US3095632A - Method for continuously opening crimped tow - Google Patents

Method for continuously opening crimped tow Download PDF

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Publication number
US3095632A
US3095632A US127437A US12743761A US3095632A US 3095632 A US3095632 A US 3095632A US 127437 A US127437 A US 127437A US 12743761 A US12743761 A US 12743761A US 3095632 A US3095632 A US 3095632A
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United States
Prior art keywords
tow
filaments
crimps
rolls
filament
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Expired - Lifetime
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US127437A
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English (en)
Inventor
Smith John Winston
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
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Eastman Kodak Co
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Filing date
Publication date
Priority to NL113019D priority Critical patent/NL113019C/xx
Priority to BE573050D priority patent/BE573050A/xx
Priority to NL232663D priority patent/NL232663A/xx
Priority claimed from US695080A external-priority patent/US3016581A/en
Priority to CH350236D priority patent/CH350236A/fr
Priority to FR778554A priority patent/FR1222494A/fr
Priority to DEE16679A priority patent/DE1141928B/de
Priority to GB35787/58A priority patent/GB907299A/en
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Priority to US127437A priority patent/US3095632A/en
Publication of US3095632A publication Critical patent/US3095632A/en
Application granted granted Critical
Priority to MY196411A priority patent/MY6400011A/xx
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/18—Separating or spreading
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02—Manufacture of tobacco smoke filters
    • A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/18—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being cellulose or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10—Filtering material manufacturing

Definitions

  • the present invention relates to improved crimped continuous filament tow, such as cellulose acetate tow, which is particularly useful in preparing tobacco smoke filters and especially cigarette filters and to the filters made therefrom.
  • This invention is also concerned with novel apparatus and process for the opening of continuous filament tow to increase the cross-sectional area of the tow and the uniformity of filament distribution within the tow, and is moreover directed to the eilicient elimination of shiners, married fibers and bundles of fibers within the tow.
  • tow describes a large number of aligned, continuous filaments which are associated in a somewhat loose form in a flat band-like structure. When this tow is crimped the product is crimped tow.
  • Tows suitable for cigarette filters range from 45,000 to 160,000 total denier.
  • the filament sizes normally available are usually in the range of 2 to 75 denier per filament and the tow may be made up of between 5,000 and 100,000 filaments (preferably 20,000) of from 2 to 16 (preferably denier per filament or a total denier within the range of 80,000 to 250,000 (preferably 100,000).
  • the crimps in the tow should range from 4 to 18 crimps per inch and 9 crimps per inch are preferable.
  • Denier is defined as the weight in grams of a 9,000 meter length of yarn. Thus, a filament 9,000 meters long which weighs 1 gram is designated 1 denier. The size of the tow is given in total denier. Total denier is the product of the denier per filament (D/F) times the number of filaments contained in the tow. Thus, a 5 D/F, 80,000 denier tow would contain 16,000 filaments and would weigh 80,000 grams per 9,000 meters.
  • the preferred cellulose acetate tow comprises continuous filaments of cellulose acetate of the specified deniers which have been spun from one or more spinnerettes, having a plurality of orifices therein, by the well-known dry spinning process and loosely drawn together in more or less parallel band-like association to form a continuous band or tow.
  • a cellulose acetate tow can be made,
  • the cellulose acetate from which the tow is manufactured may be an acetyl value of 38 to 41%, preferably 38.8 to 39.2% and is available commercially.
  • the tow is crimped by any suitable crimping process which can give the desired highly crimped filament tow.
  • the tow may be advantageously supplied for use in my apparatus and process in the form of a bale about 40 inches high, 25 inches wide, and 50 inches long which weighs 600 to 800 pounds. Such a bale contains a continuous tow of about 91,000 feet in length which is normally enough to supply the process for about 8 hours when making 1,000 filter tips per minute.
  • the crimped continuous filament cellulose acetate tow particularly suitable for use in the apparatus and process of the present invention is one that has also been conditio'ned with a lubricant which impartsadditional density and lubricating properties to the tow but without giving the tow additional antistatic properties.
  • a lubricant which impartsadditional density and lubricating properties to the tow but without giving the tow additional antistatic properties.
  • Such a tow is the subject of Crawford and Stevens Patent 2,794,239 of June 4, 1957.
  • the crimped cellulose acetate tow although lubricated so that it may pass easily through the steps of the process preferably carries a static charge which, due to electrostatic repulsion between filaments, assists in the 3,095,632 Patented July 2, 1963 step of filament separation and distribution which, as is described hereinafter, is carried out primarily by other means.
  • the static charge is placed on the tow by movement of the tow through the apparatus described herein.
  • An object, therefore, of the present invention is to provide an improved method and apparatus for continuously opening crimped continuous cellulose acetate tow, whereby the bulk and uniformity of filament distribution is increased and more effective elimination from the tow of shiners and married filaments occurs.
  • Still another object is to provide a process and apparatus whereby the tow can be opened more efiiciently while under less tension than has been employed in previous processes.
  • 'Yet another object is to provide a process and apparatus whereby the crimps in any one of the filaments making up the crimped tow can be positioned and maintained out of registry with the crimps in the adjacent filaments.
  • Another object is to provide a multi-filament crimped tow in which the crimps in any one of the filaments are out of registry with the crimps in the adjacent filaments.
  • Still another object of the present invention is a tobacco smoke filter unit comprising aligned crimped continuous filaments in which the crimps in any one of the filaments are out of registry with the crimps in the adjacent filaments.
  • a crimped, continuous multi-filament tow, of relatively narrow crosssection, in which the crimps are substantially in registry and which contains married filaments or filament bundles is withdrawn from a source of supply such as a tow bale and passed through a preliminary tow opener device in which air under pressure is blown against the tow substantially at right angles to the direction of movement of the tow in order to give a preliminary separation to the filaments.
  • the tow at this point is substantially wider and thinner than that still in the bale and is now conducted through the nip of a first pair of braked coacting rubber-covered rolls and thence through a ratch and through the nip of a second pair of driven coacting rubber-covered rolls.
  • ratch is meant the distance between the nips of the adjacent pairs of the coacting rubber-covered rolls.
  • the braked rolls restrain the forward movement of the tow somewhat and the driven rolls are operated to stretch the tow in the ratch between the pairs of rolls until the crimps in the filaments are straightened to a considerable extent but not sufiicient to overcome the tendency of the crimps to reform.
  • the stretched tow is conducted under substantially the same tension to a third pair of driven coacting rubbercovered rolls and through the nip therebetween.
  • a particular feature of the present invention is occasioned by the angular arrangement of the first and second pairs of rolls with respect to the third pair. This may be comprehended by reference particularly to FIG. 2 of the related drawings.
  • the tow is conducted away from the nip of the third pair of rolls at a relaxing tension so that the crimps are suddenly restored in each filament of the tow.
  • the sudden release of the tension on the spring-like stretch, crimped filaments plus the repelling effect of the static charge which is placed on the filaments by contact with the various rubber-covered rolls results in an explosive expansion. Since the filaments have been pulled out of registry they are restored in the out-of-registry position.
  • the cumulative effect of the longitudinal plus the angular stretching is to eliminate substantially completely all married filaments or filament bundles in the crimped, continuous filaments of the tow.
  • the tow is preferably passed through another airoperated tow opener device similar to that mentioned above to widen the tow still further and through a cham her in which a bonding medium is placed on each side of the tow.
  • the continuous filament cellulose acetate tow is now in condition to be formed into cigarette filter units.
  • the tow is therefore introduced into the filter forming device through a condensing trumpet which reforms the flat tow into a round strand, a paper wrapper is then placed around the continuously moving condensed rod of tow.
  • the product at this point is a continuous round and compact paper-covered filter rod in which the crimped filaments are also in substantial parallel alignment and with the crimps in said out-of-registry condition.
  • This rod has a diameter the same or slightly less than that of the cigarette with which the filter is to be assembled.
  • the continuous rod is then subjected to a heat treatment for purposes of stiffening the rod.
  • the heat causes the bonding of the filaments to each other where they contact within the filter structure and given a more rigid structure to the rod which facilitates handling and assembly operations.
  • the moving filter rod is periodically cut into lengths suitable for use in filter cigarette manufacture or for use in pipes and cigar holders.
  • 16. 1 is an elevational view of my novel apparatus which may be employed for carrying out my novel method of opening continuous crimped cellulose acetate tow;
  • FIG. 2 is a plan view of the apparatus shown in FIG. 1;
  • FIG. 3 is a rear view in elevation of the two pairs of rubber-covered rolls showing their mounting means and the driving means for the driven pair of rolls;
  • FIG. 4 is a view of the gearing and pulley assembly which coacts with other elements to drive portions of the apparatus;
  • FIG. 5 is an isometric drawing of the apparatus for wrapping the processed tow into a continuous wrapped rod and cutting the rod into filter units;
  • FIG. 6 is a vertical section along the path of tow movement through the banding jet
  • FIG. 7 is an enlarged representation showing the filter rod with the crimps in the filaments in out-of-registry position
  • FIG. 8 is an enlarged longitudinal section through a portion of a tipped cigarette assembled with a filter made by the instant process.
  • FIG. 1 there is shown apparatus suitable for use in accordance with the present invention for continuously opening crimped continuous filament tow such as cellulose acetate tow.
  • the tow 15 is drawn upwardly from the tow bale and passes through a preliminary tow opener 16 which is generally similar to that shown in Jackson Patent 2,737,688 of March 13, 1956.
  • the tow 15 then continues over roll 17 which is a fixed guide.
  • Tow opener 16 and roll 17 are suitably mounted on support 18.
  • the tow then continues to the nip between rubber-covered rolls 19 and 21 and thence to the nip between the rubber-covered rolls 22 and 23.
  • These pairs of rolls are suitably mounted on respective supports 25 and 24 and as shown more clearly in FIG. 2, are spaced from each other.
  • Rolls 19 and 21 are the braked rolls which grip the tow 15 passing therebetween and restrain its forward movement somewhat.
  • the braking means represented in part by member 20, may be of any suitable construction such as a conventional hydraulic operated brake adapted to be adjusted to retard the rotation of the rolls to the desired amount.
  • Rolls 22 and 23 are positively driven, by means described hereinafter, and are rotated at a rate sufiicient to stretch the crimped tow 15 until the crimps are straightened to a considerable extent.
  • the tow on leaving the nip of rolls 22 and 23 continues to the pair of rubber-covered rolls 26 and 27 and passes through the nip therebetween.
  • Rolls 26 and 27 are also driven rolls and are driven at a rate sufiicient to maintain tension on the tow which has been placed thereon by rolls 22 and 23. These rolls are suitably mounted on support 28.
  • the first and second pairs of rolls are positioned at an angle to the third pair of rolls.
  • the angle between the second pair of rolls and the third pair of rolls may be within the range of 5 to degrees. 30 degrees appears to be the preferred angular displacement when processing 100,000 denier tow of 5 denier per filament.
  • the tow is withdrawn from the nip of rolls 26 and 27 at a relaxing tension which permits the crimps in the filaments to reform.
  • This equal and unequal stretching of the tow substantially completely eliminates married fibers or filter bundles.
  • the equal length stretching of the filaments accomplished by the coaction of the first and second pairs of rolls separates into a parallel relationship the majority of the filaments in the tow but the crimps across the width of the tow are substantially still in registry.
  • the tow now continues at the relaxing tension through a guide 29 to another air-operated tow opener 31 which is similar in operation to that shown at 16. This spreads out the filaments so that the tow is substantially at its maximum width, the adjacent filaments touching only a horizontal plane.
  • the moving tow now in the form of the fiat band of parallel disposed filaments with the crimps out of registry is conducted through a spray chamber 34 where a fluid plasticizing bonding medium is applied on each side of the tow by spray guns, not shown, to cause the filaments to be capable of bonding at a subsequent stage in the process to an adjacent filament wherever contacted by the spray.
  • the plasticizer is sprayed so as to form minute droplets at random points along the top and bottom surfaces of substantially each of the filaments of the tow in sufiicient quantity so that substantially each of the filaments will have a plurality of bonding points along any length corresponding to the length of the smoke filtering unit which is to be the ultimate product.
  • a plasticizing agent such as methyl phthalyl ethyl glycolate (carbethoxymethyl phthalate) is advantageously employed.
  • suitable nontoxic plasticizers which have nontoxic decomposition products and do not adversely aifect the taste of tobacco smoke filtered through elements of the invention, are dibutyl phthalate, tripropionin and acetyl triethyl citrate.
  • the plasticizing agent preferebly is sprayed on until the fibers contain 4 to 30% (preferably 6-15%) by weight of plasticizer. If desired, the temperature at which the fluid treatment takes place may be controlled by means, not shown.
  • the tow now having the plasticizer therein is conducted between delivery rolls 35 and 36 and thence into the filter forming device shown in FIG. through condensing trumpet 37 which forms the flat tow into a round multifilament strand 38.
  • the first two pairs of rolls are mounted to turn respectively on shafts 60, 61, 62, 63 which are suitably supported by members 64 or 65.
  • the lower rolls may be brought into engagement with the upper rolls by suitable adjustment of members 50 as is apparent from the drawing.
  • Roll 22 is positively driven by belt 66 which engages pulleys 67 and 68.
  • the latter pulley 68 is turned by belt 69 from driven pulley 71 which, as shown in FIG. 4, is mounted on shaft 72 and is driven through gears 73 and 74 and shaft 75 which is turned by pulley 76.
  • These various elements are conventionally mounted on a supporting frame 78.
  • belt 77 is turned by pulley 76 which is associated with a transmission box 81 which is operated by pulley 84 which is turned by belt 88 by means of pulley 89 which is rotated by transmission 90.
  • the latter is operated by a motor, not shown.
  • Pulley and belt 83 turns pulley 82 which operates a pump, not shown, for forcing the bonding medium' through the above-mentiondd spray nozzles which are positioned on either side of the tow as it passes through chamber 34.
  • Pulley 92 and belt 93 turn pulley 94 and furnish power to the device shown in FIG. 5 for forming the tow into a continuous filter rod.
  • FIG. 5 A device suitable for wrapping the round strand 38 of continuous filaments into a filter unit is shown in FIG. 5.
  • the device comprises an endless belt 39 which revolves around drums 41 and 42 and is maintained taut by drums 40.
  • the belt is driven by means not shown.
  • the Wrapper 43 which may be filter paper, is continuously unwound from roll 44 and passes over guide roll 45 and is carried by endless belt 39 through a wrapper forming device 46 which bends the wrapper into a U-shapaed [form just before it comes into contact with the now round strand of filaments 38.
  • the U-shaped wrapper containing the strand 38 is now carried by endless belt 39 through a second forming device 47 in which the wrapper is lapped around the strand 38 leaving one edge 48 of the paper standing upwardly.
  • the standing edge 48 of the paper then moves along to contact rotating wheel 49 which applies a suitable adhesive to the inner side of standing edge 48.
  • the source of the adhesive may be conventional and is not shown.
  • the standing edge 48 is now smoothed down over the adjacent paper edge by forming member 51 and is then heat sealed into a permanent adhesive bond by electric heating shoe 52.
  • the product therefore at this point in the process is a continuous round and compact filter rod 53 having a diameter approximately the same as that of the cigarette with which the filter is to be assembled.
  • the filter rod is then passed through an electrically heated die 54.
  • the heat treatment may be conducted at F. and as described above, stiffens the filter rod.
  • the filter rod 53 is cut into appropriate lengths by cutter 55 which is rotated by means, not shown.
  • the end product is a round filter element having an external paper wrapper containing a compact, rigid structurally unitary debundlized mass of crimped cellulose acetate filaments, each filament of the mass being substantially coextensive therewith.
  • the filaments as a whole are in substantial alignment longitudinally of the mass but substantially each of the individual filaments has non-oriented short portions thereof disposed randomly in diverging and converging relationship to the main filament axis.
  • FIG. 8 shows the filter unit of the present invention assembled in normal position with a cigarette.
  • the filters are usually 25 mm. in circumference and 13 mm. long.
  • tows of other suitable synthetic filaments may be made into tobacco smoke filters by employing my novel apparatus and process.
  • a method for continuously opening a crimped continuous multi-filament tow which comprises subjecting substantially equal lengths of the filaments in the tow to a first tension suflicient to stretch the filaments and temporarily straighten out the crirnps, subjecting said filaments to a second tension sufiicient to maintain the cr-imps in the straightened condition, said second tension being applied to adjacent filaments of the tow at different lengths thereof and at an angle to said first tension whereby the crimps in adjacent filaments are drawn out of registry with one another, expanding the cross-sectional dimensions of the tow and restoring the crimps in the tow in the out-ot-registry position by abruptly relaxing said second tension.
  • a method for continuously opening a crimped continuous multi-filament tow which comprises subjecting substantially equal engths of the filaments in the tow to a first tension sufiicient to stretch he filamens and temporarily straighten out the crirnps, subjecting said filaments to a second tension sufficient to maintain the crimps in the straightened condition, said second tension being applied to adjacent filaments of the tow at difierent lengthsthereof and at an angle of from 5 to 65 degrees to said first tension whereby the crimps in adjacent filaments are drawn out of registry with one another, expanding the crosssectional dimensions of the tow and restoring the crimps in the tow in the out-of-registry position by abruptly relaxing said second tension.
  • a method for continuously opening a crimped continuous multi-filament tow which comprises subjecting substantially equal lengths of the filaments in the tow to a first tension sufiicient to stretch the filaments and temporarily straighten out the crimps, subjecting said filaments to a second tension suflicient to maintain the crimps in the straightened condition, said second tension being applied to adjacent filaments of the tow at difvferent lengths thereof and at an angle of 30 degrees to said first tension whereby the crimps in adjacent filaments are drawn out of registry with one another, expanding the cross-sectional dimensions of the tow and restoring the erimps in the tow in the out-of-registry position by abruptly relaxing said second tension.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
US127437A 1957-11-07 1961-07-14 Method for continuously opening crimped tow Expired - Lifetime US3095632A (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
NL113019D NL113019C (ja) 1957-11-07
BE573050D BE573050A (ja) 1957-11-07
NL232663D NL232663A (ja) 1957-11-07
CH350236D CH350236A (fr) 1957-11-07 1958-11-05 Procédé de fabrication d'une étoupe, appareil pour la mise en oeuvre du procédé, étoupe obtenue par ce procédé et utilisation de cette étoupe
FR778554A FR1222494A (fr) 1957-11-07 1958-11-06 Procédé et appareil pour l'ouverture de cordons de filaments crêpés, nouveaux produits obtenus et leurs applications, en particulier à la fabrication de filtres pour cigarettes
DEE16679A DE1141928B (de) 1957-11-07 1958-11-06 Verfahren zum Herstellen eines fuer Tabakrauchfilter geeigneten Stranges und Vorrichtung zum Durchfuehren des Verfahrens
GB35787/58A GB907299A (en) 1957-11-07 1958-11-07 Tow and tobacco smoke filters and method for their production
US127437A US3095632A (en) 1957-11-07 1961-07-14 Method for continuously opening crimped tow
MY196411A MY6400011A (en) 1957-11-07 1964-12-31 Tow and tobacco smoke filters and method for their production

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US695080A US3016581A (en) 1957-11-07 1957-11-07 Apparatus for opening continuous multifilament crimped tow
US127437A US3095632A (en) 1957-11-07 1961-07-14 Method for continuously opening crimped tow

Publications (1)

Publication Number Publication Date
US3095632A true US3095632A (en) 1963-07-02

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US127437A Expired - Lifetime US3095632A (en) 1957-11-07 1961-07-14 Method for continuously opening crimped tow

Country Status (8)

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US (1) US3095632A (ja)
BE (1) BE573050A (ja)
CH (1) CH350236A (ja)
DE (1) DE1141928B (ja)
FR (1) FR1222494A (ja)
GB (1) GB907299A (ja)
MY (1) MY6400011A (ja)
NL (2) NL113019C (ja)

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3220061A (en) * 1963-06-06 1965-11-30 Celanese Corp Tow spreading apparatus
US3220060A (en) * 1964-01-07 1965-11-30 Eastman Kodak Co Apparatus and method for debundlizing filter tow
US3262178A (en) * 1963-06-12 1966-07-26 Eastman Kodak Co Tow treating apparatus
US3262181A (en) * 1963-11-22 1966-07-26 Eastman Kodak Co Method for opening fibrous tow
US3345697A (en) * 1964-07-27 1967-10-10 Eastman Kodak Co Apparatus for banding filamentary tow
US3852007A (en) * 1970-05-13 1974-12-03 Celanese Corp Apparatus for making filters
US4179776A (en) * 1977-09-19 1979-12-25 Harold Wortman Method and apparatus for deregistering and processing an open synthetic tow into fiber-filled articles
US20040159658A1 (en) * 2003-02-14 2004-08-19 Mclaughlin Michael Ray Packages, packaging systems, methods for packaging and apparatus for packaging
US20050066493A1 (en) * 2003-09-26 2005-03-31 Celanese Acetate, Llc Method and apparatus for making an absorbent composite
EP1559333A2 (de) * 2004-01-29 2005-08-03 Hauni Maschinenbau AG Separate Entspannung und Besprühung eines Filtertowstreifens
US20050284775A1 (en) * 2003-02-14 2005-12-29 Mclaughlin Michael R Packages, packaging systems, methods for packaging, and apparatuses for packaging
EP1834531A1 (de) 2006-03-10 2007-09-19 Hauni Maschinenbau AG Aufbereitung eines Filtermaterialstreifens der Tabak verarbeitenden Industrie
US20080182099A1 (en) * 2006-11-17 2008-07-31 Jennifer Hoyt Lalli Robust electrodes for shape memory films
US20080206550A1 (en) * 2007-02-26 2008-08-28 Michael Jeremiah Borlner Hydrophobic surface
US20080213570A1 (en) * 2007-02-16 2008-09-04 Jennifer Hoyt Lalli Self-assembled conductive deformable films
US20080245413A1 (en) * 2007-04-04 2008-10-09 Hang Ruan Self assembled photovoltaic devices
US20080261044A1 (en) * 2003-02-10 2008-10-23 Jennifer Hoyt Lalli Rapidly self-assembled thin films and functional decals
US20090035513A1 (en) * 2007-03-28 2009-02-05 Michael Jeremiah Bortner Tethered nanorods
WO2009037461A2 (en) * 2007-09-19 2009-03-26 Filtrona International Limited Tobacco smoke filter
US20090087348A1 (en) * 2007-02-16 2009-04-02 Richard Otto Claus Sensor applications
US20090104438A1 (en) * 2007-10-17 2009-04-23 Jennifer Hoyt Lalli Abrasion resistant coatings
US20090136574A1 (en) * 2006-04-19 2009-05-28 Galderma S.A. Compositions comprising at least one aqueous phase and at least one fatty phase which comprises avermectin compounds
EP2213184A1 (de) 2003-11-25 2010-08-04 Hauni Maschinenbau AG Vorrichtung zum Aufbereiten von Filtertowmaterial sowie Vorrichtung zur Herstellung von Filtern
CN110678586A (zh) * 2017-07-11 2020-01-10 株式会社大赛璐 乙酸纤维素丝束带及乙酸纤维素丝束带的制造方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3329543A (en) * 1963-03-08 1967-07-04 Celanese Corp Method of making cigarette filter rods

Citations (2)

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Publication number Priority date Publication date Assignee Title
US2794239A (en) * 1952-12-05 1957-06-04 Eastman Kodak Co Tow for use in the production of tobacco smoke filters
US2843881A (en) * 1956-06-26 1958-07-22 Eastman Kodak Co Apparatus for opening crimped continuous filament tow

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1733262U (de) * 1953-03-24 1956-10-31 Zigarettenfabrik Haus Neuerbur Zigarettenfilter.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2794239A (en) * 1952-12-05 1957-06-04 Eastman Kodak Co Tow for use in the production of tobacco smoke filters
US2843881A (en) * 1956-06-26 1958-07-22 Eastman Kodak Co Apparatus for opening crimped continuous filament tow

Cited By (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3220061A (en) * 1963-06-06 1965-11-30 Celanese Corp Tow spreading apparatus
US3262178A (en) * 1963-06-12 1966-07-26 Eastman Kodak Co Tow treating apparatus
US3262181A (en) * 1963-11-22 1966-07-26 Eastman Kodak Co Method for opening fibrous tow
US3220060A (en) * 1964-01-07 1965-11-30 Eastman Kodak Co Apparatus and method for debundlizing filter tow
US3345697A (en) * 1964-07-27 1967-10-10 Eastman Kodak Co Apparatus for banding filamentary tow
US3852007A (en) * 1970-05-13 1974-12-03 Celanese Corp Apparatus for making filters
US4179776A (en) * 1977-09-19 1979-12-25 Harold Wortman Method and apparatus for deregistering and processing an open synthetic tow into fiber-filled articles
US20080261044A1 (en) * 2003-02-10 2008-10-23 Jennifer Hoyt Lalli Rapidly self-assembled thin films and functional decals
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Also Published As

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NL113019C (ja)
GB907299A (en) 1962-10-03
FR1222494A (fr) 1960-06-10
BE573050A (ja)
NL232663A (ja)
MY6400011A (en) 1964-12-31
DE1141928B (de) 1962-12-27
CH350236A (fr) 1960-11-15

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