US303150A - Egbert hadfield - Google Patents
Egbert hadfield Download PDFInfo
- Publication number
- US303150A US303150A US303150DA US303150A US 303150 A US303150 A US 303150A US 303150D A US303150D A US 303150DA US 303150 A US303150 A US 303150A
- Authority
- US
- United States
- Prior art keywords
- steel
- manganese
- per cent
- melted
- hadfield
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 description 37
- 239000010959 steel Substances 0.000 description 37
- 229910052748 manganese Inorganic materials 0.000 description 18
- 239000011572 manganese Substances 0.000 description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 14
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 229910000616 Ferromanganese Inorganic materials 0.000 description 8
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 8
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 229910052742 iron Inorganic materials 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000005266 casting Methods 0.000 description 3
- 238000005242 forging Methods 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000009618 Bessemer process Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Forging (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
UNTTED STATES ROBERT HADFIELD, OF SHEFFIELD, COUNTY OF YORK, ENGLAND.
MANUFACTURE OF STEEL.
SPECIFICATION forming part of Letters Patent No. 303,150, dated August 5, 1884.
Application filed February 13, 1884. (No specimens.) Patented in England January 12, 1883, N0. 200.
20 all; whom it may concern:
Be it known that I, Bonner HADFIELD, of Sheffield, in the county of York, England, have invented a new and useful Improvement in the Manufacture of Steel; and I do hereby declare the following to be a full, clear, and exact description thereof.
My improvement consists in the admixture of a large percentage of manganese with molt-en iron in a decarburized or nearly decarburized condition, or to molten steel, whereby I prod uce a new description of steel of great toughexperiments, that when manganese is added to the metal or to melted steel in the process of manufacture in any proportions not less than about seven nor more than twenty parts of manganese, which said per cent. is obtained by theusc of ordinary commercial ferro-manganese, in one hundred parts of molten metal nearly or wholly decarburized, or to melted steel, most beneficial effects are produced, and a new product results, which has the valuable qualities of ordinary steel while differing from it in several important respects, so that my new manufacture of steel is distinguishable from the grades of steel produced by any of the ordinary processes heretofore known in the following particulars: first, in its freedom from honeycomb and othcr'siniilar defects;
second, in its great toughness and extreme hardness, by reason of which the hitherto indispensable prooesscs of rolling, forging, hammering, hardening,- and tempering become unnecessary and may be in many cases entire- 1y dispensed with, though of course this material can, if desired, be rolled or forged in the usual manner; third, in its greater thinness and fluidity, whereby fine steel castings can be the thin and thick parts of the casting. These characteristics of my improved steel render it specially adapted for the manufacture of steel V rolls to be used in place of chilled rolls; also, for casting guns and armor-plates, and for wheels for railroad-cars and street-cars, and for the railway plant generally; also, for the manufacture of various implements and parts of machinery, and for making articles known in the trade as steel toys, and for the larger edged tools, which, when cast of my improved steel, need only to be ground, as they can be used without forging or tempering.
In carrying my invention into effect the ordinary form-manganese of commerce may be used but I prefer in all cases a rich ferromangauese as high as possible in manganese, containing about eighty per cent. of manganese, and as low as possible in carbon, silicon, and other foreign bodies. And here I may remark that my improved process for the manufacture of steel renders the presence of silicon unnecessary for producing soundness.
The form-manganese to be used in my process is first carefully melted in a reverberat i'ng or other suitable furnace before adding it to the molten dccarburized iron or steel, into which it is poured in a melted or hi ghly-heated state.
I need not describe the process of preparing the iron or steel for receiving the addition of manganese, as such processes are well known, and my invention is applicable to any method of melting and dccarburizing cast-iron or making steel in rcverbcrating or other furnaces, and by the Bessemer process, or that known as the open-hearth process. Then the metal is decarburized, or nearly so, or the steel melted, as the case may be, in any desired manner, the melted or heated form-manganese is poured into it, or the melted dccarburized metal or steel may be poured into the melted term-manganese. The mixed molten mass is then well stirred by any known means, so as to incorporate the manganese thoroughly with the molten decarburized iron or the steel. Then this has been effected, nothing remains but to pour out my improved steel thus produced into ingot or other suitable molds, when, after cooling, it is ready for use without tempering, rolling, forging, or hardening, though it may be forged or rolled in the usual manner.
It remains only to state the proportions in which the manganese should be mixed with the iron or steel to produce the desired result. This will depend on the purpose for which the steel is desired to be used. To produce a steel suitable for armor-plates, I add such a quantity of rich ferro-manganese (containing about eighty per cent. of manganese) as to obtain in the steel, decarburized iron, &c., under treatment aboutten per cent. of manganese. If the steel is to be used for making car-wheels or railway-plant, I add such a quantity of ferro-manganese which yields a steel containing about eleven per cent. of manganese. In edge-tools and steel toys I add such a quantity of ferro-mang anese as to obtain a steel containing about twelve per cent. of manganese. More or less ferro-manganese may be used, according to the hardness of steel required. The range of proportions which I have ,found to produce beneficial invention, is from about seven to twenty per cent. of manganese.
The steel thus produced I have found to be harder, stronger, denser, and. tougher than steel now made, even when the latter has been forged and rolled.
I am aware that in British Patent No. 1, 728 of 1863 it proposed to combine with crushed iron ores as much oxide or carbonate of manganese as will produce a metal containing five to eight per cent. of metallic manganese; but this differs from my improvement not only in the process, but also because it is inapplicable to the manufacture of steel, for the reason that the resultant product would contain too 5 high a percentage of carbon to make steel.
I herein refer in the claims to the use of ferro-manganese containing eighty'per cent. of manganese; butI do not limit myself to the percentage of ferro-manganese therein given, because if it is less rich .in manganese the amount added to the molten metal must beincreased proportionately, in order that the resultant product shall contain the proper amount of manganese. I
Having thus described my improvement, whatI claim as my invention, and desire to secure by Letters Patent, is-
1. In the process of making steel, adding to and thoroughly mixing with the molten steel from eight to twenty-five per cent. of melted ferro-mangane'se containing eighty per cent. of manganese, whereby the resultant product shall contain from about seven to twenty per cent. of manganese, substantially as and for the purposes described.
2. The process of making steel, consisting of adding to molten pig metal previously either wholly or partially decarburized by any desired method from eight to twenty-five per cent. of melted ferro-manganese containing eighty per cent. of manganese, whereby the resultant product shall contain from about seven to twenty per cent. of manganese, substantially as and for the purposes described.
In testimony whereof I have hereunto set -my hand this 15th day of January, A. D. 1884.
ROBERT HADFIELD.
Publications (1)
Publication Number | Publication Date |
---|---|
US303150A true US303150A (en) | 1884-08-05 |
Family
ID=2372322
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US303150D Expired - Lifetime US303150A (en) | Egbert hadfield |
Country Status (1)
Country | Link |
---|---|
US (1) | US303150A (en) |
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0
- US US303150D patent/US303150A/en not_active Expired - Lifetime
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