US2876139A - Method of bonding coating on a refractory base member and coated base - Google Patents

Method of bonding coating on a refractory base member and coated base Download PDF

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US2876139A
US2876139A US594236A US59423656A US2876139A US 2876139 A US2876139 A US 2876139A US 594236 A US594236 A US 594236A US 59423656 A US59423656 A US 59423656A US 2876139 A US2876139 A US 2876139A
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molybdenum
coating
coated
tungsten
alloys
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US594236A
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Joseph K Flowers
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General Electric Co
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General Electric Co
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    • C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/02—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
    • C04B37/023—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
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    • C04B37/02—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
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    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
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    • C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
    • C04B41/5138—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal with a composition mainly composed of Mn and Mo, e.g. for the Moly-manganese method
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Definitions

  • THE MATERIAL,METALLIC OR NON-METALLIC,TO BE BONDED TO THE ARTICLE IS PLACED ON THE COATED AND REDUCED SURFACE THEREOF AND HEATED IN AN INERT-OR REDUCING ATMOSPHERE TO AT LEAST,AND PREFERABLY BEYOND,THE'MELTING TEMPERATURE OF THE MATERIAL TO CAUSE THE MATERIAL TO SPREAD OVER THE SUR- FACE AND BOND TO THE ARTICLE.
  • the present invention relates to the bonding of an adherent metallic or non-metallic coating on to refractory base members. More particularly, it relates to the formation of an adherent stable continuous coating of an element or alloy, such as copper, gold, tin, indium, germanium, solders'comprising copper and silver and known as silver solders, silver, iron and nickel, upon an article or object made of a refractory metal such as molybdenum and tungsten and alloys thereof, and of a material such as graphitic carbon.
  • an element or alloy such as copper, gold, tin, indium, germanium, solders'comprising copper and silver and known as silver solders, silver, iron and nickel
  • molybdenum and tungsten and alloys thereof have coefiicients of expansion comparable to the coefficients of expansion of silicon, germanium, glass, ceramics and the like. Consequently, where it is desired to make a metallic bond to such substances as those in the latter category, either directly or indirectly, it should be desirable to use molybdenum, tungsten and alloys thereof.
  • difiiculty has been experienced in suitably coating molybdenum, tungsten and alloys thereof with the materials mentioned in the first paragraph'above in order that good bonding could be achieved. Difficulty has also been experienced in making conventional lead or silver solder connections to molybdenum, tungsten and alloys thereof.
  • the present invention is directed to the solution of such problems as those requiring the formationof a tightly adhering bond of a metal or non-metal to objects consisting of molybdenum, tungsten and alloys thereof, and also carbon.
  • an object of the present invention is to provide an improved conductive object consisting of molybdenum, tungsten and alloys thereof having other metals or non-metals bonded to the surfaces thereof.
  • Another object of the present invention is to provide a method of applying an adherent metallic or nonmetallic coating on an article composed of a metal selected from the group consisting of tungsten and molybdenum and alloys thereof. 7
  • a further object of the present invention is to provide an improved method of applying an adherent metallic or non-metallic coating on a body of graphite.
  • Figure l is a flow diagram illustrating how the present invention may be practiced.
  • Figure 2 is a perspective view of a product in accordance with the present invention.
  • the present invention will now be described with respect to a specific embodiment thereof, for example, the application of an adherent copper coating to the surface of a plate of molybdenum or molybdenum-based alloy.
  • the molybdenum plate is first. cleaned in any suitable manner, for example, by scouring with a soapy abrasive.
  • the cleaned surface of the plate is then coated with molybdenum trioxide.
  • the coating may be applied in one of several ways.
  • the cleaned article may be immersed in an oxidizing agent such as nitric acid, preferably a 40-60% solution by weight for about two seconds.
  • the molybdenum is immersed in the solu- United States Patent I tion for a much longer period, the molybdenum rapidly etches away. After removal of the plate of molybdenum, the surface is blotted to remove the excess solution.
  • the molybdenum coated with the molybdenum trioxide is then heated in a reducing atmosphere, preferably hydrogen.
  • the temperature of the plate is raised to about at least 6Q0. C, at which temperaturethe molybdenum trioxide 'beginsto, reduce. The higher the temperature, the more rapid is' the reduction process. I have found that when the temperature is raised to about 800 C., substantially complete reduction of the molybdenum trioxide takes place is a few seconds.
  • a fine deposit of particles of molybdenum is formed on the surface of the molybdenum plate as a result of the reduction process. These par ticles are apparently loosely attached since they can be wiped off.
  • a piece of copper is placed on the treated molybdenum surface and the temperature of the molybdenum is raised in a reducing or non-oxidizing atmosphere to beyond the melting temperature of the copper. At this temperature copper melts and simultaneously alloys and spreads over the entire surface of the molybdenum in the matter of a few seconds. At this time, the plate is allowed to cool.
  • the entire operation of reduction'of the molybdenum trioxide and the alloying of the copper into the molybdenum may be performed in a single operation by first placing the piece of copper on the surface coated with molybdenum trioxide and then raising the temperature of the place sufiiciently to reduce the molybdenum trioxide and finally raising the temperature further to melt the copper and cause the alloying action described.
  • the wetting action of copper on molydenum which takes place resembles very much the wetting action that takes place when water spreads in a blotter.
  • the resulting copper-coated molybdenum plate has a strongly adherent smooth coating of copper on the surface thereof free from blisters to'which solder and other contacts may be very readily made.
  • molybdenum plate for example, indium, tin. gold, germanium, silver solders, copper, silver, goldantimony alloys. Nickel and iron may be similarly applied to molydenum and alloys thereof to form an adherent coating.
  • the steps for bonding such other ma terials is the same as specified above for copper except that in the case of the other materials specified in this parargraph in final step the temperature is raised sutliciently to cause the material which is to be bonded to melt, spread over and alloy, into the molybdenum.
  • the invention has particular utility in the making of semiconductor devices constituted of germanium and silicon.
  • it is necessary to make ohmic and other kinds of connections to the germanium or silicon body of the device.
  • Molybdenum or tungsten are desirable for such use since they have coefiicients of expansion comparable to the coefiicients of expansion of germanium and silicon; and thus fracturing of connections is minimized in the fabricating operation, as well as when large currents are passed through the device.
  • modybdenum and tungsten are desirable for the reason that they have good thermal and electrical conductivities. While molybdenum and tungsten have been desirable for these reasons, it has been difiicult to bond other materials to them.
  • the present invention solves such problems as these.
  • a gold and antimony alloy gold 99%-antimony 1%
  • it has been a problem to make a good adherent coatingof the gold-antimony alloy to the surface of a molybdenum plate.
  • the technique of the present invention it is possible to produce an excellent coating of gold antimony on the surface of the molybdenum plate.
  • the other side of the molybdenum plate may be coated with copper as described above to provide an external surface which may be easily soldered to.
  • the method of providing an adherent coating on an article composed of a substance selected from the group consisting of tungsten, molybdenum, tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating a surface of said article with molybdenum trioxide, reducing the molybdenum trioxide on said surface to molybdenum, applying to said reduced surface a material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
  • the method of providing an adherent coating on an article composed of a substance selected from the group consisting of tungsten, molybdenum, tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating :1 surface of said article with a solution including molybdenum trioxide as solute, removing the solvent to leave said surface coated with molybdenum trioxide, reducing the molybdenum trioxide on said surface to molybdenum, applying to said reduced surface a material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
  • the method of providing an adherent coating on an article composed of a substance selected from the group consisting of tungsten, molybdenum, tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating :1 surface of said article with an ammonium hydroxide solution of molybdenum trioxide, removing the solvent to leave said surface coated with molybdenum trioxide, reducing the molybdenum trioxide on said surface to molybdenum, applying to said reduced surface a material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
  • the method of providing an adherent coating on an article composed of a substance selected from the group consisting of tungsten, molybdenum, tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating the surface of said article with molybdenum trioxide, reducing the molybdenum trioxide on said coated article to molybdenum, applying to said surface in a non-oxidizing atmosphere a material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
  • the method of providing an adherent coating on an article composed of a substance selected from the group consisting of tungsten and molybdenum and tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating a surface of said article with molybdenum trioxide, raising the temperature of said surface in non-oxidizing atmosphere to a temperature in excess of substantially 600 C.
  • a non-oxidizing atmosphere :1 material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
  • the method of providing an adherent coating on an article composed of molybdenum comprising the steps of oxidizing a surface of said article to form molybdenum trioxide thereon, reducing the molybdenum trioxide on said surface to form a coating of fine particles of molybdenum distributed on said surface, applying to said surface in a non-oxidizing atmosphere a material to be coated thereon selected from the grouuonsisting of cup per, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
  • the method of providing an adherent coating on an article composed of graphitic carbon comprising the steps of coating a surface of said article with molybdenum trioxide, reducing the molybdenum trioxide on said surface in a non-oxidizing atmosphere to form a coating of line particles of molybdenum on said surface, applying to said surface in a non-oxidizing atmosphere a material to be coated thereon selected from the group consisting admir 0! MW. gold. tin, indium. germenium ail er. iron and nickel and alloys thereof at the melting temperature of said material.
  • the method of providing an adherent coating of an article composed of molybdenum comprising the steps of coating a surface of said article with molybdenum trioxide, reducingth'emolybdenum trioxide on said surface to form acoating of finepa'rticles of molybdenum I distributed on said surface 'applying" tosaid surface in a non-oxidizing atmosphere a mate'ri'al to be coated thereon selected from 'the group 'consisting of copper, gold, tin, indium, germanium, .silver, iron and nickel and alloys thereof at the melting temperature of said material.
  • the we l! of providing an adherent coating on an article composed of tungsten comprising the steps of coating a surface of said article with molybdenum tn oxide, reducing the molybdenum trioxide on said surface '10 thereof at the melting temperature of said material.

Description

METHOD OF BONDING COATING ON A REFRACTORY v m! 3; 1959 .I. K. FLOWERS 2,876,139
BASE MEMBER AND COATED BASE Filed June 27, 1956 FIG.I.
SURFACE OF AN ARTICLE COMPOSED OF ASUBSTANCE SELECTED FROM THE GROUP OF TUNGSTEN,MOLYBDENUM AND ALLOYS THEREOF,AND GRAPHITEJS CLEANED.
THE CLEANED SURFACE OF ARTICLE IS COATED WITH A SOLUTION OF MOLYBDENUM OXIDE,PREFERABLY A CONCEN- TRATED AMMONIUM HYDROXIDE SOLUTION OF MOLYBDENUM TRIOXIDE,AND DRIED IN AIR.
THE SURFACE COATED WITH THE MOLY BDENUM TRIOXIDE IS HEATED IN A REDUCING ATMOSPHERE, HYDRO6EN,FOR EXAMPLEJO A TEMPERATURE SUFFICIENTLY HIGHIAT LEA- ST ABOUT 600C) FOR A TIME TO REDUCE THE MOLYBD- ENUM TRIOXIDE TO MOLYBDENUM.
THE MATERIAL,METALLIC OR NON-METALLIC,TO BE BONDED TO THE ARTICLE IS PLACED ON THE COATED AND REDUCED SURFACE THEREOF AND HEATED IN AN INERT-OR REDUCING ATMOSPHERE TO AT LEAST,AND PREFERABLY BEYOND,THE'MELTING TEMPERATURE OF THE MATERIAL TO CAUSE THE MATERIAL TO SPREAD OVER THE SUR- FACE AND BOND TO THE ARTICLE.
COATING OF A METAL OR NON-METAL MOLYBDENUM OR TUNGSTEN OR ALLOYS THEREOF OR AND GRAPHITIC CARBON INVEN TOR 1 JOSEPH K. FLOWERS,
METHOD OF BONDING COATING ON A REFRAC- TORY BASE MEMBER AND COATED BASE I Joseph K. Flowers: North: Syracuse, .N. Y assignor to The present invention relates to the bonding of an adherent metallic or non-metallic coating on to refractory base members. More particularly, it relates to the formation of an adherent stable continuous coating of an element or alloy, such as copper, gold, tin, indium, germanium, solders'comprising copper and silver and known as silver solders, silver, iron and nickel, upon an article or object made of a refractory metal such as molybdenum and tungsten and alloys thereof, and of a material such as graphitic carbon.
As is well known, molybdenum and tungsten and alloys thereof have coefiicients of expansion comparable to the coefficients of expansion of silicon, germanium, glass, ceramics and the like. Consequently, where it is desired to make a metallic bond to such substances as those in the latter category, either directly or indirectly, it should be desirable to use molybdenum, tungsten and alloys thereof. However, in the past difiiculty has been experienced in suitably coating molybdenum, tungsten and alloys thereof with the materials mentioned in the first paragraph'above in order that good bonding could be achieved. Difficulty has also been experienced in making conventional lead or silver solder connections to molybdenum, tungsten and alloys thereof.
The present invention is directed to the solution of such problems as those requiring the formationof a tightly adhering bond of a metal or non-metal to objects consisting of molybdenum, tungsten and alloys thereof, and also carbon.
Accordingly, an object of the present invention is to provide an improved conductive object consisting of molybdenum, tungsten and alloys thereof having other metals or non-metals bonded to the surfaces thereof.
Another object of the present invention is to provide a method of applying an adherent metallic or nonmetallic coating on an article composed of a metal selected from the group consisting of tungsten and molybdenum and alloys thereof. 7
A further object of the present invention is to provide an improved method of applying an adherent metallic or non-metallic coating on a body of graphite.
Referring to the drawing:
Figure l is a flow diagram illustrating how the present invention may be practiced; and
Figure 2 is a perspective view of a product in accordance with the present invention.
The present invention will now be described with respect to a specific embodiment thereof, for example, the application of an adherent copper coating to the surface of a plate of molybdenum or molybdenum-based alloy. The molybdenum plate is first. cleaned in any suitable manner, for example, by scouring with a soapy abrasive. The cleaned surface of the plate is then coated with molybdenum trioxide. The coating may be applied in one of several ways. For example, the cleaned article may be immersed in an oxidizing agent such as nitric acid, preferably a 40-60% solution by weight for about two seconds. If the molybdenum is immersed in the solu- United States Patent I tion for a much longer period, the molybdenum rapidly etches away. After removal of the plate of molybdenum, the surface is blotted to remove the excess solution. The molybdenum coated with the molybdenum trioxide is then heated in a reducing atmosphere, preferably hydrogen. The temperature of the plate is raised to about at least 6Q0. C, at which temperaturethe molybdenum trioxide 'beginsto, reduce. The higher the temperature, the more rapid is' the reduction process. I have found that when the temperature is raised to about 800 C., substantially complete reduction of the molybdenum trioxide takes place is a few seconds. A fine deposit of particles of molybdenum is formed on the surface of the molybdenum plate as a result of the reduction process. These par ticles are apparently loosely attached since they can be wiped off.
In the next step of the process, a piece of copper is placed on the treated molybdenum surface and the temperature of the molybdenum is raised in a reducing or non-oxidizing atmosphere to beyond the melting temperature of the copper. At this temperature copper melts and simultaneously alloys and spreads over the entire surface of the molybdenum in the matter of a few seconds. At this time, the plate is allowed to cool. If desired, the entire operation of reduction'of the molybdenum trioxide and the alloying of the copper into the molybdenum may be performed in a single operation by first placing the piece of copper on the surface coated with molybdenum trioxide and then raising the temperature of the place sufiiciently to reduce the molybdenum trioxide and finally raising the temperature further to melt the copper and cause the alloying action described. The wetting action of copper on molydenum which takes place resembles very much the wetting action that takes place when water spreads in a blotter. The resulting copper-coated molybdenum plate has a strongly adherent smooth coating of copper on the surface thereof free from blisters to'which solder and other contacts may be very readily made.
Excellent results have also been obtained by using molybdenum trioxide solutions to form a deposit of molybdenum trioxide on surfaces coated with metallic and non-metallic materials. A saturated water solution at room temperature is satisfactory (0.106 gram of M00 in a liter of water). A hot water solution works better (2 grams of M00 in one liter of solution). Preferably, a concentrated solution of molybdenum trioxide in ammonium hydroxide as the solvent is used. These molybdenum trioxide solutions are applied to wet the cleaned surface of the molybdenum plate and preferably allowed to dry in air. The dried plate is then heated in a reducing atmosphere as specified above to reduce the molybdenum trioxide. The remainder of the process is the same as described above.
An additional way in which the trioxide coating may be produced on the surface of an article of molybdenum is by simply heating the cleaned surface of the molybdenum in oxidizing atmosphere up to about 800 C., at which temperature the oxide forms quite readily. The plate is then subjected to the operations mentioned in the preceding examples.
In a similar manner, other metals and non-metals may be applied to the molybdenum plate, for example, indium, tin. gold, germanium, silver solders, copper, silver, goldantimony alloys. Nickel and iron may be similarly applied to molydenum and alloys thereof to form an adherent coating. The steps for bonding such other ma terials is the same as specified above for copper except that in the case of the other materials specified in this parargraph in final step the temperature is raised sutliciently to cause the material which is to be bonded to melt, spread over and alloy, into the molybdenum.
- Patented Mar. 3,1959
body and of obtaining good alloying action is not fully understood but it is believed that the reduced molydenum trioxide leaves irregularities on the surface of the body to be coated which is conducive. to good wetting and alloying action with the result that good bonding over the entire surface of the body is obtained. Additionally, it is mentioned that the reduction of the oxide to elemental material leaves this material in fine particle form which facilitates alloying and wetting action.
While the process has been described in illustrative examples in which plates of refractory substances were used, it is to be understood that other forms such as cylinder wires, etc., may be used.
The invention has particular utility in the making of semiconductor devices constituted of germanium and silicon. In the making of such devices, it is necessary to make ohmic and other kinds of connections to the germanium or silicon body of the device. Molybdenum or tungsten are desirable for such use since they have coefiicients of expansion comparable to the coefiicients of expansion of germanium and silicon; and thus fracturing of connections is minimized in the fabricating operation, as well as when large currents are passed through the device. Additionally, modybdenum and tungsten are desirable for the reason that they have good thermal and electrical conductivities. While molybdenum and tungsten have been desirable for these reasons, it has been difiicult to bond other materials to them. The present invention solves such problems as these. For example, in making an ohmic contact between silicon and molybdenum, it is desirable to use a gold and antimony alloy (gold 99%-antimony 1%); however, heretofore, it has been a problem to make a good adherent coatingof the gold-antimony alloy to the surface of a molybdenum plate. By the technique of the present invention, it is possible to produce an excellent coating of gold antimony on the surface of the molybdenum plate. The other side of the molybdenum plate may be coated with copper as described above to provide an external surface which may be easily soldered to.
I, therefore, intend in the appended claims to cover all changes and modifications of the examples of my invention herein chosen for purposes of disclosure which do not constitute departures from the spirit and scope of the invention.
What I claim as new and desire to securc by Letters Patent of the United States is:
l. The method of providing an adherent coating on an article composed of a substance selected from the group consisting of tungsten, molybdenum, tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating a surface of said article with molybdenum trioxide, reducing the molybdenum trioxide on said surface to molybdenum, applying to said reduced surface a material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
2. The method of providing an adherent coating on an article composed of a substance selected from the group consisting of tungsten, molybdenum, tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating :1 surface of said article with a solution including molybdenum trioxide as solute, removing the solvent to leave said surface coated with molybdenum trioxide, reducing the molybdenum trioxide on said surface to molybdenum, applying to said reduced surface a material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
3. The method of prividing an adherent coating on an article composed of a substance selected from the group consisting of tungsten, molybdenum, tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating a surface of said article with a water solution of molybdenum trioxide, removing the solvent to leave said surface coated with molybdenum trioxide, reducing the molybdenum trioxide on said surface to molybdenum, applying to said reduced surface a material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
4. The method of providing an adherent coating on an article composed of a substance selected from the group consisting of tungsten, molybdenum, tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating :1 surface of said article with an ammonium hydroxide solution of molybdenum trioxide, removing the solvent to leave said surface coated with molybdenum trioxide, reducing the molybdenum trioxide on said surface to molybdenum, applying to said reduced surface a material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
5. The method of providing an adherent coating on an article composed of a substance selected from the group consisting of tungsten, molybdenum, tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating the surface of said article with molybdenum trioxide, reducing the molybdenum trioxide on said coated article to molybdenum, applying to said surface in a non-oxidizing atmosphere a material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
6. The method of providing an adherent coating on an article composed of a substance selected from the group consisting of tungsten and molybdenum and tungsten and molybdenum-based alloys and graphitic carbon comprising the steps of coating a surface of said article with molybdenum trioxide, raising the temperature of said surface in non-oxidizing atmosphere to a temperature in excess of substantially 600 C. for a time to reduce the molybdenum trioxide on said surface to molybdenum, thereby forming a coating of fine particles of molybdenum metal distributed on said surface of the metal, applying to said surface in a non-oxidizing atmosphere :1 material to be coated thereon selected from the group consisting of copper, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
7. The method of providing an adherent coating on an article composed of molybdenum comprising the steps of oxidizing a surface of said article to form molybdenum trioxide thereon, reducing the molybdenum trioxide on said surface to form a coating of fine particles of molybdenum distributed on said surface, applying to said surface in a non-oxidizing atmosphere a material to be coated thereon selected from the grouuonsisting of cup per, gold, tin, indium, germanium, silver, iron and nickel and alloys thereof at the melting temperature of said material.
8. The method of providing an adherent coating on an article composed of graphitic carbon comprising the steps of coating a surface of said article with molybdenum trioxide, reducing the molybdenum trioxide on said surface in a non-oxidizing atmosphere to form a coating of line particles of molybdenum on said surface, applying to said surface in a non-oxidizing atmosphere a material to be coated thereon selected from the group consisting amaze 0! MW. gold. tin, indium. germenium ail er. iron and nickel and alloys thereof at the melting temperature of said material.
9. An article of manufacture produced by the practice ofthe process recited in claim 1.
10. The method of providing an adherent coating of an article composed of molybdenum comprising the steps of coating a surface of said article with molybdenum trioxide, reducingth'emolybdenum trioxide on said surface to form acoating of finepa'rticles of molybdenum I distributed on said surface 'applying" tosaid surface in a non-oxidizing atmosphere a mate'ri'al to be coated thereon selected from 'the group 'consisting of copper, gold, tin, indium, germanium, .silver, iron and nickel and alloys thereof at the melting temperature of said material.
6 1!. The we l! of providing an adherent coating on an article composed of tungsten comprising the steps of coating a surface of said article with molybdenum tn oxide, reducing the molybdenum trioxide on said surface '10 thereof at the melting temperature of said material.
ammo inthe file ofthis patent I I UNITED STATES PATENTS Pollard Apr. 3, 1951

Claims (1)

1. THE METHOD OF PROVIDING AN ADHERENT COATING ON AN ARTICLE COMPOSED OF A SUBSTANCE SELECTED FROM THE GROUP CONSISTING OF TUNGSTEN, MOLYBDENUM, TUNGSTEN AND MOLYBDENUM-BASED ALLOYS AND GRAPHITIC CARBON COMPRISING THE STEPS OF COATING A SURFACE OF SAID ARTICLE WITH MOLYBDENUM TRIOXIDE, REDUCING THE MOLYBDENUM TRIOXIDE ON SAID SURFACE TO MOLYBDENUM, APPLYING TO SAID REDUCED SURFACE A MATERIAL TO BE COATED THEREON SELECTED FROM THE GROUP OF COPPER, GOLD, TIN, INDIUM, GERMANIUM, SILVER, IRON, AND NICKEL AND ALLOYS THEREOF AT THE MELTING TEMPERATURE OF SAID MATERIAL.
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Cited By (18)

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US3028256A (en) * 1958-12-31 1962-04-03 Massoud T Simnad Method for forming a coating of molybdenum carbide on a carbon body
US3069288A (en) * 1959-08-06 1962-12-18 Gen Electric Self-repairing coatings for metal
US3097965A (en) * 1961-06-27 1963-07-16 Richard A Wilkins Conductive wire coating alloys, wires coated therewith and process for improving solderability therefor
US3215555A (en) * 1962-03-29 1965-11-02 Rca Corp Methods and materials for metallizing ceramic or glass bodies
US3288573A (en) * 1960-10-03 1966-11-29 Polycarbide Corp High temperature resistant member and process for forming
US3306764A (en) * 1959-08-19 1967-02-28 Nuclear Technical Service Corp Method for forming a refractory metal or carbide coating on refractory materials and article
US3386896A (en) * 1964-11-05 1968-06-04 Bell Telephone Labor Inc Electroplasting onto molybdenum surfaces
US3440181A (en) * 1965-03-22 1969-04-22 Dow Chemical Co Metal coated vermicular expanded graphite and polymer composition containing same
US3503118A (en) * 1964-12-14 1970-03-31 Union Carbide Corp Oxidation resistant graphite composite article
US3547692A (en) * 1968-10-17 1970-12-15 Engelhard Min & Chem Metal coating carbon substrates
US3619233A (en) * 1969-03-06 1971-11-09 Globe Union Inc Method of metallizing a ceramic member
US3664865A (en) * 1968-12-13 1972-05-23 Euratom Graphite impregnated with bismuth-nickel alloy
US3860437A (en) * 1959-03-10 1975-01-14 Atomic Energy Commission Method for producing refractory carbide coatings on graphite
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US4404492A (en) * 1981-08-24 1983-09-13 North American Philips Consumer Electronics Corp. Cathode structure for cathode ray tubes and method for producing same
US5721060A (en) * 1988-12-05 1998-02-24 Martin Marietta Corportion High-temperature, High-emissivity, optically black boron surface

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3028256A (en) * 1958-12-31 1962-04-03 Massoud T Simnad Method for forming a coating of molybdenum carbide on a carbon body
US3860437A (en) * 1959-03-10 1975-01-14 Atomic Energy Commission Method for producing refractory carbide coatings on graphite
US3860445A (en) * 1959-03-10 1975-01-14 Atomic Energy Commission Method for producing refractory carbide coatings on graphite
US3015579A (en) * 1959-06-15 1962-01-02 Chromizing Corp Metal coating process
US3069288A (en) * 1959-08-06 1962-12-18 Gen Electric Self-repairing coatings for metal
US3306764A (en) * 1959-08-19 1967-02-28 Nuclear Technical Service Corp Method for forming a refractory metal or carbide coating on refractory materials and article
US3288573A (en) * 1960-10-03 1966-11-29 Polycarbide Corp High temperature resistant member and process for forming
US3097965A (en) * 1961-06-27 1963-07-16 Richard A Wilkins Conductive wire coating alloys, wires coated therewith and process for improving solderability therefor
US3215555A (en) * 1962-03-29 1965-11-02 Rca Corp Methods and materials for metallizing ceramic or glass bodies
US3386896A (en) * 1964-11-05 1968-06-04 Bell Telephone Labor Inc Electroplasting onto molybdenum surfaces
US3503118A (en) * 1964-12-14 1970-03-31 Union Carbide Corp Oxidation resistant graphite composite article
US3440181A (en) * 1965-03-22 1969-04-22 Dow Chemical Co Metal coated vermicular expanded graphite and polymer composition containing same
US3547692A (en) * 1968-10-17 1970-12-15 Engelhard Min & Chem Metal coating carbon substrates
US3664865A (en) * 1968-12-13 1972-05-23 Euratom Graphite impregnated with bismuth-nickel alloy
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