US2896591A - Furnace wall for forced once-through boiler - Google Patents

Furnace wall for forced once-through boiler Download PDF

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US2896591A
US2896591A US671770A US67177057A US2896591A US 2896591 A US2896591 A US 2896591A US 671770 A US671770 A US 671770A US 67177057 A US67177057 A US 67177057A US 2896591 A US2896591 A US 2896591A
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tubes
furnace
panels
boiler
tube
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US671770A
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Willburt W Schroedter
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Combustion Engineering Inc
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Combustion Engineering Inc
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B37/00Component parts or details of steam boilers
    • F22B37/02Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
    • F22B37/10Water tubes; Accessories therefor
    • F22B37/14Supply mains, e.g. rising mains, down-comers, in connection with water tubes
    • F22B37/146Tube arrangements for ash hoppers and grates and for combustion chambers of the cyclone or similar type out of the flues
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B29/00Steam boilers of forced-flow type
    • F22B29/06Steam boilers of forced-flow type of once-through type, i.e. built-up from tubes receiving water at one end and delivering superheated steam at the other end of the tubes
    • F22B29/061Construction of tube walls
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S122/00Liquid heaters and vaporizers
    • Y10S122/05Critical pressure

Definitions

  • the fluid medium which is generally boiler water and steam, passes through the heat exchange surface in a continuous path from entrance into the boiler to exit from the boiler and for this reason there are long continuous tube circuits in such a boiler through which the medium is forced by means of the feed pump.
  • boilers of this type operating at supercritical pressure the temperature along these long tube runs continuously changes thereby creating a problem with regard to dififerential thermal expansion when portions of the tube circuits are placed in adjacent relation.
  • the present invention is concerned with the lining of the furnace wall of such a once-through supercritical boiler with tubes which form a portion of the heat absorbing surface of the boiler.
  • a group of adjacent tubes connected between common inlet and outlet headers so that the tubes are in parallel flow relation with the tubes being formed into vertical loops so that they extend up and down the furnace walls throughout at least the lower portion of the furnace and around a substantial portion of the furnace interior, as for example, half of the furnace interior.
  • the vertical runs of these adjacent tubes form, in effect, vertically disposed panels with adjacent panels being intercom nected by U-bends and with there being a sufficient nurnber of tubes with relation to the dimension of the furnace wall so that a symmetrical pattern in the panel arrangement is provided.
  • the vertical tube runs in each of the panels are supported from their upper ends by means of a horizontal structural support element with each of the tube elements being free to expand downwardly.
  • the invention comprises an arrangement, construction and combination of the elements of the inventive organization in such a manner as to attain the results desired as hereinafter more particularly set forth in the following detailed description of an illustrative embodiment, said embodiment being shown by the accompanying drawings wherein:
  • Fig. l is a vertical section through the lower portion of a furnace of a supercritical once-through boiler embodying the present invention, with the section being taken on line 11 of Fig. 2 looking at one of the end walls of the furnace;
  • Fig. 2 is a transverse section of the furnace taken along line 2--2 of Fig. 1;
  • Fig. 3 is a view in the nature of a fragmentary perspective of the tube circuit disposed about the inner surface of the lower end of the furnace shown in Figs. 1 and 2;
  • Fig. 4 is a development of this tube circuit which covers half of the circumference of the lower end of the furnace.
  • the illustrative and preferred embodiment of the invention shown therein comprises a furnace 20 of a supercritical once-through boiler and which, as shown, has its lower portion linedwith heat exchange tubes that form a portion of the heat exchange circuit of the boiler with it being understood that these tubes may line a greater portion of the furnace than indicated, and, if desired, may line the entire furnace.
  • Furnace 20 is of the hopper bottom type and accordinglyhas the lower portion of its side Walls 22 and 24 sloping inwardly and terminating in spaced relation to form a discharge opening 26. These side Walls extend between the end walls 28 and 30 so that the furnace, as indicated in Fig. 2, is generally square in transverse section.
  • the tube arrangement above the section line 1-1 of Fig. 2 is identical with the tube arrangement lining the furnace half below this section line so that only one of these arrangements need be described with one of these arrangements being shown in perspective in Fig. 3 and in development of Fig. 4.
  • the tubes lining each of these halves of the furnace comprise a group of continuous, adjacent parallel tubes connected to a common inlet header 32 and a common outlet header 34 so that the arrangement of the panels on the furnace walls tends to tubes of each group are in parallel flow relation.
  • Fig. 1 there are 24 tubes interconnecting these headers (with only half the tubesbeing shown in Figs. 2 and 4 and one quarter in Fig.
  • Panels 36 and 38 line one half of the inner surface of front or side wall 22 with the tubes in these panels extending downwardly along this side wall to the opening 26 in the bottom of the furnace where these tubes, as clearly shown in Fig. 3, are bent laterally outwardlyand interconnected by internested U-bends.
  • This particular arrangement forms a laterally extending tube portion, which for the innermost pair of interconnected tubes of these two panels is indicated as 54 and is of sufficient length to accommodate the dilferential expansion of the interconnected vertical tube runs of the panels with the laterally extending tube portions ,of the other interconnected. tubes of these panels of course beinggreater than that indicated at 5 and accordingly more than sufficient to accommodate the differential expansion encountered.
  • Panels 40 and 42 which line one half of the end wall 28 have their tubes interconnected at the lower end in a manner which will accommodate relative vertical movement of the interconnected tube portions and also will change the relative location of the interconnected tube portions in each panel.
  • the tubes 1 through 6 (Fig. 4) in panel 40 are accordingly connected to the tubes It through 6 in panel 42 in reverse relation While. the tubes 7 through 12 in panel 443 are connected with the tubes 7 through 12 in panel 42 in reverse relation with the latter group of tubes in panel 40 being crossed over the former group of tubes in this panel.
  • This arrangement provides a sufliicent lateral. run or horizontal extend of the U-bend interconnecting the tubes in these two panels to accommodate the differential expansion of the interconnected tube portions and it also changes the location of'the re spective interconnected tube portions in each panel with respect to the edges of each panel.
  • tubes 1 through 8 in panel 44 are connected with tubes 5 through 12 in panel 46 with the U-bends interconnecting these tubes being internestedas shown while tubes 9 and 10 in panel 44 are crossed in relation to tubes 'lland 12 of this panel with tubes 9 and 10 interconnecting tubes 2 and 1 of panel 46 and tubes 11 and 12. interconnecting tubes 4 and 3 ofpanel 46 so that the U bends by means of which the tube elements are interconnected will have a sufficient horizontal run to accommodate'the necessary differential expansion of. the interconnected tube elements.
  • Panels 48 and50 are similarto panels. 36 and 38 with panels 48 and 50 liningthe inner surface of onejhalf of the side or rear wall 24 and with the. laterally'extending tube portions formed on the lower end of those panels accommodating differential vertical movement of the interconnected tube elements of the panels.
  • the lower end of the tube elements of each of the panels are positioned exteriorily of the furnace in order that a pressure tight furnace wall 'may be had even though relatively complicated tube bending is required necessitating the crossing of tubes in the end walls to accommodate differential expansionof the interconnected vertical-tube runs of thepanels and also in order to simplify the fabrication and construction problems.
  • the effect of a symmetric panel arrangement in the furnace with regard to producing an unbal- 4 extending tube portions in adjacent panels may move relative to one another as is required in a supercritical once-through unit where the temperature along each of the tubes continuously varies with these results being obtained in a relatively simple and economic manner involving a minimum of fabrication problems.
  • a vertical furnace of rectangular transverse section having its front and rear walls sloped inwardly and terminating in spaced relation thereby forming a hoppertbottom with an opening at the bottom thereof
  • the lower portion of the furnace having the inner surfaceof the walls lined with tubes which comprise one group of side by side parallel tubes connected at their opposite ends to common inletand outlet headers and extending up and down the furnace wall from the furnace bottom and a location intermediate the top and bottom of the furnace and covering half the circumference of the furnace from adjacent the center ofthefront. wall across an end wall to adjacent the center of the back wall, eachvertical run of the entire group of adjacent. tubes forming in effect a panel with the lower ends. of the panels being exteriorly of the furnace bottom, means connected :with.
  • the tubes of each panel at the upper region thereof and eifective to support the tubes from this regionforexpansion downwardly, the number of tubes in the group and the width of the furnace walls being; such that there is a symmetrical arrangement of panels onthe walls with their being only complete panels on each wall and being at least two panels on the front and back walls and .at least four panels on. theend wall, the groups of tubes being disposed so that the tubes of adjacent pairs of'panelslare interconnected at their upper and. lower ends by return bends with the return bends at the upper. end being completely internested: so as to lie flat andparallel with thewall, the return bends at the lowerend'of one of the adjacent pair of panels on the end .wall being. crossed in a manner.
  • each return bend is of sufficient le'ngthto accommodate substantialidiiferential expansionof the tubes in the panels, the. tubes. of the interconnected panels on the front and reartwallsextend. downwardly along the wall to the openinginvthe; furnace bottom; and:then laterally horizontally outward. a sufficient distance to accommodate a substantial,..differentiall expansion of the .tubes of these panels and with the.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Description

FURNACE W LL. FOR FORCED ONCE-THROUGH BOILER Filed .July 15, 1957 July 28, 1959 -w. w. SCHROEDTER 4 Sheets-Sheet 1 Fig. l.
y, 1959 w. w. SCHROEDTER 2,896,591
v FURNACE WALL FOR FORCED ONCE-THROUGH BOILER Filed July 15, 1957 4 Sheets-Sheet 2 INVENTOR Willburt W. Schroedter ATTORNEY w. W. SCHRQEDTER FURNACE WALL FOR FORCED 0NCETHROUGH BOILER Filgd July 15, 1957 July 28, 1959 4 Sheets-Sheet 3 Willburt W. Schroedier (M ZW ATTORNEY W. W. SCHROEDTER FURNACE WALL FOR FORCED ONCE-THROUGH BOILER Filed July 15, 1957 4 SheetsSheet 4.
I NVENTOR Willburt W. Schroedter ATTORNEY.
United States Patent Ofiice 2,896,591 Patented July 28, 1959 FURNACE WALL FOR FORCED ON CE-THROUGH BOIL Application July 15, 19"57, Serial No. 671,770 1 Claim. (Cl. 122-435) This invention relates generally to boilers of the supercritical once-through type and has particular relation to a furnace wall organization for such a boiler.
In once-through boilers the fluid medium, which is generally boiler water and steam, passes through the heat exchange surface in a continuous path from entrance into the boiler to exit from the boiler and for this reason there are long continuous tube circuits in such a boiler through which the medium is forced by means of the feed pump. in boilers of this type operating at supercritical pressure the temperature along these long tube runs continuously changes thereby creating a problem with regard to dififerential thermal expansion when portions of the tube circuits are placed in adjacent relation. The present invention is concerned with the lining of the furnace wall of such a once-through supercritical boiler with tubes which form a portion of the heat absorbing surface of the boiler.
In accordance with the invention there is provided a group of adjacent tubes connected between common inlet and outlet headers so that the tubes are in parallel flow relation with the tubes being formed into vertical loops so that they extend up and down the furnace walls throughout at least the lower portion of the furnace and around a substantial portion of the furnace interior, as for example, half of the furnace interior. The vertical runs of these adjacent tubes form, in effect, vertically disposed panels with adjacent panels being intercom nected by U-bends and with there being a sufficient nurnber of tubes with relation to the dimension of the furnace wall so that a symmetrical pattern in the panel arrangement is provided. The vertical tube runs in each of the panels are supported from their upper ends by means of a horizontal structural support element with each of the tube elements being free to expand downwardly. Since, with a supercritical boiler the tube elements in adjacent panels will have different metal temperatures they will of course expand different amounts so that means must be provided to permit this differential movement of the interconnected vertical tube runs in adjacent panels. This is accomplished in the present invention by providing a suflicient laterally extending length of tube at the lower end of the interconnected tubes to accommodate this movement. The lower end of the panels on the side walls are bentoutwardly so that they extend laterally outward from the bottom of the furnace to provide this lateral tube length and the interconnecting tube portions at the lower end of the panels on the end walls are crossed in a manner to provide the required lateral tube run. The symmetrical 'anced fluid and metal temperature in the tubes across the width of each panel because some of the elements would continuously traverse zones of high heat absorption while others would repeatedly be in zones of low heat absorption. In order to overcome this result to a substantial extent, the interconnection of the tubes of a centrally disposed pair of panels is such as to change the relative .location of the interconnected tubes in these panels thereby'destroying the effect of the symmetrical panel arrangement with regard to producing an unbalanced temperature across the width of each panel.
It is an object of this invention to provide an improved furnace wall construction for supercritical once-through boilers wherein the wall is lined with heat exchange tube elements.
Other and further objects of the invention will become apparent to those skilled in the art as the description proceeds,
With the aforementioned objects in view, the invention comprises an arrangement, construction and combination of the elements of the inventive organization in such a manner as to attain the results desired as hereinafter more particularly set forth in the following detailed description of an illustrative embodiment, said embodiment being shown by the accompanying drawings wherein:
Fig. l is a vertical section through the lower portion of a furnace of a supercritical once-through boiler embodying the present invention, with the section being taken on line 11 of Fig. 2 looking at one of the end walls of the furnace;
Fig. 2 is a transverse section of the furnace taken along line 2--2 of Fig. 1;
Fig. 3 is a view in the nature of a fragmentary perspective of the tube circuit disposed about the inner surface of the lower end of the furnace shown in Figs. 1 and 2;
Fig. 4 is a development of this tube circuit which covers half of the circumference of the lower end of the furnace.
Referring now to the drawing, wherein like reference characters are used throughout to designate like elements, the illustrative and preferred embodiment of the invention shown therein comprises a furnace 20 of a supercritical once-through boiler and which, as shown, has its lower portion linedwith heat exchange tubes that form a portion of the heat exchange circuit of the boiler with it being understood that these tubes may line a greater portion of the furnace than indicated, and, if desired, may line the entire furnace. Furnace 20 is of the hopper bottom type and accordinglyhas the lower portion of its side Walls 22 and 24 sloping inwardly and terminating in spaced relation to form a discharge opening 26. These side Walls extend between the end walls 28 and 30 so that the furnace, as indicated in Fig. 2, is generally square in transverse section.
As embodied, the tube arrangement above the section line 1-1 of Fig. 2 is identical with the tube arrangement lining the furnace half below this section line so that only one of these arrangements need be described with one of these arrangements being shown in perspective in Fig. 3 and in development of Fig. 4. The tubes lining each of these halves of the furnace comprise a group of continuous, adjacent parallel tubes connected to a common inlet header 32 and a common outlet header 34 so that the arrangement of the panels on the furnace walls tends to tubes of each group are in parallel flow relation. As indicated in Fig. 1 there are 24 tubes interconnecting these headers (with only half the tubesbeing shown in Figs. 2 and 4 and one quarter in Fig. 3 for the sake of clarity) 'and they are wound or formed into vertical loops so that they extend up and down the furnace wall throughout the lower end of the furnace and around half of the furnace interior commencing at the center of side or front wall 22 and terminating at the center of side or rear wall 24. This tube arrangement or formation in effect provides a tubes in effect hanging from these support channels and being free to expand downwardly therefrom and with members 52 supported from rods iiii'which in turn hang from the framework 55 (Fig. 3).
Panels 36 and 38line one half of the inner surface of front or side wall 22 with the tubes in these panels extending downwardly along this side wall to the opening 26 in the bottom of the furnace where these tubes, as clearly shown in Fig. 3, are bent laterally outwardlyand interconnected by internested U-bends. This particular arrangement forms a laterally extending tube portion, which for the innermost pair of interconnected tubes of these two panels is indicated as 54 and is of sufficient length to accommodate the dilferential expansion of the interconnected vertical tube runs of the panels with the laterally extending tube portions ,of the other interconnected. tubes of these panels of course beinggreater than that indicated at 5 and accordingly more than sufficient to accommodate the differential expansion encountered.
Panels 40 and 42 which line one half of the end wall 28 have their tubes interconnected at the lower end in a manner which will accommodate relative vertical movement of the interconnected tube portions and also will change the relative location of the interconnected tube portions in each panel. The tubes 1 through 6 (Fig. 4) in panel 40 are accordingly connected to the tubes It through 6 in panel 42 in reverse relation While. the tubes 7 through 12 in panel 443 are connected with the tubes 7 through 12 in panel 42 in reverse relation with the latter group of tubes in panel 40 being crossed over the former group of tubes in this panel. This arrangement provides a sufliicent lateral. run or horizontal extend of the U-bend interconnecting the tubes in these two panels to accommodate the differential expansion of the interconnected tube portions and it also changes the location of'the re spective interconnected tube portions in each panel with respect to the edges of each panel.
In panels 44 and 46, tubes 1 through 8 in panel 44 are connected with tubes 5 through 12 in panel 46 with the U-bends interconnecting these tubes being internestedas shown while tubes 9 and 10 in panel 44 are crossed in relation to tubes 'lland 12 of this panel with tubes 9 and 10 interconnecting tubes 2 and 1 of panel 46 and tubes 11 and 12. interconnecting tubes 4 and 3 ofpanel 46 so that the U bends by means of which the tube elements are interconnected will have a sufficient horizontal run to accommodate'the necessary differential expansion of. the interconnected tube elements.
Panels 48 and50 are similarto panels. 36 and 38 with panels 48 and 50 liningthe inner surface of onejhalf of the side or rear wall 24 and with the. laterally'extending tube portions formed on the lower end of those panels accommodating differential vertical movement of the interconnected tube elements of the panels.
The lower end of the tube elements of each of the panels are positioned exteriorily of the furnace in order that a pressure tight furnace wall 'may be had even though relatively complicated tube bending is required necessitating the crossing of tubes in the end walls to accommodate differential expansionof the interconnected vertical-tube runs of thepanels and also in order to simplify the fabrication and construction problems.
With the furnace wall construction in accordance with the invention the effect of a symmetric panel arrangement in the furnace with regard to producing an unbal- 4 extending tube portions in adjacent panelsmay move relative to one another as is required in a supercritical once-through unit where the temperature along each of the tubes continuously varies with these results being obtained in a relatively simple and economic manner involving a minimum of fabrication problems.
While I have illustrated and described a preferred embodiment of my invention it is to be understood that such is merely illustrative and not restrictive and that variations and modifications may be made therein without departing from the spirit and scope of the invention. I therefore do not wish to be limited to the precise details set forth but desire to avail myself of such changes as fall within the purview of my invention.
What I claim is:
In a once-through boiler the combination of a vertical furnace of rectangular transverse section having its front and rear walls sloped inwardly and terminating in spaced relation thereby forming a hoppertbottom with an opening at the bottom thereof, the lower portion of the furnace having the inner surfaceof the walls lined with tubes which comprise one group of side by side parallel tubes connected at their opposite ends to common inletand outlet headers and extending up and down the furnace wall from the furnace bottom and a location intermediate the top and bottom of the furnace and covering half the circumference of the furnace from adjacent the center ofthefront. wall across an end wall to adjacent the center of the back wall, eachvertical run of the entire group of adjacent. tubes forming in effect a panel with the lower ends. of the panels being exteriorly of the furnace bottom, means connected :with. the tubes of each panel at the upper region thereof and eifective to support the tubes from this regionforexpansion downwardly, the number of tubes in the group and the width of the furnace walls being; such that there is a symmetrical arrangement of panels onthe walls with their being only complete panels on each wall and being at least two panels on the front and back walls and .at least four panels on. theend wall, the groups of tubes being disposed so that the tubes of adjacent pairs of'panelslare interconnected at their upper and. lower ends by return bends with the return bends at the upper. end being completely internested: so as to lie flat andparallel with thewall, the return bends at the lowerend'of one of the adjacent pair of panels on the end .wall being. crossed in a manner. to interconnect the tubes in' these adjacent panelsin reverse order from the center of each panel. outward, and the return bends at the lower endof other panels onthe'end wall being crossed only with respect to a limited number of the tubes ofeach pair of panels that. are nearest each other in a manner so .Lthat, the .laterally extending portion of each return bend is of sufficient le'ngthto accommodate substantialidiiferential expansionof the tubes in the panels, the. tubes. of the interconnected panels on the front and reartwallsextend. downwardly along the wall to the openinginvthe; furnace bottom; and:then laterally horizontally outward. a sufficient distance to accommodate a substantial,..differentiall expansion of the .tubes of these panels and with the. return bendsinterconnecting these. tubes being internested, the other half of the furnace circuma fefrence being lined with another and similarly disposed group of tubes References Cited in the fileof this patent UNITED STATES PATENTS 1,961,233 Mayr -i June 5, 1934 FOREIGN PATENTS 827,384 Germany Jan; 10, 1952
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2995118A (en) * 1958-10-09 1961-08-08 Sulzer Ag Tubular lining for the combustion chamber of a radiant heat tubular heat exchanger
US3030937A (en) * 1958-01-10 1962-04-24 Combustion Eng Furnace wall and support
US3060904A (en) * 1959-07-30 1962-10-30 Babcock & Wilcox Ltd Vapor generators
US3129698A (en) * 1960-03-18 1964-04-21 Sulzer Ag Forced flow steam generator
US3247830A (en) * 1962-06-08 1966-04-26 Sulzer Ag Forced flow steam generator having plural tube systems
US3832978A (en) * 1972-03-17 1974-09-03 Tubing for a combustion chamber
US3832979A (en) * 1972-03-30 1974-09-03 Sulzer Ag Tubing for a combustion chamber
US5775265A (en) * 1994-10-17 1998-07-07 Austrian Energy & Environment Sgp/Waagner-Biro Gmbh Cooling surface cladding
WO2017079104A1 (en) * 2015-11-04 2017-05-11 Cain Martin Internally heated steam generation system and heat exchanger

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1961233A (en) * 1929-07-03 1934-06-05 Siemens Ag Steam generating apparatus
DE827384C (en) * 1950-08-16 1952-01-10 Borsig A G Procedure for relocating the transition point for once-through boilers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1961233A (en) * 1929-07-03 1934-06-05 Siemens Ag Steam generating apparatus
DE827384C (en) * 1950-08-16 1952-01-10 Borsig A G Procedure for relocating the transition point for once-through boilers

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3030937A (en) * 1958-01-10 1962-04-24 Combustion Eng Furnace wall and support
US2995118A (en) * 1958-10-09 1961-08-08 Sulzer Ag Tubular lining for the combustion chamber of a radiant heat tubular heat exchanger
US3060904A (en) * 1959-07-30 1962-10-30 Babcock & Wilcox Ltd Vapor generators
US3129698A (en) * 1960-03-18 1964-04-21 Sulzer Ag Forced flow steam generator
US3247830A (en) * 1962-06-08 1966-04-26 Sulzer Ag Forced flow steam generator having plural tube systems
US3832978A (en) * 1972-03-17 1974-09-03 Tubing for a combustion chamber
US3832979A (en) * 1972-03-30 1974-09-03 Sulzer Ag Tubing for a combustion chamber
US5775265A (en) * 1994-10-17 1998-07-07 Austrian Energy & Environment Sgp/Waagner-Biro Gmbh Cooling surface cladding
WO2017079104A1 (en) * 2015-11-04 2017-05-11 Cain Martin Internally heated steam generation system and heat exchanger

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