US3181961A - Self-propelling liquid textile sizing composition - Google Patents
Self-propelling liquid textile sizing composition Download PDFInfo
- Publication number
- US3181961A US3181961A US184553A US18455362A US3181961A US 3181961 A US3181961 A US 3181961A US 184553 A US184553 A US 184553A US 18455362 A US18455362 A US 18455362A US 3181961 A US3181961 A US 3181961A
- Authority
- US
- United States
- Prior art keywords
- percent
- starch
- self
- spray
- sizing composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
- D06M13/453—Phosphates or phosphites containing nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Definitions
- Suitable water dispersible sizing agents include starch selected from the group consisting of oxidized starch, acid-modified starch, enzymemodified starch, chemically derivatized starch, and gelatinized starch, water-soluble cellulosic materials such as carboxymethyl cellulose, and synthetic sizes such as acrylates and other synthetic resins.
- spray starches for convenience, were comprised of a very dilute starch solution packaged in an aerosol-dispensing container with a propellant.
- a dilute solution packaged in an aerosol-dispensing container with a propellant.
- the starch solution was increased to meet the demand of the consumer, other problem arose.
- These problems included clogging of the nozzle, corrosion of the interior of the dispenser, spoilage of the starch solution, foaming, and undesirable odors.
- Another object is to provide a spray starch product, which when applied to textiles, aids the ease with which the textile is ironed.
- pregelatinzed starch is dispersed in water in the amount of between about 1 and about 10 percent by weight.
- variou components such as a preservative, an antifoaming agent, a corrosion inhibitor, a perfume, and an ironing aid comprising one or more phosphatides.
- gelatinized starch e.g., corn, wheat, rice, grain sorghum, waxy grain sorghum, waxy maize, or tapioca, or mixtures thereof, or water-dispersible modifications or derivatives thereof, or water-soluble cellulosic materials such as carboxymethyl cellulose or water-soluble synthetic resins may be employed in the process of the present invention.
- Example 4 The process of Example 1 is followed except that carboxymethyl cellulose is substituted in the amount of 1 percent by weight of the total mixture for the enzyme-modified water dispersible starch of Example 1.
- An ironing aid for a self-propelling liquid textile sizing composition consisting essentially of 200 parts of a 3.3% lecithin in water emulsion and 823 parts of dimethyl silicone emulsion having 35% solids.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
3,1til,961 SELF-PRUPELLING LIQUKD TEXTELE diZlWG C(HVKOSHTEGN Walter J. Katzheclr, Gal: Park, and Ronald R. Gabei,
Western Springs, ill, assignors to Corn Products Company, New York, N.Y., a corporation of Delaware No Drawing. Filed Apr. 2, 1962, Ser. No. 184,553 2 Claims. (Cl. 196-213) The present invention relates to an improved self-propelling liquid textile sizing composition. More particularly, it relates to a self-propelling liquid textile sizing product having non-sticking properties.
Liquid textile sizes have become increasingly popular, and more recently it has been recognized that it is desirable to package a liquid textile size or liquid laundry starch together with a propellant gas in aerosol-dispensing containers so that the size can be readily expelled in spray form onto a fabric which has already been washed and dried and is ready for ironing.
Any water dispersible sizing agent is suitable for application in the present invention. Suitable water dispersible sizing agents include starch selected from the group consisting of oxidized starch, acid-modified starch, enzymemodified starch, chemically derivatized starch, and gelatinized starch, water-soluble cellulosic materials such as carboxymethyl cellulose, and synthetic sizes such as acrylates and other synthetic resins.
initially, self-propelling liquid textile sizes, hereinafter referred to as spray starches for convenience, were comprised of a very dilute starch solution packaged in an aerosol-dispensing container with a propellant. In order to satisfactorily expel the starch solution, it was necessary to use such a dilute solution that the consumer had to make several applications of the spray to the fabric, each followed by ironing, in order to obtain the desired stiffness. As the starch content was increased to meet the demand of the consumer, other problem arose. These problems included clogging of the nozzle, corrosion of the interior of the dispenser, spoilage of the starch solution, foaming, and undesirable odors. These problems have been minimized by the incorporation of various additives and changes in the construction of the dispenser. Various type nozzles have been developed which minimize clogging and provide a relatively even spray. Corrosion inhibitors such as polyphosphate have almost eliminated the corrosion of the interior of the dispenser. Spoilage of the starch solution has been greatly reduced by the addition of a preservative such as sodium-orthophenyl phenate. Foaming has been essentially eliminated by the addition of a silicone-containing anti-foam agent and to counteract any undesirable odors imparted to the fabric,,a small amount of perfume is added.
However, with an increase in the amount of starch present in the solution, as per the desire of the consumer, there is an increase in the tendency of the sizing agent to deposit on the iron. All of the presently available spray starches possess this one objectionable characteristic.
It is an object of the present invention to substantially completely eliminate the sticking tendencies of a selfpropelling liquid textile sizing composition.
Another object is to provide a spray starch product, which when applied to textiles, aids the ease with which the textile is ironed.
Other objects of the invention will be apparent from the following description and claims.
According to the present invention, a substantial improvement in the ironing properties of a spray starch is obtained by incorporating a naturally occurring phosphatide into the spray starch formulation. The presence of one or more phosphatides, such as lecithin, cephalin, or the like, in spray starch increases the ease with which ited States Patent 0 Bddlfiiil Fatenterl ll/ ey 4, 1965 the iron slides over the textile being ironed, thereby preventing the sticking of the sizing material to the iron, and substantially eliminating objectionable scorching and spotting resulting from a sticking iron.
Many additives have been tried heretofore, but until the discovery of the present invention, no satisfactory agent or combination of agents was found. For example, the use of silicones had been practiced, but though sticking was reduced, undesirable spots, having the appearance of grease spots, remained on the fabric. Although moderate amounts of silicone may be incorporated in spray starches without adverse effects, amounts suflicient to reduce sticking to any degree, result in undesirable spotting of the fabric.
In accordance with one embodiment of the present invention, pregelatinzed starch is dispersed in water in the amount of between about 1 and about 10 percent by weight. To this aqueous starch dispersion are added variou components, such as a preservative, an antifoaming agent, a corrosion inhibitor, a perfume, and an ironing aid comprising one or more phosphatides. These additives may be incorporated by simply admixing them in any desirable order with the starch dispersion after which the resulting aqueous dispersion is packaged in an aerosol dispensing container with a propellant.
Any type of gelatinized starch, e.g., corn, wheat, rice, grain sorghum, waxy grain sorghum, waxy maize, or tapioca, or mixtures thereof, or water-dispersible modifications or derivatives thereof, or water-soluble cellulosic materials such as carboxymethyl cellulose or water-soluble synthetic resins may be employed in the process of the present invention.
As heretofore mentioned, precooked and gelatinized starch may be slurried in water to form the base for the spray starch formulation of the present invention. However, in another embodiment of this invention, untreated, ungelatinized starch is slurried in an aqueous medium containing the other additives, including lecithin, of the spray starch formulation except the propellant, and the resulting mixture is then heated or cooked in order to efiect gelatinization of the starch. After cooling, the mixture is packaged with a propellant in an aerosol-dispensing container.
In still another embodiment of the present invention, carboxymethyl cellulose is simultaneously admixed with cephalin and the other components comprising a spray starch. The mixture is then packaged With a propellant in an aerosol-dispensing container.
The sizing agent may be present in the final formulation in an amount between about 1 and about 10 percent by weight, preferably between about 2 and about 6 percent by Weight. The phosphatide is either premixed with other components, such as borax, polyethylene glycol and silicone, and then added to the formulation, or it may be added separately at any point in the mixing process. The desired phosphatide or mixture of phosphatides is present in the final formulation in an amount between about 0.001 percent and about 1.0 percent by weight. For a spray starch formulation containing between about 2 and about 6 percent by weight of starch it is preferable to include between about 0.005 and about 0.3 percent phosphatide by weight of the final formulation.
The following operating examples will more clearly illustrate the invention:
Example 1 Two hundred parts of a 3.3 percent lecithin-in-water emulsion were blended with 823 parts of a dimethyl silicone emulsion having 35 percent solids. In a separate container an aqueous solution was prepared containing borax, polyethylene glycol, sodium hydroxide, a preservative, and a mixture of sodium tripolyphosphate and sili' cate in amounts corresponding to those set forth in the formulation chart below. An enzyme-modified water dispersible starch was dispersed in an aqueous solution in an amount so that the final formulation contained 4.1 percent by weight of starch. The starch-containing dispersion was then admixed with the lecithin-silicone emulsion, and the perfume and antifoam were added. This mixture was packaged in an aerosol-dispensing container with a propellant. The over-all formulation for Example 1 is as follows:
Example 2 The process of Example 1 is repeated except that a 2 percent hypochlorite-oxidized White milo starch is substituted for the enzyme-modified water dispersible starch of Example 1.
Example 3 The process of Example 1 is duplicated except that a 80-fluidity thin boiling acid-modified corn starch is substituted for the enzyme-modified water dispersible starch of Example 1.
Example 4 The process of Example 1 is followed except that carboxymethyl cellulose is substituted in the amount of 1 percent by weight of the total mixture for the enzyme-modified water dispersible starch of Example 1.
Example 5 The process of Example 1 is repeated except that cephalin is substituted for lecithin.
The process of Example 1 i repeated except that thin boiling hydroxyethyl starch is substituted for the enzymemodified Water dispersible starch of Example 1.
Although the invention has been described by reference to certain specific embodiments thereof, it is to be understood that such matters are purely illustrative for the purpose of clarifying the invention, and the invention is in no sense to be considered limited thereto. Numerous modifications and equivalents of the present invention will be apparent from the foregoing description to those skilled in the art.
In accordance with the foregoing description, the following claims distinctly claim the subject matter of the invention.
We claim:
1. A self-propelling liquid laundry starch consisting essentially of 4.1 percent starch, 0.8 percent dimethyl silicone emulsion, 0.4 percent borax, 0.1 percent polyethylene glycol, 0.01 percent lecithin, 0.01 percent silicone antifoam agent, 0.002 percent mixture of sodium tripolyphosphate and sodium silicate, 0.015 percent sodiumortho-phenyl phenate, 6.3 percent dichlor-odifluoromethane, 0.032 percent perfume, 0.08 percent sodium hydroxide, and 88.151 percent water.
2. An ironing aid for a self-propelling liquid textile sizing composition consisting essentially of 200 parts of a 3.3% lecithin in water emulsion and 823 parts of dimethyl silicone emulsion having 35% solids.
References Cited by the Examiner UNITED STATES PATENTS 2,701,238 2/55 Renold 106213 2,796,354 6/57 Fuller 106-213 2,883,300 4/59 Rickert 106-213 2,938,809 5/60 Katzbeck 106-213 2,999,761 9/61 Miller et al. 106-213 3,066,037 11/62 Curtin et al. 106213 3,068,111 12/62 Seymour l06213 3,085,100 4/63 Chang 106-213 ALEXANDER H. BRODMERKEL, Primary Examiner.
JOHN R. SPECK, Examiner.
Claims (1)
1. A SELF-PROPELLING LIQUID LAUNDRY STARCH CONSISTING ESSENTIALLY OF 4.1 PERCENT STARCH, 0.8 PERCENT DIMETHYL SILICONE EMULSION, 0.4 PERCENT BORAX, 0.1 PERCENT POLYETHYLENE GYCOL, 0.01 PERCENT LECITHIN, 0.01 PERCENT SILICONE ANTIFOAM AGENT, 0.002 PERCENT MIXTURE OF SODIUM TRIPOLYPHOSPHATE AND SODIUM SILICATE, 0.015 PERCENT SODIUMORTHO-PHENYL PHENATE, 6.3 PERCENT DICHLORODIFULOROMETHANE, 0.032 PERCENT PERFUME, 0.08 PERCENT SODIUM HYDROXIDE, AND 88.151 PERCENT WATER.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE621772D BE621772A (en) | 1962-04-02 | ||
| NL280642D NL280642A (en) | 1962-04-02 | ||
| US184553A US3181961A (en) | 1962-04-02 | 1962-04-02 | Self-propelling liquid textile sizing composition |
| GB26841/62A GB963382A (en) | 1962-04-02 | 1962-07-12 | Improvements in and relating to self-propelling liquid textile sizing compositions |
| DEC27617A DE1153713B (en) | 1962-04-02 | 1962-08-02 | Self-propelling liquid laundry stiffener |
| CH946862A CH423702A (en) | 1962-04-02 | 1962-08-08 | Sizing agents for textiles |
| FR906855A FR1336408A (en) | 1962-04-02 | 1962-08-13 | Self-propelling liquid compositions, for finishing textiles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US184553A US3181961A (en) | 1962-04-02 | 1962-04-02 | Self-propelling liquid textile sizing composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3181961A true US3181961A (en) | 1965-05-04 |
Family
ID=22677380
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US184553A Expired - Lifetime US3181961A (en) | 1962-04-02 | 1962-04-02 | Self-propelling liquid textile sizing composition |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3181961A (en) |
| BE (1) | BE621772A (en) |
| CH (1) | CH423702A (en) |
| DE (1) | DE1153713B (en) |
| GB (1) | GB963382A (en) |
| NL (1) | NL280642A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3462384A (en) * | 1967-04-11 | 1969-08-19 | Dow Corning | Aerosol starch |
| US3833393A (en) * | 1968-04-15 | 1974-09-03 | Johnson & Son Inc S C | Fabric-stiffening composition and process |
| US4023978A (en) * | 1973-10-29 | 1977-05-17 | Colgate-Palmolive Company | Aerosol spray starch formulation |
| US4643919A (en) * | 1986-02-06 | 1987-02-17 | The Procter & Gamble Company | Textile treating compositions and methods |
| US5726567A (en) * | 1991-12-20 | 1998-03-10 | Solartron Group Limited | Network-connectable displacement sensor with stored ID |
| EP2047869A1 (en) * | 2007-10-11 | 2009-04-15 | Reckitt Benckiser (UK) LIMITED | Aerosol compositions |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2596078A1 (en) * | 1986-03-19 | 1987-09-25 | Langlais Christian | Antistain treatment process for textiles |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2701238A (en) * | 1952-03-11 | 1955-02-01 | Bates Mfg Co | Silver protecting cloth and process of making the same |
| US2796354A (en) * | 1954-03-23 | 1957-06-18 | Staley Mfg Co A E | Liquid laundry starch |
| US2883300A (en) * | 1957-04-12 | 1959-04-21 | Dow Chemical Co | Aqueous coating composition of coal acids, starch and a plasticizer and a base coated therewith |
| US2938809A (en) * | 1957-06-10 | 1960-05-31 | Corn Products Co | Cold water dispersible laundry starch |
| US2999761A (en) * | 1959-02-20 | 1961-09-12 | Staley Mfg Co A E | Liquid laundry starch |
| US3066037A (en) * | 1962-07-02 | 1962-11-27 | Anheuser Busch | Starch product and method of making same |
| US3068111A (en) * | 1959-12-17 | 1962-12-11 | Nat Gypsum Co | Paint colorant |
| US3085100A (en) * | 1960-12-05 | 1963-04-09 | Staley Mfg Co A E | Oxyalkylated lecithin |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2745761A (en) * | 1956-05-15 | Cooked laundry starch | ||
| US2745760A (en) * | 1956-05-15 | Foreign | ||
| DE649483C (en) * | 1930-11-04 | 1937-08-25 | I G Farbenindustrie Akt Ges | Process for treating cellulosic fibers |
| GB450159A (en) * | 1934-01-26 | 1936-07-10 | British Celanese | Improvements in the production of lubricated artificial filaments, yarns and the like |
-
0
- NL NL280642D patent/NL280642A/xx unknown
- BE BE621772D patent/BE621772A/xx unknown
-
1962
- 1962-04-02 US US184553A patent/US3181961A/en not_active Expired - Lifetime
- 1962-07-12 GB GB26841/62A patent/GB963382A/en not_active Expired
- 1962-08-02 DE DEC27617A patent/DE1153713B/en active Pending
- 1962-08-08 CH CH946862A patent/CH423702A/en unknown
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2701238A (en) * | 1952-03-11 | 1955-02-01 | Bates Mfg Co | Silver protecting cloth and process of making the same |
| US2796354A (en) * | 1954-03-23 | 1957-06-18 | Staley Mfg Co A E | Liquid laundry starch |
| US2883300A (en) * | 1957-04-12 | 1959-04-21 | Dow Chemical Co | Aqueous coating composition of coal acids, starch and a plasticizer and a base coated therewith |
| US2938809A (en) * | 1957-06-10 | 1960-05-31 | Corn Products Co | Cold water dispersible laundry starch |
| US2999761A (en) * | 1959-02-20 | 1961-09-12 | Staley Mfg Co A E | Liquid laundry starch |
| US3068111A (en) * | 1959-12-17 | 1962-12-11 | Nat Gypsum Co | Paint colorant |
| US3085100A (en) * | 1960-12-05 | 1963-04-09 | Staley Mfg Co A E | Oxyalkylated lecithin |
| US3066037A (en) * | 1962-07-02 | 1962-11-27 | Anheuser Busch | Starch product and method of making same |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3462384A (en) * | 1967-04-11 | 1969-08-19 | Dow Corning | Aerosol starch |
| US3833393A (en) * | 1968-04-15 | 1974-09-03 | Johnson & Son Inc S C | Fabric-stiffening composition and process |
| US4023978A (en) * | 1973-10-29 | 1977-05-17 | Colgate-Palmolive Company | Aerosol spray starch formulation |
| US4643919A (en) * | 1986-02-06 | 1987-02-17 | The Procter & Gamble Company | Textile treating compositions and methods |
| US5726567A (en) * | 1991-12-20 | 1998-03-10 | Solartron Group Limited | Network-connectable displacement sensor with stored ID |
| EP2047869A1 (en) * | 2007-10-11 | 2009-04-15 | Reckitt Benckiser (UK) LIMITED | Aerosol compositions |
| WO2009047479A1 (en) * | 2007-10-11 | 2009-04-16 | Reckitt-Benckiser (Uk) Limited | Aerosol compositions |
| AU2008229700B2 (en) * | 2007-10-11 | 2010-09-09 | Reckitt Benckiser (Uk) Limited | Aerosol compositions |
| AU2008229700C1 (en) * | 2007-10-11 | 2011-02-24 | Reckitt Benckiser (Uk) Limited | Aerosol compositions |
| KR101464242B1 (en) | 2007-10-11 | 2014-11-21 | 레킷트 앤드 콜만 (오버시스) 리미티드 | Aerosol Compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| CH423702A (en) | 1967-05-13 |
| NL280642A (en) | |
| GB963382A (en) | 1964-07-08 |
| DE1153713B (en) | 1963-09-05 |
| BE621772A (en) | |
| CH946862A4 (en) | 1967-05-13 |
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