US3013966A - Textile lubricants - Google Patents

Textile lubricants Download PDF

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Publication number
US3013966A
US3013966A US18233A US1823360A US3013966A US 3013966 A US3013966 A US 3013966A US 18233 A US18233 A US 18233A US 1823360 A US1823360 A US 1823360A US 3013966 A US3013966 A US 3013966A
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US
United States
Prior art keywords
oil
textile
butyl
mineral oil
glycerol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US18233A
Other languages
English (en)
Inventor
Knapel F Schiermeier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell USA Inc
Original Assignee
Shell Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE601845D priority Critical patent/BE601845A/xx
Priority to NL262835D priority patent/NL262835A/xx
Application filed by Shell Oil Co filed Critical Shell Oil Co
Priority to US18233A priority patent/US3013966A/en
Priority to DES73175A priority patent/DE1244321B/de
Priority to FR856911A priority patent/FR1302405A/fr
Priority to GB11079/61A priority patent/GB930336A/en
Application granted granted Critical
Publication of US3013966A publication Critical patent/US3013966A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104—Aromatic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106—Naphthenic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

  • This invention relates to textile lubricants for processing various natural and synthetic fibers. More particularly, this invention is directed to mineral oil compositions, for use in processing various types of fibers, which compositions are stable, non-corrosive, prevent staining and size build-up and which possess good scourability properties.
  • suitable textile lubricants the art discloses mineral oils containing small amounts of soap or sulfonates or mixtures of soaps and fats or derivatives thereof.
  • these lubricants tend .to cause staining, size build-up and they possess poor scoura-bility properties.
  • a textile lubricant for processing nylon has been developed which is the subject of US. Patent 2,913,407.
  • the lubricants described therein are restricted to processing nylon fibers and therefore their use is limited.
  • an excellent multifunctional textile lubricant is provided by a highly refined, essentially aromatic-containing light mineral oil having a viscosity range of 100 F. SUS of from 30 to 200 and preferably from 50 to 150, containing an additive combination, in small but critical amounts of (a) an oil-soluble alkali metal, e.g. Na or K petroleum sulfonate having a molecular weight range of from about 300 to about 900, preferably from about 350 to about 450, (b) a partial ester derived from simple alkanepolyols and fatty acids of at least 12, preferably 14-18 carbon atoms, a highly sulfurized hydrocarbon and (d) an alkyl phenol.
  • an oil-soluble alkali metal e.g. Na or K petroleum sulfonate having a molecular weight range of from about 300 to about 900, preferably from about 350 to about 450
  • oil-soluble alkali metal petroleum sulfonates (a) are well known in the art and are prepared by reacting a mineral oil with concentrated or fuming sulfuric acid to form oil-soluble sulfonic acids which are then recovered by treatment with an alkali metal base such as sodium hydroxide followed by extraction.
  • alkali metal base such as sodium hydroxide followed by extraction.
  • These oil-soluble soaps are available as 30% to 70% concentrates in mineral oil and are used preferably in an amount of from about 0.01% to about 0.5%, preferably from about 0.05% to about 0.2% by weight.
  • the second essential additive (b) is a partial ester of a simple alkanepolyol and a C1248 saturated or unsaturated fatty acid.
  • the alkanepolyols include alkylene glycols e.g. ethylene or propylene glycol, glycerol, erythritol, pentaerythritol, sorbitol, mannitol and the like.
  • the acids which can be used to make the partial esters from any of the above alcohols include saturated and unsaturated fatty acids of from 12 to 18 carbon atoms, such as lauric, myristic, stearic, oleic, linoleic, linolenic and ricinoleic acids. These partial esters are used in an amount of from 0.25% to about 3%, preferably from about .5% to about 1.5% by weight.
  • esters derived from simple alkanepolyols and long chain fatty acids include glycerol monooleate, glycerol monostearate, glycerol monoricinoleate, pentaerythritol mono and dilaurate, pentaerythritol monoand dioleate, pentaerythritol monoand distearatmono-, diand triethylene glycol monooleate, propylene glycol monoricinoleate, ethylene glycol monooleate, triethylene glycol monostearate, sorbitol monolaurate, mannitol monooleate, mannitol dioleate, sorbitol dioleate, etc.
  • the highly sulfurized hydrocarbon product (c) include hydrocarbons such as olefins, mineral oils, terpenes and the like which have been reacted with sulfur under a minimum elevated temperature of 100 C. until the sulfur content of the treated hydrocarbon is at least 20%, preferably about 30%, more preferred being in the range of 30 to 40% sulfur.
  • the hydrocarbons thus treated are olefinic hydrocarbons such as polyolefins, e.g.
  • the sulfurization may be prepared by any of the accepted methods of sulfurizing unsaturated hydrocarbons such as by the direct combination with sulfur at atmospheric or superatomspheric pressures or with sulfur under pressure of hydrogen sulfide or the like.
  • a particularly suitable material is available under the trade name Stan-Add 48 from Standard Oil Co.
  • (1nd.) is a sulfurized hydrocarbon having the following properties: specific gravity1.165; flash, F.- 250; pour, F.--50; viscosity, SUS at 210 F.--l50; percent sulfur--34.7%.
  • This additive is used in amounts of from 0.01% to about 0.5%, preferably from about 0.1% to about 0.2% by weight.
  • the final essential additive (d) is an alkyl phenol and included are monoand bisphenols, preferably phenols containing at least one and preferably two tertiary alkyl radicals.
  • Phenols of this type include 2,4, 2,6, 2,4,6- tert-butyl phenol, 2,4-ditert-butyl-6-methyl-, 2,6-ditertbutyl-4-methyl, 2,4,6-tritert-butyl-, 2,6-dicyclohexyl-4- tertbutyl-, 2,6-tertoctyl-4-cyclohexyl-phenols, 2,6-ditertbutyl, 2,2-ditertbutyl, 2,6-tertbutylcyclohexyl, Z-methyl- 6-tertbutyl-4-methylphenols.
  • the alkyl bisphenols include 1,1 'bis( 2 hydroxy-3-tert-butyl-5-methylphenyl)- methane; bis(2-hydroxy-3-tert-butyl-5-methylphenyl)ethane; 1,l-bis(2-hydroxy-3-t-butyl-5-methylphenyl)butane; bis(2-hydroxy-3-t-butyl 5 methylphenyl)isobutane; 1,1- bis(6-hydroxy-5-t-butyl-3-methylphenyl)methane; bis(2- hydroxy-5-t-butyl-3-methylpheny1)ethane; 1,1 bis( 2 hydroxy 5 t butyl-3-methylphenyl)butane; 1,1-bis(2-hydroxy-S-t-amyl-3-methylphenyl)isobutane; etc.
  • 6-trialkyl phenols containing two tertiary alkyl groups in the 2,4- or 2,6-posit-ions are preferred, such as 2,4-ditertbutyl-6-methyl-, 2,6-ditert-butyl-4-methylphenol or 2,6- ditert-butyl-4-methylolphenol or 4,4'-methylene bis(2,6- dibutyl-phenol).
  • This additive is used in amounts of from about 0.1% to about 1%, preferably from about 0.3% to about 0.8% by weight.
  • the base oil is a highly refined mineral oil containing from 10% to 20% aromatics, a viscosity index of at least (90-120) and is in the viscosity range of from 30 to 200 SUS at F., preferably in the range of 40-150 SUS at 100 F.
  • a typical mineral oil (X) is a highly refined mineral oil having a viscosity index of about 95, an aromatic content .01? 10-15% and a viscosity in the range of 75-100 SUS at 100 F. which has been seleco tively solvent (phenol or furfural) refined.
  • composition D an oil composition similar to Example I was used except that the sulfurized hydrocarbon was omitted (Composition D), considerable build-up and wear occurred and the operation had to be stopped within a few days. Also no improvement to Composition D was noted when to Composition D a lightly sulfurized hydrocarbon, 1% S was added (Composition E) and it was used as a spindle oil under similar conditions as Composition D was used.
  • compositions of the present invention can be used as spindle oils, needle oils, textile processing oils, scouring oils and as general lubricants for textile processing equipment.
  • a textile lubricating composition consisting essentially of a highly refined lightmineral oil having a viscosity range at 100 SUS of from 30 to 200, containing from about 0.01% to about 5% of an oil-soluble alkali metal petroleum sulfonate, from about 0.01% to about 3% of a partial ester of a simple alkanepolyol selected from the group consisting of glycerol and pentaerythritol and a fatty acid having from 12 to 18 carbon atoms, from about 0.01% to about 0.5% of a highly sulfurized hydrocarbon and from about 0.1% to about 1% of a trialkyl phenol.
  • a textile lubricating composition consisting essentially of a highly refined light mineral oil having a viscosity range at 100' F. SUS of from 30 to 200, containing from about 0.01% to about 0.5% sodium petroleum sulfonate, from about 0.5% to about 3% of a partial ester of glycerol and a fatty acid having from 12 to 18 carbon atoms, from about 0.01% to about 0.5% of a highly sul' furized terpene hydrocarbon, and from about 0.1% of a trialkyl phenol.
  • a textile lubricating composition consisu'ng essentially of a highly refined mineral oil having a viscosity at 100 F. of 50-150, containing from about 0.05% to about 0.2% sodium petroleum sulfonate, from about 0.5% to about 1.5% of glycerol monooleate, from about 0.1% to about 0.2% of a highly sulfurized terpene hydro- 450) 0.2 Glycerol monoole 1.0 5 2,6-ditert-butyl-4-methylphenol 0.5 "Stan-Add 48 (sulfurized hydrocarbon, 34.7% 0 1 S) Mineral oil (X) Balance EXAMPLE n Percent by weight Sodium petroleum sulfonate (oil-soluble, M.W.
  • a textile lubricating composition consisting essentially of a highly refined mineral oil having a viscosity at 100' F. of 50-150, containing from about 0.05% to about 0.2% sodium petroleum sulfonate, from about 1% to about 2% of pentaerythritol monooleate, from about 0.1% to about 0.2% of a highly sulfurized terpene hydrocarbon and from about 0.3% to about 0.8% of 2,6-ditertbutyl-i'methylphenol.
  • a textile lubricating composition consisting essen- Table I Dom Cu and Composition Oxidation Storage Stability Beourebility Staining 0! Fiber Build-up Brass Cer- 250 It, (Room Temp.) rosion Min.)
  • Composition A--commercial textile oil comprising a mineral oil containing a soap. fatty oil, tstty acid and e lulionated vegeihi osltm B-minerel oil containing 107
  • Composition C-mineni oil containing 0. 0 Examples I and II were used as spindle oils in the processing of cotton and nylon fibers. The fibers and machine were in excellent condition with no signs of size build-up of damage to the machine after more lard than one 0.5% to about 1.5%
  • a textile lubricating composition consisting essentially of a highly refined mineral oil having a viscosity at 6 100' F of 50-150, containing from about 0.05% to about 2% sodium petroleum sulfonate, from about 0.5% to about 1.5% of glycerol monooleate, from about 0.1% to about 0.2% of a highly sulfurized terpene hydrocarbon and from about 0.3% to about 0.8% of 2,6-ditertbutyl- 10 4-methylolphenol.
  • a textile lubricating composition consisting essentially of a highly refined mineral oil having a viscosity 6 at 100' F. of 50-150, containing from about 0.05% to about 2% sodium petroleum sulfonate, from about 0.5% to about 1.5% of glycerol monooleate, from about 0.1% to about 0.2% of a highly sulfurized terpene hydrocarbon and from about 0.3% to about 0.8% of 4,4'-methylencbis(2,6-ditertbutyl phenol).

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Lubricants (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US18233A 1960-03-29 1960-03-29 Textile lubricants Expired - Lifetime US3013966A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BE601845D BE601845A (en)van) 1960-03-29
NL262835D NL262835A (en)van) 1960-03-29
US18233A US3013966A (en) 1960-03-29 1960-03-29 Textile lubricants
DES73175A DE1244321B (de) 1960-03-29 1961-03-27 Textilmaschinenoel
FR856911A FR1302405A (fr) 1960-03-29 1961-03-27 Lubrifiants pour textiles
GB11079/61A GB930336A (en) 1960-03-29 1961-03-27 Textile lubricants

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US18233A US3013966A (en) 1960-03-29 1960-03-29 Textile lubricants

Publications (1)

Publication Number Publication Date
US3013966A true US3013966A (en) 1961-12-19

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ID=21786901

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US18233A Expired - Lifetime US3013966A (en) 1960-03-29 1960-03-29 Textile lubricants

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US (1) US3013966A (en)van)
BE (1) BE601845A (en)van)
DE (1) DE1244321B (en)van)
GB (1) GB930336A (en)van)
NL (1) NL262835A (en)van)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4822542A (en) * 1985-02-21 1989-04-18 Japan Styrene Paper Corporation Method of production of expansion-molded article, from foamable thermoplastic resin particles and apparatus therefor
CN119968483A (zh) * 2022-10-05 2025-05-09 竹本油脂株式会社 合成纤维用处理剂以及合成纤维

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IN169084B (en)van) * 1986-09-26 1991-08-31 Du Pont
US5478485A (en) * 1994-06-16 1995-12-26 Henkel Kommanditgesellschaft Auf Aktien Thermally stable textile lubricants
US5464546A (en) * 1994-06-16 1995-11-07 Henkel Kommanditgesellschaft Auf Aktien Thermally stable textile lubricants
US6537662B1 (en) * 1999-01-11 2003-03-25 3M Innovative Properties Company Soil-resistant spin finish compositions

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2392891A (en) * 1943-09-30 1946-01-15 Standard Oil Co Stable sulphurized oils and the method of preparing same
US2443823A (en) * 1945-03-02 1948-06-22 Du Pont Sulfurized terpenes
US2913407A (en) * 1957-07-29 1959-11-17 Shell Dev Textile lubricants

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2392891A (en) * 1943-09-30 1946-01-15 Standard Oil Co Stable sulphurized oils and the method of preparing same
US2443823A (en) * 1945-03-02 1948-06-22 Du Pont Sulfurized terpenes
US2913407A (en) * 1957-07-29 1959-11-17 Shell Dev Textile lubricants

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4822542A (en) * 1985-02-21 1989-04-18 Japan Styrene Paper Corporation Method of production of expansion-molded article, from foamable thermoplastic resin particles and apparatus therefor
CN119968483A (zh) * 2022-10-05 2025-05-09 竹本油脂株式会社 合成纤维用处理剂以及合成纤维

Also Published As

Publication number Publication date
DE1244321B (de) 1967-07-13
GB930336A (en) 1963-07-03
BE601845A (en)van)
NL262835A (en)van)

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