US2936247A - Transfer sheets for forming thermosensitive copies - Google Patents
Transfer sheets for forming thermosensitive copies Download PDFInfo
- Publication number
- US2936247A US2936247A US739988A US73998858A US2936247A US 2936247 A US2936247 A US 2936247A US 739988 A US739988 A US 739988A US 73998858 A US73998858 A US 73998858A US 2936247 A US2936247 A US 2936247A
- Authority
- US
- United States
- Prior art keywords
- red
- weight
- parts
- thermo
- sensitive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 11
- 239000010439 graphite Substances 0.000 claims description 9
- 229910002804 graphite Inorganic materials 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 230000005855 radiation Effects 0.000 claims description 4
- 238000009877 rendering Methods 0.000 claims description 4
- 239000004203 carnauba wax Substances 0.000 claims description 3
- 235000013869 carnauba wax Nutrition 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 235000010919 Copernicia prunifera Nutrition 0.000 claims 1
- 244000180278 Copernicia prunifera Species 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 description 10
- 239000000203 mixture Substances 0.000 description 7
- 238000004040 coloring Methods 0.000 description 6
- 239000000549 coloured material Substances 0.000 description 4
- 239000003738 black carbon Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000012505 colouration Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- LLWJPGAKXJBKKA-UHFFFAOYSA-N victoria blue B Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)=C(C=C1)C2=CC=CC=C2C1=[NH+]C1=CC=CC=C1 LLWJPGAKXJBKKA-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 235000016936 Dendrocalamus strictus Nutrition 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/46—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by the light-to-heat converting means; characterised by the heat or radiation filtering or absorbing means or layers
- B41M5/465—Infrared radiation-absorbing materials, e.g. dyes, metals, silicates, C black
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/10—Duplicating or marking methods; Sheet materials for use therein by using carbon paper or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/392—Additives, other than colour forming substances, dyes or pigments, e.g. sensitisers, transfer promoting agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/914—Transfer or decalcomania
Definitions
- TRANSFER SHEETS FOR FORMING THERMOSENSITIVE COPIES Filed June 5, 1958 Coloured bans/er sbee/ male/7'01 Ped, blue or olber coloured lra/zsfemble coal/21g on base web.
- TRANSFER SHEETS FGR FURMING THERMO- SENSITIVE COPIES (Md Southgate, London, and Seaward, Enfield, England, assiguors to Limited, London, England, a liritish coni- Frederick George Francis,
- the present invention relates to carbon paper and transfer sheet materials generally and is concerned in particular with carbon papers which are coloured, i.e. other than black.
- thermosensitive paper or other sheet material a sheet of thermo-sensitive material, such as a sheet of paper coated with one or more layers of a thermo-sensitive composition which produces a distinctive colouration in those areas subjected to a suitable increase in temperature, is placed in contact with and above the typewritten or other material to be copied and the sheets are then irradiated with infra-red rays.
- This generates a heat pattern in the copy sheets in accordance with the characters or other markings on the material to be copied and this heat pattern develops the copy sheet by producing the colouration in the thermo-sensitive composition thereof to produce a copy of the original material.
- the infra-red rays are directed on to the material to be copied through the copy sheet, which is not itself absorbent of infra-red radiation.
- a coloured carbon paper or other coloured transfer sheet material which is adapted atent O to produce coloured written copy matter capable of being copied by a thermo-sensitive copying process
- a paper web carrying a transferable coating which comprises at least one coloured material and graphite for rendering the coloured Written copy matter suificiently heat-absorbative to produce a heat pattern in a thermo-sensitive copy sheet when the latter is exposed to a source of heat when in contact with the coloured written copy matter, the graphite being present in an amount of up to 20% by Weight of the transferable coating, the colour of which is that due to the coloured material.
- Example 1.-F0r making red carbon paper sensitive to 1 Blue resinate consists of one part of Victoria Blue B Base (the base of Victoria Blue B, Colour Index N o. 729) mixed and milled on a hot threeroll mill with two parts of rosin.
- Red transfer sheet material which is adapted to produce red written copy matter capable of being copied by a thermo-sensitive copying process, which comprises a paper web carrying a transferable coating which comprises 12.2 parts by weight of fatty grey carnauba wax, 11.9 parts by weight of ceresine wax, 30.7 parts by weight of mineral oil and 27.7 parts by weight of Strong Red Lake, the transferable coating also including 17.5 parts by weight of graphite for rendering the red written copy matter sufficiently heat-absorptive to produce a heat pattern in a thermo-sensitive copy sheet when the latter is irradiated with infra-red radiation when in contact with the red written copy matter.
- Blue transfer sheet material which is adapted to produce blue written copy matter capable of being copied by a thermo-sensitive copying process, which comprises a paper web carrying a transferable coating which comprises 19.75 parts by weightof fatty grey carnauba wax, 1750 parts by weight of petroleum jelly, 9.83 parts by weight of mineral oil, 7.33 parts by weight of Blue Resinate, 16.17 parts by weight of Strong Blue Lake, 15.16 parts by weight of Ultramarine Blue and 14.26 parts by weight of china clay, the transferable coating also included- 4 ing 22.00 parts by weight of graphite for rendering the blue written copy mater sufficiently heat-absorptive to produce a heat pattern'in a thermo-sensitive copy sheet when the latter is irradiated with infra-red radiation in contact with the blue written copy matter.
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Color Printing (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Description
y 10, 1960 F. G. FRANCIS ETAL 2,936,247
TRANSFER SHEETS FOR FORMING THERMOSENSITIVE COPIES Filed June 5, 1958 Coloured bans/er sbee/ male/7'01 Ped, blue or olber coloured lra/zsfemble coal/21g on base web.
Base
web.
[mpress/bns 0/ e bea s on base web.
Peel blue or olber coloured wr/llen cbaraclers on copy sbeel.
C sbeel lbe mall r on wb/cb Can b qaiea' by means of a l/lermo-sens/five topy/hg process.
TRANSFER SHEETS FGR FURMING THERMO- SENSITIVE COPIES (Md Southgate, London, and Seaward, Enfield, England, assiguors to Limited, London, England, a liritish coni- Frederick George Francis,
John Albert Carihonum P y The present invention relates to carbon paper and transfer sheet materials generally and is concerned in particular with carbon papers which are coloured, i.e. other than black.
Copying processes are known which make use of thermosensitive paper or other sheet material. In such processes, a sheet of thermo-sensitive material, such as a sheet of paper coated with one or more layers of a thermo-sensitive composition which produces a distinctive colouration in those areas subjected to a suitable increase in temperature, is placed in contact with and above the typewritten or other material to be copied and the sheets are then irradiated with infra-red rays. This generates a heat pattern in the copy sheets in accordance with the characters or other markings on the material to be copied and this heat pattern develops the copy sheet by producing the colouration in the thermo-sensitive composition thereof to produce a copy of the original material. In general, the infra-red rays are directed on to the material to be copied through the copy sheet, which is not itself absorbent of infra-red radiation.
It has been found that, generally speaking, satisfactory copies can be obtained by such processes only from black writings, such as duplicates made using black carbon paper, and that it is virtually impossible to operate a thermo-Sensitive copying process with coloured material. This method of copying is therefore not normally feasible with typewritten or other duplicates which are made with a coloured, e.g. red carbon paper. Good copies can be obtained from typed duplicates produced by means of a black carbon paper, which almost invariably carries a transfer composition which contains carbon black. Red carbon papers and other coloured transfer sheet material, such as purple, green and blue, are almost completely unsatisfactory from the standpoint of obtaining copies by means of thermo-sensitive copying paper from duplicates made by using them. Depending upon the colouring material used, brown carbon papers will sometimes produce matter which can be copied in this way, particularly if the brown colouring material in the transfer composition is obtained by the addition of carbon black to another colouring matter, such as a red pigment.
If graphite is added to the coloured pigmentary matter used in the manufacture of transfer compositions, in an attempt to overcome this defect of coloured material, small quantities of graphite are not particularly efiective, presumably because small quantities do not cause a sufiicient increase in the infra-red absorbative properties of the Whole mixture, while the addition of high proportions of graphite are also unsatisfactory because of their dulling effect on the written matter for ordinary purposes.
It is therefore an object of the present invention to provide a carbon paper or other transfer sheet material carrying a coloured, i.e. non-black, transfer composition which overcomes the defects of ordinary colouring materials in respect of thermo-sensitive copying processes.
According to the invention, a coloured carbon paper or other coloured transfer sheet material which is adapted atent O to produce coloured written copy matter capable of being copied by a thermo-sensitive copying process is provided, which comprises a paper web carrying a transferable coating which comprises at least one coloured material and graphite for rendering the coloured Written copy matter suificiently heat-absorbative to produce a heat pattern in a thermo-sensitive copy sheet when the latter is exposed to a source of heat when in contact with the coloured written copy matter, the graphite being present in an amount of up to 20% by Weight of the transferable coating, the colour of which is that due to the coloured material.
in the accompanying drawing, the single figure illustrates in fragmentary perspective transfer sheet material according to the invention.
it has been found that fairly large quantities of graphite within the stated range are generally required to give satisfactory results, namely between 15 and 20% by weight, but the colour of the other pigmentary or colouring matter used in the colouring material is not adversely affected to any appreciable extent and good results can be obtained in producing written matter by using the carbon paper. It has also been found that if the pro portion is increased beyond 20% by weight, the aforementioned disadvantage becomes apparent and, although duplicates made by using the carbon paper give good copies on thermo-sensitive paper, they are too dull in character and thereby give an extremely poor character to the writing, e.g. reds are turned into browns, and blues are turned into blue-blacks.
In order that the invention may be readily understood, the following specific examples are given.
Example 1.-F0r making red carbon paper sensitive to 1 Blue resinate consists of one part of Victoria Blue B Base (the base of Victoria Blue B, Colour Index N o. 729) mixed and milled on a hot threeroll mill with two parts of rosin.
We claim:
1. Red transfer sheet material which is adapted to produce red written copy matter capable of being copied by a thermo-sensitive copying process, which comprises a paper web carrying a transferable coating which comprises 12.2 parts by weight of fatty grey carnauba wax, 11.9 parts by weight of ceresine wax, 30.7 parts by weight of mineral oil and 27.7 parts by weight of Strong Red Lake, the transferable coating also including 17.5 parts by weight of graphite for rendering the red written copy matter sufficiently heat-absorptive to produce a heat pattern in a thermo-sensitive copy sheet when the latter is irradiated with infra-red radiation when in contact with the red written copy matter.
2. Blue transfer sheet material which is adapted to produce blue written copy matter capable of being copied by a thermo-sensitive copying process, which comprises a paper web carrying a transferable coating which comprises 19.75 parts by weightof fatty grey carnauba wax, 1750 parts by weight of petroleum jelly, 9.83 parts by weight of mineral oil, 7.33 parts by weight of Blue Resinate, 16.17 parts by weight of Strong Blue Lake, 15.16 parts by weight of Ultramarine Blue and 14.26 parts by weight of china clay, the transferable coating also includ- 4 ing 22.00 parts by weight of graphite for rendering the blue written copy mater sufficiently heat-absorptive to produce a heat pattern'in a thermo-sensitive copy sheet when the latter is irradiated with infra-red radiation in contact with the blue written copy matter.
References Cited in the file of this patent UNITED STATES PATENTS
Claims (1)
1. RED TRANSFER SHEET MATERIAL WHICH IS ADAPTED TO PRODUCE RED WRITTEN COPY MATTER CAPABLE OF BEING COPIED BY A THERMO-SENSITIVE COPYING PROCESS, WHICH COMPRISES A PAPER WEB CARRYING A TRANSFERABLE COATING WHICH COMPRISES 12.2 PARTS BY WEIGHT OF FATTY GREY CARNAUBA WAX11.9 PARTS BY WEIGHT OF FATTY GREY CARNAUBA WAX, OF MINERAL OIL AND 27.7 PARTS BY WEIGHT OF STRONG RED LAKE, THE TRANSFERABLE COATING ALSO INCLUDING 17.5 PARTS BY WEIGHT OF GRAPHITE FOR RENDERING THE RED WRITTEN COPY MATTER SUFFICIENTLY HEAT-ABSORPTIVE TO PRODUCE A HEAT PATTERN IN A THERMO-SENSITIVE COPY SHEET WHEN THE LATTER IS IRRADIATED WITH INFRA-RED RADIATION WHEN IS CONTACT WITH THE RED WRITTEN COPY MATTER.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB19338/57A GB834843A (en) | 1957-06-19 | 1957-06-19 | Improvements in or relating to carbon paper |
Publications (1)
Publication Number | Publication Date |
---|---|
US2936247A true US2936247A (en) | 1960-05-10 |
Family
ID=10127680
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US739988A Expired - Lifetime US2936247A (en) | 1957-06-19 | 1958-06-05 | Transfer sheets for forming thermosensitive copies |
Country Status (2)
Country | Link |
---|---|
US (1) | US2936247A (en) |
GB (1) | GB834843A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2992121A (en) * | 1957-05-16 | 1961-07-11 | Caribonum Ltd | Thermosensitive colouring materials |
US3252413A (en) * | 1964-07-22 | 1966-05-24 | Sharkey Melvin | Heat duplicating products and process |
US3404995A (en) * | 1965-09-20 | 1968-10-08 | Columbia Ribbon Carbon Mfg | Hectograph products and processes |
US3476578A (en) * | 1965-06-22 | 1969-11-04 | Agfa Gevaert Nv | Thermographic method for producing thermostable prints |
US3642475A (en) * | 1967-10-02 | 1972-02-15 | Agfa Gevaert Nv | Method of recording and reproducing information |
US3887742A (en) * | 1972-04-13 | 1975-06-03 | Richard E Reinnagel | Copy resistant documents |
US3933094A (en) * | 1973-11-19 | 1976-01-20 | United States Envelope Company | Substrate having colored indicia thereon for read-out by infrared scanning apparatus |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1476988A (en) * | 1921-07-02 | 1923-12-11 | Edward Barchardt | Carbonizing machine |
US1800561A (en) * | 1927-05-05 | 1931-04-14 | Neidich Process Company | Transfer material |
-
1957
- 1957-06-19 GB GB19338/57A patent/GB834843A/en not_active Expired
-
1958
- 1958-06-05 US US739988A patent/US2936247A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1476988A (en) * | 1921-07-02 | 1923-12-11 | Edward Barchardt | Carbonizing machine |
US1800561A (en) * | 1927-05-05 | 1931-04-14 | Neidich Process Company | Transfer material |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2992121A (en) * | 1957-05-16 | 1961-07-11 | Caribonum Ltd | Thermosensitive colouring materials |
US3252413A (en) * | 1964-07-22 | 1966-05-24 | Sharkey Melvin | Heat duplicating products and process |
US3476578A (en) * | 1965-06-22 | 1969-11-04 | Agfa Gevaert Nv | Thermographic method for producing thermostable prints |
US3404995A (en) * | 1965-09-20 | 1968-10-08 | Columbia Ribbon Carbon Mfg | Hectograph products and processes |
US3642475A (en) * | 1967-10-02 | 1972-02-15 | Agfa Gevaert Nv | Method of recording and reproducing information |
US3887742A (en) * | 1972-04-13 | 1975-06-03 | Richard E Reinnagel | Copy resistant documents |
US3933094A (en) * | 1973-11-19 | 1976-01-20 | United States Envelope Company | Substrate having colored indicia thereon for read-out by infrared scanning apparatus |
Also Published As
Publication number | Publication date |
---|---|
GB834843A (en) | 1960-05-11 |
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