US2938384A - Temperature-actuated power device - Google Patents

Temperature-actuated power device Download PDF

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Publication number
US2938384A
US2938384A US469098A US46909854A US2938384A US 2938384 A US2938384 A US 2938384A US 469098 A US469098 A US 469098A US 46909854 A US46909854 A US 46909854A US 2938384 A US2938384 A US 2938384A
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Prior art keywords
plunger
casing
temperature
pellet
medium
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Expired - Lifetime
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US469098A
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Edgar M Soreng
Douglas K Mcilvaine
Wilbert E Beller
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Controls Company of America
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Controls Company of America
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Priority to US469098A priority Critical patent/US2938384A/en
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    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D23/00Control of temperature
    • G05D23/01Control of temperature without auxiliary power
    • G05D23/13Control of temperature without auxiliary power by varying the mixing ratio of two fluids having different temperatures
    • G05D23/1306Control of temperature without auxiliary power by varying the mixing ratio of two fluids having different temperatures for liquids
    • G05D23/132Control of temperature without auxiliary power by varying the mixing ratio of two fluids having different temperatures for liquids with temperature sensing element
    • G05D23/1326Control of temperature without auxiliary power by varying the mixing ratio of two fluids having different temperatures for liquids with temperature sensing element details of the sensor

Definitions

  • the present invention is concerned with the type of devices operating under the action of expansion or contraction of a thermally responsive medium which is confined within a sealed chamber, the said medium acting on a plunger of relatively small cross-sectional area to produce axial movement of the plunger.
  • This axial movement of the plunger may be used to open or close valves or switches or to actuate any suitable mechanism.
  • One of the objects of our invention is the provision of a device of the foregoing character which has a high degree of sensitivity to temperature changes.
  • Another object of our invention is the provision of a thermally responsive element having a high degree of expansion and contraction.
  • Another object of our invention is the provision in a thermally responsive element of a solid heat-exchanging porous mass and an expansible fusible medium having a high coefiicient of expansion impregnated in said mass.
  • a further object of our invention is the provision of a device of the foregoing character which is highly consistent in its response to temperature changes.
  • FIG. 1 is a perspective view of a temperature-actuated power device in accordance with our invention
  • Fig. 2 is a longitudinal cross-sectionalview on an enlarged scale of the device shown in Fig. 1;
  • Fig. 3 is a longitudinal cross-sectional view of a thermostaticallycontrolled water-mixing valve incorporating our invention
  • Fig. 4 is a longitudinal cross-sectional View of a modified embodiment of our invention.
  • the said pellet may be formed, for example, from powdered copper compressed and sintered so as to form a coherent solid mass having a desired porosity.
  • the pellet 7 of course may be pre-formed and sintered and then inserted within the casing 5, or a mass of powdered metal may be compressed within the casing and both subjected to a sintering procedure.
  • the mass of the pellet or sintered mass be r 2,938,384 patented May 31, 1960 ice in very intimate contact with the inner wall surfaces of the casing to provide a direct heat exchange between the external surfaces of the casing and the pellet.
  • a pellet having a porosity of about- 40% is satisfactory for conditions involved in the use of our device in connection with thermostatically controlled water-mixing valves. It is of course to be understood that the porosity of the pellet may be varied to suit the desired conditions of application. 7
  • fusible crystalline materials taken preferably from the general class of crystalline waxes which includes paratfins and soaps. Combinations of such materials give desired fusion points. These materials have a high coefficientof expansion in their transition phases or changes of state in desired temperature ranges during which they undergo substantial volumetric changes. Following are some examples of proportions of combined materials and the resulting fusion points of each combination:
  • Example 1 parafiin wax 10% micro-crystalline wax Fusion point 120 F.
  • Example 2 50% parafin wax 50% mineral oil Fusion point 104 F.
  • Example 4 75% paratlin wax 25% petrolatum Fusion po'int 121 F.
  • Fig. 3 of the drawings which illustrates a practical application of our device in combination with a water-
  • the temperature-responsive device of our invention is suitably'secured within the hot water inlet chamber 17 of the valve housing 18, with the plunger 11 acting ,on a spring-loaded valve 19 in the cold water inlet chamber 20.
  • hot water enters through port 21 and circulates around the casing 5.
  • motion-transmitting boot 31 shaped substantially like that illustrated in Fig. 4 lies against the throat portion 26 and enters into the-bore 27.
  • the boot is provided with anannularflange 32 which is confined between vthe casing and the bonnet, the fiange'serving also as a gasket for sealing purposes.
  • the boot 31 is provided with, an axial bore 33 in which is received a rigid plug 34, the exposed end of the plug being in contact with the motive medium which fills thechamber immediately above the impregnated pellet.
  • a disk 37 of elastic material of such character Disposed between the head 36 of the boot and the plunger 28-is a disk 37 of elastic material of such character that it will flow under pressure of the plunger 28and contract to its original shape when the pressure is removed, thereby providing a sealing means with a minimum of friction on the side walls ofthe bore 27.
  • the disk 37 reduces the clearance between the plunger 28 and the bore 27 by making actual contact with the wall of the bore.
  • the boot 31 may be formed of any suitable elastic material which will permit periodic extension of the head 36 into the bore of the bonnet without rupture under prolonged service conditions.
  • pressure on the plug 34 will effect movement of the same axially to the right, as viewed in Fig. 4, effecting extension of the head 36 of the boot into the bore 27 and compression of the same against the end of the plunger 28 through the sealing disk 37, resulting in axial movement of the plunger 28.
  • the plug 34 is used preferably in applications where the character of the motive medium is such that space within the boot may not be effectively filled by the said medium.
  • Theterm fusible material is a generic term embodying those materials which have a high coeflicient of expansion in their transition phases or changes of state in specific temperature ranges-
  • the term includes the specific mixtures listed previously and other compositions generally known in the art such as parafiin wax (alone) which may be used for this purpose depending on the fusion point desired.
  • a thermostatic expansible, contractible power generating element having a casing, a plunger reciprocable in the casing, a pressure chamber in the casing, a single solid heat exchanging porous metallic body substantially comi and plunger with pletely filling the chamber, a fusible material impregnated in the body, the material being expansible on'fusio'n and being fusible in the operating range of the'thermostatic element, and force transferring means between the body and plunger and operable to transmit the expansive force of the material to the plunger.

Description

May 31, 1960 E. M. SORENG ET AL 2,938,384
TEMPERATURE-ACTUATED POWER DEVICE Filed Nov. 16, 1954 2 Sheets-Sheet 1 y 1950 E. M. SORENG ET AL 2,938,384
TEMPERATURE-ACTUATED POWER DEVICE Filed Nov. 16, 1954 2 Sheets-Sheet 2 Z g; "f"
teristics.
copper particles is bonded to the casing walls.
United States Patent TEMPERATURE-ACTUATED POWER DEVICE Edgar M. Soreng, Glenview, Douglas K. McIlvaine, Des
Plaines, and Wilbert E. Beller, Park Ridge, 111., assignors, by mesne assignments, to Controls Company of America, Schiller Park, 111., a corporation of Delaware Filed Nov. 16, 1954, Ser. No. 469,098
4 Claims. (Cl. 73-358) Our invention relates to temperature-actuated power devices.
The present invention is concerned with the type of devices operating under the action of expansion or contraction of a thermally responsive medium which is confined within a sealed chamber, the said medium acting on a plunger of relatively small cross-sectional area to produce axial movement of the plunger. This axial movement of the plunger may be used to open or close valves or switches or to actuate any suitable mechanism.
One of the objects of our invention is the provision of a device of the foregoing character which has a high degree of sensitivity to temperature changes.
Another object of our invention is the provision of a thermally responsive element having a high degree of expansion and contraction.
Another object of our invention is the provision in a thermally responsive element of a solid heat-exchanging porous mass and an expansible fusible medium having a high coefiicient of expansion impregnated in said mass.
A further object of our invention is the provision of a device of the foregoing character which is highly consistent in its response to temperature changes.
Other and further objects and advantages of our invention will become apparent from the following description when considered in connection with the accompanying drawings, in which Fig. 1 is a perspective view of a temperature-actuated power device in accordance with our invention;
Fig. 2 is a longitudinal cross-sectionalview on an enlarged scale of the device shown in Fig. 1;
Fig. 3 is a longitudinal cross-sectional view of a thermostaticallycontrolled water-mixing valve incorporating our invention;
Fig. 4 is a longitudinal cross-sectional View of a modified embodiment of our invention.
According to one form of our invention, as illustrated in Fig. 2, we provide a cup-shaped casing 5 having an integral annular flange 6, the said casing being formed preferably of metal having high heat-exchanging charac- Contained within and substantially filling said casing is a pellet or mass of porous metal 7. The said pellet may be formed, for example, from powdered copper compressed and sintered so as to form a coherent solid mass having a desired porosity. The pellet 7 of course may be pre-formed and sintered and then inserted within the casing 5, or a mass of powdered metal may be compressed within the casing and both subjected to a sintering procedure. In the latter case, the mass of In any event, it is essential that the pellet or sintered mass be r 2,938,384 patented May 31, 1960 ice in very intimate contact with the inner wall surfaces of the casing to provide a direct heat exchange between the external surfaces of the casing and the pellet. We have found that a pellet having a porosity of about- 40% is satisfactory for conditions involved in the use of our device in connection with thermostatically controlled water-mixing valves. It is of course to be understood that the porosity of the pellet may be varied to suit the desired conditions of application. 7
While copper is highly desirable for use in applications where high heat-exchanging characteristics are desired, it is to be understood, however, that other materials such as stainless steel, aluminum, or brass may be used where different degrees of heat conductivity are desired. For example, in applications where a delayed heat transfer is desired, stainless steel, because of its lower heat conductivity characteristics would be employed.
To serve as the motive or power medium we employ fusible crystalline materials, taken preferably from the general class of crystalline waxes which includes paratfins and soaps. Combinations of such materials give desired fusion points. These materials have a high coefficientof expansion in their transition phases or changes of state in desired temperature ranges during which they undergo substantial volumetric changes. Following are some examples of proportions of combined materials and the resulting fusion points of each combination:
Example 1 parafiin wax 10% micro-crystalline wax Fusion point 120 F.
Example 2 50% parafin wax 50% mineral oil Fusion point 104 F.
Example 3 25% paraffin wax 75% pe'trolat'ttm Fusion point F.
Example 4 75% paratlin wax 25% petrolatum Fusion po'int 121 F.
In carrying out our invention, we impregnate or saturate the porous pellet with a composition of crystalline material having a desired fusion point while said material is in a liquid or molten state. The same is accomplished by first evacuating air from the interstices or pores of the pellet as by heating the pellet or subjecting it to a vacuum. The material is then forced under pressure into the pores or interstices of the pellet until the pellet is completely saturated with the material. When the charged pellet thereafter is subjected to heat Within a prescribed temperature range, the crystalline material undergoes a change of state from solid to liquid accompanied with a correspondingly large increase in volume of such liquid material. Upon cooling of the material below its fusion point, the material undergoes corresponding contraction when reverting to its crystalline state. It is believed that upon cooling and contraction of the material within the pores of the pellet a capillary action is inducedwhich ensures return of the material back into the pores-and mixing valve.
interstices of the pellet over and above the externally engagement as with a coupling collar 16 which is spun over the marginal edges of the flange and the bonnet.
. "It will be understood, however, that other suitable means may be provided for securing the two parts together.
The space within the casing between the saturated pellet 7 and the inner end of the plunger 11 is charged .with a suitable force-transferring medium capable of flow, which material also acts as a lubricant. It will be understood, however, that under certain conditions of operation or application, the force-transferring medium ;may be omitted, in which event the pressure-responsive material will act directly on the plunger. 1
It is required in our invention that the plunger ll'be spring-biased to eifect a return of the same when contraction of the motive medium is efiected, as when the device is cooled below the fusion point of the motive -medium. This may be accomplished, as is illustrated in Fig. 3 of the drawings, which illustrates a practical application of our device in combination with a water- Here the temperature-responsive device of our invention is suitably'secured within the hot water inlet chamber 17 of the valve housing 18, with the plunger 11 acting ,on a spring-loaded valve 19 in the cold water inlet chamber 20. In the operation of the thermostatically controlled water-mixing valve illustrated in Fig. 3, hot water enters through port 21 and circulates around the casing 5. If the temperature of the water is higher than the fusion point of the motive medium, it is caused to expand to move the plunger 11 to the right, as viewed'in Fig. 3, to unseat the valve 19 to admit cold water entering through the port opening 22 into the chamber 17. As the temperature of the water chamber 17 is lowered contraction of the motive medium within the casing is eflected, permitting the plunger 11 to be casing by a coupling collar 29.which is spun over the marginal .edges of the casing flange and bonnet. A
. motion-transmitting boot 31 shaped substantially like that illustrated in Fig. 4 lies against the throat portion 26 and enters into the-bore 27. The boot is provided with anannularflange 32 which is confined between vthe casing and the bonnet, the fiange'serving also as a gasket for sealing purposes. The boot 31 is provided with, an axial bore 33 in which is received a rigid plug 34, the exposed end of the plug being in contact with the motive medium which fills thechamber immediately above the impregnated pellet. Disposed between the head 36 of the boot and the plunger 28-is a disk 37 of elastic material of such character that it will flow under pressure of the plunger 28and contract to its original shape when the pressure is removed, thereby providing a sealing means with a minimum of friction on the side walls ofthe bore 27. Thus, when the pressure is high and the elastic boot-31 has; a; greater tendency for extrusion,
the disk 37 reduces the clearance between the plunger 28 and the bore 27 by making actual contact with the wall of the bore.
The boot 31 may be formed of any suitable elastic material which will permit periodic extension of the head 36 into the bore of the bonnet without rupture under prolonged service conditions. Upon expansion of the motive medium within the casing, it will be apparent that pressure on the plug 34 will effect movement of the same axially to the right, as viewed in Fig. 4, effecting extension of the head 36 of the boot into the bore 27 and compression of the same against the end of the plunger 28 through the sealing disk 37, resulting in axial movement of the plunger 28. It is to be understood that the plug 34 is used preferably in applications where the character of the motive medium is such that space within the boot may not be effectively filled by the said medium. It will of course be understood that, under certain conditions, the use of a plug may be eliminated and the motive medium caused to flow "directly into the bore of the 'boot. Additionally, the disk member 37 may be eliminated when the pressures are so low as to eliminate any tendency of the boot extruding into the space between the plunger and the bore.
While the inherent elasticity of the boot 31 in the embodiment illustrated in Fig. 4, upon contraction of the required'that spring means, such as employed in the device illustrated in Fig. 3, be used to efiect a return of the plunger 28.
It is evident in each of the embodiments hereinabove described that the bore of the bonnet and plunger are of reduced cross-section compared to that of the casing. Accordingly, any expansion occurring'within the casing results in a magnification of linear motion within the bore of the bonnet, resulting in substantial axial movement of the plunger, which may be utilized for useful work.
Various changes coming within the spirit of our invention may suggest themselves to those skilled in the art. Hencetwe do not wishto be limited to the specific embodiments described or uses mentioned, but intend the same to be merely exemplary, the scope of our invention being limited only by the appended claims.
Theterm fusible material, as used in the claims, is a generic term embodying those materials which have a high coeflicient of expansion in their transition phases or changes of state in specific temperature ranges- The term includes the specific mixtures listed previously and other compositions generally known in the art such as parafiin wax (alone) which may be used for this purpose depending on the fusion point desired.
We claim: v 3 U a 1. A thermostatic expansible, contractible power generating elementhavinga casing, a plunger reciprocable in the casing, a pressure chamber in the casing, a single solid heat exchanging porous metallic body substantially comi and plunger with pletely filling the chamber, a fusible material impregnated in the body, the material being expansible on'fusio'n and being fusible in the operating range of the'thermostatic element, and force transferring means between the body and plunger and operable to transmit the expansive force of the material to the plunger.
2. The combination according to claim 1 in which the ,eratingelement having a'casing, a plunger reciprocable in the-casing, -a pressure chamber in the casing, a single solid heat exchanging porous metallic: body substantially completely filling. the chamber, a fusible material impreg- References Cited in the file of this patent UNITED STATES PATENTS Davis Nov. 5, 1940 Vernet Oct. 21, 1941 Vernet Dec. 9, 1-941 6 Truxell et a1. Oct. 6, 1942 Kunzog Aug. 31, 1948 Jensen June 6, 1950 Albright Apr. 15, 1952 Scherer Oct. 22, 1957 FOREIGN PATENTS Great Britain Oct. 18, 1935 Great Britain Apr. 6, 1949
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Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3067944A (en) * 1959-11-23 1962-12-11 Meier Bernhard Temperature controlled radiator valve
US3129589A (en) * 1960-04-01 1964-04-21 Ametek Inc Pressure responsive instrument
US3131563A (en) * 1958-12-24 1964-05-05 Jack A Britton Thermal power device
US3194009A (en) * 1963-09-20 1965-07-13 Baker Res And Dev Corp Thermal actuators
US3212337A (en) * 1960-11-03 1965-10-19 Texas Instruments Inc Thermally responsive actuators
US3302391A (en) * 1965-01-25 1967-02-07 Tempstat Corp Thermal actuators
US3329022A (en) * 1963-11-04 1967-07-04 Emerson Electric Co Temperature measurement by sublimation of layers of radioactive material
US3386065A (en) * 1967-03-15 1968-05-28 Dole Valve Co Snap acting thermal element
US3404530A (en) * 1967-03-01 1968-10-08 United Carr Inc Heat motor
US3505809A (en) * 1968-05-20 1970-04-14 Thermal Hydraulics Corp Thermal motor
US3591078A (en) * 1965-06-17 1971-07-06 Maurice Feinberg Thermostatic device
US3665770A (en) * 1970-07-24 1972-05-30 Bio Medical Sciences Inc Temperature indicator
US3805528A (en) * 1972-10-02 1974-04-23 Gould Inc Thermal actuator
US4344450A (en) * 1980-04-08 1982-08-17 Walters William R Icing preventor
US4507922A (en) * 1981-11-30 1985-04-02 Leonard W. Suroff Thermostatic assembly
US4818119A (en) * 1986-05-19 1989-04-04 Rastech, Inc. Hot bearing warning bolt
US4979372A (en) * 1988-03-10 1990-12-25 Fuji Koki Mfg. Co. Ltd. Refrigeration system and a thermostatic expansion valve best suited for the same
US5044170A (en) * 1988-03-10 1991-09-03 Fujikoki Mfg. Co., Ltd. Refrigeration system and a thermostatic expansion valve best suited for the same
US5419133A (en) * 1989-09-05 1995-05-30 Schneider; Edward T. High speed thermochemical actuator
US5685149A (en) * 1995-11-14 1997-11-11 Tcam Technologies, Inc. Proportionally controlled thermochemical mechanical actuator
US5692535A (en) * 1996-12-03 1997-12-02 Walters; William R. Icing preventer with temperature adjustment washer
WO1997049914A1 (en) * 1996-06-24 1997-12-31 Metex Corporation Wax motor
US5720169A (en) * 1995-05-23 1998-02-24 Schneider; Edward T. Thermochemical/mechanical actuator
US5822989A (en) * 1996-06-03 1998-10-20 Tcam Technologies, Inc. Thermochemical/mechanical brake and clutch unit
US20050211153A1 (en) * 2004-03-23 2005-09-29 Ribi Hans O Thermopolymeric switching mediums and temperature monitoring devices embodying such mediums
US20080210895A1 (en) * 2006-12-14 2008-09-04 Flow Design, Inc Pressure Relieved Thermal Regulator for Air Conditioning Application

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB436836A (en) * 1934-02-16 1935-10-18 Georges Gaston Royer Improvements in or relating to thermostats
US2220641A (en) * 1936-06-18 1940-11-05 Gen Motors Corp Porous metal filter element
US2259846A (en) * 1937-06-17 1941-10-21 Vernay Patents Company Temperature responsive element
US2265586A (en) * 1938-08-11 1941-12-09 Vernay Patents Company Control device
US2297817A (en) * 1939-01-30 1942-10-06 Gen Motors Corp Filter element and method of making the same
US2448315A (en) * 1945-02-14 1948-08-31 Gen Motors Corp Combination restrictor and heat exchanger
GB621261A (en) * 1947-02-12 1949-04-06 H B Clarke Engineering Company Improvements in and relating to power thermostats
US2510473A (en) * 1945-04-16 1950-06-06 Garrett Corp Temperature control valve for heat exchangers
US2593238A (en) * 1948-10-21 1952-04-15 William J Adams Thermally responsive device
US2810290A (en) * 1954-04-08 1957-10-22 James F Scherer Thermo-actuator

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB436836A (en) * 1934-02-16 1935-10-18 Georges Gaston Royer Improvements in or relating to thermostats
US2220641A (en) * 1936-06-18 1940-11-05 Gen Motors Corp Porous metal filter element
US2259846A (en) * 1937-06-17 1941-10-21 Vernay Patents Company Temperature responsive element
US2265586A (en) * 1938-08-11 1941-12-09 Vernay Patents Company Control device
US2297817A (en) * 1939-01-30 1942-10-06 Gen Motors Corp Filter element and method of making the same
US2448315A (en) * 1945-02-14 1948-08-31 Gen Motors Corp Combination restrictor and heat exchanger
US2510473A (en) * 1945-04-16 1950-06-06 Garrett Corp Temperature control valve for heat exchangers
GB621261A (en) * 1947-02-12 1949-04-06 H B Clarke Engineering Company Improvements in and relating to power thermostats
US2593238A (en) * 1948-10-21 1952-04-15 William J Adams Thermally responsive device
US2810290A (en) * 1954-04-08 1957-10-22 James F Scherer Thermo-actuator

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3131563A (en) * 1958-12-24 1964-05-05 Jack A Britton Thermal power device
US3067944A (en) * 1959-11-23 1962-12-11 Meier Bernhard Temperature controlled radiator valve
US3129589A (en) * 1960-04-01 1964-04-21 Ametek Inc Pressure responsive instrument
US3212337A (en) * 1960-11-03 1965-10-19 Texas Instruments Inc Thermally responsive actuators
US3194009A (en) * 1963-09-20 1965-07-13 Baker Res And Dev Corp Thermal actuators
US3329022A (en) * 1963-11-04 1967-07-04 Emerson Electric Co Temperature measurement by sublimation of layers of radioactive material
US3302391A (en) * 1965-01-25 1967-02-07 Tempstat Corp Thermal actuators
US3591078A (en) * 1965-06-17 1971-07-06 Maurice Feinberg Thermostatic device
US3404530A (en) * 1967-03-01 1968-10-08 United Carr Inc Heat motor
US3386065A (en) * 1967-03-15 1968-05-28 Dole Valve Co Snap acting thermal element
US3505809A (en) * 1968-05-20 1970-04-14 Thermal Hydraulics Corp Thermal motor
US3665770A (en) * 1970-07-24 1972-05-30 Bio Medical Sciences Inc Temperature indicator
US3805528A (en) * 1972-10-02 1974-04-23 Gould Inc Thermal actuator
US4344450A (en) * 1980-04-08 1982-08-17 Walters William R Icing preventor
US4507922A (en) * 1981-11-30 1985-04-02 Leonard W. Suroff Thermostatic assembly
US4818119A (en) * 1986-05-19 1989-04-04 Rastech, Inc. Hot bearing warning bolt
US4979372A (en) * 1988-03-10 1990-12-25 Fuji Koki Mfg. Co. Ltd. Refrigeration system and a thermostatic expansion valve best suited for the same
US5044170A (en) * 1988-03-10 1991-09-03 Fujikoki Mfg. Co., Ltd. Refrigeration system and a thermostatic expansion valve best suited for the same
US5419133A (en) * 1989-09-05 1995-05-30 Schneider; Edward T. High speed thermochemical actuator
US5720169A (en) * 1995-05-23 1998-02-24 Schneider; Edward T. Thermochemical/mechanical actuator
US5685149A (en) * 1995-11-14 1997-11-11 Tcam Technologies, Inc. Proportionally controlled thermochemical mechanical actuator
US5822989A (en) * 1996-06-03 1998-10-20 Tcam Technologies, Inc. Thermochemical/mechanical brake and clutch unit
WO1997049914A1 (en) * 1996-06-24 1997-12-31 Metex Corporation Wax motor
US5692535A (en) * 1996-12-03 1997-12-02 Walters; William R. Icing preventer with temperature adjustment washer
US20050211153A1 (en) * 2004-03-23 2005-09-29 Ribi Hans O Thermopolymeric switching mediums and temperature monitoring devices embodying such mediums
US7204199B2 (en) * 2004-03-23 2007-04-17 Volk Enterprises, Inc. Thermopolymeric switching mediums and temperature monitoring devices embodying such mediums
US20080210895A1 (en) * 2006-12-14 2008-09-04 Flow Design, Inc Pressure Relieved Thermal Regulator for Air Conditioning Application
US7909262B2 (en) * 2006-12-14 2011-03-22 Flow Design, Inc. Pressure relieved thermal regulator for air conditioning application

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