US3232763A - Gelatin compositions containing a bisisomaleimide hardener - Google Patents

Gelatin compositions containing a bisisomaleimide hardener Download PDF

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Publication number
US3232763A
US3232763A US265043A US26504363A US3232763A US 3232763 A US3232763 A US 3232763A US 265043 A US265043 A US 265043A US 26504363 A US26504363 A US 26504363A US 3232763 A US3232763 A US 3232763A
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US
United States
Prior art keywords
gelatin
bisisomaleimide
hardener
compositions containing
gelatin compositions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US265043A
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English (en)
Inventor
Donald M Burness
Burton D Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to GB1054123D priority Critical patent/GB1054123A/en
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Priority to US265043A priority patent/US3232763A/en
Priority to FR966014A priority patent/FR1383643A/fr
Application granted granted Critical
Publication of US3232763A publication Critical patent/US3232763A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/30Hardeners

Definitions

  • hexamethylene bisisomaleimide were added to separate portions of a high speed gelatin-silver bromoiodide emul- Thls lnvemlon relates to gelatm coatmg compqsltlons 10 sion, which had been panchromatical-ly sensitized with a d layers prepared therefrom composed of ge af and cyanine dye, in the proportions indicated inthe table.
  • n is an integer of 4 to 10.
  • Example 2 A slurry of 51.2 grams of N,N-tetramethylene-bismaleamic acid in 500 ml. of dichloromethane was stirred vigorously while a solution of 82.5 grams of commercial dicyclohexylcarbodiimide in ml. of dichloromethane Was added dropwise over a period of 50 minutes. The mixture was stirred for 24 hours, then cooled and the solids were removed by filtration. The crude residue was extracted with hot benzene, filtered and evaporated to dryness. The residue was slurried with cold ether and filtered. The crude, colorless crystalline solid was recrystallized With benzene-ether to give N,N'-tetramethylenebisisomaleimide having a melting point of 146.5 to 148.5 C.
  • Example 2 The tetramethylene bisisomaleimide prepared in Example 2 was added to separate portions of high-speed silver bromoiodide emulsion which had been panchromatically sensitized with a cyanine dye, in the proportions indicated in the table. A sample of the emulsion without hardener was also taken. Each emulsion sample was coated onto a cellulose acetate film support at a coverage of 459 mg. of silver and 1040 mg. of gelatin per square foot. A sample of each film coating was exposed on an Eastman 1B sensitometer, processed for five mine; utes in Kodak DK-SO developer, fixed, Washed and dried with the following results:
  • composition comprising gelatin containing therein hexamethylene bisisomaleimide.
  • HC-O o n being an integer of 4 to 10.
  • composition comprising gelatin containing therein tetrarnethylene bisisomaleimide.

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US265043A 1963-03-14 1963-03-14 Gelatin compositions containing a bisisomaleimide hardener Expired - Lifetime US3232763A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB1054123D GB1054123A (cs) 1963-03-14
US265043A US3232763A (en) 1963-03-14 1963-03-14 Gelatin compositions containing a bisisomaleimide hardener
FR966014A FR1383643A (fr) 1963-03-14 1964-03-04 Nouvelle composition à base de gélatine utilisable en photographie

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US265043A US3232763A (en) 1963-03-14 1963-03-14 Gelatin compositions containing a bisisomaleimide hardener

Publications (1)

Publication Number Publication Date
US3232763A true US3232763A (en) 1966-02-01

Family

ID=23008712

Family Applications (1)

Application Number Title Priority Date Filing Date
US265043A Expired - Lifetime US3232763A (en) 1963-03-14 1963-03-14 Gelatin compositions containing a bisisomaleimide hardener

Country Status (3)

Country Link
US (1) US3232763A (cs)
FR (1) FR1383643A (cs)
GB (1) GB1054123A (cs)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3462273A (en) * 1965-10-08 1969-08-19 Agfa Gevaert Nv 2-dioxolanones (carboxylic acid esters) protein hardeners
EP0124795A2 (en) 1983-04-11 1984-11-14 Fuji Photo Film Co., Ltd. Silver halide photographic emulsion
US5744574A (en) * 1995-12-05 1998-04-28 Minnesota Mining And Manufacturing Company Isomaleimides and polymers derived therefrom
US6020398A (en) * 1998-05-22 2000-02-01 Eastman Kodak Company Pigmented ink jet inks for poly (vinylalcohol) receivers
US6045219A (en) * 1998-05-22 2000-04-04 Eastman Kodak Company Pigmented ink jet prints on gelatin overcoated with hardeners
US6074057A (en) * 1998-05-22 2000-06-13 Eastman Kodak Company Pigmented ink jet inks and recording elements containing hardening agents
US6082853A (en) * 1998-05-22 2000-07-04 Eastman Kodak Company Printing apparatus with processing tank
US6161929A (en) * 1998-05-22 2000-12-19 Eastman Kodak Company Inkjet images on PVA overcoated with hardener solution
US6176574B1 (en) 1998-05-22 2001-01-23 Eastman Kodak Company Printing apparatus with spray bar for improved durability
US6254230B1 (en) 1998-05-22 2001-07-03 Eastman Kodak Company Ink jet printing apparatus with print head for improved image durability
US6435678B1 (en) 1998-05-22 2002-08-20 Eastman Kodak Company Waterfast ink jet images treated with hardeners
US20060181658A1 (en) * 2005-02-16 2006-08-17 Eastman Kodak Company Conductive absorption layer for flexible displays
US20060215077A1 (en) * 2005-03-22 2006-09-28 Eastman Kodak Company High performance flexible display with improved mechanical properties
WO2008038764A1 (en) 2006-09-28 2008-04-03 Fujifilm Corporation Spontaneous emission display, spontaneous emission display manufacturing method, transparent conductive film, electroluminescence device, solar cell transparent electrode, and electronic paper transparent electrode
US7507449B2 (en) 2006-05-30 2009-03-24 Industrial Technology Research Institute Displays with low driving voltage and anisotropic particles
DE112007001129T5 (de) 2006-06-29 2009-07-09 Industrial Technology Research Institute Gast-Wirt-Polymer-Flüssigkristallanzeigen auf einem einzigen Substrat
EP2385425A1 (en) 2010-05-07 2011-11-09 Fujifilm Corporation Silver halide photographic light-sensitive material for movie
WO2012035314A1 (en) 2010-09-17 2012-03-22 Fujifilm Manufacturing Europe Bv Photographic paper
WO2021213762A1 (en) 2020-04-24 2021-10-28 Fujifilm Manufacturing Europe Bv Photographic paper

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2726162A (en) * 1951-12-01 1955-12-06 Eastman Kodak Co Hardening of gelatin
US2899327A (en) * 1959-08-11 Glue setting accelerators
US2992109A (en) * 1960-06-17 1961-07-11 Eastman Kodak Co Hardening of photographic emulsions
US2994611A (en) * 1958-03-19 1961-08-01 Hoechst Ag Hardening of protein

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2899327A (en) * 1959-08-11 Glue setting accelerators
US2726162A (en) * 1951-12-01 1955-12-06 Eastman Kodak Co Hardening of gelatin
US2994611A (en) * 1958-03-19 1961-08-01 Hoechst Ag Hardening of protein
US2992109A (en) * 1960-06-17 1961-07-11 Eastman Kodak Co Hardening of photographic emulsions

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3462273A (en) * 1965-10-08 1969-08-19 Agfa Gevaert Nv 2-dioxolanones (carboxylic acid esters) protein hardeners
EP0124795A2 (en) 1983-04-11 1984-11-14 Fuji Photo Film Co., Ltd. Silver halide photographic emulsion
US5744574A (en) * 1995-12-05 1998-04-28 Minnesota Mining And Manufacturing Company Isomaleimides and polymers derived therefrom
US6435678B1 (en) 1998-05-22 2002-08-20 Eastman Kodak Company Waterfast ink jet images treated with hardeners
US6074057A (en) * 1998-05-22 2000-06-13 Eastman Kodak Company Pigmented ink jet inks and recording elements containing hardening agents
US6082853A (en) * 1998-05-22 2000-07-04 Eastman Kodak Company Printing apparatus with processing tank
US6161929A (en) * 1998-05-22 2000-12-19 Eastman Kodak Company Inkjet images on PVA overcoated with hardener solution
US6176574B1 (en) 1998-05-22 2001-01-23 Eastman Kodak Company Printing apparatus with spray bar for improved durability
US6254230B1 (en) 1998-05-22 2001-07-03 Eastman Kodak Company Ink jet printing apparatus with print head for improved image durability
US6020398A (en) * 1998-05-22 2000-02-01 Eastman Kodak Company Pigmented ink jet inks for poly (vinylalcohol) receivers
US6045219A (en) * 1998-05-22 2000-04-04 Eastman Kodak Company Pigmented ink jet prints on gelatin overcoated with hardeners
US7630029B2 (en) 2005-02-16 2009-12-08 Industrial Technology Research Institute Conductive absorption layer for flexible displays
US20060181658A1 (en) * 2005-02-16 2006-08-17 Eastman Kodak Company Conductive absorption layer for flexible displays
US20060215077A1 (en) * 2005-03-22 2006-09-28 Eastman Kodak Company High performance flexible display with improved mechanical properties
US7557875B2 (en) 2005-03-22 2009-07-07 Industrial Technology Research Institute High performance flexible display with improved mechanical properties having electrically modulated material mixed with binder material in a ratio between 6:1 and 0.5:1
US7507449B2 (en) 2006-05-30 2009-03-24 Industrial Technology Research Institute Displays with low driving voltage and anisotropic particles
DE112007001129T5 (de) 2006-06-29 2009-07-09 Industrial Technology Research Institute Gast-Wirt-Polymer-Flüssigkristallanzeigen auf einem einzigen Substrat
WO2008038764A1 (en) 2006-09-28 2008-04-03 Fujifilm Corporation Spontaneous emission display, spontaneous emission display manufacturing method, transparent conductive film, electroluminescence device, solar cell transparent electrode, and electronic paper transparent electrode
EP2385425A1 (en) 2010-05-07 2011-11-09 Fujifilm Corporation Silver halide photographic light-sensitive material for movie
WO2012035314A1 (en) 2010-09-17 2012-03-22 Fujifilm Manufacturing Europe Bv Photographic paper
WO2021213762A1 (en) 2020-04-24 2021-10-28 Fujifilm Manufacturing Europe Bv Photographic paper

Also Published As

Publication number Publication date
FR1383643A (fr) 1964-12-24
GB1054123A (cs)

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