, R represents an alkylene radical and n represents an integer,
- the radical R may be any alkylene radical, preferably an alkylene radical with 2 to 8 carbon atoms. Still more preferred in the compositions of the invention are the polyoxyalkylene fluids in which the alkylene radical is an ethylene or propylene radical.
- alkylene radicals with ditferent numbers of carbon atoms. They may for instance consist of both oxyethylene and oxypropylene radicals. In case the polyoxyalkylene chain contains different alkylene radicals,
- compositions of the invention preference is given to polyoxyalkylene liquids in which the polyoxyalkylene chain consists of blocks of (for instance 1 to 8) oxyethylen'e radicals alternating with blocks of (for instance 1 to 8) oxypropylene radicals.
- radicals represented in the above general formula by R and/ or R are hydrocarbon radicals
- the radicals may be saturated or unsaturated, straight chained or branched, or similar or dissimilar, nonaromatic hydrocarbon radicals.
- radicals R and/ or R are acyl radicals
- the radicals may be derived from any carboxylic acid. Preference is given to the alkane or alkene monocarboxylic acids such as acetic acid, propionic acid, buty'ric acid, lauric acid, stearic acid and oleic acid.
- the molecular weight of the compounds which may be employed in the invention may vary over a wide range.
- Compounds of the type falling within the scope of this invention generally have molecular weights from 350 up to 10,000 the polyoxyalkylene liquids possessing a molecular weight between 800 and 6,000 being perferred.
- polyoxyalkylene liquids such as their viscosity and their visocity index depend upon the length of the polyoxyalkylene chain, the nature of the oxyalkylene chain and the nature of the terminal groups. It will be clear that apart from the obvious requirement of compatability with the ester oils, the
- polyoxyalkylene liquids should have a viscosity which is higher than the viscosity of the ester oils in order to act as a thickener for these oils. Moreover, they should have a high viscosity index so as to ensure that the viscosity index of the finished composition is not lower or not appreciably lower than the viscosity index of the ester oils.
- Suitable heterocyclic polyalkylene fluids are heterocyclic copolymers of ethylene oxide and propylene oxide in the viscosity range of 380700 at 100 F. SUS and prepared by the methods described in US. Patents 2,425,755 and 2,425,845. Specific examples of such copolymers are: (A) copolymer of ethylene oxide and 1,2-propylene oxide having a viscosity at 100 F. SUS of 385, VI of 144 and PP, F., of 40; (B) copolymer of ethylene oxide and 1,2-propylene oxide having a viscosity at 100 F. SUS of 525 and (C) copolymer of ethylene oxide and 1,2- propylene oxide having a viscosity at 100 F.
- block copolymers of ethylene oxide and propylene is meant that first one of the oxides, e.g. propylene oxide is polymerized and thereafter this polymer is treated With a dissimilar alkylene oxide compound as described in US. Patent 2,677,700.
- the ether and ester derivatives of these polymers are preferably alcohols and fatty acids of from 1 to about carbon atoms. Still more preferably are the esters and ethers of aliphatic monohydric alcohols and saturated aliphatic monocar-boxylic acids having from 1 to 4 carbon atoms.
- the thickener of class (3) can be exemplified by neopentyl glycol, 2-methyl 2-n-propyl propan-1,3 diol.
- Suitaible monocanboxylic acids are those containing from 4 to 9 carbon atoms.
- a preferred class of oxetanes is that represented by the formula:
- X 0 CH x o ofiz wherein one X is C1 or Br and the others are chosen from H, C1 or Br.
- the preferred compound of this class is 3,3-bis(chloromethyl)oxetane.
- Polymers of the re- 4 chosen so as to yield a polymer which is not appreciably volatile at 200 C.
- Example 1 245 g. of 3,34bis(chloromethyl)oxetane were placed in a flask fitted with a double surface air condenser. The system was sealed from the atmosphere by leading a tube from the top of the condenser so that it dipped beneath the surface of a mercury reservoir. Nitrogen was blown through the system before heat was applied. The monomer was refluxed at 210 C. for 11 days. During this period the color of the reaction mixture changed to amber. At no time was air allowed to get into the system. Unreacted monomer (83 g.) was distilled from the reaction mixture. The polymer residue (162 g., i.e. 66% w.
- the polymer so prepared had an average molecular weight of 450 and a chlorine content of 44.9% W.
- Example 2 g. of 3,3-bis(chloromethyl) oxetane were refluxed in a nitrogen atmosphere as in Example 1 for 10 days. The product was then fractionally distilled as follows:
- Fraction A consisted of unreacted monomer. Fractions B, C and D were predominantly the dimer, trimer and tetramer respectively.
- Example 3 TABLE I Examples Composition Di (2-ethyl hexyl) sebacate, percent w 97 97 97 D nsooctyl azelate, percent w 94 94 94 94 94 Azclaic acld, percent w 0.02 0. 02 0.02 0.02 0. 02 0.02 0.02 0. 02 Adlpic acid, percent w 0.02 0.02 3,7 dioctyl phenothiazine, percent w 1. 5 1. 5 1. 5 1. 5 1. 5 1. 5 1. 5 1 henyl a-naphthyleminc, percent w 1. 5 1. 5 1. 5 1. 5 1. 5 1. 5 1. 5 1. 5 1. 5 1.
- antioxidants such as phenothiazine or its derivatives or naphthylamines may be used.
- Rust inhibitors may be incorporated, for example, the metal salts of petroleum sulfonates and in particular lead corrosion can be inhibited by the use of taining ether linkages.
- the degree of polymerization is 75 certain dibasic carboxylic acids, for exampl al l acid- Small amounts of antifoaming agents may be incorporated.
- organic phosphate or phosphite esters for example, tricresyl phosphate, may be added.
- Other suitable extreme pressure additives are the chlorinated di and polyphenyls.
- compositions of Examples 413 were tested on an I.A.E. 3 /4 inch gear lubricant testing machine as described by Mansion in the Journal of the Institute of Petroleum, 1952, 38, 633, using B.S.S. EN34 steel gears. Results, expressed in 1b., are given in Table 11.
- Table II shows that the lubricant compositions of the present invention gave improved performance over compositions which did not contain the polymer of the present invention.
- compositions of Examples 6-10 also comply with the United States Military Specification MIL-L-7808Du
- MILL-7808 D Oxidation/Corrosion test at 175 C ⁇ the following results were obtained with Example 9.
- composition of claim 2 containing a minor amount of a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
- a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
- composition of claim 3 containing a minor amount of a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
- composition of claim 4 containing a minor amount of a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
- a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
- a synthetic lubricating composition comprising a major amount of di(2'ethyl hexyl) sebacate, from about 0.5% to about 10% of a polymer of 3,3-bis(ch10romethyl)oxetane having .from 2 to 4 units and a minor amount of a polymer of lauryl methacrylate.
- a synthetic lubricating composition comprising a major amount of diisooctyl azelate from about 0.5 to about 10% of a polymer of 3,3-bis(chloromethyl)oxetane having from 2 to 4 units and a minor amount of a polymer of lauryl methacrylate.
- a synthetic lubricating composition comprising a major amount of di(2-et-hyl hexyl) sebacate, from about 0.5% to about 10% of a polymer of 3,3-bis(chloromethyl)oxetane having from 2 to 4 units and a minor amount of a polymer copolymer of ethylene oxide and 1,2-propylene oxide in the viscosity range at 100 F. SUS of 380 to 700.
- Example 10 yielded a weight loss of 34 mg. Pb/in. after days at 85 C.
- the specification limit is 1501ng./in.
- a synthetic lubricating composition comprising a major amount of a dibasic ester of an aliphatic dica boxylic acid and a branched chain aliphatic alcohol and from 0.5 to 10% of a polymeric halogen-containing oxetane having from 2 to 20 oxetane units each of which contains at least one halogen which is on carbons other than the carbons adjacent to the oxygen atom of each unit.
- a synthetic lubricating composition comprising a major amount of a dibasic ester of an aliphatic dicarboxylic acid and a branched chain aliphatic alcohol in the viscosity range of from about 2 to about 10 cs. at 210 F. and from about 0.5% to about 10% of a polymeric ch10- rine containing oxetane having from 2 to 20 oxetane units, the chlorine being present on carbons other than the carbons adjacent to the oxygen atom in the oxetane units.
- a synthetic lubricating composition comprising a major amount of di-2-ethylhexyl sebacate and from 0.5% to 10% of a polymer of chlorinated oxetane having from 2 to 20 of such units in the polymer, the chlorine being present on carbons other than the carbons adjacent to the oxygen atom in the oxetane units.
- a synthetic lubricating composition comprising a major amount of di-Z-ethylhexyl sebaca-te and from 0.5% to 10% of a polymer of 3,3-bis(chloromethyl) oxetane having from 2 to 20 of such units in the polymer.
- composition of claim 1 containing a minor amount of a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
- a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
- a synthetic lubricating composition comprising a major amount of diisooctyl azelate from about 0.5% to about 10% of a polymer of 3,3-bis(chloromethyl)oxetane having from 2 to 4 units and a minor amount of a polymer of copolymer of ethylene oxide and 1,2-propylene oxide in the viscosity range at F. SUS of 380 to 700.
- composition of claim 9 containing a small amount of an organic amine antioxidant.
- composition of claim 10 containing a small amount of an organic amine antioxidant.
- composition of claim 11 containing a small amount of an organic amine antioxidant.
- composition of claim 12 containing a small amount of an organic amine antioxidant.
Description
United States Patent 3,275,555 SYNTHETIC LUBRICANT CONTAINING UXETANE POLYMERS Francis Henry Waight, Eastham, Wirral, Alexander C. B. MacPhail, Little Sutton, Wirral, and Derek Southern, Heswall, Wirral, England, assignors to Shell Oil Company, New York, N.Y., a corporation of Delaware No Drawing. Filed May 3, 1963, Ser. No. 277,733 Claims priority, application Great Britain, May 11, 1962,
8,206/ 62 16 Claims. (Cl. 252-54.6)
This invention relates to synthetic ester lubricants and more particularly to synthetic ester lubricants useful for lubrication over wide temperature ranges required in the lubrication of moving parts of combustion turbines such as in gas turbine engines and the like.
The most effective lubricating bases developed for uses mentioned above are the ester types, particularly the diesters of aliphatic dicarboxylic acids and branchedchain aliphatic alcohols in the viscosity range of from about 2 to about 10 cs. at 210 F., preferably between 3 and 5 cs. at 210 F. Ester bases of this type have been fully described in such publications as the Industrial and Engineering Chemistry, 1947, 39, page 484 and 1950, 42, page 2421, and 1953, 45, page 1766 as well as ASTM Special Technical Publication No. 77 on Symposium on Synthetic Lubricants, and Gundersons text entitled, Synthetic lubricants, chapter 5, pages l51245. The art also discloses that stabilization of these synthetic ester bases with various types of organic nitrogen containing compounds such as phenyl-a-naphthylamine and phenothiazine has been quite satisfactory. However, the problem of imparting load-bearing properties to such lubricants has not been solved successfully and has become more urgent as demands on turbo engines become more pressing.
It has now been discovered that load and extreme pressure properties can be imparted to ester base lubricants by addition thereto of a minor amount of from about 0.5% to about preferably between about 1% and 5% by weight of a polymeric oxetane having at least one halogen atom in each oxetane unit and which halogen is at least one carbon atom removed from the oxygen atom in each of the oxetane units.
The ester base which comprises the major portion of the lubricat consists of a diester of an aliphatic dicarboxylic acid containing from 6 to carbon atoms in the molecule and a branched-chain aliphatic monohydric alcohols containing from 6 to 12 carbon atoms in the molecule, or a blend of such esters and their free acids.
Examples of the dicarboxylic esters of the present invention are dinonyl sebacate, di(2-ethyl hexyl) sebacate, di-iso-octyl azelate, di( 3, 5, 5-tri-methylhexyl) adipate and the like. Mixtures of these esters an mixtures of the esters and the free acid may also be used. Such mixtures include: di-octyl sebacate and di-octyl azelate, di(2-ethyl hexyl) sebacate and sebacic acid (90%, 10%
The viscosity of the above exemplified esters ranges between 3 and 4.7 cs. at 210 F. In order to increase their viscosity range to 510 cs. at 210 F. which is desirable when temperature above 350 F. and higher are encountered, it is advantageous to blend with the ester base a minor amount of from 1% to 20% of an oxygen-containing polymeric thickener selected from the group consisting of (1) a polymer of an ester of a C alkyl acrylate, (2) a hetero or block polymer of dissimilar alkylene oxides and (3) a complex ester corresponding to the general formula:
or a mixture of compounds corresponding to any or all of these esters, where R is a residue from a monohydric 3,275,555 Patented Sept. 27, 1966 ICC aliphatic alcohol, D is a residue from a dibasic acid, G is a residue from a glycol HOR4OH which is either a simple glycol wherein R is a branched or unbranched alkylene radical or is a polyoxyalkylene glycol formed by the polymerization of ethylene or propylene oxides or a mixture of these compounds, in which case R is a divalent polyether radical and n is a number from 1 to 6.
Preferably R in above cases is a residue from a branched-chain alcohol, e.g. 2-ethyl hexyl alcohol, 2,2, 4-trimethylpentan-1-ol and D is a residue from an aliphatic acid, e.g. sebasic acid, adipic acid, azelaic acid, glutaric acid. Polymers of class (1) can be exemplified by esters of acrylic or methacrylic acid and C valkanols and mixtures thereof such as octyl, lauryl or stearyl methacrylate polymers in the molecular weight range of from 1,000 to 45,000 preferably between 10,000 and 20,000 of which preferred are lauryl and/ or stearyl methacrylate having a molecular weight of from 5,000 to 15,000 as determined by the light scattering method.
The thickeners of class (2) are the polyoxyalkylene glycols and their monoand di-ethers or esters having the general formula:
wherein R and R each represent a hydrogen atom, a non-aromatic hydrocarbon radical or an. acyl group, R represents an alkylene radical and n represents an integer,
In the polyoxyalkylene chain (R O) the radical R may be any alkylene radical, preferably an alkylene radical with 2 to 8 carbon atoms. Still more preferred in the compositions of the invention are the polyoxyalkylene fluids in which the alkylene radical is an ethylene or propylene radical.
In the polyoxyalkylene chain -(R O) there may be present alkylene radicals with ditferent numbers of carbon atoms. They may for instance consist of both oxyethylene and oxypropylene radicals. In case the polyoxyalkylene chain contains different alkylene radicals,
these may be randomly distributed throughout the molecule or may be arranged in regularly recurring units or blocks, each consisting of one or a plurality of similar oxyalkylene radicals. For the compositions of the invention preference is given to polyoxyalkylene liquids in which the polyoxyalkylene chain consists of blocks of (for instance 1 to 8) oxyethylen'e radicals alternating with blocks of (for instance 1 to 8) oxypropylene radicals.
In those cases where the radicals represented in the above general formula by R and/ or R are hydrocarbon radicals, the radicals may be saturated or unsaturated, straight chained or branched, or similar or dissimilar, nonaromatic hydrocarbon radicals. For the compositions of the invention preference is given to the polyoxyalkylene liquids in which the radical R is a hydrogen atom and the radical R is an alkyl group such as a propyl, butyl, pentyl or decyl group.
In those cases Where the radicals R and/ or R are acyl radicals, the radicals may be derived from any carboxylic acid. Preference is given to the alkane or alkene monocarboxylic acids such as acetic acid, propionic acid, buty'ric acid, lauric acid, stearic acid and oleic acid.
The molecular weight of the compounds which may be employed in the invention may vary over a wide range. Compounds of the type falling within the scope of this invention generally have molecular weights from 350 up to 10,000 the polyoxyalkylene liquids possessing a molecular weight between 800 and 6,000 being perferred.
The physical properties of the polyoxyalkylene liquids such as their viscosity and their visocity index depend upon the length of the polyoxyalkylene chain, the nature of the oxyalkylene chain and the nature of the terminal groups. It will be clear that apart from the obvious requirement of compatability with the ester oils, the
polyoxyalkylene liquids should have a viscosity which is higher than the viscosity of the ester oils in order to act as a thickener for these oils. Moreover, they should have a high viscosity index so as to ensure that the viscosity index of the finished composition is not lower or not appreciably lower than the viscosity index of the ester oils.
Suitable heterocyclic polyalkylene fluids are heterocyclic copolymers of ethylene oxide and propylene oxide in the viscosity range of 380700 at 100 F. SUS and prepared by the methods described in US. Patents 2,425,755 and 2,425,845. Specific examples of such copolymers are: (A) copolymer of ethylene oxide and 1,2-propylene oxide having a viscosity at 100 F. SUS of 385, VI of 144 and PP, F., of 40; (B) copolymer of ethylene oxide and 1,2-propylene oxide having a viscosity at 100 F. SUS of 525 and (C) copolymer of ethylene oxide and 1,2- propylene oxide having a viscosity at 100 F. SUS of 625. By block copolymers of ethylene oxide and propylene is meant that first one of the oxides, e.g. propylene oxide is polymerized and thereafter this polymer is treated With a dissimilar alkylene oxide compound as described in US. Patent 2,677,700.
The ether and ester derivatives of these polymers are preferably alcohols and fatty acids of from 1 to about carbon atoms. Still more preferably are the esters and ethers of aliphatic monohydric alcohols and saturated aliphatic monocar-boxylic acids having from 1 to 4 carbon atoms.
The thickener of class (3) can be exemplified by neopentyl glycol, 2-methyl 2-n-propyl propan-1,3 diol. Suitaible monocanboxylic acids are those containing from 4 to 9 carbon atoms.
The novel load and extreme pressure agent of the present invention is a halogen-containing polymeric oxetane having at least 2 and not more than repeating units, each of said units having at least one halogen atom (X=Cl or Br) which is not on the carbons adjacent to the oxygen atom of the oxetane units and which halogen is preferably attached to the number 3 position of the oxetane units through a radical OH X, OHX and CX and the carbons adjacent to the oxygen can have attached substituent groups such as alkyl radicals, e.g. C C alkyl radicals.
A preferred class of oxetanes is that represented by the formula:
X 0 CH x o ofiz wherein one X is C1 or Br and the others are chosen from H, C1 or Br. The preferred compound of this class is 3,3-bis(chloromethyl)oxetane. Polymers of the re- 4 chosen so as to yield a polymer which is not appreciably volatile at 200 C.
The preparation of substituted oxetane polymers suitable for the purpose of the present invention is illustrated by the following examples.
Example 1 245 g. of 3,34bis(chloromethyl)oxetane were placed in a flask fitted with a double surface air condenser. The system was sealed from the atmosphere by leading a tube from the top of the condenser so that it dipped beneath the surface of a mercury reservoir. Nitrogen was blown through the system before heat was applied. The monomer was refluxed at 210 C. for 11 days. During this period the color of the reaction mixture changed to amber. At no time was air allowed to get into the system. Unreacted monomer (83 g.) was distilled from the reaction mixture. The polymer residue (162 g., i.e. 66% w. yield), was an amber, viscous liquid and was poured into aq. industrial methylated spirits (I.M.S.); the two liquids were immiscible. The mixture was stirred and when the layers had completely separated the I.M.S. was decanted from the polymer. The final traces of water and alcohol were removed from the polymer by distillation at 10 15 mm. Hg. The polymer so prepared had an average molecular weight of 450 and a chlorine content of 44.9% W.
Example 2 g. of 3,3-bis(chloromethyl) oxetane were refluxed in a nitrogen atmosphere as in Example 1 for 10 days. The product Was then fractionally distilled as follows:
Fraction Boiling range, 0. Weight, 01 content,
g. percent w.
84/15 mm. Hg 67 memo/0.1 mm. Hg 41 45.4 /01 mm. l-Ig270/5 31 .5.4 270/5 Hg 36 45. 3
Fraction A consisted of unreacted monomer. Fractions B, C and D were predominantly the dimer, trimer and tetramer respectively.
Example 3 TABLE I Examples Composition Di (2-ethyl hexyl) sebacate, percent w 97 97 97 97 D nsooctyl azelate, percent w 94 94 94 94 94 94 Azclaic acld, percent w 0.02 0. 02 0.02 0.02 0. 02 0.02 0.02 0. 02 Adlpic acid, percent w 0.02 0.02 3,7 dioctyl phenothiazine, percent w 1. 5 1. 5 1. 5 1. 5 1. 5 1 henyl a-naphthyleminc, percent w 1. 5 1. 5 1. 5 1. 5 1. 5 5 Methyl benzotriazole, p.p.m 25 25 25 25 25 Silicone MS 200/12, 500, p.p.m 5 5 5 5 5 3% of the Polymer of Example 1 1 2B 2C 2D 3 1 quired degree of polymerization can readily be obtained by heating the monomer (preferably in the absence of air) at a temperature sufiicient to induce polymerization. An acceptable rate of polymerization is obtained at temperatures of about 200 C. The configuration of the polymer is not known with certainty but it is though that cyclization occurs with the formation of large rings con- In addition to the halogen containing oxetane polymer other additives may be incorporated into the lubricant of the present invention if desired. Thus, antioxidants such as phenothiazine or its derivatives or naphthylamines may be used. Rust inhibitors may be incorporated, for example, the metal salts of petroleum sulfonates and in particular lead corrosion can be inhibited by the use of taining ether linkages. The degree of polymerization is 75 certain dibasic carboxylic acids, for exampl al l acid- Small amounts of antifoaming agents may be incorporated. It further load carrying capacity is required organic phosphate or phosphite esters, for example, tricresyl phosphate, may be added. Other suitable extreme pressure additives are the chlorinated di and polyphenyls.
The compositions of Examples 413 were tested on an I.A.E. 3 /4 inch gear lubricant testing machine as described by Mansion in the Journal of the Institute of Petroleum, 1952, 38, 633, using B.S.S. EN34 steel gears. Results, expressed in 1b., are given in Table 11.
Table II shows that the lubricant compositions of the present invention gave improved performance over compositions which did not contain the polymer of the present invention.
The compositions of Examples 6-10 also comply with the United States Military Specification MIL-L-7808Du For example, in the MILL-7808 D Oxidation/Corrosion test at 175 C}, the following results were obtained with Example 9.
6. The composition of claim 2 containing a minor amount of a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
'7. The composition of claim 3 containing a minor amount of a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
0. The composition of claim 4 containing a minor amount of a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
9. A synthetic lubricating composition comprising a major amount of di(2'ethyl hexyl) sebacate, from about 0.5% to about 10% of a polymer of 3,3-bis(ch10romethyl)oxetane having .from 2 to 4 units and a minor amount of a polymer of lauryl methacrylate.
10. A synthetic lubricating composition comprising a major amount of diisooctyl azelate from about 0.5 to about 10% of a polymer of 3,3-bis(chloromethyl)oxetane having from 2 to 4 units and a minor amount of a polymer of lauryl methacrylate.
11. A synthetic lubricating composition comprising a major amount of di(2-et-hyl hexyl) sebacate, from about 0.5% to about 10% of a polymer of 3,3-bis(chloromethyl)oxetane having from 2 to 4 units and a minor amount of a polymer copolymer of ethylene oxide and 1,2-propylene oxide in the viscosity range at 100 F. SUS of 380 to 700.
Volatility Viscosity Metal wt. change, mgJcm.
Loss, Acidity Increase, Percent w. Increase Percent Cu Mg Ag Al Fe Example!) 0.6 1.5 12.2 -0.37 Nil +0.12 Nil 0.02 Specification limits 2.0 -5 to +15 0.4 $0.2 $0.2 $0.2 $0.2
In the MIlr-Ir7808D Oven Storage Lead Corrosion Test, Example 10 yielded a weight loss of 34 mg. Pb/in. after days at 85 C. The specification limit is 1501ng./in.
We claim as our invention:
1. A synthetic lubricating composition comprising a major amount of a dibasic ester of an aliphatic dica boxylic acid and a branched chain aliphatic alcohol and from 0.5 to 10% of a polymeric halogen-containing oxetane having from 2 to 20 oxetane units each of which contains at least one halogen which is on carbons other than the carbons adjacent to the oxygen atom of each unit.
2. A synthetic lubricating composition comprising a major amount of a dibasic ester of an aliphatic dicarboxylic acid and a branched chain aliphatic alcohol in the viscosity range of from about 2 to about 10 cs. at 210 F. and from about 0.5% to about 10% of a polymeric ch10- rine containing oxetane having from 2 to 20 oxetane units, the chlorine being present on carbons other than the carbons adjacent to the oxygen atom in the oxetane units.
3. A synthetic lubricating composition comprising a major amount of di-2-ethylhexyl sebacate and from 0.5% to 10% of a polymer of chlorinated oxetane having from 2 to 20 of such units in the polymer, the chlorine being present on carbons other than the carbons adjacent to the oxygen atom in the oxetane units.
4. A synthetic lubricating composition comprising a major amount of di-Z-ethylhexyl sebaca-te and from 0.5% to 10% of a polymer of 3,3-bis(chloromethyl) oxetane having from 2 to 20 of such units in the polymer.
5. The composition of claim 1 containing a minor amount of a polymeric thickener selected from the class consisting of polymeric C alkyl acrylate, polyoxyalkylene fluid and an ester of a polyol and a monocarboxylic acid.
12. A synthetic lubricating composition comprising a major amount of diisooctyl azelate from about 0.5% to about 10% of a polymer of 3,3-bis(chloromethyl)oxetane having from 2 to 4 units and a minor amount of a polymer of copolymer of ethylene oxide and 1,2-propylene oxide in the viscosity range at F. SUS of 380 to 700.
1.3. The composition of claim 9 containing a small amount of an organic amine antioxidant.
14. The composition of claim 10 containing a small amount of an organic amine antioxidant.
The composition of claim 11 containing a small amount of an organic amine antioxidant.
16. The composition of claim 12 containing a small amount of an organic amine antioxidant.
References Cited by the Examiner UNITED STATES PATENTS 2,137,782 11/1938 Prutton 252--5 r 2,722,340 11/1955 Feild 260-333 X 2,914,540 11/1959 Goddu 260- 333 2,958,706 11/1960 Hurwitz.
3,112,280 11/1963 Farthing 260333 X 3,190,926 6/1965 Edwards 252-54 OTHER REFERENCES Cohen, Aliphatic Esters, Industrial. and Engineering Chemistry, pp. 17661774, vol. 45, No. 8, August 1953.
Kalichevsky, Petroleum Refining With Chemicals, Elsevier Publishing Company, 1956, New York, New York, pp. 549, 550 relied upon.
DANIEL E. WYMAN, Primary Examiner.
C. O. THOMAS, W. H. CANNON, Assistant Examiners.
Claims (1)
1. A SYNTHETIC LUBRICATING COMPOSITION COMPRISING A MAJOR AMOUNT OF A DIBASIC ESTER OF AN ALIPHATIC DICARBOXYLIC ACID AND AND A BRANCHED CHAIN ALIPHATIC ALCOHOL AND FROM 0.5 TO 10% OF A POLYMERIC HALOGEN-CONTAINING OXETANE HAVING FROM 2 TO 20 OXTANE UNITS EACH OF WHICH CONTAINS AT LEAST ONE HALOGEN WHICH IS ON CARBONS OTHER THAN THE CARBONS ADJACENT TO THE OXYGEN ATOM OF EACH UNIT.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB18206/62A GB964672A (en) | 1962-05-11 | 1962-05-11 | Improvements in or relating to lubricants |
Publications (1)
Publication Number | Publication Date |
---|---|
US3275555A true US3275555A (en) | 1966-09-27 |
Family
ID=10108477
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US277733A Expired - Lifetime US3275555A (en) | 1962-05-11 | 1963-05-03 | Synthetic lubricant containing oxetane polymers |
Country Status (5)
Country | Link |
---|---|
US (1) | US3275555A (en) |
BE (1) | BE632079A (en) |
DE (1) | DE1263212B (en) |
GB (1) | GB964672A (en) |
NL (1) | NL292528A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3546118A (en) * | 1968-11-25 | 1970-12-08 | Phillips Petroleum Co | Metal working operations and lubricants |
EP0190869A2 (en) * | 1985-01-31 | 1986-08-13 | Exxon Chemical Patents Inc. | Lubricating oil composition |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2137782A (en) * | 1935-07-16 | 1938-11-22 | Lubri Zol Dev Corp | Lubricating composition |
US2722340A (en) * | 1954-09-02 | 1955-11-01 | Hercules Powder Co Ltd | 3,3-bis(chloromethyl)oxetane coated articles and method of coating |
US2914540A (en) * | 1957-07-05 | 1959-11-24 | Hercules Powder Co Ltd | Stabilization of monomeric 3, 3-bis(chloromethyl)-oxetane |
US2958706A (en) * | 1958-02-28 | 1960-11-01 | Rohm & Haas | Process for preparation of pentaerythritol and polypentaerythritol ester plasticizers |
US3112280A (en) * | 1951-08-22 | 1963-11-26 | Ici Ltd | New polymeric substances |
US3190926A (en) * | 1959-11-19 | 1965-06-22 | Castrol Ltd | Halogenated organic compounds |
-
0
- NL NL292528D patent/NL292528A/xx unknown
- BE BE632079D patent/BE632079A/xx unknown
-
1962
- 1962-05-11 GB GB18206/62A patent/GB964672A/en not_active Expired
-
1963
- 1963-05-03 US US277733A patent/US3275555A/en not_active Expired - Lifetime
- 1963-05-09 DE DES85111A patent/DE1263212B/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2137782A (en) * | 1935-07-16 | 1938-11-22 | Lubri Zol Dev Corp | Lubricating composition |
US3112280A (en) * | 1951-08-22 | 1963-11-26 | Ici Ltd | New polymeric substances |
US2722340A (en) * | 1954-09-02 | 1955-11-01 | Hercules Powder Co Ltd | 3,3-bis(chloromethyl)oxetane coated articles and method of coating |
US2914540A (en) * | 1957-07-05 | 1959-11-24 | Hercules Powder Co Ltd | Stabilization of monomeric 3, 3-bis(chloromethyl)-oxetane |
US2958706A (en) * | 1958-02-28 | 1960-11-01 | Rohm & Haas | Process for preparation of pentaerythritol and polypentaerythritol ester plasticizers |
US3190926A (en) * | 1959-11-19 | 1965-06-22 | Castrol Ltd | Halogenated organic compounds |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3546118A (en) * | 1968-11-25 | 1970-12-08 | Phillips Petroleum Co | Metal working operations and lubricants |
EP0190869A2 (en) * | 1985-01-31 | 1986-08-13 | Exxon Chemical Patents Inc. | Lubricating oil composition |
EP0190869A3 (en) * | 1985-01-31 | 1987-11-25 | Exxon Chemical Patents Inc. | Lubricating oil composition |
US4891145A (en) * | 1985-01-31 | 1990-01-02 | Exxon Chemical Patents Inc. | Lubricating oil composition |
Also Published As
Publication number | Publication date |
---|---|
NL292528A (en) | |
DE1263212B (en) | 1968-03-14 |
GB964672A (en) | 1964-07-22 |
BE632079A (en) |
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