US2976243A - Stable calcium acetate-mineral oil dispersion - Google Patents
Stable calcium acetate-mineral oil dispersion Download PDFInfo
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- US2976243A US2976243A US693820A US69382057A US2976243A US 2976243 A US2976243 A US 2976243A US 693820 A US693820 A US 693820A US 69382057 A US69382057 A US 69382057A US 2976243 A US2976243 A US 2976243A
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- calcium acetate
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M5/00—Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
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- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/286—Esters of polymerised unsaturated acids
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/26—Amines
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Definitions
- -' sponding T represents tertiary alkyl primary amines.
- This invention relates to lubricating oil compositions containing stabilized dispersions of calcium acetate. Particularly, it relates to lubricating oil compositions containingcalcium acetate and a tertiary alkyl amine as a stabilizing agent.
- Simple dispersion of calcium acetate, in lubricating oil imparts load-carrying ability and anti-wear properties to the oil. But, simple dispersions of this type are unstable and upon storage the metal salt settles out of the composition.
- One proposed method of forming more stable lubricants is by emulsifying a water solution of calcium acetate into lubricating oil. However, such emulsions are not completely satisfactory since they are rather corrosive because of their water content and are still somewhat unstable, tending to separate upon storage over long periods. It had also been proposed to dehydrate the emulsion type of material. While this reduces the danger of corrosion, it still results in an unstable product and unless the dehydration is carefully controlled, a grainy unsatisfactory dispersion results.
- dispersions of calcium acetate in lubricating oil may be stabilized with a small quantity of certain amines.
- Such dispersions are relatively inexpensive, and yet because of their calcium acetate content, they have extremely good load-carrying and anti-wear properties.
- the amine material function as a stabilizing agent, but it also acts as an antioxidant to inhibit degradation of the oil.
- either grease compositions or fluid lubricants can be formed.
- Such greases can be used for general purpose lubrication, such as, ball and roller bearings, automotive chassis lubrication and other industrial applications.
- the fluid type lubricants can be used in the crankcase of internal combustion engines, and for lubricating the upper cylinders of marine diesel engines.
- metal salts and correacid-neutralizing ability are particularly useful when the engine is operating on an acid forming fuel, such as the high sulfur-content diesel fuels currently coming into favor for marine diesel use.
- the amines used as stabilizers include tertiary alkyl primary amines and tertiary alkyl polyalkyleneoxy amines. These materials maybe represented by the general formula:
- R, R, R" are straight or branched-chain alkyl radicals of 1 to 18 carbon atoms, the sum of R, R and R" being about 16 to 36, e.g. 17 to 23 carbon atoms; R is a C to C aliphatic hydrocarbonradical and x is 0 When x of the above formula is 0, then the. formula
- Such polymers and copolymers are well known synthetic olefins in the petroleum industry. However, in such polymerizations, various isomerizations l and migrations may occursuch that a mixture of olefins are produced. Thus, when making a tertiary alkyl pri-...
- tertiary alkyl primary amines which may be used include the following:
- the lubricating oil used in the compositions of the invention may be either a mineral lubricating oil or a synthetic lubricating oil. If synthetic oils are used, they are preferably used with a major amount of mineral oil. Synthetic oils which may be used include esters of monobasic acids (e.g. C oxo alcohol ester of C oxo acid), esters of dibasic acids (e.g. di-2-ethyl hexyl sebacate), esters of glycols (e.g. C oxo acid diester of tetraethylene glycol), complex esters, esters of phosphoric acid, halocarbon oils, silicones, polyglycol type synthetic oils;
- esters of monobasic acids e.g. C oxo alcohol ester of C oxo acid
- esters of dibasic acids e.g. di-2-ethyl hexyl sebacate
- esters of glycols e.g. C oxo acid die
- weight percent of the metal salt and about1.0 to 5.0 weight percent of the amine is used, while the fluid lubricants will generally contain about 2.5 to 8.0 weight percent salt and 0.5 to 5.0 weight percent amine. All of said weight percents being based on theweight of the total composition.
- Various other additives may also' be' added to the lubricating composition in amounts of about 0.1 to 10.0 weight percent, based on the total weight of the composition. Examples of such additives include oxidation inhibitors such as phony] alpha naphthylamine; viscosity index improvers such as polyisob utyleneicorrosion inhibitors such as sorbitan monooleate; pour depressants; dyes; detergents and the like.
- compositions of the 'invention will be prepared by neutralizing lime or calcium oxide with acetic acid or acetic anhydride in the presence of lubricating oil or-otherinertliquid dispersant.
- the mixture may then be heated to about 250 to 500 F. sufiicientto at least-evaporate any free water.
- the amine may also be present during this neutralization step or it may be added later.
- a preferred method consists of dispersing lime and the amine in the lubricating oil followed by addition of acetic acid or its anhydride.
- the mixture is then heated to a temperature of about 300 to 500 F. until complete dehydration occurs, i.e. anhydrous calcium acetate is formed.
- the product may then be cooled while stirring and any conventional additives can be added.
- T'he mixture may then be homogenized by passing it through a Gaulin homogenizer, a Charlotte mill, a Morehouse mill, etc.
- the mixture may be cut back with additional lubricating oil to form the final lubricant product which is further homogenized.
- the lubricating compositions may also be formed by simple mixing of calcium acetate and the amine into lubricating oil. However, this latter method is not preferred because of the difficulty of obtaining a fine dispersion of the calcium acetate.
- the lime, Primene IM-T, and lubricating oil were intimately mixed in a steam kettle.
- the acetic acid was then slowly added while mixing, the temperature during this time rising to about 220 F. with the formation of a heavy solid lubricant.
- Mixing was continued for an additional /2 hour and then heating was initiated to raise the temperature to about 320 F. This temperature was maintained for about 30 minutes in order to insure complete dehydration of the mixture and formation of anhydrous calcium acetate.
- the mixture was then cooled, while stirring, to about 100 F. after which it was passed through a Gaulin homogenizer operating at about 6000 p.s.i. shear.
- EXAMPLE II 20 weight percent of the final product of Example I was blended with an additional 80 weight percent of the mineral lubricating oil used in Example I. This blend was twice passed through a Gaulin homogenizer operating at 6000 p.s.i.
- EXAMPLE III A product containing 6.0 weight percent of calcium acetate, 1.0 weight percent of the C1844 tertiary alkyl primary amine mixture (Prirnene JM-T) and 93.0 weight percent of a mineral lubricating oil having a viscosity of 65 SUS at 210 F. was prepared in the manner of Example II, i.e. by first forming a concentrate of the calcium acetate in situ and then blending it with additional oil. This product was tested in a single cylinder Caterpillar 1A diesel test engine. This test was carried out for hours operating on a fuel containing one percent sulfur and using the Caterpillar l-A test procedure CRC-L-1-545. On completion of the test, the engine was inspected and the amount of wear and deposit formation determined. The results of this test was summarized in the following table along with comparable data on a solvent extracted Mid-Continent base stock used in a commercial heavy duty premium oil.
- compositions of the invention can serve as crankcase lubricants, having low deposit forming tendencies and yet at the same time substantially reducing wear.
- compositions can be prepared as follows:
- Example I is repeated but using 2.0 weight percent of S-amino-S,l3-dimethyl-hexadecane in place of the 2.0 wt. percent of Primene .lM-T.
- a dehydrated lubricating composition comprising a major portion of lubricating oil, about 2.5 to 30.0 wt. percent of anhydrous calcium acetate as the sole salt component and about 0.1 to 10.0 wt. percent of an amine having the general formula:
- a fluid dehydrated lubricating oil composition comprising a major portion of lubricating oil, about 2.5 to 8.0 wt. percent of anhydrous calcium acetate and about 0.5 to 5.0 wt. percent of an amine having the general formula:
- R, R and R" are C; to C alkyl radicals, and R, R and R combined contain a total of 16 to 36 carbon atoms.
- a method of preparing a stable dehydrated lubricating composition comprising a major portion of lubricating oil and containing calcium acetate as the sole salt component, which comprises neutralizing lime in said lubricating oil with a material selected from the group consisting of acetic acid and acetic acid anhydride, in the presence of a stabilizing amount of an amine having the general formula:
- RI R1110) II RI/lo) FH wherein R, R and R" are C to C alkyl radicals, and R, R and R combined contains a total of 16 to 36 carbon atoms, R is a C to C aliphatic hydrocarbon radical and x is 0 to 10.
Description
-' sponding T represents tertiary alkyl primary amines. can be prepared from tertiary olefins, e.g. the various poly- United States Patent 1 2,976,243 STABLE CALCIUM ACETATE-MINERAL 01L DISPERSION Arnold J. Morway, Clark, N.J., and John 0. Smith, In, 'Swampscott, Mass., assignors to Esso Research and Engineering Company, a corporation of Delaware No Drawing. Filed Nov. v1, 1957, Ser. No. 693,820
7 Claims. (Cl. 252-40.7)
This invention relates to lubricating oil compositions containing stabilized dispersions of calcium acetate. Particularly, it relates to lubricating oil compositions containingcalcium acetate and a tertiary alkyl amine as a stabilizing agent.
Simple dispersion of calcium acetate, in lubricating oil, imparts load-carrying ability and anti-wear properties to the oil. But, simple dispersions of this type are unstable and upon storage the metal salt settles out of the composition. One proposed method of forming more stable lubricants is by emulsifying a water solution of calcium acetate into lubricating oil. However, such emulsions are not completely satisfactory since they are rather corrosive because of their water content and are still somewhat unstable, tending to separate upon storage over long periods. It had also been proposed to dehydrate the emulsion type of material. While this reduces the danger of corrosion, it still results in an unstable product and unless the dehydration is carefully controlled, a grainy unsatisfactory dispersion results. It has now been found that dispersions of calcium acetate in lubricating oil may be stabilized with a small quantity of certain amines. Such dispersions are relatively inexpensive, and yet because of their calcium acetate content, they have extremely good load-carrying and anti-wear properties. Furthermore, not only does the amine material function as a stabilizing agent, but it also acts as an antioxidant to inhibit degradation of the oil. In this manner, either grease compositions or fluid lubricants can be formed. Such greases can be used for general purpose lubrication, such as, ball and roller bearings, automotive chassis lubrication and other industrial applications. The fluid type lubricants can be used in the crankcase of internal combustion engines, and for lubricating the upper cylinders of marine diesel engines.
Because of their high content of metal salt and correacid-neutralizing ability, they are particularly useful when the engine is operating on an acid forming fuel, such as the high sulfur-content diesel fuels currently coming into favor for marine diesel use.
The amines used as stabilizers include tertiary alkyl primary amines and tertiary alkyl polyalkyleneoxy amines. These materials maybe represented by the general formula:
RI RIIIO) H RI! RIIIO)X H wherein R, R, R" are straight or branched-chain alkyl radicals of 1 to 18 carbon atoms, the sum of R, R and R" being about 16 to 36, e.g. 17 to 23 carbon atoms; R is a C to C aliphatic hydrocarbonradical and x is 0 When x of the above formula is 0, then the. formula Such amines mers of propylene and isobutene; copolymers of propylene and isobutene; copolymers-of isobutene and butenes or pentenes; etc. Such polymers and copolymers are well known synthetic olefins in the petroleum industry. However, in such polymerizations, various isomerizations l and migrations may occursuch that a mixture of olefins are produced. Thus, when making a tertiary alkyl pri-...
mary amine of 18 carbon atoms from hem-propylene, a
2,976,243 Patented Mar. 21, 1961 polymer of propylene, one may obtain a mixture of tertiary alkyl primary amines having predominantly 18 carbon atoms per molecule with minor amounts of homologous molecules with 19, 20, 21, 22, 23 and/or 24 carbon atoms. A commercial amine material of this general type is manufactured by Rohm and Haas and is a mixture of C tertiary alkyl primary amines. This commercial material is available under the trade-name Primene JM-T and was used in several examples of the invention.
Specific examples of other tertiary alkyl primary amines which may be used include the following:
S-amino-S,13-dirnethyhhexadecane 3-amino-3,5,7,9,IZ-pentamethyl-tridecane 4-amino-2,4,6,8,IO-pentamethyl-tridecane 2-amino-2,4,4,6,6,8,8-heptamethyl-nonane 6-amino-2,2,4,4,6,8,S-heptamethyl-nonane When at least one x of the above formula is one or greater, the formula represents tertiary alkyl polyalkyleneoxy amines. These materials are prepared by reacting an alkylene oxide (e.g. ethylene oxide, propylene oxide or butylene oxide) with any of the tertiary alkyl primary amines described above. Products of this type are also commercially available. Examples of such commercial materials include:
4,. wherein R, R and R are as before defined.
The lubricating oil used in the compositions of the invention may be either a mineral lubricating oil or a synthetic lubricating oil. If synthetic oils are used, they are preferably used with a major amount of mineral oil. Synthetic oils which may be used include esters of monobasic acids (e.g. C oxo alcohol ester of C oxo acid), esters of dibasic acids (e.g. di-2-ethyl hexyl sebacate), esters of glycols (e.g. C oxo acid diester of tetraethylene glycol), complex esters, esters of phosphoric acid, halocarbon oils, silicones, polyglycol type synthetic oils;
.etc. or mixtures of any of the above in any proportions.
desired, then about 20 to 30 Weight percent of the metal salt and about1.0 to 5.0 weight percent of the amine is used, While the fluid lubricants will generally contain about 2.5 to 8.0 weight percent salt and 0.5 to 5.0 weight percent amine. All of said weight percents being based on theweight of the total composition. Various other additives may also' be' added to the lubricating composition in amounts of about 0.1 to 10.0 weight percent, based on the total weight of the composition. Examples of such additives include oxidation inhibitors such as phony] alpha naphthylamine; viscosity index improvers such as polyisob utyleneicorrosion inhibitors such as sorbitan monooleate; pour depressants; dyes; detergents and the like. U
Generally, the compositions of the 'invention will be prepared by neutralizing lime or calcium oxide with acetic acid or acetic anhydride in the presence of lubricating oil or-otherinertliquid dispersant. The mixture may then be heated to about 250 to 500 F. sufiicientto at least-evaporate any free water. The amine may also be present during this neutralization step or it may be added later. A preferred method consists of dispersing lime and the amine in the lubricating oil followed by addition of acetic acid or its anhydride. The mixture is then heated to a temperature of about 300 to 500 F. until complete dehydration occurs, i.e. anhydrous calcium acetate is formed. The product may then be cooled while stirring and any conventional additives can be added. T'he mixture may then be homogenized by passing it through a Gaulin homogenizer, a Charlotte mill, a Morehouse mill, etc. The mixture may be cut back with additional lubricating oil to form the final lubricant product which is further homogenized. The lubricating compositions may also be formed by simple mixing of calcium acetate and the amine into lubricating oil. However, this latter method is not preferred because of the difficulty of obtaining a fine dispersion of the calcium acetate.
The invention will be further understood by the following examples which include preferred embodiments of the invention.
EXAMPLE I A grease composition was prepared from the following ingredients:
The lime, Primene IM-T, and lubricating oil were intimately mixed in a steam kettle. The acetic acid was then slowly added while mixing, the temperature during this time rising to about 220 F. with the formation of a heavy solid lubricant. Mixing was continued for an additional /2 hour and then heating was initiated to raise the temperature to about 320 F. This temperature was maintained for about 30 minutes in order to insure complete dehydration of the mixture and formation of anhydrous calcium acetate. The mixture was then cooled, while stirring, to about 100 F. after which it was passed through a Gaulin homogenizer operating at about 6000 p.s.i. shear.
EXAMPLE II 20 weight percent of the final product of Example I was blended with an additional 80 weight percent of the mineral lubricating oil used in Example I. This blend was twice passed through a Gaulin homogenizer operating at 6000 p.s.i.
The properties of the products of Examples I and II are summarized in the following table:
EXAMPLE III A product containing 6.0 weight percent of calcium acetate, 1.0 weight percent of the C1844 tertiary alkyl primary amine mixture (Prirnene JM-T) and 93.0 weight percent of a mineral lubricating oil having a viscosity of 65 SUS at 210 F. was prepared in the manner of Example II, i.e. by first forming a concentrate of the calcium acetate in situ and then blending it with additional oil. This product was tested in a single cylinder Caterpillar 1A diesel test engine. This test was carried out for hours operating on a fuel containing one percent sulfur and using the Caterpillar l-A test procedure CRC-L-1-545. On completion of the test, the engine was inspected and the amount of wear and deposit formation determined. The results of this test was summarized in the following table along with comparable data on a solvent extracted Mid-Continent base stock used in a commercial heavy duty premium oil.
Table II CATERPILLAR ENGINE PERFORMIANCE (120 HOURS) Dernerit Top Ratings Percent Ring Lubricant Weight TRG 3 Loss, Hz 1 RZ-l 1 mg.
3.0 2. 8 1,100 1.0% 01H; t.alkyl primary amine 0.6 0. G 0. 5 300 93.0% Mineral oil 1 Total ring zone area. 1 Area below top ring groove. 3 Top ring groove.
The results summarized in Table II illustrate that the compositions of the invention can serve as crankcase lubricants, having low deposit forming tendencies and yet at the same time substantially reducing wear.
To further illustrate the invention, other compositions can be prepared as follows:
(A) Example I is repeated but using 2.0 weight percent of S-amino-S,l3-dimethyl-hexadecane in place of the 2.0 wt. percent of Primene .lM-T.
(B) Example I is repeated but using 5.0 weight percent of an amine of the formula:
02H! CuHrr+NH(CH:C 2 )l Ca s (C) Example I is repeated but using 5.0 weight percent of an amine of the formula:
C H }CH CH O) H ieHa:|-N
CzHg, CH3CH:|O):H
What is claimed is:
l. A dehydrated lubricating composition comprising a major portion of lubricating oil, about 2.5 to 30.0 wt. percent of anhydrous calcium acetate as the sole salt component and about 0.1 to 10.0 wt. percent of an amine having the general formula:
R! n! R --N wherein R, R and R" are C; to C alkyl radicals, and R, R and R" combined contains a total of 16 to 36 carbon atoms, R'" is a C, to C aliphatic hydrocarbon .radical and x is to 10.
2. A dehydrated lubricant according to claim 1, wherein said lubricating oil is a mineral oil.
3. A dehydrated lubricant according to claim 1, wherein said amine is a tertiary alkyl primary amine.
4. A dehydrated lubricant according to claim 1, wherein said amine is a tertiary alkyl polyalkyleneoxy amine.
5. A fluid dehydrated lubricating oil composition comprising a major portion of lubricating oil, about 2.5 to 8.0 wt. percent of anhydrous calcium acetate and about 0.5 to 5.0 wt. percent of an amine having the general formula:
wherein R, R and R" are C; to C alkyl radicals, and R, R and R combined contain a total of 16 to 36 carbon atoms.
6. A dehydrated lubricating oil composition according to claim 5, wherein R, R and R" combined contains a total of 17 to 23 carbon atoms.
7. A method of preparing a stable dehydrated lubricating composition comprising a major portion of lubricating oil and containing calcium acetate as the sole salt component, which comprises neutralizing lime in said lubricating oil with a material selected from the group consisting of acetic acid and acetic acid anhydride, in the presence of a stabilizing amount of an amine having the general formula:
RI R1110) II RI/lo) FH wherein R, R and R" are C to C alkyl radicals, and R, R and R combined contains a total of 16 to 36 carbon atoms, R is a C to C aliphatic hydrocarbon radical and x is 0 to 10.
References Cited in the file of this patent UNITED STATES PATENTS 2,079,051 Sullivan et al. May 4, 1937 2,744,870 Stillebroer et al May 8, 1956 2,854,410 Bidault Sept. 30,1958
OTHER REFERENCES Georgi: Motor Oils and Engine Lubrication, Reinhold Pub. Corp., New York, N.Y., 1950, page 170.
Tertiary-Alkyl Primary Amines, pub. by Rohm and Haas Co., September 1954, page 16.
Claims (1)
1. A DEHYDRATED LUBRICATING COMPOSITTION COMPRISING A MAJOR PORTION OF LUBRICATING OIL, ABOUT 2.5 TO 30.0 WT. PERCENT OF ANHYDROUS CALCIUM ACETATE AS THE SOLE SALT COMPONENT AND ABOUT 0.1 TO 10.0 WT. PERCENT OF AN ANIME HAVING THE GENERAL FORMULA:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US693820A US2976243A (en) | 1957-11-01 | 1957-11-01 | Stable calcium acetate-mineral oil dispersion |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US693820A US2976243A (en) | 1957-11-01 | 1957-11-01 | Stable calcium acetate-mineral oil dispersion |
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US2976243A true US2976243A (en) | 1961-03-21 |
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US693820A Expired - Lifetime US2976243A (en) | 1957-11-01 | 1957-11-01 | Stable calcium acetate-mineral oil dispersion |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3216935A (en) * | 1962-08-22 | 1965-11-09 | Exxon Research Engineering Co | Lubricant |
US3231495A (en) * | 1962-08-22 | 1966-01-25 | Exxon Research Engineering Co | Finely divided calcium acetate particles and lubricating compositions thereof |
US3259577A (en) * | 1963-02-19 | 1966-07-05 | Socony Mobil Oil Co Inc | Lubricant and additives therefor |
EP0903398A2 (en) * | 1997-09-23 | 1999-03-24 | Exxon Research And Engineering Company | Lubricating grease containing alkoxylated amine corrosion inhibitor |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2079051A (en) * | 1933-03-15 | 1937-05-04 | Standard Oil Co | Lubricating oil |
US2744870A (en) * | 1953-11-24 | 1956-05-08 | Shell Dev | Lubricating compositions |
US2854410A (en) * | 1952-12-12 | 1958-09-30 | Exxon Standard Sa | Soap-thickened lubricating greases containing an alcohol-substituted amide |
-
1957
- 1957-11-01 US US693820A patent/US2976243A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2079051A (en) * | 1933-03-15 | 1937-05-04 | Standard Oil Co | Lubricating oil |
US2854410A (en) * | 1952-12-12 | 1958-09-30 | Exxon Standard Sa | Soap-thickened lubricating greases containing an alcohol-substituted amide |
US2744870A (en) * | 1953-11-24 | 1956-05-08 | Shell Dev | Lubricating compositions |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3216935A (en) * | 1962-08-22 | 1965-11-09 | Exxon Research Engineering Co | Lubricant |
US3231495A (en) * | 1962-08-22 | 1966-01-25 | Exxon Research Engineering Co | Finely divided calcium acetate particles and lubricating compositions thereof |
US3259577A (en) * | 1963-02-19 | 1966-07-05 | Socony Mobil Oil Co Inc | Lubricant and additives therefor |
EP0903398A2 (en) * | 1997-09-23 | 1999-03-24 | Exxon Research And Engineering Company | Lubricating grease containing alkoxylated amine corrosion inhibitor |
EP0903398A3 (en) * | 1997-09-23 | 2000-02-02 | Exxon Research And Engineering Company | Lubricating grease containing alkoxylated amine corrosion inhibitor |
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