US2867172A - Detonation of unprimed base charges - Google Patents
Detonation of unprimed base charges Download PDFInfo
- Publication number
- US2867172A US2867172A US444383A US44438354A US2867172A US 2867172 A US2867172 A US 2867172A US 444383 A US444383 A US 444383A US 44438354 A US44438354 A US 44438354A US 2867172 A US2867172 A US 2867172A
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- explosive
- detonation
- slurry
- formation
- fissures
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42D—BLASTING
- F42D1/00—Blasting methods or apparatus, e.g. loading or tamping
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42D—BLASTING
- F42D1/00—Blasting methods or apparatus, e.g. loading or tamping
- F42D1/08—Tamping methods; Methods for loading boreholes with explosives; Apparatus therefor
- F42D1/10—Feeding explosives in granular or slurry form; Feeding explosives by pneumatic or hydraulic pressure
Definitions
- the sensitivity of such a preparation of primer and base explosive is so great as to require extensive safety precautions where shooting is being done.
- the initiation into the bore hole of the primed material in a slurry form by conventional slurry pumps is not practical. If the slurried material could be forced into the formation it would be difficult, if not impossible, to initiate detonation with the explosive and primer remote from the detonator. Subsequent cleanout operations, where primed explosive residue remained, would be extremely hazardous.
- Figure 1 is a section view schematically illustrating the bottom of a bore hole and showing rock fissures in a formation to be blasted.
- Figure 2 is a section view of the bottom portion of a bore hole and showing schematically the packed explosive in granular form which has been filtered out by the movement of the liquid portion of the explosiveliquid slurry through rock fissures and showing a shot string of Munroe jets in random position for firing with lines indicating the direction of the principal shock wave from each.
- Figure 3 is an enlarged and exaggerated section view of a fissures permeated strata and illustrating the screening action of the fissures entrapping the granular explosive portion of a slurry such as ammonium nitrate.
- Solid explosives such as ammonium nitrate, trinitrotoluene, RDX, composition B and other explosive materials in unprimed form are granulated and slurried.
- the slurry may be aqueous, oleaginous, or acid, depending upon the solubility and compatibility of the explosive in the particularmaterial intended to become the vehicle of the slurry. It is, however, desirable that the particles of explosive material be well dispersed in the slurry, and that the dispersion of explosive material be substantially uniform.
- the slurry thus prepared may be pumped into a well or bore hole using conventional slurry pump equipment. Pressure is applied to the slurry as desired and as dictated by the porosity of the formation into which the slurry is pumped.
- the fissures in the geologic strata act as filters and trap the granular explosive material to produce a continuous phase train of explosive material.
- the pressure of the slurry column assists inthis fissure penetration and packs entrained explosive particles into the formation.
- the formation treated consists of open hole (uncased) the slurry moves directly into the formation and is prevented from traveling upward around the casing by cementing above the treated formation.
- the casing may be perforated using conventional type casing perforators before the slurry is introduced. In the latter case the slurry moves through the perforations and into the formation.
- a shot train is then prepared which consists of a plurality of grouped shaped charges known in the art as Munroe jets.
- the shaped charge is a shaped block of explosive material focused by forming an open conical face wherein the primary shock wave is amplified and concentrated along the principal axis of the cone.
- An ordinary detonator imbedded in the shaped charge explodes the charge to form the Munroe jet.
- the plurality of' shaped charges are arranged to direct their principal shock waves radially and angularly through the geologic formation. In this manner a diffusion of principal shock waves is accomplished calculated to intersect the explosive packed fissures and layers.
- Experimental results have proven that irrespective of intervening media, i. e., air, water, earth, stone, or combinations of these, the principal shock wave of the Munroe type shaped charge will shock penetrate the barriers, with sufficient intensity to initiate the unprimed base charge.
- the shot train is lowered into the well or bore hole until it is adjacent the explosive impregnated structure.
- the detonator is initiated and the jets are fixed.
- the principal shock waves radiate from the shot train in accord with the position of the shaped charges, and etfectively penetrate through the intervening media to detonate with high order explosion the explosives packed in the fissures of the geologic formation.
- Surface testing has indicated that thin sections down to one-sixteenth yi of an inch initiate efiiciently.
- high order detonation was observed using a Munroe type jet for initiation through an air and solid media at various selected angles between zero degrees andninety degrees.
- Composition B percent trinitrotoluene and 40 percent RDX was selected since it is characteristic of the family of high explosives and ammonium nitrate was selected because it characterizes a .low explosive in performance. Some influence was noted of grain size and the tests demonstrated that grain size should preferably range below twenty mesh for best results. No evidences of unburned powder were observed.
- IISlubility and dilutional efiects test Control slurries of explosive materials in inhibited acid, brine, sweet and sour crude oil were detonated with Munroe jets and the degree of detonation was observed using a standard barograph recording machine. The concentration of granular explosive materials in the vehicle was maintained at two pounds per gallon throughout the series of tests using composition B, trinitrotoluene and ammonium nitrate. The controls were fired and the resultant shock wasrecorded on the barograph. Subsequently, and in the various media, identical samples were detonated after seven days exposure in the slurry concentration at a temperature of 100 degrees Fahrenheit.
- IIISZurry insensitivity tests thus indicating complete shot propagation. All shots exceeded the minimum-recorded control indicating detonation in every case.
- Slurry asused herein with respect to the condition of explosive material and fluid prepared for insertion in a borehole, has reference to a dispersion of solid granular explosive material where the grain or particle size is maintained discrete in a relatively thin pumpable liquid mix with water, for example, and wherein the explosive material is relatively insoluble in the fluid.
- steps which include: preparing a slurry of granular unsensitized explosive material in a fluid media; forcing said slurry material into a geologic formation whereby the fissures in said formation filter pack said granular unmprimed explosive allowing the liquid media to through; lowering a string of shaped charges down said bore hole adjacent said filter packed formation; detonating said shaped charges causing shock detonation of saidexplosive material in said geologic formation through intervening barriers.
- said granular explosive material in said slurry is of a particle size ranging between 20 mesh and size admitting the suspension of solid particles in a given liquid and wherein said explosive material is substantially insoluble in said liquid.
- steps which include: slurrying a mixture of liquid and granular explosive material; pumping said slurry into a geologic formation thus filter packing openings in said formation with granular explosive material; lowering at least one shaped charge into said bore hole so that upon positioning, the principal axis of said shaped charge intersects, upon projection, the geologic formation bearing said filter packed explosive; detonating said shaped charge thereby remotely initiating said filter packed explosive through intervening media.
Description
Jan. 6, 1959 J. R. HRADEL- DETONATION 0F UNPRIMED BASE CHARGES 2 Sheets-Sheet 1 Filed July 19, 1954 BORE HOLE FISSURES FILTER PACKED FISSURES SHOT STRING BORE HOLE PRmc|PAL SHOCK uouw MOVES INTO FORMATION INVENTOR. 524/6 rfmala Arman/6y:
FILTER PACKED FISSURES 1959 J. R. HRADEL 2,867,172
DETONATION 0F UNPRIMED BASE CHARGES Filed July '19, 1954 2 Sheets-Sheet 2 SLURRY TANK GRANULAR EXPLOSIVES GRANULAR EXPLOSWE PACKED EXPLOSIVE GRANULAR FISSURES FILTER PACKED WATER v SAND ,W/ DETONATOR SEAT MUNROE JET UNIT RANGE OF JET TH ROUGH B INTERVENING BARRIERS M ATTORNEYS k e an t 1'" tae Z,8?,l72 Fatented Jan. 6, 1959 2,867,172 DETGNATKQN 0F UNPRIMED BASE CHARGE? Joseph R. Hradel, Mount Pleasant, Mich. Application July 19, 1954, Serial No. 444,383 9 Ciaims. (Cl. 102-23) necessary that the detonator and primer be intimately associated with the basic explosive material. The sensitivity of such a preparation of primer and base explosive is so great as to require extensive safety precautions where shooting is being done. Further, the initiation into the bore hole of the primed material in a slurry form by conventional slurry pumps is not practical. If the slurried material could be forced into the formation it would be difficult, if not impossible, to initiate detonation with the explosive and primer remote from the detonator. Subsequent cleanout operations, where primed explosive residue remained, would be extremely hazardous.
It is, therefore, one of the objects of the present invention to provide a shooting method in which an unprimedcharge can be slurried and pumped into the desired geological formation.
It is another object of the present invention to teach the detonation of unprimed base charges in a bore hole after the explosive material has been forced into the fissures of a geological formation or strata and the detonating means is separated from the explosive material.
' It is another object to teach a practical utilization of shaped charges of the Munroe type in initiating detonations in borehole shooting.
It is another object to teach eflicient explosive procedures in bore hole shooting wherein the combination of slurried explosive material and shaped charges accomplish detonation results beyond the expectations of conventional shooting inasmuch as the explosion occurs in the fissures of the formation and not merely in the bore hole.
Further objects and advantages will become apparent to those skilled in the art as the description proceeds.
Figure 1 is a section view schematically illustrating the bottom of a bore hole and showing rock fissures in a formation to be blasted.
Figure 2 is a section view of the bottom portion of a bore hole and showing schematically the packed explosive in granular form which has been filtered out by the movement of the liquid portion of the explosiveliquid slurry through rock fissures and showing a shot string of Munroe jets in random position for firing with lines indicating the direction of the principal shock wave from each.
Figure 3 is an enlarged and exaggerated section view of a fissures permeated strata and illustrating the screening action of the fissures entrapping the granular explosive portion of a slurry such as ammonium nitrate.
Solid explosives such as ammonium nitrate, trinitrotoluene, RDX, composition B and other explosive materials in unprimed form are granulated and slurried. The slurry may be aqueous, oleaginous, or acid, depending upon the solubility and compatibility of the explosive in the particularmaterial intended to become the vehicle of the slurry. It is, however, desirable that the particles of explosive material be well dispersed in the slurry, and that the dispersion of explosive material be substantially uniform.
The slurry thus prepared may be pumped into a well or bore hole using conventional slurry pump equipment. Pressure is applied to the slurry as desired and as dictated by the porosity of the formation into which the slurry is pumped. The fissures in the geologic strata act as filters and trap the granular explosive material to produce a continuous phase train of explosive material. The pressure of the slurry column assists inthis fissure penetration and packs entrained explosive particles into the formation. Where the formation treated consists of open hole (uncased) the slurry moves directly into the formation and is prevented from traveling upward around the casing by cementing above the treated formation. Where the area sought to be treated by the explosive is behind cemented casing, the casing may be perforated using conventional type casing perforators before the slurry is introduced. In the latter case the slurry moves through the perforations and into the formation.
, A shot train is then prepared which consists of a plurality of grouped shaped charges known in the art as Munroe jets. The shaped charge is a shaped block of explosive material focused by forming an open conical face wherein the primary shock wave is amplified and concentrated along the principal axis of the cone. An ordinary detonator imbedded in the shaped charge explodes the charge to form the Munroe jet. The plurality of' shaped charges are arranged to direct their principal shock waves radially and angularly through the geologic formation. In this manner a diffusion of principal shock waves is accomplished calculated to intersect the explosive packed fissures and layers. Experimental results have proven that irrespective of intervening media, i. e., air, water, earth, stone, or combinations of these, the principal shock wave of the Munroe type shaped charge will shock penetrate the barriers, with sufficient intensity to initiate the unprimed base charge.
The shot train is lowered into the well or bore hole until it is adjacent the explosive impregnated structure. The detonator is initiated and the jets are fixed. The principal shock waves radiate from the shot train in accord with the position of the shaped charges, and etfectively penetrate through the intervening media to detonate with high order explosion the explosives packed in the fissures of the geologic formation. Surface testing has indicated that thin sections down to one-sixteenth yi of an inch initiate efiiciently. In tests utilizing composition B and, separately, ammonium nitrate, high order detonation was observed using a Munroe type jet for initiation through an air and solid media at various selected angles between zero degrees andninety degrees. Composition B percent trinitrotoluene and 40 percent RDX) was selected since it is characteristic of the family of high explosives and ammonium nitrate was selected because it characterizes a .low explosive in performance. Some influence was noted of grain size and the tests demonstrated that grain size should preferably range below twenty mesh for best results. No evidences of unburned powder were observed. I
Similarly, various slurries including water, brine, oil (crude) and containing high and low explosives in granular form exhibited excellent explosive results with no ap parent dilutional effects in the presence of the various materials. was observed to be of high order. The term high order detonation herein has relation to completeness of detonation. at maximum velocity for the explosive material employed Surface testing was undertaken to indicate the underground phenomena under observable and controlled conditions. The test series included the following:
I]et penetration of intervening media test Unprimed base charges were placed in containers re mote from a Munroe jet and air, fluid, and solid media (earth) barriers were placed between the jet and the base charge. The experiments showed that an initiating shock wave was transmitted through the interposed barriers, alone or in combination, tov detone explosive materials ranging in sensitivity fromcomposition, B and trinitrotoluene to ammonium-nitrate. No detonation of the base charge was observed where conventional primers and detonators were remotely positioned from the base charge with or without interposing various barriers. Using con ventional primers, explosion of the base charges was observed only when the detonator was intimately associated with the base charge.
IISlubility and dilutional efiects test Control slurries of explosive materials in inhibited acid, brine, sweet and sour crude oil were detonated with Munroe jets and the degree of detonation was observed using a standard barograph recording machine. The concentration of granular explosive materials in the vehicle was maintained at two pounds per gallon throughout the series of tests using composition B, trinitrotoluene and ammonium nitrate. The controls were fired and the resultant shock wasrecorded on the barograph. Subsequently, and in the various media, identical samples were detonated after seven days exposure in the slurry concentration at a temperature of 100 degrees Fahrenheit. Upon detonation at the end of the exposure periodnomaterial deviation from the control observation was observed. Enhanced high order explosions occurred indicating an increase in explosive sensitivity as recorded on the barograph under identical positioning. Observations of the slurry materialcunder dissolved'suspension, or settled out conditions when detonation occurred indicate that the Munroe jet appears capable of detonating the explosive materials indicated in whatever state they may be in at the time of initiation in the bore hole.
IIISZurry insensitivity tests thus indicating complete shot propagation. All shots exceeded the minimum-recorded control indicating detonation in every case.
IVSimulated strata tests In order to simulate strata conditions, artificial fissures were created and filter packed with explosive materials in slurry form as indicated in priortests. Using progressively diminishing sized simulated fissures down to and including one-sixteenth of an inch uniform shot propagation was observed in each detonation using the Mame jet .fired transversely of the plane of said fissure and in another shot fired parallel to the plane of said fissure notwithstanding interposed air, fluid, and solid media. No
Detonation by means of the shapedcharge simulated strata tests were conducted on fissures less than one-sixteenth of an inch across inasmuch'as this size powder train was thought to reach a practical limit at this point insofar as the detonation in smaller fissures.
The above tests were made to simulate conditions obtained underground and effective explosive propagation was observed under variant conditions to the end that an enhanced explosive underground result could be obtained and sothat theoretical underground conditions could be verified by measured observation.
In oilwells and bore holes, granular explosive material can now be slurried and pumped into selected geologic strata. Detonation is accomplished using a string or shot train of shaped charges lowered into the explosive impregnated formation. High order detonation was observed using these procedures. Subsequent clean-out operations after initiation showed little to no undetonated residue indicating excellent explosion propagation within the range of the jets produced by the shaped charges.
It will have been observed that at no time during the slurry-or pumping operations is the high explosive material primed. It is not primed after insertion into the bore hole, yet it can be effectively detonated as desired in a safe manner. Explosives handling is greatly simplified and shooting etfectiveness is vastly increased by reason of the fissure entrapment of granulated explosive materials under pressure. The blasting of strata in bore holes and oilwells has been simplified and rendered more 7 effective byreason of this invention.
.Unprirned as used herein, in reference to explosive materials, relates to the unsensitized condition of the explosive material as it is slurried.
Slurry asused herein, with respect to the condition of explosive material and fluid prepared for insertion in a borehole, has reference to a dispersion of solid granular explosive material where the grain or particle size is maintained discrete in a relatively thin pumpable liquid mix with water, for example, and wherein the explosive material is relatively insoluble in the fluid.
Having thus described my invention it will be understood that certain obvious modifications are intended to be included, limited only by the scope of the hereinafter appended claims.
I claim:
1. In a process for loading and shooting bore holes as in oilwell and mining operations, the steps which include: preparing a slurry of granular unsensitized explosive material in a fluid media; forcing said slurry material into a geologic formation whereby the fissures in said formation filter pack said granular unmprimed explosive allowing the liquid media to through; lowering a string of shaped charges down said bore hole adjacent said filter packed formation; detonating said shaped charges causing shock detonation of saidexplosive material in said geologic formation through intervening barriers.
- 2. The process in accord with claim 1 wherein said fluid in said slurry is crude petroleum where the explosive is substantially insoluble in said fluid.
3. The process in accord with claim 1 wherein said fluid in said slurry is brine water where the explosive is substantially insoluble in said fluid.
4. The process in accord with claim 1 wherein said fiuid is inhibited acid where the explosive is substantially insoluble in said fluid.
5. The process in accord with claim 1 wherein said granular explosive material in said slurry is of a particle size ranging between 20 mesh and size admitting the suspension of solid particles in a given liquid and wherein said explosive material is substantially insoluble in said liquid.
6. In a process for loading and shooting bore holes in oil well drilling and mining operations, the steps which include: slurrying a mixture of liquid and granular explosive material; pumping said slurry into a geologic formation thus filter packing openings in said formation with granular explosive material; lowering at least one shaped charge into said bore hole so that upon positioning, the principal axis of said shaped charge intersects, upon projection, the geologic formation bearing said filter packed explosive; detonating said shaped charge thereby remotely initiating said filter packed explosive through intervening media.
7. The process in accord with claim 6 wherein said granular explosive is ammonium nitrate.
8. In a process for loading and shooting bore holes, the steps which include: slurrying a mixture of a fluid and granular explosive material; pumping said slurry into a geologic formation, thus filter packing openings in said formation with granular explosive material, the fluid ma- References Cited in the file of this patent UNITED STATES PATENTS 2,171,416 Lee Aug. 29, 1939 2,316,596 Kennedy Apr. 13, 1943 2,420,201 Seavey May 6, 1947 2,463,709 McFarland Mar. 8, 1949 2,494,256 Muskat et a1. Jan. 10, 1950 2,504,611 Zandmer Apr. 18, 1950 2,703,528 Lee Mar. 8, 1955 2,704,515 Barlow Mar. 22, 1955 2,708,876 Nowak May 24, 1955 FOREIGN PATENTS 701,074 Great Britain Dec. 16, 1953
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US444383A US2867172A (en) | 1954-07-19 | 1954-07-19 | Detonation of unprimed base charges |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US444383A US2867172A (en) | 1954-07-19 | 1954-07-19 | Detonation of unprimed base charges |
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| US2867172A true US2867172A (en) | 1959-01-06 |
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| US444383A Expired - Lifetime US2867172A (en) | 1954-07-19 | 1954-07-19 | Detonation of unprimed base charges |
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Cited By (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3024727A (en) * | 1958-10-13 | 1962-03-13 | Dow Chemical Co | Area detonation |
| US3059575A (en) * | 1957-08-19 | 1962-10-23 | Trojan Powder Co | Seismographic exploration |
| US3075464A (en) * | 1959-03-20 | 1963-01-29 | Reserve Mining Co | Blast hole charge and charging method |
| US3075463A (en) * | 1959-09-04 | 1963-01-29 | Dow Chemical Co | Well fracturing |
| US3083127A (en) * | 1960-06-17 | 1963-03-26 | Trojan Powder Co | Aqueous nitrostarch explosive slurries |
| US3094069A (en) * | 1959-01-05 | 1963-06-18 | Dow Chemical Co | Method of blasting and ammonium nitrate explosive composition |
| US3108917A (en) * | 1961-07-03 | 1963-10-29 | Canadian Ind | Tnt-tetraborate gelled aqueous explosive slurry |
| US3116189A (en) * | 1961-06-28 | 1963-12-31 | Howard J Fisher | Plastic explosive composition |
| US3121036A (en) * | 1958-02-28 | 1964-02-11 | Canada Iron Ore Co | Explosive composition comprising ammonium nitrate and a heat-producing metal |
| US3129126A (en) * | 1961-12-22 | 1964-04-14 | Du Pont | Blasting composition |
| DE1171786B (en) * | 1959-07-22 | 1964-06-04 | The Dow Chemical Company, Midland, Mich. (V. St. A.) | Borehole-bound blasting method. |
| US3147163A (en) * | 1960-08-25 | 1964-09-01 | Trojan Powder Co | Sensitized oil-slurried explosives |
| US3160538A (en) * | 1963-07-01 | 1964-12-08 | Commercial Solvents Corp | Aqueous explosive gel composition and process |
| US3212945A (en) * | 1961-05-24 | 1965-10-19 | Dynamit Nobel Ag | Production of detonatable explosive emulsion preparations |
| US3235425A (en) * | 1960-11-07 | 1966-02-15 | Hercules Powder Co Ltd | Slurry-type blasting compositions containing ammonium nitrate and smokeless powder |
| US3236180A (en) * | 1966-02-22 | Blasting charge and method | ||
| US3270815A (en) * | 1963-09-11 | 1966-09-06 | Dow Chemical Co | Combination hydraulic-explosive earth formation fracturing process |
| US3303738A (en) * | 1963-10-14 | 1967-02-14 | Intermountain Res And Engineer | Method for mixing and pumping of slurry explosive |
| US3366053A (en) * | 1958-10-29 | 1968-01-30 | Trojan Powder Co | Ammonium nitrate explosive mixture |
| US3561532A (en) * | 1968-03-26 | 1971-02-09 | Talley Frac Corp | Well fracturing method using explosive slurry |
| US3602309A (en) * | 1968-12-16 | 1971-08-31 | Continental Oil Co | Method of exploding or igniting materials using adiabatic compression of gas |
| US3659652A (en) * | 1971-01-27 | 1972-05-02 | Talley Frac Corp | Liquid explosive for well fracturing |
| US3690378A (en) * | 1970-09-30 | 1972-09-12 | Cities Service Oil Co | Well completion method and apparatus for explosive stimulation |
| US3747679A (en) * | 1971-11-22 | 1973-07-24 | Talley Ind | Method of fracturing a formation using a liquid explosive |
| US3947301A (en) * | 1959-01-05 | 1976-03-30 | The Dow Chemical Company | Ammonium nitrate explosive composition |
| US4057780A (en) * | 1976-03-19 | 1977-11-08 | The United States Of America As Represented By The United States Energy Research And Development Administration | Method for describing fractures in subterranean earth formations |
| DE2809311A1 (en) * | 1978-03-03 | 1979-09-13 | Thomas Milton Sullivan | Shallow coal seam mining system - uses shaped charge to blast cavity at bottom of one shaft through which water is pumped to form slurry raised through second shaft |
| US5853224A (en) * | 1997-01-22 | 1998-12-29 | Vastar Resources, Inc. | Method for completing a well in a coal formation |
| US6024171A (en) * | 1998-03-12 | 2000-02-15 | Vastar Resources, Inc. | Method for stimulating a wellbore penetrating a solid carbonaceous subterranean formation |
| US20040226715A1 (en) * | 2003-04-18 | 2004-11-18 | Dean Willberg | Mapping fracture dimensions |
| US20080041592A1 (en) * | 2004-11-16 | 2008-02-21 | Stephen Wheller | Oil Well Perforators |
| US20130247789A1 (en) * | 2012-03-20 | 2013-09-26 | Brent Dee Alexander | Hot hole charge system |
| CN103573285A (en) * | 2013-10-25 | 2014-02-12 | 山西潞安环保能源开发股份有限公司五阳煤矿 | Cylindrical mining method for three-low coal bed to extract coal bed methane |
| US10138720B2 (en) * | 2017-03-17 | 2018-11-27 | Energy Technology Group | Method and system for perforating and fragmenting sediments using blasting material |
| US11719516B2 (en) | 2018-10-23 | 2023-08-08 | Moon-Jong Kwon | Method of blasting using jet units charged in a blast-hole |
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| US2171416A (en) * | 1937-02-23 | 1939-08-29 | Lee Angular Drill Corp | Method of treating a producing formation |
| US2316596A (en) * | 1938-11-04 | 1943-04-13 | Gulf Research Development Co | Shooting wells |
| US2420201A (en) * | 1942-03-07 | 1947-05-06 | Olin Ind Inc | Blasting cap |
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| US2494256A (en) * | 1945-09-11 | 1950-01-10 | Gulf Research Development Co | Apparatus for perforating well casings and well walls |
| US2504611A (en) * | 1946-02-25 | 1950-04-18 | Zandmer Solis Myron | Pressure reduction chamber and unloading valve for explosives |
| GB701074A (en) * | 1951-02-06 | 1953-12-16 | Schlumberger Well Surv Corp | Method of and apparatus for perforating well casings and the like |
| US2703528A (en) * | 1953-11-05 | 1955-03-08 | Maumee Collieries Company | Blasting process |
| US2704515A (en) * | 1955-03-22 | Method of loading for liquid oxygen explosives | ||
| US2708876A (en) * | 1950-10-17 | 1955-05-24 | Union Oil Co | Ring detonation process for increasing productivity of oil wells |
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1954
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| US2704515A (en) * | 1955-03-22 | Method of loading for liquid oxygen explosives | ||
| US2171416A (en) * | 1937-02-23 | 1939-08-29 | Lee Angular Drill Corp | Method of treating a producing formation |
| US2316596A (en) * | 1938-11-04 | 1943-04-13 | Gulf Research Development Co | Shooting wells |
| US2420201A (en) * | 1942-03-07 | 1947-05-06 | Olin Ind Inc | Blasting cap |
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Cited By (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3236180A (en) * | 1966-02-22 | Blasting charge and method | ||
| US3059575A (en) * | 1957-08-19 | 1962-10-23 | Trojan Powder Co | Seismographic exploration |
| US3121036A (en) * | 1958-02-28 | 1964-02-11 | Canada Iron Ore Co | Explosive composition comprising ammonium nitrate and a heat-producing metal |
| US3024727A (en) * | 1958-10-13 | 1962-03-13 | Dow Chemical Co | Area detonation |
| US3366053A (en) * | 1958-10-29 | 1968-01-30 | Trojan Powder Co | Ammonium nitrate explosive mixture |
| US3094069A (en) * | 1959-01-05 | 1963-06-18 | Dow Chemical Co | Method of blasting and ammonium nitrate explosive composition |
| US3947301A (en) * | 1959-01-05 | 1976-03-30 | The Dow Chemical Company | Ammonium nitrate explosive composition |
| US3075464A (en) * | 1959-03-20 | 1963-01-29 | Reserve Mining Co | Blast hole charge and charging method |
| DE1171786B (en) * | 1959-07-22 | 1964-06-04 | The Dow Chemical Company, Midland, Mich. (V. St. A.) | Borehole-bound blasting method. |
| US3075463A (en) * | 1959-09-04 | 1963-01-29 | Dow Chemical Co | Well fracturing |
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