GB754773A - Organic oleaginous compositions - Google Patents

Organic oleaginous compositions

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Publication number
GB754773A
GB754773A GB15210/54A GB1521054A GB754773A GB 754773 A GB754773 A GB 754773A GB 15210/54 A GB15210/54 A GB 15210/54A GB 1521054 A GB1521054 A GB 1521054A GB 754773 A GB754773 A GB 754773A
Authority
GB
United Kingdom
Prior art keywords
agents
copolymer
alpha
carbon atoms
per cent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB15210/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB754773A publication Critical patent/GB754773A/en
Expired legal-status Critical Current

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    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis
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    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/146—Macromolecular compounds according to different macromolecular groups, mixtures thereof
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    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
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    • C08F2810/00—Chemical modification of a polymer
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    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
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    • C10L1/234—Macromolecular compounds
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    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
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    • C10M2201/105—Silica
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    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/026—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrile group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/02—Macromolecular compounds obtained by reactions of monomers involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy

Abstract

An oleaginous composition comprises a major proportion of an organic oleaginous material and a minor proportion of a copolymer having a molecular weight of at least 1000 prepared by copolymerization of an alpha-olefin having at least 10 carbon atoms in the molecule with an unsaturated polymerizable compound containing one, but not more than one, polar substituent, i.e. a substituent group consisting of or containing an alcoholic -OH, an -SH, an -SCN, a -CN, a -CONR2 or an -NR2 group, R being a hydrogen atom or a hydrocarbon radical. Amongst the many alphaolefins listed are decene, tetracosene, dotriacontene, and heptacontene while copolymerizable compounds are acrylonitrile, methacrylonitrile, alpha-ethyl or propyl acrylonitrile, 2 - butyl - hexenenitrile, 2 - propyl - or 2 - isopropyl - 3 - bromo - 2 - pentenenitrile, 2 - chloroethyl - or 2 - ethyl - 3 - chloro - 2 - butenenitrile and a -propyl- or a -isopropyl - beta - cyclohexyl-acrylonitrile and the corresponding amides. In a modification a copolymer of an alpha-olefin with an unsaturated polymerizable compound containing one, but not more than one, polar substituent may be prepared and converted into one containing a defined polar substituent, e.g. the halide or ester groups in a vinyl halide or ester may be converted into hydroxyl groups e.g. by hydrolysis or alcoholysis. The copolymer may have a molecular weight of 1500 to 50,000 preferably 4000 to 15,000 and a linear hydrocarbon chain of 20 to 100 carbon atoms preferably 30 to 60 carbon atoms. The amount of copolymer used is from 0.01 to 10 per cent of the whole composition, preferably from 0.1 to 5 per cent. The organic oleaginous material may be a mineral or synthetic lubricating oil, and may be thickened to a grease by a soap or inorganic colloid, e.g. silica, and may contain minor proportions of corrosion inhibitors, extreme pressure agents, fraction - refining compounds, foam - reducing agents, blooming agents, viscosity regulators and/or anti-wear agents. U.S.A. Specifications 2,421,971, 2,436,926, 2,467,774, 2,486,241 and 2,551,643 are referred to.ALSO:An oleaginous composition comprises a major proportion of an organic oleaginous material and a minor proportion generally from 0.01-10 per cent, of a copolymer which has a molecular weight of at least 1000 and which has been prepared by copolymerization of an alpha-olefin having at least 10 carbon atoms in the molecule with an unsaturated polymerizable compound containing one, but not more than one, polar substituent (see Group IVa). The organic oleaginous material may be a natural and/or synthetic lubricating oil, e.g. a mineral oil obtained from a paraffinic naphthenic, asphaltic, or mixed base crude oil or maybe a fuel. The mineral oils may be blended with natural ester oils such as castor oil and lard oil, and/or with synthetic lubricant oils such as polymerized olefins, the polyalkylene glycols, polyesters, polymeric tetrahydrofuran and silicones. There may also be present in the lubricating oil compositions other additives, e.g. corrosion inhibitors, such as sulphonic or fatty acids, extreme pressure compounds such as alkyl phosphates, friction-reducing compounds such as allophanates, interfacial tension modifiers or foam-reducing agents, blooming agents, viscosity regulators, such as aeryloid polymers and antiwear agents, usually in amounts from 0.05-5 per cent. The lubricating compositions may be thickened to a grease consistency by a soap or an inorganic colloid such as silica. U.S.A. Specifications 2,421,971, 2,436,926, 2,467,774 2,486,241 and 2,551,643 are referred to.
GB15210/54A 1953-05-25 1954-05-24 Organic oleaginous compositions Expired GB754773A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US754773XA 1953-05-25 1953-05-25

Publications (1)

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GB754773A true GB754773A (en) 1956-08-15

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GB15210/54A Expired GB754773A (en) 1953-05-25 1954-05-24 Organic oleaginous compositions

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BE (1) BE529084A (en)
DE (1) DE960756C (en)
FR (1) FR1101147A (en)
GB (1) GB754773A (en)
NL (1) NL91489C (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1041691B (en) * 1955-04-22 1958-10-23 Bataafsche Petroleum Process for the preparation of oil-soluble metal-containing association compounds
BE551242A (en) * 1955-09-26
NL105971C (en) * 1957-04-09
DE1075254B (en) * 1957-11-26 1960-02-11 N. V. De Bataafsche Petroleum Maatschappij, Den Haag Mineral oil-based lubricating oil mixture
NL239309A (en) * 1958-05-19
DE1145289B (en) * 1958-06-26 1963-03-14 Monsanto Chemicals Additives to mineral lubricants, fuel oils and other hydrocarbon mixtures from mineral oils
US3089852A (en) * 1958-12-23 1963-05-14 Shell Oil Co Extreme pressure lubricating compositions
US3100748A (en) * 1959-11-10 1963-08-13 Shell Oil Co Lubricating compositions
NL260895A (en) * 1960-02-26
US3198739A (en) * 1960-11-25 1965-08-03 Shell Oil Co Lubricants and polymeric additives therefor

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Publication number Publication date
FR1101147A (en) 1955-09-28
NL91489C (en)
BE529084A (en)
DE960756C (en) 1957-03-28

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