US3181946A - Columbium base alloys - Google Patents
Columbium base alloys Download PDFInfo
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- US3181946A US3181946A US151200A US15120061A US3181946A US 3181946 A US3181946 A US 3181946A US 151200 A US151200 A US 151200A US 15120061 A US15120061 A US 15120061A US 3181946 A US3181946 A US 3181946A
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- Prior art keywords
- oxygen
- columbium
- titanium
- zirconium
- alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
- C22C27/02—Alloys based on vanadium, niobium, or tantalum
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/001—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
- C22C32/0015—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides with only single oxides as main non-metallic constituents
Definitions
- the present invention relates to improved colum'biumbase alloys, and more particularly relates to such alloys consisting essentially of relatively large amounts of oxygen, relatively small quantities of either titanium or zirconium, balance colu-mbium.
- Our invention is based upon our surprising discovery that the addition of substantial amounts of oxygen as an intentional alloying element greatly improves the mechanical and physical properties of columbium when such colurnbium also contains small amounts of either titanium or zirconium.
- the metal columbium (which at times is also referred to as niobium) is characterized by a number of mechanical and physical properties which make it particularly suitable for use as a structural material at temperatures above 2000 F. Principal among such properties are its low density (8.57 g./cm. at 20 C.), a high melting point (2468:10" C.) and good fabricability. In addition it is further characterized by a low neutron capture cross section, a feature which is important in nuclear reactor construction. Furthermore, the metal likewise is found in sufhciently good supply to be used where needed.
- a primary object of our invention is to provide a group of novel columbium alloys which are characterized by the strengthening of the base columbium metal by the dispersion strengthening effect of oxide phases therein.
- Another more specific object of our invent-ion is to provide a novel group of columbium-titanium-oxygen and columbium-zirconium-oxygen alloys.
- the alloys of the present invention have a relatively insignificant quantity of substitutional solute contained therein.
- strengthening of the base metal is obtained with elements that enter the columbiu-m lattice structure as substitutional solutes; in the present alloys, on the other hand, there are only the small quantities of substiutional solute and strengthening is obtained by the interstitial solute oxygen and by the dispersion strengthening effect of oxide phases.
- small amounts of interstitially soluble elements are normal impurities in colunibium and we recognize further that in the presence of elements more reactive than columbium such interstitially soluble elements form precipitate phases which contribute a strengthening effect.
- our invention entails the addition of considerably larger quantities of oxygen than that which is found in the normal impurity. Sush large quantities of oxygen greatly enhance the strength of the columbium alloy and thus by the teachings of our invention the large addition of substitutional solutes can readily be avoided.
- Test temperature Nominal alloy composition UTS -YS Percent Percent (wt. percent) (p.s.i.) (p.s.i.) E1 RA Cbl.5Ti0.50O 2, 200 1, 204 26, 900 24, 000 20 Cb1.5Ti-0.500... 2, 000 1, 093 34, 400 32, 000 23 Cb1.5Ti-0.500.
- An alloy consisting essentially of from 0.25 to 0.50% oxygen a metal. selected from the group 1;.5% titanium and from 1% to 3% zirconium, balance columbium, wherein the ratio by weight of oxygen to titanium or zirconium ranges from 3 to l to 12 to 1 and wherein alloy strengthening is obtained by interstitial solute oxygen and by the dispersion strengthening eifect of oxide phase.
- An alloy consisting essentially of from 0.25 to 0.50% oxygen, 1.5% titanium, balance columbium, wherein alloy strengthening is obtained by interstitial solute oxygen and by the dispersion strengthening effect of oxide phase.
- An alloy consisting essentially of from 0.25 to 0.50% oxygen, from 1 to 3% zirconium, balance columb-ium, wherein alloy strengthening is obtained by interstitial solute oxygen and by the dispersion strengthening efiect of oxide phase.
Description
United States Patent 3,181,946 CGLUMBIUM BASE ALLOYS Joseph B. McAndrew, Chicago, 111., Arthur G. Metcaife, San Diego, Calif., and Charles R. Simcoe, Evergreen Park, IlL, assignors to HT Research Institute, a corporation of Illinois No Drawing. Filed Nov. 9, 1961, Ser. No. 151,100 3 Claims. 7 (Cl. 75-474) The present invention relates to improved colum'biumbase alloys, and more particularly relates to such alloys consisting essentially of relatively large amounts of oxygen, relatively small quantities of either titanium or zirconium, balance colu-mbium.
Our invention is based upon our surprising discovery that the addition of substantial amounts of oxygen as an intentional alloying element greatly improves the mechanical and physical properties of columbium when such colurnbium also contains small amounts of either titanium or zirconium.
As is well known to those skilled in this particular art, the metal columbium (which at times is also referred to as niobium) is characterized by a number of mechanical and physical properties which make it particularly suitable for use as a structural material at temperatures above 2000 F. Principal among such properties are its low density (8.57 g./cm. at 20 C.), a high melting point (2468:10" C.) and good fabricability. In addition it is further characterized by a low neutron capture cross section, a feature which is important in nuclear reactor construction. Furthermore, the metal fortunately is found in sufhciently good supply to be used where needed.
A number of columbium alloys have been made. Such alloying has been done in most cases in the attempt to improve the high temperature strength of the metal and in fact, alloys have been fabricated which do have considerably higher strength at elevated temperatures than does the unalloyed metal. However, such strengthening has been accomplished at the expense of added difiiculties in alloy preparation and fabrication. Waste metal is expensive as a result of these alloying induced problems. Apparently the strengthening which is obtained 'by such alloying as taught by the prior art is obtained primarily with elements that enter into the columbium lattice structure as substitutional solutes, and because the refractory metals which are suitable for this use differ greatly from columbium and from one another in density and in melting point, there oftentimes results inhomogeneous melts and segregation during freezing.
In contradistinction to the teachings of the prior art, we have now discovered that the addition of very modest amounts of either titanium or zirconium and the ternary alloying of oxygen therewith markedly improves the properties of the columbium base metal.
Accordingly, a primary object of our invention is to provide a group of novel columbium alloys which are characterized by the strengthening of the base columbium metal by the dispersion strengthening effect of oxide phases therein.
Another more specific object of our invent-ion is to provide a novel group of columbium-titanium-oxygen and columbium-zirconium-oxygen alloys.
These and other objects, features and advantages of our 3,181,946 Patented May 4, 1965 ice invention will become apparent to those skilled in this particular art from the following detailed disclosure thereof.
As noted above, the alloys of the present invention have a relatively insignificant quantity of substitutional solute contained therein. In the alloys of the prior art strengthening of the base metal is obtained with elements that enter the columbiu-m lattice structure as substitutional solutes; in the present alloys, on the other hand, there are only the small quantities of substiutional solute and strengthening is obtained by the interstitial solute oxygen and by the dispersion strengthening effect of oxide phases. We recognize that small amounts of interstitially soluble elements are normal impurities in colunibium and we recognize further that in the presence of elements more reactive than columbium such interstitially soluble elements form precipitate phases which contribute a strengthening effect. However, our invention entails the addition of considerably larger quantities of oxygen than that which is found in the normal impurity. Sush large quantities of oxygen greatly enhance the strength of the columbium alloy and thus by the teachings of our invention the large addition of substitutional solutes can readily be avoided.
It is known that the high oxygen content in otherwise pure colum'lJ-ium has a marked embrittling effect. With this feature in hand, then, essentially the success of our invention is dependent upon the ability of the metals titanium or zirconium to combine with much of the oxygen that we add and to form a precipitate phase of suitable size, distribution, and stability which leads to relatively ductile columlbium alloys while at the same time retaining the advantages of improved physical and mechanical properties. The compositions that are hereinafter specifically disclosed and other compositions made in accord with the teachings of our invention are characterized by such desirable aspects.
In carrying out the experimental work which led to this invention a high purity columbium sheet was used as melt stock. Oxygen was added thereto in the forms of high purity titanium dioxide and zirconium dioxide powders, and in addition titanium or zirconium sponge metal was added as required to achieve the desired final compositions. Four 225 gram melts were made of each alloy. Melting was performed in an arc furnace equipped with a water-cooled tungsten electrode and water-cooled copper crucible. During melting an inert atmosphere was maintained (argon or helium or mixtures thereof, for example, are quite satisfactory), and each ingot was inverted and remelted four times in order to assure homogeneity thereof.
The pancake shaped ingots resulting from such procedure were then heated in a protective atmosphere, removed and hammer forged to /2 in. bar on flat dies with reheating as necessary. It is readily apparent that this constitutes a rather severe forgeability test. Cb-LSTi- 0.50 oxygen was forged at 1200 C.; Ob-lZr0.25O at 1050 and 1200 C.; Cb-3Zr-0.25O at 1200 and 1300" C.; and Cb3Zr-0.5=0O at 1300 C.
Short-time tensile tests were performed in inert atmospheres on specimens machined from the as-forged bars, with the following results.
Test temperature Nominal alloy composition UTS -YS Percent Percent (wt. percent) (p.s.i.) (p.s.i.) E1 RA Cbl.5Ti0.50O 2, 200 1, 204 26, 900 24, 000 20 Cb1.5Ti-0.500... 2, 000 1, 093 34, 400 32, 000 23 Cb1.5Ti-0.500. 2, 000 1, 093 31, 400 000 13 013-1 Ti0.500 2, 000 1, 093 29, 900 27, 000 19 Cb1.5'1i-0.500 1, 800 982 36, 500 33,000 14 Cb-l 5Ti0.500 1, 600 871 44, 600 40, 000 19 Cb1.5Ti-0.50O RT RT 73, 500 60, 000 29 Cb-1.5Ti0.500 --76 60 89, 200 000 16 Cb1.5'1i0.500 76 (i0 94, 400 64,000 29 Cb1Zr-0.250 2, 000 1, 093 32, 500 30, 000 26 Ob1Zr-0.250 2, 000 1, 093 34, 500 32, 000 Gb-1Zr0.250 1, 800 982 45, 300 42, 000 17 Cb1Zr0.25O RT RT 76, 900 68, 000 16 Cb1Zr-0.25O 76 ---60 88, 700 17 Cb3Zr-0.25O 1, 600 871 55, 700 53, 000 6 Ob-3Zr0.250.- 1, 400 760 56, 000 49, 000 7 Cb3Zt-0.250. RT RT 64, 800 52, 000 19 Ob3Zr-0.250.- 76 60 85, 500 73,000 19 Cb-3Zr0.500 2, 000 1, 093 39, 000 35, 000 6 Cb-3Zr-0.500.- 2, 000 1, 093 42, 500 39, 000 5 Cb3Zr0.500-- l, 800 982 48, 000 47, 000 2 For comparison, the properties of commercially pure colum bium, vacuum arc melted and annealed have been reported as follows:
Within the present compositional ranges there are certain critical features. The larger additions of titanium are known to be detrimental to the high temperature strength of columbium alloys, and on the other hand large amounts of zirconium generally decrease the ductility at high temperature. Furthermore, the amount and distribution of precipitate oxide phases are sensitive to the proportions and absolute concentrations of the component elements. In addition, the properties of the resulting alloy are'in turn of a function of the size, quantity, and distribution of the precipitate. These alloys are therefore distinctly different from others which might be cited that contain the same elements but in substantially different concentrations. It might also be mentioned that differences in oxygen concentration of 0.1% or even less may be very important because oxygen has a low atomic weight compared to columbium and because strong bonds are developed between columbium and oxygen.
In view of the foregoing disclosure, it will be readily apparent to those skilled in this particular art the various modifications and variations may be afiected without departing from the spirit or scope of the novel concepts of our invention.
We claim as our invention:
1. An alloy consisting essentially of from 0.25 to 0.50% oxygen a metal. selected from the group 1;.5% titanium and from 1% to 3% zirconium, balance columbium, wherein the ratio by weight of oxygen to titanium or zirconium ranges from 3 to l to 12 to 1 and wherein alloy strengthening is obtained by interstitial solute oxygen and by the dispersion strengthening eifect of oxide phase.
2. An alloy consisting essentially of from 0.25 to 0.50% oxygen, 1.5% titanium, balance columbium, wherein alloy strengthening is obtained by interstitial solute oxygen and by the dispersion strengthening effect of oxide phase.
3. An alloy consisting essentially of from 0.25 to 0.50% oxygen, from 1 to 3% zirconium, balance columb-ium, wherein alloy strengthening is obtained by interstitial solute oxygen and by the dispersion strengthening efiect of oxide phase.
References Cited by the Examiner UNITED STATES PATENTS 2/61 Frank 174 3/ 62 Begley et a1. 75-174 RAY K. WINDHAM, WINSTON A. DOUGLAS,
Examiners.
Claims (1)
1. AN ALLOY CONSISTING ESSENTIALLY OF FROM 0.25 TO 0.50% OXYGEN A METAL SELECTED FROM THE GROUP 1.5% TITANIUM AND FROM 1% TO 3% ZIRCONIUM, BALANCE COLUMBIUM, WHEREIN THE RATIO BY WEIGHT OF OXYGEN TO TITANIUM OR ZIRCONIUM RANGES FROM 3 TO 1 TO 12 TO 1 AND WHEREIN ALLOY STRENGTHENING IS OBTAINED BY INTERSTITIAL SOLUTE OXYGEN AND BY THE DISPERSION STRENGTHENING EFFECT OF OXIDE PHASE.
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US151200A US3181946A (en) | 1961-11-09 | 1961-11-09 | Columbium base alloys |
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US151200A US3181946A (en) | 1961-11-09 | 1961-11-09 | Columbium base alloys |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3275480A (en) * | 1962-08-27 | 1966-09-27 | Jr Jesse O Betterton | Method for increasing the critical current density of hard superconducting alloys and the improved products thereof |
US3282690A (en) * | 1963-12-02 | 1966-11-01 | United Aircraft Corp | Alloy |
US3310398A (en) * | 1964-08-14 | 1967-03-21 | Nat Res Corp | Electrical materials and devices |
US3434811A (en) * | 1965-02-26 | 1969-03-25 | Gen Electric | Tungsten-hafnium-oxygen alloys |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2973261A (en) * | 1959-06-11 | 1961-02-28 | Gen Electric | Columbium base alloys |
US3027255A (en) * | 1960-02-08 | 1962-03-27 | Westinghouse Electric Corp | High strength niobium base alloys |
-
1961
- 1961-11-09 US US151200A patent/US3181946A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2973261A (en) * | 1959-06-11 | 1961-02-28 | Gen Electric | Columbium base alloys |
US3027255A (en) * | 1960-02-08 | 1962-03-27 | Westinghouse Electric Corp | High strength niobium base alloys |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3275480A (en) * | 1962-08-27 | 1966-09-27 | Jr Jesse O Betterton | Method for increasing the critical current density of hard superconducting alloys and the improved products thereof |
US3282690A (en) * | 1963-12-02 | 1966-11-01 | United Aircraft Corp | Alloy |
US3310398A (en) * | 1964-08-14 | 1967-03-21 | Nat Res Corp | Electrical materials and devices |
US3434811A (en) * | 1965-02-26 | 1969-03-25 | Gen Electric | Tungsten-hafnium-oxygen alloys |
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