US2953849A - Reinforcement of metal - Google Patents

Reinforcement of metal Download PDF

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Publication number
US2953849A
US2953849A US606293A US60629356A US2953849A US 2953849 A US2953849 A US 2953849A US 606293 A US606293 A US 606293A US 60629356 A US60629356 A US 60629356A US 2953849 A US2953849 A US 2953849A
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metal
glass
fibers
pellets
bers
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US606293A
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Willard L Morgan
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Owens Corning
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Owens Corning Fiberglas Corp
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Priority to US858255A priority patent/US3187422A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C47/00Making alloys containing metallic or non-metallic fibres or filaments
    • C22C47/02Pretreatment of the fibres or filaments
    • C22C47/025Aligning or orienting the fibres
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C47/00Making alloys containing metallic or non-metallic fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/19Inorganic fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/36Processes of making metal-ceramics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49789Obtaining plural product pieces from unitary workpiece
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49789Obtaining plural product pieces from unitary workpiece
    • Y10T29/49798Dividing sequentially from leading end, e.g., by cutting or breaking
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49801Shaping fiber or fibered material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49826Assembling or joining
    • Y10T29/49885Assembling or joining with coating before or during assembling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4998Combined manufacture including applying or shaping of fluent material
    • Y10T29/49982Coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12486Laterally noncoextensive components [e.g., embedded, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12597Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2929Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/294Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
    • Y10T428/2956Glass or silicic fiber or filament with metal coating

Definitions

  • This invention is related to reinforcement of metals with mineral fibers and more particularly to a method for reinforcing metal products with glass bers in metal working processes.
  • Glass in fibrous form is capable of tensile strengths considerably in excess of metals. Glass fibers, however, are frequently Irestricted in utilization because of an inherent weakness to surface abrasion.
  • this is accomplished according to the ,present invention by combining and surrounding glass fibers with metal in the form of pellets, segments, chips or patties within which the fibers are protected -against abrasion during shaping operations.
  • the forms thusproduced are then worked to desired shapes in operations such as drawing, rolling, pressing, forging or extrusion which would otherwise be damaging to -t-he glass *fibers -if the fibers were subjected to such action independently ofthe composite forms.
  • Figure 1 is a sideelevational .view-of ⁇ anarrangement o apparatus fo-r producing pellets of metal and glass lfibers produced directly in a ber forming process; Y
  • Figure 2 is a front elevational viewof the apparatus ⁇ of Figure l;
  • Figure 3 is an enlarged isometric View of a ,pellet vof the present invention produced by the method and .apparatus of Figures l and 2;
  • Figure 4 is a somewhat schematic, ⁇ partially ⁇ sectional isometric view of another arrangement of apparatus for producing pellets of metal containing glass ftbers wherein already formed glass fibers are incorporated into rods of metal prior to pelletization; Y Y ,Y
  • Figure 5 is an enlarged isometric v iew of a pellet of the present invention as produced by the method and appara-y tus of Figure 4;
  • Patented Sept. 27; 1969 Figure 6 is a somewhat schematic, partially sectional isometric view of still another arrangement for producing metal and glass ber pellets in accordance with the .principles of the present invention
  • Figure 7 Vis a schematic view of an arrangement for producing an extruded sheet structure yof metal andglass fibers adaptable to fabrication of pellets;
  • Figure 8 is an illustration -of ano-ther type of pellet adaptable to use in accordance with the principles of the present invention.
  • Figure 9 is an isometric view partially in cross section of a press having a cavity mold therein within which pellets of metaland glass fibers are deposited for pressure shaping into desired shape;
  • Figure lO is a side elevational viewsin cross section of an extrusion press for extrusion Vof pellets .into rods of cross-sectional shape corresponding to that of the press nozzle opening; Y
  • Figure l1 isa front View of the extrusion press of Figure 9 showing the shape ofthe nozzle opening as illustration of the rod shapes capable of beingproduced with pellets according to the present invention
  • Figure l2 is a sectional isometric View of an arrangement forproducing patties or barsof metal and glass fibers adaptable to further reshaping; andV l Figure 13 'is an isometric view of a pair .of mill rolls into which a patty o-r bar composed of metal and glass fibers, such as is produced by the method V and apparatus of Figure l-l, can .be introduced for reshaping to forms such as a channel as illustrated.
  • Metal may be worked in accordance with therpr'inciples of the present invention in such processes las drawing, rolling, forging,wor extrusion-either -in a ⁇ n on-l 1eated state or while heated ⁇ to a 4temperature' ashigl'i'asfthatat which the glass inclusions are softenedsluicientlyto permit plastic flow on deformation without disintegration of the metal, the vmetal also being plastic at such working tem# peratures'.
  • the Ywideirange of metals which may be pelletized with glassfibers such ⁇ manner ⁇ are alurnij num, lead, zinc, copper, iron, steel, magnesium, etc.
  • Figures 1 -and 2 illustrate an arrangeme -t and 4method whereby pellets of 'metal-aud glass fibers are kproduced directly in a glass fiber forming process.
  • a source of molten ⁇ glass l@ such as melting-tank or nfur-nace suppliesV glass to a feeder vlllhaving 'Oriftced tips 121therein fromwhich Yglass fibers i4 are attenuated.
  • the metal coated fbers'l are gathered or grouped together by passage over va gathering roll'158 and then redrawnas Va strand through a globular strip 4of metal 20 held in projected 4relationship in the path'ofthe strand at the face of a second metal-coating applicator 19.
  • the strand of metal coated fibers 17 receives a coating which binds the fibers together into a stick-like grouping 21.
  • the metal which effects the bonding of the metal coated glass fibers into the stick form may be the same as that coated on the fibers, or may be of a different type of higher or lower melting temperature than that of the coating directly on the fibers.
  • the bonding metal has a higher melting temperature than the coating directly on the glass, it can be readily applied by rapidly drawing the metalled fibers through the globule at such a rate that the air surrounding the stick acts to chill the bonding metal prior to its being effective to melt the direct coating of metal on the glass.
  • the stick-like form 21 of metal bonded, metal coated fibers is drawn at a relatively rapid rate of speed by a pair of pull wheels 22 which operate to provide the force for attenuation of fibers 14 from the feeder 11.
  • the rate of attenuation is in the order of up to 10,000 feet per minute, or may be as low as 100 feet per minute or lower, if desired. In this respect the speed is not critical since the attenuation rate and rate of coating the fibers is not known to be limited.
  • Figure 3 illustrates in greater detail the structural form of a pellet 30 in which the glass fibers 14 are coated with a metal 17 and are bonded together by additional metal.
  • the length of the pellets 30 according to this method may be any of a wide range of lengths the order of 1A" to 2" or longer While the diameter of the sticklike form 21 from which they are cut may be in the order of 1,44" to 1A depending upon the thickness of metal coating placed on the individual fibers as well as the number of coated fibers grouped and the thickness of coating applied to the combined grouping of coated fibers.
  • Figure 4 illustrates another arrangement for making metal-fibrous glass pellets wherein glass fibers in strand form, twisted or untwisted, are supplied from packages after having already been formed.
  • the strands 41 are drawn from packages 40 through guide eyes 42 to a bath of molten metal 45 in a suitable high temperature Crucible or tank 44.
  • the strands 41 are drawn into the bath 45 in spaced relationship but are gathered into a common grouping over a Wheel 48 located under the surface of the bath.
  • 'Ihe strands are thus each individually coated before being gathered together and are then bonded together into a common metal coated rodlike form 49 which, upon leaving the bath 45, is drawn through a wiping die 50 which assures uniformity in the final dimension of the rod as well as effects a smoothening of the surface thereof.
  • the bonded rod 49 is drawn through a pair of pull wheels 52 which provide the force for withdrawal of the individual strands 41 from the packages.
  • the pull wheels supply the rod to a shear mechanism comprising a shear block 55 and a blade 54 which cooperate to cut the rod 49 into pellets 56 of desired length.
  • the pellets upon being cut by the shear mechanism are deposited into a container 57 in which they are accumulated for subsequent use in further fabrication of metal structures.
  • Figure 5 illustrates with greater clarity the appearance of the pellets 56 made by the method and apparatus of Figure 4 showing the fibrous strands 41 grouped and bonded together by the metal coating the grouped strands.
  • Each individual strand itself is coated in this instance while a complete grouping of metal coated strands is bonded together by the metal coated thereover.
  • the strands 41 can be made of metal coated fibers, if desired, such as Iare produced by gathering fibers after the first stage of metal coating in the process of Figures 1 and 2.
  • the bath of metal 45 can be of the same meta-l as is coated on the strand, or can be a different metal adapted to bonding the metal coated strands together.
  • the metal coated fibers would also first be independently bonded as strands, and then subsequently bonded together as a rod after passage over the guide wheel 48.
  • FIG. 6 illustrates still another method for forming pellets starting with glass fibers in the form of fabric.
  • Fabric 61 either of woven or unwoven type is drawn from a roll 60 and passed through a molten metal bath 65 in a suitable tank reservoir 64. The fabric is passed under a roll 66 within the bath and after receiving a coating thereof is withdrawn from the bath by passage over an upper sup- -ported guide roll 68 at the exterior of the reservoir 64.
  • the coated fabric is then passed through a pair of rolls 70 in a roll stand 69 where a compressive force is exerted thereon to extrude the combination as a sheet of thickness desired.
  • the sheet is cut into longitudinal strips 75 by a series of rotary knife blades 72 cooperatively disposed above and below the path of the sheet and spaced apart to provide the widths of strip desired.
  • the strips 75 are introduced to an upper surface of a support 74 upon which they are cut into segments or pellets 76 by a guillotinetype cutter 73 reciprocably operated to cut the strips to length corresponding to the pellet size desired.
  • the pellets 76 are then deposited in a container 77 for accumulation and subsequent fabrication into products as hereinafter described.
  • Dipping and coating of various weaves of glass cloths, mats, or combinations can be effected in this manner, the coatings being metals or alloys such as aluminum, lead, zinc, etc.
  • the coatings being metals or alloys such as aluminum, lead, zinc, etc.
  • a leno cloth can be drawn through a molten metal bath in accordance with this method to produce a continuous sheet of metal reinforced by glass fibers. Variations in the amount of metal to glass in the sheet may be achieved by altering the metal temperature as well as the speed of drawing the fabric through the bath.
  • aluminum or lead which have poor tensile strengths and relatively high coefiicients of expansion, can be reinforced to provide the high tensile strengths and lower coefficients of expansion to make them adaptable for use in many applications where they would otherwise be incapable of use.
  • a non-woven mat of glass fibers may be carried by a Woven fabric such as a leno fabric, and upon passage through the bath of molten metal can be made to form a composite of a metal sheet reinforced by both a woven and nonwoven fabric.
  • glass fibers are arranged in an oriented as well as non-oriented manner within the plane of the sheet of metal to provide tensile strengths in all directions of the plane of the sheet.
  • differential temperatures may be established through the depth of the bath.
  • the upper levels of the bath are maintained at a somewhat lower temperature than the bottom of the bath.
  • the upper surface might be at a temperature in the order of 1250 F. while the bottom of the bath is at a temperature of 1500 F.
  • the lower viscosity of the molten metal at the higher temperatures at the bottom of the tank lends itself to penetration of the fabric and then as it moves upwardly to cooler zones at the upper level of the bath, the impregnated material is more susceptible to acceptance of the coating of metal throughout its thickness.
  • the coating can be arranged to be sufficiently adhering to the mass that dripping of the material from the fabric will not take effect. In this way shock heating and cooling of the fabric to the degree which it might otherwise be subjected is avoided while at the same time providing the degree of penetration by metal to provide a matrix for the sheet is effected.
  • a flux can be provided at the surface of the metal bath through which the fabric or mat is introduced prior to passage through the bath. Oxidation at the surface of the bath can thus be reduced and the more intimate association between the glass and metal can be established.
  • perforation of the fabric may be resorted to to promote more positive adherence of the metal to the fabric.
  • slugs of metal are formed at each perforation by reason of a ⁇ web and then a slug being formed therein during the dipping step thereby providing anchors or keys for fibers intersecting the slugs.
  • the coating of metal on the fabric is thus tixed relative to the anchors, minimizing the possibility of shift between the fibers and the metalin the final coated fabric.
  • a suitably chosen pattern of perforations in the fabric minimizes fiber or strand movement to the degree that loads can be imparted to the reinforcement material before the disruption limit of the metal ⁇ film is reached.
  • Figure 7 illustrates another arrangement for 'producing metal sheets reinforced with glass fibers adaptable to formation of pellets.
  • glass fibers 82 are attenuated from orificed tips 81 ifi a feeder Sil associated with a molten glass supply source.
  • the fibers are drawn across the face of a metal coat-ing applicator 84 having a quantity of molten metal 85 projecting in the path of the fibers for application of a coating to the fibers.
  • Coated fibers are drawn by a pair of co-acting pulling rollers 87 which supply the force for attenuation of the bers 82 and also advance the iibers to a chopping device including a rubber back-up roll 88 and a bladed chopping roll 89 which cooperatively engages the coated fibers to chop them into short lengths for collection on the metal sheet or foil 91 passed under the chopping device.
  • the chopped coated fibers are deposited on a metal sheet or foil 91 by way of a bame member 90 inclined downwardly to the sheet or foil and disposed angularly in the path of the dropping chopped fibers.
  • the member 90 promotes uniform distribution onvv the sheet or foil and, if desired, may have an associated air blast directed thereagainst over its upper surface to assure uniform removal in those instances where hangup may tend to occur.
  • the sheet or foil 91 is withdrawn from a roll 92 and passed over a series of spot rollers 93 in the 'zone where the chopped coated fibers are deposited and conveyed prior to introduction into a roll stand 9S. Before introduction of the sheet 91 and the fiber conveyed thereon into the roll stand, another metal sheet or foil 96 is laid thereover to cause the chopped coated fibers to become sandwiched interposed between the two sheets.
  • the sheet or foil 96 is withdrawn from a roll 94 disposed behind the roll stand 98 and above the path of movement of the sheet 91.
  • the roll stand 98 includes a pair of compression rolls 97 adjustable in degree of compression by anadjustment screw 99.V
  • the assembly of two sheets 91 and 96 with chopped fibers therebetween is passed between the compression rolls under adequate pressure to establish an intimate integral relationship between the three components to form an extruded metallic structure 100 reinforced by the fibers therebetween.
  • the composite sheet structure 100 is adaptable to end uses such as finishing of wall surfaces, both interior and exterior, roong surfaces, and reinforcement of other materials.
  • the two sheets brought together to form the composite structure can be of different metals or the same metal, while the coating metal of the chopped coated fibers can be the same or different from that of the sheets.
  • the thickness of the sheets is usually identical but may be of different thicknesses, if desired.
  • the bottom sheet might be more rigid with the top ⁇ sheet being flexible, and upon combination into the composite structure being reinforced by the coated glass bers can be made still more rigid.
  • Two flexible metallic sheets joined together in this wayA can likewise be joined to produce a rigid or plate-like structure.
  • Figure 8V illustrates another type of pellet adaptable to fabrication into metal products reinforced by glass fibers.
  • the pellets of this arrangement comprise chopped metal coated fibers of the type produced in the arrangement of Figure 7 which-rare, in a sense, balled or nodulated into the pellets 101.
  • Such pelletization can be accomplishedin a ball-type mill wherein the metal coated bers are accumulated and rolled rinto the pelletized forms ⁇ and then withdrawn ready for further processing.
  • pelletization can be accomplished by introduction of metalled fibers or roving between a pair of closely spaced belts operating at diiferential speeds. Fibers or roving of considerable length coated with metal are adaptable to pelletization in this manner as well as chopped fibers of short length. In the latter instance each pellet is formed of an accumulation of a number of the chopped fibers, while in the case of the longer lmetal coated fibers, eachlength of fiber can be modulated into a single pellet.
  • Still ⁇ another method ofwmaking pellets involves the use of short glass bers or ground glass mixed with ne metal powders subjected to pressure at elevated temperatures to sinter and form dense integrated mixtures. If the sintering and hot working temperatures of the metal are above the softening point of the glass used, such sintered pellets can be hot extruded or hot rolled. The bers of the pellets are further attenuated during such operations While ground glass becomes berized under the high pressures exercised during the processes.
  • the resultant glass reinforced metal has a superior high temperature character with lower yield characteristics than unreinforced metals. Powders of copper, iron, nickel, stainless steel and numerous other alloy powders can thus be incorporated in pellets for further fabrication.
  • pellets containing 50% by weight of chopped one mil glass bers and the remainder in copper powder form can be pelletized into sintered pellets at a temperature of 1650 F. under a pressure of 14,000 p.s.i. applied for 30 minutes.
  • Figure 9 illustrates the manner in which pellets of the present invention can be processed into metal products reinforced by glass bers.
  • the pellets 105 are introduced into a mold cavity for application of compressive forces between two halves of a mold 103 and 104 inserted between the platens 106 and 108 of a press.
  • the mold be heated so as to impart a condition of plasticity to the metal to permit more ready flow thereof into an integrated matrix for the glass bers while at the same time conforming to the contours of the mold.
  • the pellets it is desirable to heat the pellets to a degree of plasticity in the glass bers as well as in the metal in order to cause a distribution of the glass bers through the contoured matrix especially when the molded products are of intricate contoured shape. If the pressure exerted upon the pellets, however, is of suicient magnitude, the ilow of metal within the mold can be eected even when cool. In the case of application of heat to the pellets, however, it has been found desirable that the temperature be applied for a period during application of pressure to effect a soaking to permit uniform pressure distribution and to eliminate or minimize the possibility of voids in the nal molded product.
  • sulcient metal is provided to prevent abrasion of bers against one another during the application of pressure forces. Additionally, plastic flow can be effected by application of suicient pressure after raising 'the temperature of the matrix to within approximately 2/3 to of the absolute melting point of the metal or alloy used. Sufcient time is also allowed under pressure to cause uniform distribution of forces to eliminate voids. A thermal equilibrium through the accumulated pellets is further desired to minimize tendencies toward breakage of bers. If these principles are followed, the metal surrounding the bers acts as a lubricant to prevent ber damage and in turn the strength of the bers is imparted to the product made with the pellets.
  • powdered metal can be incorporated with the pellets to promote the intimacy of metal particles prior to application of pressure.
  • the metal in powdered form and as coatings on the bers is copper and is a predominant portion of the material in the mold cavity, that is more than 50% by weight; and the mixture is stirred well to eect intimate contact between the metal particles and the metal coated glass bers, a sintered product molded in conformity with the cavity can be produced.
  • Metal such as aluminum and copper have proven quite successful for production of sintered products of this type.
  • powdered glass can be incorporated in the accumulation of metal pellets reinforced by glass bers. In such instances, application of pressure to the accumulation when at a high temperature results in distribution of the glass particles in extended form through the metal matrix forming actual and close semblances of glass bers which become active in reinforcing the metal product.
  • Figures 10 and 11 illustrate an extrusion press 110 from which pellets 112 of metal reinforced with glass bers can be extruded into bar-type forms of various shapes such as a bar 113 upon application of pressure by way of a piston 111 of the press.
  • the temperature of the press is maintained at a value such that the pellets acquire a degree of plasticity on emission from the press nozzle to bring the metal of the pellets in intimate relationship as a matrix for the glass bers.
  • Powdered metal may be incorporated with the pellets, if desired, as well as powdered glass, but preferably suicient metal is provided in the pellets such that a mixture of other particles is unnecessary.
  • Figure 12 illustrates a method whereby patties or rodtype bars of metal reinforced by glass bers may be produced for fabrication into products such as a channel extruded in the manner illustrated in Figure 13.
  • either metal coated glass bers or bare glass bers are inserted in a holder which has a foraminous seat 121 at its bottom having a suction chamber 124 thereunder from which air is withdrawn through a tube 125 connected to a Vacuum pump, not shown.
  • the glass bers are compacted in the holder to conform to the general shape of the cavity of the holder, after which molten metal 128 is poured from a crucible 126 for impregnation and coverage of the mass of bers.
  • the metal 128 is distributed over the surface of the compacted mass of bers and is caused to be drawn into the mass by the forces of gravity as well as the forces created by establishment of the low pressure zone below the mass in the chamber 124. Enough metal is poured into the recess of the holder to cause complete distribution through the mass, while the mass of bers deposited in the holder is limited in depth so that sucient forces exerted on the metal poured on the mass to draw it to the lower levels of the mass of bers. Upon solidication, a metal patty or bar results having glass bers distributed throughout and shaped to lend itself to further fabrication.
  • patties of aluminum containing reinforcing bers can be formed to desired shapes by raising the temperature of the patty to 600 F. and subjecting it to pressures in the order of 80,000 p.s.i.
  • a lead-cadmium-zinc alloy patty containing continuous glass bers When a lead-cadmium-zinc alloy patty containing continuous glass bers is used, it may be formed to desired shapes at a temperature of 400 F. under pressures in the order to 20,000 p.s.i.
  • a zinc patty is used with continuous glass bers reinforcing the form, a temperature of 500 F. and a pressure of 40,000 p.s.i. will produce desired shapes in a die.
  • the patties or the rod-type bars may be machined into chips or otherwise to turnings by various milling, lathe turning, or rough grinding methods. Premolding of notches into the patties, rods, or sticks may be done as desired to aid in such subdivision steps.
  • a bar or patty of metal reinforced with glass bers can be passed through a pair of rolls such as rolls 130 and 131, respectively, having grooves 132 therein properly shaped and positioned to produce a channel member of the bar 134 on passage therethrough.
  • the rolling of the patty or bar to the shape desired is conventional in that it resembles processes utilized in rolling various shapes from ingots.
  • the rolling process is effected while the bar 134 is hot to the extent that the material thereof is plastic and conformable to the roll contours.
  • the temperature of the bar for extrusion is not limited to metals having extrusion temperatures below the softening temperature .Ofthe glass bers used.
  • the glass Under the high pressures of such extrusion processes, the glass will remain in ber form of various lengths even when in plastic condition in view of the fact that the pressure exerted acts to elongate particles of material in plastic form within bars during such processes, thus resulting in retention of the fibrous form regardless of the fact that the temperature of the bar is above the softening temperature of the glass bers.
  • Metal coated bers or rovings, chopped or continuous, as well as bare glass bers or rovings, chopped or continuous, can be incorporated in patties or bars of this type and can be fabricated into rods, bars, plates, sheets, channels and I-beams and other structural shapes in further metal working steps such as pressing, extrusion or rolling.
  • Powdered metal, or powdered glass can also be incorporated in patties of glass bers in methods such as are exemplied in Figure 12, prior to pouring of metal 128 thereover.
  • the holder 120 can be heated to a temperature sucient to assure ow of molten metal introduced thereto to the bottom of the mass of bers, in those instances where dilculty is experienced in this regard.
  • the pellets or small units of glass reinforced metal which are provided by the invention oier a desired convenience to the metal fabricator who is concerned With forming a metal article from any given metal reinforced with glass.
  • the direct introduction of glass into metal is both inconvenient generally to metal fabricators and involves Working with bulky masses in some cases. Where it is desired to preserve the advantages of freshly formed glass surfaces, this also can not be done as the metal fabricator is expected to Work with glass bers that have been processed and made elsewhere.
  • the composite of glass bers or metal is provided in a form readily adaptable to extrusion, pressing, or shaping by various means of compacting either under heat and pressure or pressure alone.
  • the glass bers are parallel in arrangement with respect to each other. It is obvious that under a compacting process that these sticks will generally arrange themselves also parallel with respect to each other thus giving a product in which most of the glass bers Will be found in alignment and in one direction.
  • metal masses which are made with substantially squared, cubical or spherical pellets are characterized in that the bers in the adjacent areas corresponding to the original pellets carry glass bers which lie at yall diierent angles thus giving a compacted glass ber reinforced metal article wherein the glass bers are either completely non-oriented or are oriented only in small discrete areas adjacent to other areas where the bers are oriented in an entirely different direction.
  • metal masses may be made wherein the physical properties do not change with respect to the direction through the mass being tested.
  • a method yfor producing glass reinforced metal articles comprising metal coating each of a plurality of continuous strands of glass bers, grouping said plurality of coated strands into adjacent parallel relationship, bonding the grouped coated strands with metal into an integral longitudinal body, cutting said longitudinal body into segments of Arelatively short length, accumulating said segments into a mass and applying heat and pressure to said mass of segments to work them into integrated relationship as a metal matrix of the shape desired reinforced by said glass bers distributed throughout the matrix.

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Description

Sept. 27, 1960 w. L. MORGAN REINFORCEMENT oF METAL 4 Sheets-Sheiet 1 Filed Aug. 27, 1956 IE -Z- l/ILLAHD I. M 0125.121.
INVEN TUR r TTYE.
SePt- 27, 1960 w. L. MORGAN y 2,953,849
REINFORCEMENT OF METAL Filed Aug. 27, 1956 4 Sheets-Sheet 2 "'15 INVENTUR H/LMHD LMUREAN.
i- HMM@ y ATTY'S.
Sept. 27, 1960 w. l.. MORGAN 2,953,849
REINFORCEMENT OF METAL Filed Aug. 27, 1956 4 Sheets-Sheet 5 ETE-T' vW- INVETDH r IML ARD L. M UH EAN.
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Sept. 27, 1960 w. x.. MORGAN 2,953,849
REINF'ORCEMENT OF METAL INVENTUE.- s
V WILLAHD.; LM/:HMM
RElNFURCEhmNT OF METAL WillardlL. Morgan, Newark, hio, assigner to Gwens- Corning Fiberglas Corporation, Va corporation of Dela- Ware Filed Aug. 27, 1956, Ser. No. 606,293
3 Claims. (Cl. 29-419) This invention is related to reinforcement of metals with mineral fibers and more particularly to a method for reinforcing metal products with glass bers in metal working processes.
Glass in fibrous form, it is well known, is capable of tensile strengths considerably in excess of metals. Glass fibers, however, are frequently Irestricted in utilization because of an inherent weakness to surface abrasion.
It is a purpose of this invention to vprovide a novel method for utilizing the strength of glass in brous form to reinforce metals while at the same time protecting the fibrous glass against development of weakness'by abrasion.
in brief, this is accomplished according to the ,present invention by combining and surrounding glass fibers with metal in the form of pellets, segments, chips or patties within which the fibers are protected -against abrasion during shaping operations. The forms thusproduced are then worked to desired shapes in operations such as drawing, rolling, pressing, forging or extrusion which would otherwise be damaging to -t-he glass *fibers -if the fibers were subjected to such action independently ofthe composite forms. Y
It is thus another object of the present invention to incorporate the strengths of glass fibers in ymetallic bodies of desired shapes with a minimum loss of strength inthe glass fibers in order to impart `greater strength itothe bodies.
The pelletization of glass fibers with metal yis successful in minimizing strength 1loss in glass `fibers duningthe-steps of working the metal in vthat the `metal matrix `acts `as .a cushion and/or lubricant for the glass fibers 'during the often extremely rugged .and 'almost .consistent forceful abrasive handling to which metal forms are subjected during shaping.
The novel features which I believe to be'characteristic of my invention are set forth with particularity in the appended claims. My invention itself, however, both as to its manner of construction and method of operation, together with other objects and advantages thereof Ymay best be understood by reference to -the following description taken in connection with thefaccompan-ying drawings, in which:
Figure 1 is a sideelevational .view-of `anarrangement o apparatus fo-r producing pellets of metal and glass lfibers produced directly in a ber forming process; Y
Figure 2 is a front elevational viewof the apparatus `of Figure l;
Figure 3 is an enlarged isometric View of a ,pellet vof the present invention produced by the method and .apparatus of Figures l and 2;
Figure 4 is a somewhat schematic, `partially `sectional isometric view of another arrangement of apparatus for producing pellets of metal containing glass ftbers wherein already formed glass fibers are incorporated into rods of metal prior to pelletization; Y Y ,Y
Figure 5 is an enlarged isometric v iew of a pellet of the present invention as produced by the method and appara-y tus of Figure 4;
Patented Sept. 27; 1969 Figure 6 is a somewhat schematic, partially sectional isometric view of still another arrangement for producing metal and glass ber pellets in accordance with the .principles of the present invention;
Figure 7 Vis a schematic view of an arrangement for producing an extruded sheet structure yof metal andglass fibers adaptable to fabrication of pellets;
Figure 8 is an illustration -of ano-ther type of pellet adaptable to use in accordance with the principles of the present invention;
Figure 9 is an isometric view partially in cross section of a press having a cavity mold therein within which pellets of metaland glass fibers are deposited for pressure shaping into desired shape;
Figure lO is a side elevational viewsin cross section of an extrusion press for extrusion Vof pellets .into rods of cross-sectional shape corresponding to that of the press nozzle opening; Y
Figure l1 isa front View of the extrusion press of Figure 9 showing the shape ofthe nozzle opening as illustration of the rod shapes capable of beingproduced with pellets according to the present invention;
Figure l2 is a sectional isometric View of an arrangement forproducing patties or barsof metal and glass fibers adaptable to further reshaping; andV l Figure 13 'is an isometric view of a pair .of mill rolls into which a patty o-r bar composed of metal and glass fibers, such as is produced by the method V and apparatus of Figure l-l, can .be introduced for reshaping to forms such as a channel as illustrated.
In referring tothe `pelletization or formation `ofpellets in the present description, no specific geometric form or shapeY is intended, but rather any compositerstructural or particulate assembly of metal and glass which .canbe gathered in an accumulation of similar structures lfor treatment as mass is intended. Y
Metal may be worked in accordance with therpr'inciples of the present invention in such processes las drawing, rolling, forging,wor extrusion-either -in a `n on-l 1eated state or while heated `to a 4temperature' ashigl'i'asfthatat which the glass inclusions are softenedsluicientlyto permit plastic flow on deformation without disintegration of the metal, the vmetal also being plastic at such working tem# peratures'. Among the Ywideirange of metals which may be pelletized with glassfibers such `manner` are alurnij num, lead, zinc, copper, iron, steel, magnesium, etc. @In pelletization of these metals they may be incorporated while 'in .an initial stage Suchas powdered metal -or metal 'shavings which are then pressed into combination with metal coated fibers'. Any cfa Variety of fiberizable glass is subjectable .tothe Vpelletization yprocesses o'f the present invention and as zpresently -known `'the glass is not dimited to Vany criticalformulation.
Figures 1 -and 2 illustrate an arrangeme -t and 4method whereby pellets of 'metal-aud glass fibers are kproduced directly in a glass fiber forming process. In arrange` ment, a source of molten `glass l@ such as melting-tank or nfur-nace suppliesV glass to a feeder vlllhaving 'Oriftced tips 121therein fromwhich Yglass fibers i4 are attenuated. Upon formation, the bers 14 k-are drawn over the face of a metal-coating applicator 11.5 similar to the .type shownrand described in Whitehurst et al. application, Serial Number 322,598 whereby coating 4meta-l in `molten condition .is supported in projected relationship from the face of the applicator in the formof aV longitudinal globular strip 16 through which nthe `fibers are drawn for acquisitionofa metalY coating thereover toform metal coatedbers 17;. g. A ,n ,7, m Y
The metal coated fbers'l are gathered or grouped together by passage over va gathering roll'158 and then redrawnas Va strand through a globular strip 4of metal 20 held in projected 4relationship in the path'ofthe strand at the face of a second metal-coating applicator 19. In being drawn through a globule of molten metal, the strand of metal coated fibers 17 receives a coating which binds the fibers together into a stick-like grouping 21. The metal which effects the bonding of the metal coated glass fibers into the stick form may be the same as that coated on the fibers, or may be of a different type of higher or lower melting temperature than that of the coating directly on the fibers. If the bonding metal has a higher melting temperature than the coating directly on the glass, it can be readily applied by rapidly drawing the metalled fibers through the globule at such a rate that the air surrounding the stick acts to chill the bonding metal prior to its being effective to melt the direct coating of metal on the glass.
The stick-like form 21 of metal bonded, metal coated fibers is drawn at a relatively rapid rate of speed by a pair of pull wheels 22 which operate to provide the force for attenuation of fibers 14 from the feeder 11. The rate of attenuation is in the order of up to 10,000 feet per minute, or may be as low as 100 feet per minute or lower, if desired. In this respect the speed is not critical since the attenuation rate and rate of coating the fibers is not known to be limited. Upon leaving the pull wheels 22, the stick structure 21 is fed into a tubular shear guide 23 supported in the path of the stick to guide it into a gear-like cutting wheel 24 having cutting teeth 27 which cooperate with the lower edge of the guide 23 to shear off lengths of the stick into pellets 30 illustrated in greater detail in Figure 3.
Successive portions of the stick 21, on leaving the lower edge of the guide 23 are engaged by successive cutting teeth 27 of the wheel 24 to effect shearing of the stick into the pellets 30 having a length dependent upon the speed of the stick in its path through the guide 23 and the rate of revolution of the wheel 24. 'I'he Wheel 24 is driven through a drive pinion 25 by a motor 26. Both the motor 26 and a container 28 to which the pellets 30 are introduced upon cutting are supported by a table structure 29. Upon accumulation in the container 28, the pellets 30 are ready for further use according to processes described hereinafter.
Figure 3 illustrates in greater detail the structural form of a pellet 30 in which the glass fibers 14 are coated with a metal 17 and are bonded together by additional metal. The length of the pellets 30 according to this method may be any of a wide range of lengths the order of 1A" to 2" or longer While the diameter of the sticklike form 21 from which they are cut may be in the order of 1,44" to 1A depending upon the thickness of metal coating placed on the individual fibers as well as the number of coated fibers grouped and the thickness of coating applied to the combined grouping of coated fibers.
Figure 4 illustrates another arrangement for making metal-fibrous glass pellets wherein glass fibers in strand form, twisted or untwisted, are supplied from packages after having already been formed. The strands 41 are drawn from packages 40 through guide eyes 42 to a bath of molten metal 45 in a suitable high temperature Crucible or tank 44. The strands 41 are drawn into the bath 45 in spaced relationship but are gathered into a common grouping over a Wheel 48 located under the surface of the bath. 'Ihe strands are thus each individually coated before being gathered together and are then bonded together into a common metal coated rodlike form 49 which, upon leaving the bath 45, is drawn through a wiping die 50 which assures uniformity in the final dimension of the rod as well as effects a smoothening of the surface thereof.
On leaving the die 50, the bonded rod 49 is drawn through a pair of pull wheels 52 which provide the force for withdrawal of the individual strands 41 from the packages. The pull wheels supply the rod to a shear mechanism comprising a shear block 55 and a blade 54 which cooperate to cut the rod 49 into pellets 56 of desired length. The pellets upon being cut by the shear mechanism are deposited into a container 57 in which they are accumulated for subsequent use in further fabrication of metal structures.
Figure 5 illustrates with greater clarity the appearance of the pellets 56 made by the method and apparatus of Figure 4 showing the fibrous strands 41 grouped and bonded together by the metal coating the grouped strands. Each individual strand itself is coated in this instance while a complete grouping of metal coated strands is bonded together by the metal coated thereover. The strands 41 can be made of metal coated fibers, if desired, such as Iare produced by gathering fibers after the first stage of metal coating in the process of Figures 1 and 2. In such instance the bath of metal 45 can be of the same meta-l as is coated on the strand, or can be a different metal adapted to bonding the metal coated strands together. In such case, it will be noted that the metal coated fibers would also first be independently bonded as strands, and then subsequently bonded together as a rod after passage over the guide wheel 48.
Thus far the pelletization of metal and glass fibers has only been described in relation to formation of pellets from fibers in strand-like form while Figure 6 illustrates still another method for forming pellets starting with glass fibers in the form of fabric. Fabric 61 either of woven or unwoven type is drawn from a roll 60 and passed through a molten metal bath 65 in a suitable tank reservoir 64. The fabric is passed under a roll 66 within the bath and after receiving a coating thereof is withdrawn from the bath by passage over an upper sup- -ported guide roll 68 at the exterior of the reservoir 64.
The coated fabric is then passed through a pair of rolls 70 in a roll stand 69 where a compressive force is exerted thereon to extrude the combination as a sheet of thickness desired. Upon advancement through the rolls 70, the sheet is cut into longitudinal strips 75 by a series of rotary knife blades 72 cooperatively disposed above and below the path of the sheet and spaced apart to provide the widths of strip desired. The strips 75 are introduced to an upper surface of a support 74 upon which they are cut into segments or pellets 76 by a guillotinetype cutter 73 reciprocably operated to cut the strips to length corresponding to the pellet size desired. The pellets 76 are then deposited in a container 77 for accumulation and subsequent fabrication into products as hereinafter described.
Dipping and coating of various weaves of glass cloths, mats, or combinations can be effected in this manner, the coatings being metals or alloys such as aluminum, lead, zinc, etc. For example, a leno cloth can be drawn through a molten metal bath in accordance with this method to produce a continuous sheet of metal reinforced by glass fibers. Variations in the amount of metal to glass in the sheet may be achieved by altering the metal temperature as well as the speed of drawing the fabric through the bath. In this way aluminum or lead which have poor tensile strengths and relatively high coefiicients of expansion, can be reinforced to provide the high tensile strengths and lower coefficients of expansion to make them adaptable for use in many applications where they would otherwise be incapable of use.
As still yanother variation of this concept, a non-woven mat of glass fibers may be carried by a Woven fabric such as a leno fabric, and upon passage through the bath of molten metal can be made to form a composite of a metal sheet reinforced by both a woven and nonwoven fabric. In this way glass fibers are arranged in an oriented as well as non-oriented manner within the plane of the sheet of metal to provide tensile strengths in all directions of the plane of the sheet.
To promote wetting of the fabric 61 upon passage through the molten metal bath 65, differential temperatures may be established through the depth of the bath. In accordance with this principle, the upper levels of the bath are maintained at a somewhat lower temperature than the bottom of the bath. For example, if the depth of the bath were in the order of 15" to 20", the upper surface might be at a temperature in the order of 1250 F. while the bottom of the bath is at a temperature of 1500 F. Upon passage of the fabric into the bath, it is thus brought up in temperature gradually as it approaches the lower level, rather thanpbeing subjected to the high temperature immediately. The lower viscosity of the molten metal at the higher temperatures at the bottom of the tank lends itself to penetration of the fabric and then as it moves upwardly to cooler zones at the upper level of the bath, the impregnated material is more susceptible to acceptance of the coating of metal throughout its thickness. Upon leaving the upper zones of the bath at a lower temperature, the coating can be arranged to be sufficiently adhering to the mass that dripping of the material from the fabric will not take effect. In this way shock heating and cooling of the fabric to the degree which it might otherwise be subjected is avoided while at the same time providing the degree of penetration by metal to provide a matrix for the sheet is effected. To further promote the compatibility of glass fibers with the molten metal, a flux can be provided at the surface of the metal bath through which the fabric or mat is introduced prior to passage through the bath. Oxidation at the surface of the bath can thus be reduced and the more intimate association between the glass and metal can be established.
In other instances where the fabric is of non-woven type and a shift of libers therein is likely to occur, perforation of the fabric may be resorted to to promote more positive adherence of the metal to the fabric. By providing perforations in the fabric, slugs of metal are formed at each perforation by reason of a `web and then a slug being formed therein during the dipping step thereby providing anchors or keys for fibers intersecting the slugs. The coating of metal on the fabric is thus tixed relative to the anchors, minimizing the possibility of shift between the fibers and the metalin the final coated fabric. A suitably chosen pattern of perforations in the fabric minimizes fiber or strand movement to the degree that loads can be imparted to the reinforcement material before the disruption limit of the metal `film is reached. i
Figure 7 illustrates another arrangement for 'producing metal sheets reinforced with glass fibers adaptable to formation of pellets. In this arrangement glass fibers 82 are attenuated from orificed tips 81 ifi a feeder Sil associated with a molten glass supply source. The fibers are drawn across the face of a metal coat-ing applicator 84 having a quantity of molten metal 85 projecting in the path of the fibers for application of a coating to the fibers. Coated fibers are drawn by a pair of co-acting pulling rollers 87 which supply the force for attenuation of the bers 82 and also advance the iibers to a chopping device including a rubber back-up roll 88 and a bladed chopping roll 89 which cooperatively engages the coated fibers to chop them into short lengths for collection on the metal sheet or foil 91 passed under the chopping device. The chopped coated fibers are deposited on a metal sheet or foil 91 by way of a bame member 90 inclined downwardly to the sheet or foil and disposed angularly in the path of the dropping chopped fibers. The member 90 promotes uniform distribution onvv the sheet or foil and, if desired, may have an associated air blast directed thereagainst over its upper surface to assure uniform removal in those instances where hangup may tend to occur.
The sheet or foil 91 is withdrawn from a roll 92 and passed over a series of spot rollers 93 in the 'zone where the chopped coated fibers are deposited and conveyed prior to introduction into a roll stand 9S. Before introduction of the sheet 91 and the fiber conveyed thereon into the roll stand, another metal sheet or foil 96 is laid thereover to cause the chopped coated fibers to become sandwiched interposed between the two sheets. The sheet or foil 96 is withdrawn from a roll 94 disposed behind the roll stand 98 and above the path of movement of the sheet 91. The roll stand 98 includes a pair of compression rolls 97 adjustable in degree of compression by anadjustment screw 99.V The assembly of two sheets 91 and 96 with chopped fibers therebetween is passed between the compression rolls under adequate pressure to establish an intimate integral relationship between the three components to form an extruded metallic structure 100 reinforced by the fibers therebetween.
In addition to the formation of pellets in the manner of pelletizing the reinforced sheet produced in the arrangement of Figure 7, lthe composite sheet structure 100 is adaptable to end uses such as finishing of wall surfaces, both interior and exterior, roong surfaces, and reinforcement of other materials. The two sheets brought together to form the composite structure can be of different metals or the same metal, while the coating metal of the chopped coated fibers can be the same or different from that of the sheets. The thickness of the sheets is usually identical but may be of different thicknesses, if desired. In this respect the bottom sheet might be more rigid with the top` sheet being flexible, and upon combination into the composite structure being reinforced by the coated glass bers can be made still more rigid. Two flexible metallic sheets joined together in this wayA can likewise be joined to produce a rigid or plate-like structure. Although chopped coated fibers have been illustrated as being interposed between two sheets in this arrangement, it will be recognized that continuous coated fibers can also be incorporated between two sheets to produce a composite reinforced product according to these principles.
In addition to the foregoing methods of establishing an intimate relation between two flexible sheets of metal adaptable to later pelletization, it will be recognized that more than-two sheets of metal might be built into a composite in this way to produce a more rigid nal sheet of metal having corresponding strength properties. Each additional layer under such circumstances would have metal coated fibers interposed between it and the adjacent underlayer of metal with which it is associated. Additionally, powdered metal might be incorporated in between layers of metal together with the metal coated fibers to promote increased adherence between the joined sheets as well as to ll in voids between metal coated bers. Still further7 the metal coated fibers interposed between metal sheets prior to introduction between extrusion rolls may be in the form of a mat of coated fibers of the type such as might be produced in the arrangement of Figure 6 prior to being pelletized.
Figure 8V illustrates another type of pellet adaptable to fabrication into metal products reinforced by glass fibers. The pellets of this arrangement comprise chopped metal coated fibers of the type produced in the arrangement of Figure 7 which-rare, in a sense, balled or nodulated into the pellets 101. Such pelletization can be accomplishedin a ball-type mill wherein the metal coated bers are accumulated and rolled rinto the pelletized forms `and then withdrawn ready for further processing. In still another method, pelletization can be accomplished by introduction of metalled fibers or roving between a pair of closely spaced belts operating at diiferential speeds. Fibers or roving of considerable length coated with metal are adaptable to pelletization in this manner as well as chopped fibers of short length. In the latter instance each pellet is formed of an accumulation of a number of the chopped fibers, while in the case of the longer lmetal coated fibers, eachlength of fiber can be modulated into a single pellet.
Still `another method ofwmaking pellets involves the use of short glass bers or ground glass mixed with ne metal powders subjected to pressure at elevated temperatures to sinter and form dense integrated mixtures. If the sintering and hot working temperatures of the metal are above the softening point of the glass used, such sintered pellets can be hot extruded or hot rolled. The bers of the pellets are further attenuated during such operations While ground glass becomes berized under the high pressures exercised during the processes. The resultant glass reinforced metal has a superior high temperature character with lower yield characteristics than unreinforced metals. Powders of copper, iron, nickel, stainless steel and numerous other alloy powders can thus be incorporated in pellets for further fabrication. By way of example, pellets containing 50% by weight of chopped one mil glass bers and the remainder in copper powder form can be pelletized into sintered pellets at a temperature of 1650 F. under a pressure of 14,000 p.s.i. applied for 30 minutes.
Figure 9 illustrates the manner in which pellets of the present invention can be processed into metal products reinforced by glass bers. In this arrangement the pellets 105 are introduced into a mold cavity for application of compressive forces between two halves of a mold 103 and 104 inserted between the platens 106 and 108 of a press. Upon compression of the pellets within the mold cavity, it is preferable that the mold be heated so as to impart a condition of plasticity to the metal to permit more ready flow thereof into an integrated matrix for the glass bers while at the same time conforming to the contours of the mold. In some instances, it is desirable to heat the pellets to a degree of plasticity in the glass bers as well as in the metal in order to cause a distribution of the glass bers through the contoured matrix especially when the molded products are of intricate contoured shape. If the pressure exerted upon the pellets, however, is of suicient magnitude, the ilow of metal within the mold can be eected even when cool. In the case of application of heat to the pellets, however, it has been found desirable that the temperature be applied for a period during application of pressure to effect a soaking to permit uniform pressure distribution and to eliminate or minimize the possibility of voids in the nal molded product.
To permit application of working pressures upon pellets according to the present principles without damaging bers incorporated therein, sulcient metal is provided to prevent abrasion of bers against one another during the application of pressure forces. Additionally, plastic flow can be effected by application of suicient pressure after raising 'the temperature of the matrix to within approximately 2/3 to of the absolute melting point of the metal or alloy used. Sufcient time is also allowed under pressure to cause uniform distribution of forces to eliminate voids. A thermal equilibrium through the accumulated pellets is further desired to minimize tendencies toward breakage of bers. If these principles are followed, the metal surrounding the bers acts as a lubricant to prevent ber damage and in turn the strength of the bers is imparted to the product made with the pellets.
To minimize the possibility of voids in some instances of molding, powdered metal can be incorporated with the pellets to promote the intimacy of metal particles prior to application of pressure. -If the metal in powdered form and as coatings on the bers is copper and is a predominant portion of the material in the mold cavity, that is more than 50% by weight; and the mixture is stirred well to eect intimate contact between the metal particles and the metal coated glass bers, a sintered product molded in conformity with the cavity can be produced. Metal such as aluminum and copper have proven quite successful for production of sintered products of this type. In still other substances, powdered glass can be incorporated in the accumulation of metal pellets reinforced by glass bers. In such instances, application of pressure to the accumulation when at a high temperature results in distribution of the glass particles in extended form through the metal matrix forming actual and close semblances of glass bers which become active in reinforcing the metal product.
Figures 10 and 11 illustrate an extrusion press 110 from which pellets 112 of metal reinforced with glass bers can be extruded into bar-type forms of various shapes such as a bar 113 upon application of pressure by way of a piston 111 of the press. The temperature of the press is maintained at a value such that the pellets acquire a degree of plasticity on emission from the press nozzle to bring the metal of the pellets in intimate relationship as a matrix for the glass bers. Powdered metal may be incorporated with the pellets, if desired, as well as powdered glass, but preferably suicient metal is provided in the pellets such that a mixture of other particles is unnecessary.
Figure 12 illustrates a method whereby patties or rodtype bars of metal reinforced by glass bers may be produced for fabrication into products such as a channel extruded in the manner illustrated in Figure 13. In the arrangement of Figure 12, either metal coated glass bers or bare glass bers are inserted in a holder which has a foraminous seat 121 at its bottom having a suction chamber 124 thereunder from which air is withdrawn through a tube 125 connected to a Vacuum pump, not shown. The glass bers are compacted in the holder to conform to the general shape of the cavity of the holder, after which molten metal 128 is poured from a crucible 126 for impregnation and coverage of the mass of bers. The metal 128 is distributed over the surface of the compacted mass of bers and is caused to be drawn into the mass by the forces of gravity as well as the forces created by establishment of the low pressure zone below the mass in the chamber 124. Enough metal is poured into the recess of the holder to cause complete distribution through the mass, while the mass of bers deposited in the holder is limited in depth so that sucient forces exerted on the metal poured on the mass to draw it to the lower levels of the mass of bers. Upon solidication, a metal patty or bar results having glass bers distributed throughout and shaped to lend itself to further fabrication.
By way of example, patties of aluminum containing reinforcing bers can be formed to desired shapes by raising the temperature of the patty to 600 F. and subjecting it to pressures in the order of 80,000 p.s.i. When a lead-cadmium-zinc alloy patty containing continuous glass bers is used, it may be formed to desired shapes at a temperature of 400 F. under pressures in the order to 20,000 p.s.i. When a zinc patty is used with continuous glass bers reinforcing the form, a temperature of 500 F. and a pressure of 40,000 p.s.i. will produce desired shapes in a die.
The patties or the rod-type bars may be machined into chips or otherwise to turnings by various milling, lathe turning, or rough grinding methods. Premolding of notches into the patties, rods, or sticks may be done as desired to aid in such subdivision steps.
A bar or patty of metal reinforced with glass bers can be passed through a pair of rolls such as rolls 130 and 131, respectively, having grooves 132 therein properly shaped and positioned to produce a channel member of the bar 134 on passage therethrough. In a sense, the rolling of the patty or bar to the shape desired is conventional in that it resembles processes utilized in rolling various shapes from ingots. Correspondingly the rolling process is effected while the bar 134 is hot to the extent that the material thereof is plastic and conformable to the roll contours. It should be noted that the temperature of the bar for extrusion is not limited to metals having extrusion temperatures below the softening temperature .Ofthe glass bers used. Under the high pressures of such extrusion processes, the glass will remain in ber form of various lengths even when in plastic condition in view of the fact that the pressure exerted acts to elongate particles of material in plastic form within bars during such processes, thus resulting in retention of the fibrous form regardless of the fact that the temperature of the bar is above the softening temperature of the glass bers.
Metal coated bers or rovings, chopped or continuous, as well as bare glass bers or rovings, chopped or continuous, can be incorporated in patties or bars of this type and can be fabricated into rods, bars, plates, sheets, channels and I-beams and other structural shapes in further metal working steps such as pressing, extrusion or rolling. Powdered metal, or powdered glass can also be incorporated in patties of glass bers in methods such as are exemplied in Figure 12, prior to pouring of metal 128 thereover. Further with regard to the arrangement of Figure l2, the holder 120 can be heated to a temperature sucient to assure ow of molten metal introduced thereto to the bottom of the mass of bers, in those instances where dilculty is experienced in this regard.
It will be appreciated that the pellets or small units of glass reinforced metal which are provided by the invention oier a desired convenience to the metal fabricator who is concerned With forming a metal article from any given metal reinforced with glass. The direct introduction of glass into metal is both inconvenient generally to metal fabricators and involves Working with bulky masses in some cases. Where it is desired to preserve the advantages of freshly formed glass surfaces, this also can not be done as the metal fabricator is expected to Work with glass bers that have been processed and made elsewhere.
By the invention there is prepared a unit article which can be conveniently shipped, stored, or fed into metal fabricating operations and as a pellet, segment, or small chip, stick, nodule, or mass, the composite of glass bers or metal is provided in a form readily adaptable to extrusion, pressing, or shaping by various means of compacting either under heat and pressure or pressure alone.
Where the pellet is made of an elongated stick form by methods such as are illustrated in Figures 1 to 5 herein, the glass bers are parallel in arrangement with respect to each other. It is obvious that under a compacting process that these sticks will generally arrange themselves also parallel with respect to each other thus giving a product in which most of the glass bers Will be found in alignment and in one direction. It is a specific advantage, however, of the invention that metal masses which are made with substantially squared, cubical or spherical pellets are characterized in that the bers in the adjacent areas corresponding to the original pellets carry glass bers which lie at yall diierent angles thus giving a compacted glass ber reinforced metal article wherein the glass bers are either completely non-oriented or are oriented only in small discrete areas adjacent to other areas where the bers are oriented in an entirely different direction. By such means, metal masses may be made wherein the physical properties do not change with respect to the direction through the mass being tested.
In View of the foregoing description, it will be understood that changes may be made in the details of the various forms of the invention illustrated herein without departing from the spirit of the invention, especially as dened in the following claims.
I claim:
1. lA method for producing glass reinforced metal articles comprising metal coating each of a multiplicity of continuous glass bers, grouping the coated glass bers and bonding them together with metal into a stick-like form, cutting said stick-like form into pellets comprising short length segments of said stick-like form, and applying forces to said pellets as a mass to eiect a Working thereof into a metal matrix of the shape desired reinforced by said glass bers distributed throughout the matriX.
2. 'Ihe method for producing glass reinforced metal articles according to claim 1 wherein the metal for coating the continuous glass bers is diiferent from the metal used to bond the coated glass bers together into sticklike form.
3. A method yfor producing glass reinforced metal articles comprising metal coating each of a plurality of continuous strands of glass bers, grouping said plurality of coated strands into adjacent parallel relationship, bonding the grouped coated strands with metal into an integral longitudinal body, cutting said longitudinal body into segments of Arelatively short length, accumulating said segments into a mass and applying heat and pressure to said mass of segments to work them into integrated relationship as a metal matrix of the shape desired reinforced by said glass bers distributed throughout the matrix.
References Cited in the le of this patent UNITED STATES PATENTS 805,963 Jackson Nov. 28, 1905 1,563,584 OShaughnessy Dec. 1, 1925 1,748,587 Smedley Feb. 25, 1930 2,234,127 Mautsch Mar. 4, 1941 2,375,178 Ruben May 1, 1945 2,559,572 Stalego July 3, 1951 2,577,205 Meyer Dec. 4, 1951 2,616,165 Brennan Nov. 4, 1952 2,628,417 Peyches Feb. 17, 1953 2,699,415 Nachtman Jan. 11, 1955 2,717,946 Peck Sept. 13, 1955 2,729,028 Slayter Jan. 3, 1956 2,730,597 Podolsky Jan. 10, 1956 2,772,518 Whitehurst Dec. 4, 1956 2,782,563 Russell Feb. 26, 1957 2,797,469 Kahn July 2, 1957

Claims (1)

1. A METHOD FOR PRODUCING GLASS REINFORCED METAL ARTICLES COMPRISING METAL COATING EACH OF A MULTIPLICITY OF CONTINUOUS GLASS FIBERS, GROUPING THE COATED GLASS FIBERS AND BONDING THEM TOGETHER WITH METAL INTO A STICK-LIKE FORM, CUTTING SAID STICK-LIKE FORM INTO PELLETS COMPRISING SHORT LENGTH SEGMENTS OF SAID STICK-LIKE FORM, AND APPLYING FORCES TO SAID PELLETS AS A MASS TO EFFECT A WORKING THEREOF INTO A METAL MATRIX OF THE SHAPE DESIRED REINFORCED BY SAID GLASS FIBERS DISTRIBUTED THROUGHOUT THE MATRIX.
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Cited By (25)

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US3084421A (en) * 1960-10-21 1963-04-09 David L Mcdanels Reinforced metallic composites
US3095642A (en) * 1957-11-26 1963-07-02 Owens Corning Fiberglass Corp Metal and fiber composite materials and methods of producing
US3098723A (en) * 1960-01-18 1963-07-23 Rand Corp Novel structural composite material
US3134704A (en) * 1960-05-13 1964-05-26 Reichhold Chemicals Inc Method of and apparatus for multiple forming and winding of glass and resin filaments
US3156283A (en) * 1961-02-14 1964-11-10 Henry F Ruschmann Operating upon sheets of foil
US3188188A (en) * 1957-07-03 1965-06-08 American Optical Corp Apparatus for making fiber optical components
US3187422A (en) * 1956-08-27 1965-06-08 Owens Corning Fiberglass Corp Reinforcement of metal
US3204326A (en) * 1960-12-19 1965-09-07 American Optical Corp Multi-element energy-conducting structures and method of making the same
US3239919A (en) * 1961-08-15 1966-03-15 Rola Company Australia Proprie Method of producing high energy permanent magnets
US3256596A (en) * 1961-02-06 1966-06-21 William S Fiedler Process for making article of vitreous material and metal
US3264074A (en) * 1962-04-04 1966-08-02 Lear Siegler Inc Thin film electron emissive electrode
US3421862A (en) * 1965-05-17 1969-01-14 Gen Technologies Corp High strength whisker composite article
US3441392A (en) * 1967-03-27 1969-04-29 Melpar Inc Preparation of fiber-reinforced metal alloy composites by compaction in the semimolten phase
US3676916A (en) * 1970-01-02 1972-07-18 Monsanto Co Method for preparing metal molding compositions
US3683485A (en) * 1970-01-02 1972-08-15 Royce G Schierding Method of fabricating a steel-filament reinforced metal composite
US3736646A (en) * 1971-10-18 1973-06-05 American Cyanamid Co Method of attaching surgical needles to multifilament polyglycolic acid absorbable sutures
US3751271A (en) * 1970-05-12 1973-08-07 Toyota Kk Sintered filter having straight holes therethrough
US3887365A (en) * 1971-03-24 1975-06-03 Nasa Process for making sheets with parallel pores of uniform size
US3904377A (en) * 1970-03-06 1975-09-09 Agency Ind Science Techn Lightweight composite containing hollow glass microspheres
US4127700A (en) * 1973-10-12 1978-11-28 G. Rau Metallic material with additives embedded therein and method for producing the same
US4776865A (en) * 1986-12-16 1988-10-11 Corning Glass Works Method of forming a fiber-reinforced inorganic composite
US5724711A (en) * 1994-03-01 1998-03-10 Global Material Technologies Incorporated Apparatus for making steel wool filter pads and related method
US6131285A (en) * 1997-12-31 2000-10-17 Dana Corporation Pultrusion method of manufacturing a composite structural component
US6465110B1 (en) 2000-10-10 2002-10-15 Material Sciences Corporation Metal felt laminate structures
US20080178985A1 (en) * 2007-01-25 2008-07-31 Ford Global Technologies, Llc Apparatus and method for making fiber reinforced sheet molding compound

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US2375178A (en) * 1941-10-01 1945-05-01 Ruben Samuel Variable electrical resistor
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Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3187422A (en) * 1956-08-27 1965-06-08 Owens Corning Fiberglass Corp Reinforcement of metal
US3188188A (en) * 1957-07-03 1965-06-08 American Optical Corp Apparatus for making fiber optical components
US3095642A (en) * 1957-11-26 1963-07-02 Owens Corning Fiberglass Corp Metal and fiber composite materials and methods of producing
US3098723A (en) * 1960-01-18 1963-07-23 Rand Corp Novel structural composite material
US3134704A (en) * 1960-05-13 1964-05-26 Reichhold Chemicals Inc Method of and apparatus for multiple forming and winding of glass and resin filaments
US3084421A (en) * 1960-10-21 1963-04-09 David L Mcdanels Reinforced metallic composites
US3204326A (en) * 1960-12-19 1965-09-07 American Optical Corp Multi-element energy-conducting structures and method of making the same
US3256596A (en) * 1961-02-06 1966-06-21 William S Fiedler Process for making article of vitreous material and metal
US3156283A (en) * 1961-02-14 1964-11-10 Henry F Ruschmann Operating upon sheets of foil
US3239919A (en) * 1961-08-15 1966-03-15 Rola Company Australia Proprie Method of producing high energy permanent magnets
US3264074A (en) * 1962-04-04 1966-08-02 Lear Siegler Inc Thin film electron emissive electrode
US3421862A (en) * 1965-05-17 1969-01-14 Gen Technologies Corp High strength whisker composite article
US3441392A (en) * 1967-03-27 1969-04-29 Melpar Inc Preparation of fiber-reinforced metal alloy composites by compaction in the semimolten phase
US3676916A (en) * 1970-01-02 1972-07-18 Monsanto Co Method for preparing metal molding compositions
US3683485A (en) * 1970-01-02 1972-08-15 Royce G Schierding Method of fabricating a steel-filament reinforced metal composite
US3904377A (en) * 1970-03-06 1975-09-09 Agency Ind Science Techn Lightweight composite containing hollow glass microspheres
US3751271A (en) * 1970-05-12 1973-08-07 Toyota Kk Sintered filter having straight holes therethrough
US3887365A (en) * 1971-03-24 1975-06-03 Nasa Process for making sheets with parallel pores of uniform size
US3736646A (en) * 1971-10-18 1973-06-05 American Cyanamid Co Method of attaching surgical needles to multifilament polyglycolic acid absorbable sutures
US4127700A (en) * 1973-10-12 1978-11-28 G. Rau Metallic material with additives embedded therein and method for producing the same
US4776865A (en) * 1986-12-16 1988-10-11 Corning Glass Works Method of forming a fiber-reinforced inorganic composite
US5724711A (en) * 1994-03-01 1998-03-10 Global Material Technologies Incorporated Apparatus for making steel wool filter pads and related method
US6131285A (en) * 1997-12-31 2000-10-17 Dana Corporation Pultrusion method of manufacturing a composite structural component
US6465110B1 (en) 2000-10-10 2002-10-15 Material Sciences Corporation Metal felt laminate structures
US20080178985A1 (en) * 2007-01-25 2008-07-31 Ford Global Technologies, Llc Apparatus and method for making fiber reinforced sheet molding compound
US7691223B2 (en) * 2007-01-25 2010-04-06 Ford Global Technologies, Llc Apparatus and method for making fiber reinforced sheet molding compound

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