US3122433A - Nickel alloy composition - Google Patents

Nickel alloy composition Download PDF

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Publication number
US3122433A
US3122433A US267063A US26706363A US3122433A US 3122433 A US3122433 A US 3122433A US 267063 A US267063 A US 267063A US 26706363 A US26706363 A US 26706363A US 3122433 A US3122433 A US 3122433A
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Prior art keywords
nickel alloy
alloy composition
base alloy
nickel
alloys
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US267063A
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Jr Herbert Greenewald
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/055Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 20% but less than 30%

Definitions

  • This invention relates to a novel alloy of nickel having unexpected and superior strength characteristics at elevat ed temperatures in the range of 2000" F.
  • this invention concerns itself with a nickel base alloy containing precipitated complex carhides.
  • Another object of this invention is to provide a novel nickel base alloy that exhibits high strength and resistance to oxidative degradation at elevated temperatures in excess of 2000* F.
  • An alloy, in accordance with this invention, may con tain the following elements within the percentage ranges set forth in Table I.
  • the present invention is based on the discovery that an unexpected improvement in elevated temperature strength and oxidative resistance results from the addition of significant amounts of carbon. Hence, the formation of complex carbides enhances the strength characteristics of the base alloy to a significant degree.
  • Example I discloses a preferred alloy within the range stated in Table I and having the following approximate analysis:
  • Example 1 Percent Tungsten 17.75 Chromium 17.17 Tantalum 7.5 8
  • the alloys of this invention are particularly resistant to oxidation at temperatures of about 2000 F. in addition to their unex ected hot strength. Also, although the utility of these alloys has been emphasized with respect to their use as liner and back up material for skin structures of re-entry space vehicles, it is to be understood that the alloys may also be utilized for making valves, valve seats, castings and other structural elements. The alloys of this invention may be compounded or made up in any desired manner employing conventional alloying technrques.
  • percent refers to ercent by weight based on the total alloy weight.
  • a nickel base alloy consisting essentially or the following composition:
  • a nickel base alloy consisting essentially of the following composition:

Description

United States This invention relates to a novel alloy of nickel having unexpected and superior strength characteristics at elevat ed temperatures in the range of 2000" F. In a more particular aspect, this invention concerns itself with a nickel base alloy containing precipitated complex carhides.
The recent advent of high speed aircraft and missiles has created a need for materials which exhibit high strength and resistance to oxidative degradation at temperatures in the range of 2030" F. and above. Presently known alloys, often referred to as superalloys do not possess the necessary high temperature tensile strength required by engine liner material and back up material for the skin structure of re-entry and space vehicles.
Accordingly, it is the primary object of this invention to provide an improved nickel base alloy.
Another object of this invention is to provide a novel nickel base alloy that exhibits high strength and resistance to oxidative degradation at elevated temperatures in excess of 2000* F.
The novel features which are believed to be characteristic of the invention are set forth in the appended claims. However, the invention, both as to its organization and method of operation, together with further objects, advantages and features thereof, may be best understood by considering the following detailed explanation of a specific embodiment of the invention.
An alloy, in accordance with this invention, may con tain the following elements within the percentage ranges set forth in Table I.
The present invention is based on the discovery that an unexpected improvement in elevated temperature strength and oxidative resistance results from the addition of significant amounts of carbon. Apparently, the formation of complex carbides enhances the strength characteristics of the base alloy to a significant degree.
Example I discloses a preferred alloy within the range stated in Table I and having the following approximate analysis:
Example 1 Element: Percent Tungsten 17.75 Chromium 17.17 Tantalum 7.5 8
atent ice Percent Aluminum 4.16 Molybdenum 3 .50 Carbon 2.46 Columhium 1.07 Iron 0.93 Titanium 0.5 2 Silicon 0.16 Zirconium 0.09 Nickel Balance The alloys of this invention are particularly resistant to oxidation at temperatures of about 2000 F. in addition to their unex ected hot strength. Also, although the utility of these alloys has been emphasized with respect to their use as liner and back up material for skin structures of re-entry space vehicles, it is to be understood that the alloys may also be utilized for making valves, valve seats, castings and other structural elements. The alloys of this invention may be compounded or made up in any desired manner employing conventional alloying technrques.
Unless otherwise indicated, the term percent, as used in the instant specification and appended claims, refers to ercent by weight based on the total alloy weight.
Although the present invention has been described with reference to preferred embodiments, those skilled in the art will readily understand that various modifications and alterations thereof may be resorted to without departing from the spirit of the invention, and that all such modifications as fall Within the scope of the appended claims are intended to be included herein.
What is claimed is:
1. A nickel base alloy consisting essentially or the following composition:
2 A nickel base alloy consisting essentially of the following composition:
Percent Tungsten 17.75 Chromium 17.17 Tantalum 7.58 Aluminum 4.16 Molybdenum 350 Carbon 2.46 Columbium 1.07 Iron 0.93 Titanium 0.52 Silicon 0.16 Zirconium 0.09 Nickel Balance References Cited in the file of this patent UNITED STATES PATENTS Thielemann Aug. 9, 1960 Michael et a1 Apr. 9, 1963

Claims (1)

1. A NICKEL BASE ALLOY CONSISTING ESSENTIALLY OF THE FOLLOWING COMPOSITION:
US267063A 1963-03-21 1963-03-21 Nickel alloy composition Expired - Lifetime US3122433A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3276866A (en) * 1964-04-14 1966-10-04 John C Freche Nickel-base alloy containing mo-w-al-cr-ta-zr-c-nb-b
US4331741A (en) * 1979-05-21 1982-05-25 The International Nickel Co., Inc. Nickel-base hard facing alloy
US5456156A (en) * 1965-09-14 1995-10-10 The United States Of America As Represented By The Secretary Of The Army Ceramic armor

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2948606A (en) * 1957-05-31 1960-08-09 Sierra Metals Corp High temperature nickel base alloy
US3085005A (en) * 1958-01-16 1963-04-09 Fansteel Metallurgical Corp Alloys

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2948606A (en) * 1957-05-31 1960-08-09 Sierra Metals Corp High temperature nickel base alloy
US3085005A (en) * 1958-01-16 1963-04-09 Fansteel Metallurgical Corp Alloys

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3276866A (en) * 1964-04-14 1966-10-04 John C Freche Nickel-base alloy containing mo-w-al-cr-ta-zr-c-nb-b
US5456156A (en) * 1965-09-14 1995-10-10 The United States Of America As Represented By The Secretary Of The Army Ceramic armor
US4331741A (en) * 1979-05-21 1982-05-25 The International Nickel Co., Inc. Nickel-base hard facing alloy

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