US2986379A - Heat exchanger - Google Patents

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US2986379A
US2986379A US663544A US66354457A US2986379A US 2986379 A US2986379 A US 2986379A US 663544 A US663544 A US 663544A US 66354457 A US66354457 A US 66354457A US 2986379 A US2986379 A US 2986379A
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core
sheets
water
paper
passageways
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Kramig Anna Louise
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28CHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
    • F28C1/00Direct-contact trickle coolers, e.g. cooling towers
    • F28C1/02Direct-contact trickle coolers, e.g. cooling towers with counter-current only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/32Packing elements in the form of grids or built-up elements for forming a unit or module inside the apparatus for mass or heat transfer
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F25/00Component parts of trickle coolers
    • F28F25/02Component parts of trickle coolers for distributing, circulating, and accumulating liquid
    • F28F25/08Splashing boards or grids, e.g. for converting liquid sprays into liquid films; Elements or beds for increasing the area of the contact surface
    • F28F25/087Vertical or inclined sheets; Supports or spacers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322Basic shape of the elements
    • B01J2219/32203Sheets
    • B01J2219/32206Flat sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322Basic shape of the elements
    • B01J2219/32203Sheets
    • B01J2219/3221Corrugated sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322Basic shape of the elements
    • B01J2219/32203Sheets
    • B01J2219/32213Plurality of essentially parallel sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322Basic shape of the elements
    • B01J2219/32203Sheets
    • B01J2219/32224Sheets characterised by the orientation of the sheet
    • B01J2219/32227Vertical orientation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324Composition or microstructure of the elements
    • B01J2219/32425Ceramic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324Composition or microstructure of the elements
    • B01J2219/32458Paper
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2245/00Coatings; Surface treatments
    • F28F2245/08Coatings; Surface treatments self-cleaning
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/70Efficient control or regulation technologies, e.g. for control of refrigerant flow, motor or heating

Definitions

  • the principal object of the present invention is to provide a novel core for use in water cooling towers of this general type which will provide a maximum amount of cooling action in a minimum space and which even after extended periods of use, will not deteriorate or become covered with fungus growth.
  • the present invention contemplates a heat exchange core comprising a plurality of sinuous, or corrugated, sheets separated by generally planar divider sheets.
  • the corrugated sheets and divider sheets are formed of an asbestos paper impregnated with a phenolic resin which is thermally set.
  • the corrugated sheets and divider sheets define a plurality of vertical tubular passageways, the sheets being oriented so that the asbestos fibers extend transversely of the passageways.
  • water is sprayed onto the core and flows downwardly through the tubular passageways. This water is contacted and cooled by streams of air flowing upwardly through the same passageways.
  • a heat exchange core of this type is substantially more efficient than comparable heating cores formed of wood, metal or the like. I have determined that this increased efficiency is due in part to the excellent wetability of an asbestos sheet impregnated with a thermally set phenolic resin. I have further determined that the orientation of asbestos fibers transverse to the passageways also contributes to the increased efliciency, since the transverse fibers tend to break up any stream of water causing the water to flow in a thin film over the entire surface of the sheet. Thus, the rate of water passage is retarded and a maximum surface of water is exposed to contact with the counter current air stream.
  • a heat exchanger of the present invention is also highly advantageous since it can be kept in use for an indefinite length of time without cleaning or repair.
  • the resin impregnated asbestos sheets are not aifected by contact with water and do not rot, corrode or deteriorate in any other manner.
  • an asbestos sheet having a thermally set phenolic resin is self-disinfecting; that is, the material inhibits fungus or other microorganic growth so that no slime coating forms on the heat exchanger in use.
  • This self-cleaning action of the core is extremely important since it prevents the water and ice , air passageways from becoming clogged so that the efliciency of the heat exchanger does not decrease with age.
  • a still further advantage of the present heat exchange unit is that it is economical to manufacture and install.
  • commercial asbestos papers having fibers running parallel to the length of the paper is first impregnated with a phenolic resin, such as Bakelite.
  • the impregnated sheet is then heated sufficiently to partially set the resin after which the sheet is corrugated.
  • this corrugated sheet is brought into contact with a similarly impregnated flat sheet, a layer of adhesive, such as polyvinyl acetate or a phenolic glue being applied between the two sheets.
  • the two sheets are pressed together with the adhesive between them and are heated in any suitable manner, such as by means of an infra-red heat oven to a sufiiciently high temperature to fully set the phenolic resin.
  • the composite corrugated and flat sheets are then cut to proper size for assembly into a contact core.
  • the contact core is fabricated by placing a plurality of composite sheets next to one another, the sheets being arranged so that the corrugated and flat sheets are alternated. Adjacent sheets are secured together by means of a suitable adhesive to produce a core subunit. Finally, these core sub-units are stacked together to form a heat exchanger core of any desired dimension. Alternatively, large sections of the composite sheets are stacked and glued together after the sheets have been finally set. The large sheet sections which are secured together in this manner form a large unit which can be sawed or otherwise cut to produce cores of the desired size.
  • Cores fabricated in this manner are very light in Weight and may be preassembled at the factory and readily transported to the installation site, where they can be erected by a relatively small labor force.
  • the cores are inherently rigid and self-supporting so that it is only necessary to support the edges of the core within the tower, eliminating the need for expensive supporting structure including perforated platforms or the like. Consequently, the present cores are not only economical to produce, but they are economical to install as well.
  • Figure 1 is a vertical cross sectional view in diagrammatic form of a water cooling tower constructed in accordance with the present invention
  • Figure 2 is a partial perspective view of a typical water-air contact core to be used in a tower, such as the tower shown in Figure 1;
  • Figure 3 is a vertical cross sectional view of a tower similar to the one shown in Figure 1, the section being taken at right angles to the section of Figure 1;
  • Figure 4 is an end view of a modified form of contact core which may be used in a tower such as that shown in Figure 3;
  • Figure 5 is an end view of a second modified form of contact core
  • Figure 6 is a diagrammatic view of equipment for the practice of the initial steps of the method of preparing phenolic res-in impregnated asbestos paper according to this invention
  • Figure 7 is a diagrammatic view of equipment for the practice of further steps in the manufacture of the contact core, utilizing paper made by the initial steps disclosed in Figure 6;
  • Figure 8 shows diagrammatically a cutting mechanism which may be placed at the right end of the apparatus shown in Figure 7 in lieu of the rolling mechanism;
  • Figure 9 is an enlarged side elevational View of the phenolic resin impregnated composite sheet as it emerges.
  • cooling tower 10 comprises a housing '11 of rectangular or other suitablecross section.
  • a water sump 12 is located at the bottom of the casing to receive and temporarily store the cooled water. Water is withdrawn from the sump and is delivered, to the place of use by means of a pump 13 having an intake line 14 connected to the sump and discharge line 15 leading to the apparatus (not shown) requiring cooling water.
  • Such apparatus may be a water cooled condenser for a refrigerating system, air conditioning system or the like.
  • Air is forced upwardly through housing 11 by any suitable means, such as blower 16 having an air intake 17 and an air discharge conduit 18 leading to the lower end of the housing.
  • Water is distributed or sprayed over the top of core 20 in any suitable way, such as by means of a rotatable spray head 22 which is turned at a predetermined rate to provide proper distribution of water over the top of the core.
  • Water is supplied to the spray head through an inlet pipe 23 which is connected to a source of water, such as the outlet connection of the condenser mentioned above.
  • Contact core 20 extends over substantially the entire cross section area of the housing and is supported at two or more of its edges by means of mounting brackets 24.
  • these mounting brackets are in the form of angle irons having a depending leg 25 secured to the inner wall of the housing and an inwardly extend-- ing leg 26 forming a supportfor the core.
  • These angle irons may either extend continuously along the side of the tower or may be in the form of a plurality of separate spaced angle irons, as shown in Figure 3.
  • contact core 20 is best shown in Figures 2 and 11.
  • contact core 20 comprises a plurality of assembled sub-core units 27. These sub-units 27 may be firmly adhered together as by gluing or by some suitable mechanical securance means; or alternatively, they may be assembled loosely together and held in place by the walls of housing 11. If desired, core 20 can be constructed as a single unitary structure.
  • each of the sub-units'27 com prises a plurality of sinuous or corrugated sheets 28 separated by generally planar divider sheets 30.
  • the divider sheets and corrugated sheets are joined together by means of any suitable adhesive, such as a polyvinyl acetate adhesive or a phenolic resin glue.
  • Corrugated sheets 28 and dividers 30 define a plurality of vertical passageways 31. The upper ends of the passageways are open to receive water from the spray head 22 and the lower ends of the tubular passageways are open to discharge water into sump 12 and to receive air from blower 16.
  • Both corrugated sheets 28 and divider sheets 30 are formed from asbestos paper impregnated with a phenolic resin, such as sheets 28 are bent to form from two to eight corrugations per inch.
  • the water to be cooled flows downwardly through the passageways or interstices 31 formed between the corrugations and the adjacent divider sheets.
  • the water thoroughly wets the sheets and is spread over the entire surface of the sheet by the transverse ridges formed by the horizontally oriented fibers. These fibers function very effectively to diffuse the water, to slightly impede its flow and to prevent the formation of any streams or rivulets.
  • air flows upwardly through the passageways so that a heat transfer is eifected between the air and water, and the water is further cooled by evaporative action.
  • modified core 32 comprises a plurality of sub-core units 33 constructed in substantially the same manner as the sub-core units of core 20 shown in Figure 2.
  • Each of the sub-cores includes alternate corrugated and planar sheets defining a plurality of vertical passageways as described above.
  • each of the sub-core units 33 has its lower surface cut in some suitable manner as by sawing. along a downwardly extending inclined plane so that each of the sub-units includes a short vertical edge 34 and a long edge 35.
  • the sub-units are alternately joined together along their short and long edges to form depending ridges 36 from which water drops from the core unit.
  • the function of the downwardly directed, or inverted, ridges 36 is to increase the efliciency of the blower by facilitating discharge of water from the core without interfering with air fiow upwardly through the core passageways.
  • the water when water passes through a core 32 having downwardly extending ridges which are preferably inclined approximately 60 from a horizontal plane, the water trickles from the lower edges of the tubular passageways and flows along the lower edges 37 of the sheets Comprising the sub-core units until the water reaches the lowermost point of the ridge from which it drops in the form of enlarged drops into sump 12.
  • the water is not picked up by the air from blower 16 as that air flows along horizontal passageways 38 between the ridges and passes upwardly into the vertical passageways.
  • the water is directed around the openings of the vertical passageways to the bottom edges 37 of the ridges so that the Water does not form a film over the bottom of the vertical air passageways which might block or interfere with the upward air flow.
  • Figure 5 shows a second form of modified core 40 comprising component core units 41.
  • component core units 41 include alternate corrugated and planar sheets forming vertical air passageways, as described above.
  • the lower surface of core subunits 41 converges upwardly toward the center of the sub-units so that twov downwardly directed semi-ridges 42 are formed.
  • complete ridges are formed which are generally similar to the ridges shown in Figure 4.
  • the manner in which water is discharged from core 40 to eliminate interference with the upward how of air is the same as that described above inconnection with the description of modified core 32.
  • modified core 43 includes, a plurality of sub-core units 44- which are glued or otherwise secured together.
  • the lower surface of each of the sub-core units 44 is sawed'or otherwise cut to form a centrally disposed downwardly directed ridge 45, the sides of which are preferably inclined at 60 from a horizontal plane. These ridges function to facilitate the discharge of water in the same manner as described above.
  • While'the precise size of the overall core unit is not critical, it.has been found that in some installations the core needbeionly fifty percent as large as previous cores of the same capacity.
  • a core of adequate capacity is 11 /2 inches by 27% inches by 27%.. inches, or about, 5.12 cu-. bic feet in size. Water is. circulated through this unit at approximatelyten gallons per minute.
  • the core size is 16 inches by 27% inchesby 27% inches. It 'is to be understood, of course, that these dimensions are merely given by way of example and that 'cores or other sizes may be employed.
  • heat exchanger'cores are constructed by the. present 'method is best illustrated in Figures .6. and7-..- As there shown; the starting-material. is in the form of aroll 460i commercial asbestos paper.
  • the paper is fed..from roll 46 through guiding rollers 47 and under'e rollers 48 mounted within bath 50.
  • This bath contains an initially soluble phenolic resin, preferably a phenol formaldehyde condensation product, commercially known as Bakelite, dissolved in isopropyl alcohol in the proportion of two parts of phenolic resin to one part of 91% isopropyl alcohol.
  • the absorption'of the-phenolic resin solution in the asbestos paper is controlled by the squeezing action of a pair of squeeze rolls 51.. These rolls squeeze out ay portion ofthe solution absorbed by the paper and return it tobath 50 so as to leave a predetermined amount of phenolic resin absorbed in the paper.
  • the phenolic resin in the paper is between 25% and 40% by weight of the final product. A ratio now preferred is 34%.
  • Such phenolic resin is an irreversible thermo setting compound, which after the final stage is water insoluble, and coacts with theasbestos paper to prevent the formation of fungus slime when such product is used in a waterair contact core.
  • the impregnated sheet 52 leaving rolls 51 enters. an oven 53 wherethe. phenolic resin within the paperis heated and 'curedto aiBFstage, the paper remaining in a relatively flexible condition. For example, in one installation, the paper remains. approximately three minutes in theoven and is heated, to a temperature of 285 After the paper leaves oven 53, it passes through pinch rolls 54 and thereafterpasses guiding rolls 55. Finally, the impregnated sheet is rolled into a roll 56 in which form it can be stored for future use in the method as disclosed in Figure 7,
  • Rolls 56 are used as a starting material for the process steps disclosed in Figure 7.
  • One such roll 56 is rot-atably mounted in any suitable manner at 57.
  • Another roll 58 which is preferably but not necessarily of the same weight and texture and impregnated and cured in the same manner as roll 56 is rotatably mounted at 60.
  • the B stage sheet 61 drawn from roll 56 passes over various guiding rolls 62, and then passes through the hot corrugating rolls 63, where the paper is corrugated and the resin is partially set.
  • the rolls preferably are maintained at 350 F. to 400 F.
  • the paper, which is corrugated to form 2 to 8 corrugations per running inch leaves the rolls 63 and passes over a support roll 64.
  • the impregnated sheet 65 leaving the roll 58, passes under guiding roll 66 and travels over an adhesive applicator 67 which includes an applying roll 68, a dipping roll 70 and an adhesive container 71.
  • the cement or ahesive in container 71 may be a polyvinyl acetate adhesive, or a phenolic resin glue of any suitable type.
  • the paper with the adhesive applied thereto, and now indicated by the numeral 72, passes around roll 73 and over support roll 64. Sheet 72 passes between roll 64 and the corrugated sheet 74 and is pressed against 6 the corrugated-sheet .74, .With' the adhesive being disposed between the sheets The sheets are firmly adhered.
  • oven 76 maybe an infra-red oven which heats the composite sheet to a temperature of approximately 400 F.
  • the composite sheet now indicated by the numeral 77 leavesthe oven 76 and is rolled into-a roll 78 for future use.
  • roll 78' asa 'cylindrical contact core
  • another adhesive applicator 8t ⁇ simi- 1ar;to applicator 67
  • Its applying roll :81 applies. anadhesive to the underside of the composite sheet 77, so the variouslayers of the composite sheet within theroll 78 are glued'to each other, and such roll can be use.d,;as a cylindrical contact core, or may be sawed to'different lengths for use as shorter cont-act cores.
  • roll '81 is omitted when it is desired to subsequently unwind roll'50 to produce cores of a rectangular cross section.
  • Roll 81 is also omitted when it is desiredrto make arcylindrical core which is held in assembled relationship by a mechanical means, such as tie bands. More specifically, such a core is formed by winding composite sheet 77convolutely upon itself to form a cylinder of the desired' diameter. The material is then held in this cylindrical shape by applying tie bands or bails formed of aluminum or the like around the circumference of the cylinder;
  • .cutting mechanism 82 shown in Figure 8 may be substituted for applicator roll 81 and winding means 83 at the right end of oven 76.
  • sheet 77 leaving oven 76 is fed directly to the cutting mechanism 82 of Figure 8 which may include a longitudinally movable anvil 84, and a longitudinally' and downwardly movable knife 85, which moves down against composite sheet 77 to cut it into the desired lengths as determined by the frequency of operation of theknife 85.
  • the longitudinal movement of the anvil 84 and knife '85 is in the same direction and at substantially the same speed. of travel as composite sheet 77, so that there is no relative movement between these ele-' ments.
  • Such cutting mechanism, per se are well known in the art and need not be further described.
  • the composite sheet 77' leaving the oven 76 is shown in enlarged scale, in Figures 9 and 10.
  • the corrugated sheet 74 and the uncorrugated sheet 72 'which entered oven 76 are now indicated by the numerals 74a and 72a respectively in Figures 9 and 10.
  • the right angled relationship of the ridges formed by the asbestos fibers at the surface, with respect to the corrugation 86 of the paper 75a, is apparent in these enlarged figures.
  • The; ridges increase the relative surface area of the paper and hence the film of water wetting the paper, and also insure a thorough distribution of the water as it descends through the core.
  • the composite sheet 77 is relatively stiff and self-supporting and can be glued to form sub-core units 27 and cores 30 or the modified sub-cores and cores as described above.
  • a gas and liquid contact apparatus the combination with the elements of such an apparatus of a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said core comprising a plurality of composite sheets adhered together side by side, each of said composite sheets comprising two asbestos sheets, one of said asbestos sheets being corrugated, the other being substantially planar, each of said sheets being impregnated with a phenolic resin heated and cured in the sheet to an advanced stage of thermo setting.
  • a gas and liquid contact apparatus comprising a plurality of asbestos sheets disposed side by side and impregnated with thermally set phenolic resin, alternate sheets of said corev being. corrugated to. form a plurality of parallel passageways through said core, and the asbestos fibers in the said asbestos sheets being oriented at substantially right angles to the passageways to form ridges within the passageways.
  • a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said core comprising sheets of asbestos paper impregnated with a phenolic resin, said sheets being alternately corrugated .and planar and being secured in assembled relationship to form a plurality ofvertical passageways through the core of the size for the flow of gasand liquid therethrough.
  • a gas and liquid contact apparatus the combination with the elements of such anapparatus of a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said core comprising sheets of asbestos paper impregnated with a phenolic resin, the surface of said sheets substantially retaining the surface roughness of the asbestos paper prior to impregnation, said sheets being alternately corrugated and planar and being secured in assembled relationship to form a plurality of. vertical passageways through the core of the size for the flow of gas and liquid therethrough.
  • a gas and liquid contact apparatus the combination with the elements of such an apparatus of a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said core comprising sheets of asbestos paper impregnated with a resin, said sheets substantially displaying the surface roughness of the unimpre'gnated asbestos paper, whereby the surfaces of said sheets are wettable and are effective to retard liquid flow, said sheets being alternately corrugated and planar and being secured in assembled relationship to form a plurality of vertical passageways through the core of the size for the flow of gas and liquid therethrough.
  • a gas and liquid contact apparatus the combination with the elements of such an apparatus of a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said core comprising sheets of asbestos paper impregnated with a thermally set phenolic resin, the surface of said sheets substantially retaining the surface roughness of said un impregnated asbestos paper, said sheets being config urated and secured in assembled relationship to form a plurality of vertical passageways through the core of the size for the flow of gas and liquid therethrough.
  • a gas and liquid contact apparatus the combination with the elements of such an apparatus of a contact core andmeans for passing a gas and liquid through said core in intimate contact with one another, said core comprising sheets of asbestos paper approximately .015 inch thick impregnated with a thermally set phenolic resin, saidsheets being alternately corrugated and' planar and being secured in assembled; relationship to form a plurality. of vertical passageways'through. the core of the size for the flow of gas and liquid therethrough'.
  • the combi nation with the elements of such an apparatus. of a con tact core and means for passing a gas andliquid through said core in intimate contacttwith one anotherg'isaid core.
  • a con tact core comprising, a mass consisting essentiallygof paper arranged in plies, at least some of the plies'being corrugated, andthecorrugations'of such plies being arranged in parallel alignment, and the corrugations of the corru-l gated plies cooperating with an adjacent ply to'form pas-.
  • the said plies being constituted of thin asbestosfiber paper, the said paper being impregnated with a resin bonding together the asbestos fibers of which the paper is made, thereby rendering the paper physically inert to liquid to which said mass is exposed during use, but with the surfacesof the corrugations of said paper conforming substantially to the surface texture of conventionalunimpregnated asbestos paper, whereby the fibers relatively'exposed'at the surfaces of said asbestos paper present obstructions to films of liquid flowing over such surfaces and thereby promote the wettability of the surfaces of said corrugations by said liquid to increase the exposure of the liquid flowing through said passageways to gas also flowing through said passageways.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Description

y 1961 R. E. KRAMIG, JR 2,986,379
HEAT EXCHANGER Filed June 4, 1957 5 Sheets-Sheet 1 INVENTOR.
ROBERT E.KRAM|G,JR, DECEASED, BY ANNA LOUISE KRAMIG,EXECUTR|X BY zmxmzzzm 9 rzoguzya.
May 30, 1961 R. E. KRAMIG, JR
HEAT EXCHANGER 5 Sheets-Sheet 2 Filed June 4, 1957 10 INVENTOR.
ROBERT E. KRAMIG, JR.,DECEASED, BY ANNA LOUISE KRAMIG, EXECUTRIX BY ATTOENL-Y5.
May 30, 1961 R. E. KRAMIG, JR
HEAT EXCHANGER 5 Sheets-Sheet 3 Filed June 4, 1957 INVENTOR. ROBERT E, KRAMIG ,JR.,DECEASED BY ANNA LOUISE KRAMIG, EXECUTRIX BY MMM/W United States Patent O HEAT EXCHANGER Robert E. Kramig, Jr., deceased, late of Wyoming, Ohio, by Anna Louise Kramig, executrix, 615 S. Springfield Pike, Wyoming 15, Ohio Filed June 4, 1957, Ser. No. 663,544 8 Claims. (Cl. 261-28) This invention relates to heat exchangers and is particularly directed to novel core units for use in water cooling towers and to a method of fabricating such core units.
Heretofore, many diiierent types of heat exchangers have been proposed for use in connection with water cooling towers. In such devices, it is conventional to introduce air at the bottom of the exchanger and water at the top of the exchanger so that the water drips downwardly through a core member. At the same time, air is forced upwardly through the core to create a counter current flow in which the water is cooled by evaporative action.
The principal object of the present invention is to provide a novel core for use in water cooling towers of this general type which will provide a maximum amount of cooling action in a minimum space and which even after extended periods of use, will not deteriorate or become covered with fungus growth.
More particularly, the present invention contemplates a heat exchange core comprising a plurality of sinuous, or corrugated, sheets separated by generally planar divider sheets. In the preferred embodiment, the corrugated sheets and divider sheets are formed of an asbestos paper impregnated with a phenolic resin which is thermally set. The corrugated sheets and divider sheets define a plurality of vertical tubular passageways, the sheets being oriented so that the asbestos fibers extend transversely of the passageways. In use, water is sprayed onto the core and flows downwardly through the tubular passageways. This water is contacted and cooled by streams of air flowing upwardly through the same passageways.
A heat exchange core of this type is substantially more efficient than comparable heating cores formed of wood, metal or the like. I have determined that this increased efficiency is due in part to the excellent wetability of an asbestos sheet impregnated with a thermally set phenolic resin. I have further determined that the orientation of asbestos fibers transverse to the passageways also contributes to the increased efliciency, since the transverse fibers tend to break up any stream of water causing the water to flow in a thin film over the entire surface of the sheet. Thus, the rate of water passage is retarded and a maximum surface of water is exposed to contact with the counter current air stream.
A heat exchanger of the present invention is also highly advantageous since it can be kept in use for an indefinite length of time without cleaning or repair. The resin impregnated asbestos sheets are not aifected by contact with water and do not rot, corrode or deteriorate in any other manner.
Moreover, I have discovered that an asbestos sheet having a thermally set phenolic resin is self-disinfecting; that is, the material inhibits fungus or other microorganic growth so that no slime coating forms on the heat exchanger in use. This self-cleaning action of the core is extremely important since it prevents the water and ice , air passageways from becoming clogged so that the efliciency of the heat exchanger does not decrease with age.
A still further advantage of the present heat exchange unit is that it is economical to manufacture and install. In the present process of producing heat exchangers, commercial asbestos papers having fibers running parallel to the length of the paper, is first impregnated with a phenolic resin, such as Bakelite. The impregnated sheet is then heated sufficiently to partially set the resin after which the sheet is corrugated. Subsequently, this corrugated sheet is brought into contact with a similarly impregnated flat sheet, a layer of adhesive, such as polyvinyl acetate or a phenolic glue being applied between the two sheets. The two sheets are pressed together with the adhesive between them and are heated in any suitable manner, such as by means of an infra-red heat oven to a sufiiciently high temperature to fully set the phenolic resin. The composite corrugated and flat sheets are then cut to proper size for assembly into a contact core. The contact core is fabricated by placing a plurality of composite sheets next to one another, the sheets being arranged so that the corrugated and flat sheets are alternated. Adjacent sheets are secured together by means of a suitable adhesive to produce a core subunit. Finally, these core sub-units are stacked together to form a heat exchanger core of any desired dimension. Alternatively, large sections of the composite sheets are stacked and glued together after the sheets have been finally set. The large sheet sections which are secured together in this manner form a large unit which can be sawed or otherwise cut to produce cores of the desired size.
Cores fabricated in this manner are very light in Weight and may be preassembled at the factory and readily transported to the installation site, where they can be erected by a relatively small labor force. The cores are inherently rigid and self-supporting so that it is only necessary to support the edges of the core within the tower, eliminating the need for expensive supporting structure including perforated platforms or the like. Consequently, the present cores are not only economical to produce, but they are economical to install as well. I
These and other objects and advantages of the present invention will be more readily apparent from a considera-' tion of the following detailed description of the drawings illustrating a preferred embodiment of the invention.
In the drawings:
Figure 1 is a vertical cross sectional view in diagrammatic form of a water cooling tower constructed in accordance with the present invention;
Figure 2 is a partial perspective view of a typical water-air contact core to be used in a tower, such as the tower shown in Figure 1;
Figure 3 is a vertical cross sectional view of a tower similar to the one shown in Figure 1, the section being taken at right angles to the section of Figure 1;
Figure 4 is an end view of a modified form of contact core which may be used in a tower such as that shown in Figure 3;
Figure 5 is an end view of a second modified form of contact core;
Figure 6 is a diagrammatic view of equipment for the practice of the initial steps of the method of preparing phenolic res-in impregnated asbestos paper according to this invention;
Figure 7 is a diagrammatic view of equipment for the practice of further steps in the manufacture of the contact core, utilizing paper made by the initial steps disclosed in Figure 6;
Figure 8 shows diagrammatically a cutting mechanism which may be placed at the right end of the apparatus shown in Figure 7 in lieu of the rolling mechanism;
Figure 9 is an enlarged side elevational View of the phenolic resin impregnated composite sheet as it emerges.
embodying the present invention is shown in Figure 1. As
there shown, cooling tower 10 comprises a housing '11 of rectangular or other suitablecross section. A water sump 12 is located at the bottom of the casing to receive and temporarily store the cooled water. Water is withdrawn from the sump and is delivered, to the place of use by means of a pump 13 having an intake line 14 connected to the sump and discharge line 15 leading to the apparatus (not shown) requiring cooling water. Such apparatus may be a water cooled condenser for a refrigerating system, air conditioning system or the like.
Air is forced upwardly through housing 11 by any suitable means, such as blower 16 having an air intake 17 and an air discharge conduit 18 leading to the lower end of the housing. The air'rises upwardly through the housing and passes upwardly through a core 20, the construction of which is explained in detail below. After the air has passed through core. 20, it is eventually discharged from housing 11 through an exhaust stack 21.
Water is distributed or sprayed over the top of core 20 in any suitable way, such as by means of a rotatable spray head 22 which is turned at a predetermined rate to provide proper distribution of water over the top of the core. Water is supplied to the spray head through an inlet pipe 23 which is connected to a source of water, such as the outlet connection of the condenser mentioned above. Contact core 20 extends over substantially the entire cross section area of the housing and is supported at two or more of its edges by means of mounting brackets 24. In the embodiment shown, these mounting brackets are in the form of angle irons having a depending leg 25 secured to the inner wall of the housing and an inwardly extend-- ing leg 26 forming a supportfor the core. These angle irons may either extend continuously along the side of the tower or may be in the form of a plurality of separate spaced angle irons, as shown in Figure 3.
One preferred form of contact core. 20 is best shown in Figures 2 and 11. As there shown, contact core 20 comprises a plurality of assembled sub-core units 27. These sub-units 27 may be firmly adhered together as by gluing or by some suitable mechanical securance means; or alternatively, they may be assembled loosely together and held in place by the walls of housing 11. If desired, core 20 can be constructed as a single unitary structure.
As shown in Figure 2, each of the sub-units'27 com prises a plurality of sinuous or corrugated sheets 28 separated by generally planar divider sheets 30. The divider sheets and corrugated sheets are joined together by means of any suitable adhesive, such as a polyvinyl acetate adhesive or a phenolic resin glue. Corrugated sheets 28 and dividers 30 define a plurality of vertical passageways 31. The upper ends of the passageways are open to receive water from the spray head 22 and the lower ends of the tubular passageways are open to discharge water into sump 12 and to receive air from blower 16. Both corrugated sheets 28 and divider sheets 30 are formed from asbestos paper impregnated with a phenolic resin, such as sheets 28 are bent to form from two to eight corrugations per inch.
In operation, the water to be cooled flows downwardly through the passageways or interstices 31 formed between the corrugations and the adjacent divider sheets. The water thoroughly wets the sheets and is spread over the entire surface of the sheet by the transverse ridges formed by the horizontally oriented fibers. These fibers function very effectively to diffuse the water, to slightly impede its flow and to prevent the formation of any streams or rivulets. At the same time that water drips downwardly over the core surface, air flows upwardly through the passageways so that a heat transfer is eifected between the air and water, and the water is further cooled by evaporative action.
A modified form of core is shown in Figure 4. As there shown, modified core 32 comprises a plurality of sub-core units 33 constructed in substantially the same manner as the sub-core units of core 20 shown in Figure 2. Each of the sub-cores includes alternate corrugated and planar sheets defining a plurality of vertical passageways as described above.
However, in modified core 32, each of the sub-core units 33 has its lower surface cut in some suitable manner as by sawing. along a downwardly extending inclined plane so that each of the sub-units includes a short vertical edge 34 and a long edge 35. The sub-units are alternately joined together along their short and long edges to form depending ridges 36 from which water drops from the core unit. The function of the downwardly directed, or inverted, ridges 36 is to increase the efliciency of the blower by facilitating discharge of water from the core without interfering with air fiow upwardly through the core passageways.
More particularly, when water passes through a core 32 having downwardly extending ridges which are preferably inclined approximately 60 from a horizontal plane, the water trickles from the lower edges of the tubular passageways and flows along the lower edges 37 of the sheets Comprising the sub-core units until the water reaches the lowermost point of the ridge from which it drops in the form of enlarged drops into sump 12. Thus, the water is not picked up by the air from blower 16 as that air flows along horizontal passageways 38 between the ridges and passes upwardly into the vertical passageways. It will be appreciated that the water is directed around the openings of the vertical passageways to the bottom edges 37 of the ridges so that the Water does not form a film over the bottom of the vertical air passageways which might block or interfere with the upward air flow.
Figure 5 shows a second form of modified core 40 comprising component core units 41. These component core units include alternate corrugated and planar sheets forming vertical air passageways, as described above. However, in modified core 40, the lower surface of core subunits 41 converges upwardly toward the center of the sub-units so that twov downwardly directed semi-ridges 42 are formed. When the sides of adjacent sub-units 41 are brought together, complete ridges are formed which are generally similar to the ridges shown in Figure 4. The manner in which water is discharged from core 40 to eliminate interference with the upward how of air is the same as that described above inconnection with the description of modified core 32.
A third modified form of core 4 3 is shown in Figure 12. As; there shown, modified core 43. includes, a plurality of sub-core units 44- which are glued or otherwise secured together. In this embodiment, the lower surface of each of the sub-core units 44 is sawed'or otherwise cut to form a centrally disposed downwardly directed ridge 45, the sides of which are preferably inclined at 60 from a horizontal plane. These ridges function to facilitate the discharge of water in the same manner as described above.
While'the precise size of the overall core unit is not critical, it.has been found that in some installations the core needbeionly fifty percent as large as previous cores of the same capacity. For example, for one. three-ton air conditioning unit, a core of adequate capacity is 11 /2 inches by 27% inches by 27%.. inches, or about, 5.12 cu-. bic feet in size. Water is. circulated through this unit at approximatelyten gallons per minute. For a five ton refrigeratingunit, the core size is 16 inches by 27% inchesby 27% inches. It 'is to be understood, of course, that these dimensions are merely given by way of example and that 'cores or other sizes may be employed.
The manner in which heat exchanger'cores are constructed by the. present 'method is best illustrated in Figures .6. and7-..- As there shown; the starting-material. is in the form of aroll 460i commercial asbestos paper. One prefrredgmaterial is six pound asbestos paper, .015 inch thick having an asbestos stock fiber and a sulphite and starch binder constituting approximately 7% by weightoflthe paper,=the remaining 93% being pure asbestos fibers which run lengthwise of the paper.
The paper is fed..from roll 46 through guiding rollers 47 and under'e rollers 48 mounted within bath 50. This bath contains an initially soluble phenolic resin, preferably a phenol formaldehyde condensation product, commercially known as Bakelite, dissolved in isopropyl alcohol in the proportion of two parts of phenolic resin to one part of 91% isopropyl alcohol.
. The absorption'of the-phenolic resin solution in the asbestos paper is controlled by the squeezing action of a pair of squeeze rolls 51.. These rolls squeeze out ay portion ofthe solution absorbed by the paper and return it tobath 50 so as to leave a predetermined amount of phenolic resin absorbed in the paper. When the paper reaches its final stage, later to be described, the phenolic resin in the paper is between 25% and 40% by weight of the final product. A ratio now preferred is 34%. Such phenolic resin is an irreversible thermo setting compound, which after the final stage is water insoluble, and coacts with theasbestos paper to prevent the formation of fungus slime when such product is used in a waterair contact core.
- The impregnated sheet 52 leaving rolls 51 enters. an oven 53 wherethe. phenolic resin within the paperis heated and 'curedto aiBFstage, the paper remaining in a relatively flexible condition. For example, in one installation, the paper remains. approximately three minutes in theoven and is heated, to a temperature of 285 After the paper leaves oven 53, it passes through pinch rolls 54 and thereafterpasses guiding rolls 55. Finally, the impregnated sheet is rolled into a roll 56 in which form it can be stored for future use in the method as disclosed in Figure 7,
Rolls 56 are used as a starting material for the process steps disclosed in Figure 7. One such roll 56 is rot-atably mounted in any suitable manner at 57. Another roll 58 which is preferably but not necessarily of the same weight and texture and impregnated and cured in the same manner as roll 56 is rotatably mounted at 60. The B stage sheet 61 drawn from roll 56 passes over various guiding rolls 62, and then passes through the hot corrugating rolls 63, where the paper is corrugated and the resin is partially set. The rolls preferably are maintained at 350 F. to 400 F. The paper, which is corrugated to form 2 to 8 corrugations per running inch leaves the rolls 63 and passes over a support roll 64.
Meanwhile, the impregnated sheet 65, leaving the roll 58, passes under guiding roll 66 and travels over an adhesive applicator 67 which includes an applying roll 68, a dipping roll 70 and an adhesive container 71. The cement or ahesive in container 71 may be a polyvinyl acetate adhesive, or a phenolic resin glue of any suitable type. The paper with the adhesive applied thereto, and now indicated by the numeral 72, passes around roll 73 and over support roll 64. Sheet 72 passes between roll 64 and the corrugated sheet 74 and is pressed against 6 the corrugated-sheet .74, .With' the adhesive being disposed between the sheets The sheets are firmly adhered. or glued to each other, to form a composite sheet 75 which enters, oven 76'where the phenolic resin in the papers is brought to the final fully set or-Cstage. For this purpose, oven 76 maybe an infra-red oven which heats the composite sheet to a temperature of approximately 400 F. The composite sheet, now indicated by the numeral 77 leavesthe oven 76 and is rolled into-a roll 78 for future use. I
Alternatively, if. it is desired to. use roll 78' asa 'cylindrical contact core, another adhesive applicator 8t}, simi- 1ar;to applicator 67, is placed at the end of the oven. Its applying roll :81, applies. anadhesive to the underside of the composite sheet 77, so the variouslayers of the composite sheet within theroll 78 are glued'to each other, and such roll can be use.d,;as a cylindrical contact core, or may be sawed to'different lengths for use as shorter cont-act cores. s I a a --'It is 'to be understood that roll '81 is omitted when it is desired to subsequently unwind roll'50 to produce cores of a rectangular cross section. Roll 81 is also omitted when it is desiredrto make arcylindrical core which is held in assembled relationship by a mechanical means, such as tie bands. More specifically, such a core is formed by winding composite sheet 77convolutely upon itself to form a cylinder of the desired' diameter. The material is then held in this cylindrical shape by applying tie bands or bails formed of aluminum or the like around the circumference of the cylinder;
As a further alternative, .cutting mechanism 82 shown in Figure 8 may be substituted for applicator roll 81 and winding means 83 at the right end of oven 76. In such an installation, sheet 77 leaving oven 76 is fed directly to the cutting mechanism 82 of Figure 8 which may include a longitudinally movable anvil 84, and a longitudinally' and downwardly movable knife 85, which moves down against composite sheet 77 to cut it into the desired lengths as determined by the frequency of operation of theknife 85. The longitudinal movement of the anvil 84 and knife '85 is in the same direction and at substantially the same speed. of travel as composite sheet 77, so that there is no relative movement between these ele-' ments. Such cutting mechanism, per se, are well known in the art and need not be further described.
The composite sheet 77' leaving the oven 76 is shown in enlarged scale, in Figures 9 and 10. The corrugated sheet 74 and the uncorrugated sheet 72 'which entered oven 76 are now indicated by the numerals 74a and 72a respectively in Figures 9 and 10. The right angled relationship of the ridges formed by the asbestos fibers at the surface, with respect to the corrugation 86 of the paper 75a, is apparent in these enlarged figures. The; ridges increase the relative surface area of the paper and hence the film of water wetting the paper, and also insure a thorough distribution of the water as it descends through the core. The composite sheet 77 is relatively stiff and self-supporting and can be glued to form sub-core units 27 and cores 30 or the modified sub-cores and cores as described above.
Having described my invention I claim:
I. In a gas and liquid contact apparatus, the combination with the elements of such an apparatus of a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said core comprising a plurality of composite sheets adhered together side by side, each of said composite sheets comprising two asbestos sheets, one of said asbestos sheets being corrugated, the other being substantially planar, each of said sheets being impregnated with a phenolic resin heated and cured in the sheet to an advanced stage of thermo setting.
2. In a gas and liquid contact apparatus, the combination with the elements of such an apparatus of a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said contact core comprising a plurality of asbestos sheets disposed side by side and impregnated with thermally set phenolic resin, alternate sheets of said corev being. corrugated to. form a plurality of parallel passageways through said core, and the asbestos fibers in the said asbestos sheets being oriented at substantially right angles to the passageways to form ridges within the passageways.
3. In a gas and liquid contact apparatus, the combination with the elements of such an apparatus of .a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said core comprising sheets of asbestos paper impregnated with a phenolic resin, said sheets being alternately corrugated .and planar and being secured in assembled relationship to form a plurality ofvertical passageways through the core of the size for the flow of gasand liquid therethrough.
4. In a gas and liquid contact apparatus, the combination with the elements of such anapparatus of a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said core comprising sheets of asbestos paper impregnated with a phenolic resin, the surface of said sheets substantially retaining the surface roughness of the asbestos paper prior to impregnation, said sheets being alternately corrugated and planar and being secured in assembled relationship to form a plurality of. vertical passageways through the core of the size for the flow of gas and liquid therethrough.
5. In a gas and liquid contact apparatus, the combination with the elements of such an apparatus of a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said core comprising sheets of asbestos paper impregnated with a resin, said sheets substantially displaying the surface roughness of the unimpre'gnated asbestos paper, whereby the surfaces of said sheets are wettable and are effective to retard liquid flow, said sheets being alternately corrugated and planar and being secured in assembled relationship to form a plurality of vertical passageways through the core of the size for the flow of gas and liquid therethrough.
6. In a gas and liquid contact apparatus, the combination with the elements of such an apparatus of a contact core and means for passing a gas and liquid through said core in intimate contact with one another, said core comprising sheets of asbestos paper impregnated with a thermally set phenolic resin, the surface of said sheets substantially retaining the surface roughness of said un impregnated asbestos paper, said sheets being config urated and secured in assembled relationship to form a plurality of vertical passageways through the core of the size for the flow of gas and liquid therethrough.
7. In a gas and liquid contact apparatus, the combination with the elements of such an apparatus of a contact core andmeans for passing a gas and liquid through said core in intimate contact with one another, said core comprising sheets of asbestos paper approximately .015 inch thick impregnated with a thermally set phenolic resin, saidsheets being alternately corrugated and' planar and being secured in assembled; relationship to form a plurality. of vertical passageways'through. the core of the size for the flow of gas and liquid therethrough'.
8. In a gas and liquid contact apparatus, the combi nation with the elements of such an apparatus. of a con tact core and means for passing a gas andliquid through said core in intimate contacttwith one anotherg'isaid core. comprising, a mass consisting essentiallygof paper arranged in plies, at least some of the plies'being corrugated, andthecorrugations'of such plies being arranged in parallel alignment, and the corrugations of the corru-l gated plies cooperating with an adjacent ply to'form pas-. sageways extending continuously from an upper surface of the mass to a lower surface of the mass through'which passageways liquid and gas may flowin contact with one another, the said plies being constituted of thin asbestosfiber paper, the said paper being impregnated with a resin bonding together the asbestos fibers of which the paper is made, thereby rendering the paper physically inert to liquid to which said mass is exposed during use, but with the surfacesof the corrugations of said paper conforming substantially to the surface texture of conventionalunimpregnated asbestos paper, whereby the fibers relatively'exposed'at the surfaces of said asbestos paper present obstructions to films of liquid flowing over such surfaces and thereby promote the wettability of the surfaces of said corrugations by said liquid to increase the exposure of the liquid flowing through said passageways to gas also flowing through said passageways.
References Cited in the file of this patent UNITED STATES PATENTS 639,523 Chapin Dec. 19, 1899 869,747 Starr Oct. 29, 1907 941,605 Baekeland Nov. 30, 1909 1,695,912 Brown Dec. 18, 1928 2,035,970 Maclldowie Mar. 31, 1936 2,104,060 Spatford Q. Jan. 4, 1938 2,231,088 Richardson Feb. 11, 1941 2,434,466 Marc Jan. 13, 1948 2,609,314 Engel et a1. Sept. 2, 1952 2,661,197 Norman Dec. 1, 1953 2,793,017 Lake May 21, 1957 2,809,818 Munters Oct. 15, 1957 FOREIGN PATENTS 550,561 Great Britain Ian. 14, 1943 571,510 Great Britain Aug. 28, 1945
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