US3113698A - Method of and apparatus for dispensing aerosol materials - Google Patents

Method of and apparatus for dispensing aerosol materials Download PDF

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Publication number
US3113698A
US3113698A US16873862A US3113698A US 3113698 A US3113698 A US 3113698A US 16873862 A US16873862 A US 16873862A US 3113698 A US3113698 A US 3113698A
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US
United States
Prior art keywords
strata
float
liquid
valve
liquids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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English (en)
Inventor
Abplanalp Robert Henry
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Individual
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE627247D priority Critical patent/BE627247A/xx
Priority to NL288224D priority patent/NL288224A/xx
Application filed by Individual filed Critical Individual
Priority to US16873862 priority patent/US3113698A/en
Priority to GB126863A priority patent/GB997829A/en
Priority to FR921833A priority patent/FR1345417A/fr
Priority to DEA42127A priority patent/DE1199643B/de
Priority to ES284423A priority patent/ES284423A1/es
Priority to DK34163A priority patent/DK103944C/da
Priority to CH91763A priority patent/CH403668A/fr
Application granted granted Critical
Publication of US3113698A publication Critical patent/US3113698A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/32Dip-tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/68Dispensing two or more contents, e.g. sequential dispensing or simultaneous dispensing of two or more products without mixing them
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/2931Diverse fluid containing pressure systems
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/8593Systems
    • Y10T137/86236Tank with movable or adjustable outlet or overflow pipe
    • Y10T137/86252Float-supported outlet

Definitions

  • This invention is a method of and apparatus for dispensing a mixture of liquids irom a pressurized three phase system.
  • a pressurized three phase system is one embodying a container in which is packaged two superimposed liquid strata of diflerent specific gravities above which is a. stratum of gas or gaseous vapor under suflicient pressure to force at least a part of the contents of the container through a discharge outlet when a manually operable valve associated with the container is opened.
  • liquid strata comprises an active ingredient and a liquefied gas over which is superimposed a propellant gas under pressure.
  • the present invention may employ such a system although it is not limited thereto as neither liquid strata of the package of this invention need be a liquefied gas.
  • the liquids of the two strata must have difl erenet specific igravities to maintain Stratified relation with respect to one another and they are immiscible liquids which, under ordinary conditions of use, will maintain their stratified condition.
  • the object of this invention is to draw oif directly from the respective liquid strata a predetermined ratio of liquid from both strata, thereafter to comming-le the same in an appropriate mixing chamber prior to their discharge from the package, whereby the resulting effluent comprises an intermixed fine dispersion of the constituents of both liquid strata.
  • one of the strata of the package may be a water-soluble insecti cide composition, while the other may be a liquefied propellant or one of the strata may be an aqueous solution of starch, while the other may be a solution of liquefied propellant and a perfume which is soluble therein, or the liquid of one of the strata may be an aqueous solution of starch while the liquid of the other stratum may be a liquefied propellant in which a fungicide soluble therein is included.
  • both of the two liquid strata may be other than liquefied propellants, in which case the propellant force may be supplied by a stratum of an inert gas, such, for example, as nitrogen, this latter arrangement being useful where it is desired to have the effluent contain a formulation of two active ingredients.
  • either one or both of the strata may contain either one or more active ingredients.
  • a mixing chamber is preferably provided bet-ween the passages of the float and the outlet to ensure a thorough admixing of such liquids before their discharge through the outlet.
  • FIG. 1 is a central vertical section through a dispenser for carrying out the method of this invention in which figure the float is shown in the form of a buoyant sphere.
  • FIG. 2 is a fragmental view showing another form of float which may be used.
  • a container which will hereinafter be referred to as a can.
  • This can has a top filling opening hermetically sealed by a cup 2 provided with a crown 3' in which is enclosed any appropriate form of manually operable dispensing valve.
  • the valve is provided with a valve stem 4 to which is aflixed a manually operable valve operating button 5. All of these parts are conventional and may partake of any appropriate conventional form.
  • the can, its closure cup, valve, Valve stem, and valve operating button may be shown in my prior Patent No. 2,631,814, March 17, 1953, while the button, for the purpose of illustration, is as shown in my Patent No. 2,884,207 of April 28, 1961.
  • the can 1 contains three distinct strata of materials 6, 7 and 8, the materials 6 and '7 of which are liquids, while the stratum 8 is a gaseous stratum.
  • stratum -8 will always be gaseous in nature. It may be any of the well known propellant gases commonly used in areosols or it may be an inert gas depending upon the particular constituents of the package .which is desired to dispense.
  • constituents knownpropell-ant gases such, for example, and without limitation, as monofluorotrichloro methane, difluorodichloro methane, tetrafluorodichloro ethane, normal butane, isobutane, or propane, commonly used in aerosols or it may be an inert gas, such as pressurized nitrogen, depending upon the particular constituents of the package which it is desired to dispense.
  • these constituents may widely vary as hereinbefore stated but, for the purpose of concrete description, I will primarily deal with the same as appropriate for the dispensing of insecticides.
  • the liquid of the stratum 6 is preferably water
  • the liquid of the stratum 7 is preferably liquefied gas, corresponding to the gas of the stratum 8, and may, for example, be a hydrocarbon liquid in which is dissolved an insecticide composition.
  • this float is shown as spherical. In practice it may be of any suitable construction and may conveniently be in the form of a molded plastic so constituted that it will float, partially submerged in the lower stratum 6 and the con tiguous portion of the intermediate stratum 7. It is provided with an interior chamber in which is connected by an eduction tube 11 with the inlet nipple 12 of the discharge valve of the can. This eduction tube is looped as shown so that it may occupy this floating relative position between the two strata 6 and 7 at all times, i.e., from the time that the can is full until it is practically exhausted, as indicated in dotted line position shown in FIG. 1.
  • the float is provided with one or more passages 13 which extend upwardly from the chamber it) to the periphery of the float so that one or more of said inlet passages always occupy a position wherein they dip into the stratum 7. Additional passages is lead from the chamber downwardly to the periphery of the float, so that the inlet ends of said passages 14 at all times dip into the liquid stratum 6.
  • the float will descend as the liquids within the package are expended and, while the float 9' may rotate slightly as it descends, it will always maintain the position stated with one or more of the passages 13 and one or more of the passages 14, continuing to dip into the respective strata so as to deliver the two liquids of different specific gravities directly to the eduction tube until the liquid content of the package is exhausted.
  • the float may be of any desired shape, such, for example, as shown in FIG. 2, wherein it is illustrated as cylindrical in form.
  • the float 9a has a central mixing chamber Illa which is in communication with the lower end of the eduction tube.
  • This float fits loosely within the confines of the can 1 and has such specific gravity as to function in the same manner as the spherical float 9.
  • Both floats may be molded from plastic of the desired specific gravity or they may be made or fabricated with 4 sea ed buoyancy chambers, without departing from this invention, so long as they possess the characteristics to function as explained above.
  • the flow capacity of the passages 13 and 14 will be engineered according to the respective viscosities of the liquids of the strata 6 and 7, which viscosities will also vary according to the liquids to be dispensed. Furthermore the sizes of the additional passages through which the mixture flows from the float to the valve operating button, as well as the size of the outlet orifice of that button, will be also engi-neeringly determined in a manner well known in the art to produce the desired spray pattern.
  • the present invention has many advantages in connwtion with the formulations of the efliuent. It permits widely different immiscible compositions to be properly blended and admixed in a spray pattern and the achievement of results which have heretofore been impossible of accomplishment under prior practice.
  • the active ingredient is a hair spray
  • the introduction of water into the float serves to dilute any flammable constituents that may be in the eifluent for such water serves to materially lower the temperature of the flammable constituents to below their kindling temperatures.
  • the water vapor in finely divided form in the effluent also serves to blanket such flammable constituents so as to render them perfectly safe.
  • one of said liquid strata comprises water.
  • one of said liquid strata comprises a liquefied propellant.
  • one of said liquid strata comprises water and the other comprises a hydrocarbon propellant composition.
  • a dispensing package comprising a container having therein three strata two of which are liquids and the third of which is gas under pressure and which container has an outlet valve with an eduction tube leading to said valve and a discharge outlet leading from said valve, the improvement which comprises: a float connected to the eduction tube and having a specific gravity to cause it to float in the plane of demarcation between the two liquid strata with a portion of the float projecting into each strata, said float being provided with at least one passage leading from each liquid stratum to the passage of the eduction tube, whereby the opening of the discharge valve will simultaneously discharge through the outlet an admixture of the liquids of both strata.
  • a dispensing package comprising a container hav-t mg therein three strata two of which are liquids and the I third of which is gaseous and which container has an outlet valve with an eduotion tube leading to said valve and a discharge outlet leading from said valve, the improvement which comprises: a float connected to the eduction tube and having a specific gravity to cause it to float in the 5 plane of demarcation between the two liquid strata with a. portion of the float projecting into each strata, said float being provided with passages leading from the respective liquid strata to the passage of the eduction tube, said float having therein a mixing ohamber interposed between the 10 several passages of the float and the passage of the eduction tube.

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  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Packages (AREA)
  • Package Specialized In Special Use (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
US16873862 1962-01-25 1962-01-25 Method of and apparatus for dispensing aerosol materials Expired - Lifetime US3113698A (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
BE627247D BE627247A (es) 1962-01-25
NL288224D NL288224A (es) 1962-01-25
US16873862 US3113698A (en) 1962-01-25 1962-01-25 Method of and apparatus for dispensing aerosol materials
GB126863A GB997829A (en) 1962-01-25 1963-01-10 A dispensing package for dispensing a mixture of liquids from a pressurised container
FR921833A FR1345417A (fr) 1962-01-25 1963-01-18 Récipient distributeur de mélanges de liquides
DEA42127A DE1199643B (de) 1962-01-25 1963-01-19 Behaelter mit einem von Hand zu betaetigenden Abgabeventil
ES284423A ES284423A1 (es) 1962-01-25 1963-01-22 Un envase perfeccionado para distribuir bajo presión una mezcla de líquidos de distintas densidades contenidos en el mismo
DK34163A DK103944C (da) 1962-01-25 1963-01-24 Beholder, der er indrettet til gennem en ventil at udtømme en blanding af væsker, der har forskellig vægtfylde.
CH91763A CH403668A (fr) 1962-01-25 1963-01-25 Distributeur d'un mélange de liquides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US16873862 US3113698A (en) 1962-01-25 1962-01-25 Method of and apparatus for dispensing aerosol materials

Publications (1)

Publication Number Publication Date
US3113698A true US3113698A (en) 1963-12-10

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ID=22612735

Family Applications (1)

Application Number Title Priority Date Filing Date
US16873862 Expired - Lifetime US3113698A (en) 1962-01-25 1962-01-25 Method of and apparatus for dispensing aerosol materials

Country Status (9)

Country Link
US (1) US3113698A (es)
BE (1) BE627247A (es)
CH (1) CH403668A (es)
DE (1) DE1199643B (es)
DK (1) DK103944C (es)
ES (1) ES284423A1 (es)
FR (1) FR1345417A (es)
GB (1) GB997829A (es)
NL (1) NL288224A (es)

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3211349A (en) * 1963-05-15 1965-10-12 Aerosol Tech Inc Aerosol dispenser with flexible dip tube
US3240396A (en) * 1963-06-11 1966-03-15 Robert M Friedenberg Aerosol dispenser
US3246885A (en) * 1963-05-27 1966-04-19 Fuller Co Saturation tank
US3272402A (en) * 1963-12-24 1966-09-13 Revion Inc Aerosol dispensing apparatus
US3348737A (en) * 1966-05-18 1967-10-24 Universal Match Corp Dispensers
US3580430A (en) * 1968-04-25 1971-05-25 Valois Sa Aerosol containers
US3877614A (en) * 1973-05-22 1975-04-15 Robert E Murphy Non-spillable liquid dispensing system
DE2559153A1 (de) * 1974-12-31 1976-11-18 Michelin & Cie Verfahren und vorrichtung zur zerstaeubung von fluiden auf oberflaechen
US4062475A (en) * 1975-04-25 1977-12-13 S. C. Johnson & Son, Inc. Pressurized container for two-phase system
FR2445275A1 (fr) * 1978-12-26 1980-07-25 American Cyanamid Co Ensemble a valve et tube plongeur pour dispositif distributeur d'aerosol
US4470526A (en) * 1981-08-10 1984-09-11 Jungkeun Cha Siphon dispensing bottle
US5195664A (en) * 1992-04-03 1993-03-23 Steven Rhea All directional fluid pick-up
US5213266A (en) * 1991-05-14 1993-05-25 Leiras Oy Inhalation aerosol nozzle
FR2707265A1 (fr) * 1993-07-05 1995-01-13 Oreal Dispositif de distribution de liquide, en particulier sous forme aérosol.
US5765601A (en) * 1994-05-17 1998-06-16 Radiator Specialty Company Tire inflator and sealant product
US5961004A (en) * 1998-03-09 1999-10-05 Demars; Robert A. Beverage container for hot liquids with separate consuming cooling reservoir
US6279609B1 (en) * 1996-12-20 2001-08-28 Per Velve Flow control means
US20030213816A1 (en) * 2002-05-15 2003-11-20 Kevin Harrity Device for retaining and for inserting a flexible tube assembly into a fluid container
EP1815970A3 (de) * 2006-02-07 2007-08-15 Michael Stehle Vorrichtung zum Ausbringen von Reifendichtmittel aus einem Behälter
US20080000527A1 (en) * 2006-06-28 2008-01-03 Stout, Tacconelli & Associates, Inc. Apparatus and Method for Slow Transport of a Liquid Body
US10961111B2 (en) * 2016-05-31 2021-03-30 Sfc Energy Ag Device for removing fuel from tank cartridges for fuel cells
EP4382452A1 (en) * 2022-12-05 2024-06-12 Motedo Co., Ltd. Liquid product container and extending drawing unit of liquid product container

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3742466C2 (de) * 1987-12-15 1993-12-02 Vorwerk Co Interholding Mischeinrichtung in Sprühdosen zur Durchmischung feststoffhaltiger Suspensionen
GB2467579B (en) * 2009-02-06 2013-07-31 Consort Medical Plc Improvements in or relating to dispensing apparatus
DE202012101017U1 (de) * 2012-03-22 2013-06-07 Kläger Plastik GmbH Vorrichtung zur Förderung liquider Medien
FR3074701B1 (fr) * 2017-12-07 2022-03-25 Fareva Dispositif de distribution a deux voies d’un melange biphasique micronise

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US222140A (en) * 1879-12-02 Improvement in water drawing and filtering apparatus for cisterns and other vessels
US727779A (en) * 1902-10-31 1903-05-12 Albert C Frieseke Hydraulic oil-tank.
US2040302A (en) * 1930-03-24 1936-05-12 Fortier Carolus Process of and apparatus for atomizing liquids
CH245041A (de) * 1945-06-29 1946-10-31 Hildenbrand Bruno Vorrichtung zum Entleeren von Flüssigkeitsbehältern.
US2705661A (en) * 1951-10-30 1955-04-05 Little Inc A Liquid dispensing system employing internally-generated gas pressure
US2832512A (en) * 1956-01-19 1958-04-29 Troy H Brooks Floating suction for liquids
US2941696A (en) * 1957-08-19 1960-06-21 Ortho Pharma Corp Dispensing container
US2995278A (en) * 1959-05-22 1961-08-08 Western Filling Corp Packaged self-propelling liquid compositions

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US222140A (en) * 1879-12-02 Improvement in water drawing and filtering apparatus for cisterns and other vessels
US727779A (en) * 1902-10-31 1903-05-12 Albert C Frieseke Hydraulic oil-tank.
US2040302A (en) * 1930-03-24 1936-05-12 Fortier Carolus Process of and apparatus for atomizing liquids
CH245041A (de) * 1945-06-29 1946-10-31 Hildenbrand Bruno Vorrichtung zum Entleeren von Flüssigkeitsbehältern.
US2705661A (en) * 1951-10-30 1955-04-05 Little Inc A Liquid dispensing system employing internally-generated gas pressure
US2832512A (en) * 1956-01-19 1958-04-29 Troy H Brooks Floating suction for liquids
US2941696A (en) * 1957-08-19 1960-06-21 Ortho Pharma Corp Dispensing container
US2995278A (en) * 1959-05-22 1961-08-08 Western Filling Corp Packaged self-propelling liquid compositions

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3211349A (en) * 1963-05-15 1965-10-12 Aerosol Tech Inc Aerosol dispenser with flexible dip tube
US3246885A (en) * 1963-05-27 1966-04-19 Fuller Co Saturation tank
US3240396A (en) * 1963-06-11 1966-03-15 Robert M Friedenberg Aerosol dispenser
US3272402A (en) * 1963-12-24 1966-09-13 Revion Inc Aerosol dispensing apparatus
US3348737A (en) * 1966-05-18 1967-10-24 Universal Match Corp Dispensers
US3580430A (en) * 1968-04-25 1971-05-25 Valois Sa Aerosol containers
US3877614A (en) * 1973-05-22 1975-04-15 Robert E Murphy Non-spillable liquid dispensing system
DE2559153A1 (de) * 1974-12-31 1976-11-18 Michelin & Cie Verfahren und vorrichtung zur zerstaeubung von fluiden auf oberflaechen
US4062475A (en) * 1975-04-25 1977-12-13 S. C. Johnson & Son, Inc. Pressurized container for two-phase system
FR2445275A1 (fr) * 1978-12-26 1980-07-25 American Cyanamid Co Ensemble a valve et tube plongeur pour dispositif distributeur d'aerosol
US4470526A (en) * 1981-08-10 1984-09-11 Jungkeun Cha Siphon dispensing bottle
US5213266A (en) * 1991-05-14 1993-05-25 Leiras Oy Inhalation aerosol nozzle
US5195664A (en) * 1992-04-03 1993-03-23 Steven Rhea All directional fluid pick-up
FR2707265A1 (fr) * 1993-07-05 1995-01-13 Oreal Dispositif de distribution de liquide, en particulier sous forme aérosol.
US5765601A (en) * 1994-05-17 1998-06-16 Radiator Specialty Company Tire inflator and sealant product
US6279609B1 (en) * 1996-12-20 2001-08-28 Per Velve Flow control means
US5961004A (en) * 1998-03-09 1999-10-05 Demars; Robert A. Beverage container for hot liquids with separate consuming cooling reservoir
US20030213816A1 (en) * 2002-05-15 2003-11-20 Kevin Harrity Device for retaining and for inserting a flexible tube assembly into a fluid container
US6935542B2 (en) 2002-05-15 2005-08-30 S. C. Johnson & Son, Inc. Device for retaining and for inserting a flexible tube assembly into a fluid container
EP1815970A3 (de) * 2006-02-07 2007-08-15 Michael Stehle Vorrichtung zum Ausbringen von Reifendichtmittel aus einem Behälter
US20080000527A1 (en) * 2006-06-28 2008-01-03 Stout, Tacconelli & Associates, Inc. Apparatus and Method for Slow Transport of a Liquid Body
US10961111B2 (en) * 2016-05-31 2021-03-30 Sfc Energy Ag Device for removing fuel from tank cartridges for fuel cells
EP4382452A1 (en) * 2022-12-05 2024-06-12 Motedo Co., Ltd. Liquid product container and extending drawing unit of liquid product container

Also Published As

Publication number Publication date
DE1199643B (de) 1965-08-26
NL288224A (es) 1900-01-01
BE627247A (es) 1900-01-01
FR1345417A (fr) 1963-12-06
ES284423A1 (es) 1963-12-01
GB997829A (en) 1965-07-07
DK103944C (da) 1966-03-14
CH403668A (fr) 1965-11-30

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