US3129126A - Blasting composition - Google Patents

Blasting composition Download PDF

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Publication number
US3129126A
US3129126A US161378A US16137861A US3129126A US 3129126 A US3129126 A US 3129126A US 161378 A US161378 A US 161378A US 16137861 A US16137861 A US 16137861A US 3129126 A US3129126 A US 3129126A
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weight
parts
composition
blasting
ferrophosphorus
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US161378A
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Harold G Carlevato
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EIDP Inc
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EI Du Pont de Nemours and Co
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Priority to US161378A priority Critical patent/US3129126A/en
Priority to GB40394/62A priority patent/GB958310A/en
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    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
    • C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase

Definitions

  • This invention relates to an improved blasting explosive composition. More particularly, this invention relates to an explosive composition characterized by unusually high bulk strength.
  • This invention provides a greatly improved slurry-type blasting composition, which in addition to having an excellent combination of properties such as those mentioned hereinbefore, is inexpensive and has greatly improved bulk strength and, consequently, greatly improved strength per unit volume of explosive. Because of its greater strength per unit volume, as compared to known slurry-type blasting agents such as those described above, the composition of [this invention can achieve equivalent blasting effects with fewer or smaller diameter boreholes, or both, thereby substantially reducing the cost of preparing the blasting site.
  • the blasting composition of this invention and preferably each 100 parts by weight thereof, consists essentially of (a) About from 20 to 30, and perferably 25 to 28 parts by weight of ammonium nitrate,
  • the ferrophosphorus employed in the compositions of this invention is conveniently obtained as a by-product from the manufacture of elemental phosphorus.
  • the ferrophosphorus contains about from 10 to 75%, and preferably about from 20 to 60% by weight of phosphorus.
  • the ferrophosphorus employed herein is finely divided; ferrophosphorus having a particle size such that it will pass through a 50, and perferably a 100 mesh screen (-U.S. standard series) is particularly preferred.
  • the particle size of the TNT, ammonium nitrate and sodium nitrate are not particularly critical. Usually, TNT "having 3-mesh (U.S. standard series) or smaller particle size is employed, while ammonium nitrate and sodium nitrate having a particle size of 20 mesh or smaller are usually used.
  • the compositions preferably contain up to 10, and usually 0.5 to 1.5% by' weight of gelling agent based on the weight of composition.
  • gelling agents are guar gum flour and other galactomannans such as locust bean flour; wheat flour; cereal products; pregelatinized starch products and mixtures thereof.
  • Other known additives for blasting agents such as, for example, RDX, PETN, DNT and fuel oils also can be added in small proportions.
  • compositions of this invention can be prepared by merely mixing the various ingredients thereof to form a homogeneous slurry.
  • the Water present in the compositions of this invention contains a high proportion of ammonium nitrate, and preferably is substantially saturated therewith.
  • the water is usually first premixed with emmonium nitrate to form a concentrated, and preferably substantially saturated solution, then the requisite proportions of the remaining ingredients are added to the solution.
  • the resulting slunry blasting agents can be stored in a container such as a bag of polyethylene or other polymeric material. When they are ready to be used, the bagged compositions of this invention can be merely dropped down a borehole.
  • compositions of this invention are inexpensive, highly efficient and have greatly improved bulk strength, hence, strength per unit volume of borehole.
  • the compositions of this invention are easily prepared from readily available commercial materials and can be used in a wide variety of blasting conditions including both wet and dry boreholes.
  • the compositions of this invention have excellent storage stability and can be handled, charged and initiated in the same general manner as known slurried blasting agents such as those mentioned hereinbefore.
  • composition thus produced has the following content by weight:
  • the density of the composition is 1.7 grams per cubic centimeter and the composition has a Triton value (the number of grams of tn'nitrotoluene required to produce the same angle of recoil of a standard ballistic mortar as ten grams of explosive under test) of 9.8, equivalent to a bulk strength value of 16.6.
  • a comparative composition is prepared by the general procedure described above, except that an oxygen balanced mixture of ammonium nitrate and sodium nitrate is substituted for the ferrophosphorus employed in preparing the composition of this invention.
  • the compara tive blasting composition has the following overall formulation:
  • the density of the composition is 1.4 grams per cubic centimeter and the composition has a Triton value of 9.2, equivalent to a bulk strength value of 12.8.
  • An aqueous slurry blasting composition each 100 parts by weight thereof consisting essentially of:
  • An aqueous slurry blasting composition each 100 parts by Weight thereof consisting essentially of:
  • gelling agent selected from the group consisting of gelactomannans; wheat flour; cereal products; pregelatinized starch products and mixtures thereof based on the total Weight of said composition.

Description

United States Patent 3,129,126 BLASTIN G COMPOSITION Harold G. Carlevato, Hagerstown, Md., assignor to E. I. du Pont de Nemours and Company, Wilmington, DeL, a corporation of Delaware N0 Drawing. Filed Dec. 22, 1961, Ser. No. 161,378 2 Claims. (ill. 149-29) This invention relates to an improved blasting explosive composition. More particularly, this invention relates to an explosive composition characterized by unusually high bulk strength.
In all quarry and stripping operations of substantial size, large quantities of explosives are used to free the rock or ore from its bed and to fragment the material so that it can be removed and further processed. The cost of the explosive and of the operations required to effect a blast constitute a substantial proportion of the cost of the materials thus obtained.
Many explosive formulations utilizing relatively cheap ingredients have been evaluated as a means of reducing the cost of blasting. Various properties such as handling characteristics, sensitivity, storability, and reliability must be considered in the selection of a blasting agent. A relatively recent blasting agent which has achieved commercial acceptance is described in U.S. Patent 2,930, 685, and comprises an aqueous slurry of trinitrotoluene and ammonium nitrate to which gelling agents and metal nitrates can be added.
This invention provides a greatly improved slurry-type blasting composition, which in addition to having an excellent combination of properties such as those mentioned hereinbefore, is inexpensive and has greatly improved bulk strength and, consequently, greatly improved strength per unit volume of explosive. Because of its greater strength per unit volume, as compared to known slurry-type blasting agents such as those described above, the composition of [this invention can achieve equivalent blasting effects with fewer or smaller diameter boreholes, or both, thereby substantially reducing the cost of preparing the blasting site.
The blasting composition of this invention, and preferably each 100 parts by weight thereof, consists essentially of (a) About from 20 to 30, and perferably 25 to 28 parts by weight of ammonium nitrate,
(b) About from to 25, and preferably 14 to 16 parts by Weight of sodium nitrate,
(c) About from 20 to 30, and preferably 26 to 28 parts by weight of tr-initrotoluene,
(d) About from 10 to 30, and preferably 18 to 22 parts by weight of ferrophosphonus, and
(2) About from 8 to 20, and preferably 10 to 12 parts by weight of water.
The ferrophosphorus employed in the compositions of this invention is conveniently obtained as a by-product from the manufacture of elemental phosphorus. Usually, the ferrophosphorus contains about from 10 to 75%, and preferably about from 20 to 60% by weight of phosphorus. The ferrophosphorus employed herein is finely divided; ferrophosphorus having a particle size such that it will pass through a 50, and perferably a 100 mesh screen (-U.S. standard series) is particularly preferred. The particle size of the TNT, ammonium nitrate and sodium nitrate are not particularly critical. Usually, TNT "having 3-mesh (U.S. standard series) or smaller particle size is employed, while ammonium nitrate and sodium nitrate having a particle size of 20 mesh or smaller are usually used.
To minimize segregation of the components of the compositions of this invention on storage, and particularly when the compositions of this invention are to be used in the presence of free water in a borehole, the compositions preferably contain up to 10, and usually 0.5 to 1.5% by' weight of gelling agent based on the weight of composition. Examples of gelling agents are guar gum flour and other galactomannans such as locust bean flour; wheat flour; cereal products; pregelatinized starch products and mixtures thereof. Other known additives for blasting agents such as, for example, RDX, PETN, DNT and fuel oils also can be added in small proportions.
The compositions of this invention can be prepared by merely mixing the various ingredients thereof to form a homogeneous slurry. For optimum blasting efficiency, the Water present in the compositions of this invention contains a high proportion of ammonium nitrate, and preferably is substantially saturated therewith. For this reason and in order to obtain a product of optimum uniformity, the water is usually first premixed with emmonium nitrate to form a concentrated, and preferably substantially saturated solution, then the requisite proportions of the remaining ingredients are added to the solution. The resulting slunry blasting agents can be stored in a container such as a bag of polyethylene or other polymeric material. When they are ready to be used, the bagged compositions of this invention can be merely dropped down a borehole.
Compositions of this invention are inexpensive, highly efficient and have greatly improved bulk strength, hence, strength per unit volume of borehole. The compositions of this invention are easily prepared from readily available commercial materials and can be used in a wide variety of blasting conditions including both wet and dry boreholes. The compositions of this invention have excellent storage stability and can be handled, charged and initiated in the same general manner as known slurried blasting agents such as those mentioned hereinbefore.
In the following example, which illustrates this invention, parts and percentages are by weight unless otherwise indicated.
Example Ten parts of grained ammonium nitrate and 15.0 parts of sodium nitrate, both having a particle size less than about 20 mesh, are blended with 27.5 parts of a 60% aqueous solution of ammonium nitrate which contains 0.5 part of guar gum. To the mix is added 20.0 parts ferrophosphorus (50/50 iron/phosphorus, smaller than mesh) and 27 parts of trinitrotoluene in the form of spherical or flaked particles that will pass a 3 mesh screen (A.S.-T.M. standard). Mlixin g is continued for two minutes. The mixture, now a thick fluid slurry, is poured while at 60 to 65 F. into cylindrical polyethylene bags 8 mils in thickness, five inches in diameter and 29 inches in height.
The composition thus produced has the following content by weight:
Percent Ammonium nitrate 26.5 Water 11.0
Trinitrotoluene 27.0 Sodium nitrate 15.0 Ferrophosphorus 20.0 Guar gum 0.5
The density of the composition is 1.7 grams per cubic centimeter and the composition has a Triton value (the number of grams of tn'nitrotoluene required to produce the same angle of recoil of a standard ballistic mortar as ten grams of explosive under test) of 9.8, equivalent to a bulk strength value of 16.6.
A comparative composition is prepared by the general procedure described above, except that an oxygen balanced mixture of ammonium nitrate and sodium nitrate is substituted for the ferrophosphorus employed in preparing the composition of this invention. The compara tive blasting composition has the following overall formulation:
Percent Ammonium nitrate 34.0 Water 15.0 Trinitrotoluene 25.0 Sodium nitrate 25.0 Guar gum 1.0
The density of the composition is 1.4 grams per cubic centimeter and the composition has a Triton value of 9.2, equivalent to a bulk strength value of 12.8.
In field trials, an increase in loading density, i.e., pounds of explosive per foot of borehole, of about 21.5% is obtained with the composition of this invention containing ferrophosphorus as contrasted with the comparative composition. Inasmuch as the Triton value of the composition of this invention exceeds that of the comparative composition, this increased loading density permits increased spacing of drilling patterns. In all trials, with the composition of this invention described above, tragmentation was very good, and superior to that obtained with the comparative composition.
The present invention has been described in detail in the foregoing. I intend, therefore, to be limited only by the following claims.
I claim:
1. An aqueous slurry blasting composition, each 100 parts by weight thereof consisting essentially of:
(a) about from 20 to 30 parts by Weight of ammonium nitrate,
(b) about from 10 to 25 parts by weight of sodium nitrate,
(c) about from 20 to 30 parts by weight of trinitrotoluene,
(d) about from 10 to 30 parts 'by weight of ferrophosphorus, and
(e) about from 8 to 20 parts by weight of water.
2. An aqueous slurry blasting composition, each 100 parts by Weight thereof consisting essentially of:
(a) about from 25 to 28 parts by weight of ammonium nitrate,
(b) about from 14 to 16 parts by Weight of sodium nitrate,
(0) about from 26 to 28 parts by weight of trinitrotoluene,
(d) about from 18 to 22 parts by weight of ferrophosphorus,
(e) about from 10 to 12 parts by weight of Water, and
!( about from 0.5 to 1.5 percent by weight of gelling agent selected from the group consisting of gelactomannans; wheat flour; cereal products; pregelatinized starch products and mixtures thereof based on the total Weight of said composition.
References Cited in the file of this patent UNITED STATES PATENTS 2,095,302 Wood ford et a1. Oct. 12, 1937 2,103,698 Schmid Dec. 28, 1937 2,768,073 Davidson Oct. 23, 1956 2,867,172 Hra del Jan. 6, 1959 2,930,685 Cook et al Oct. 13, 1960 FOREIGN PATENTS 633,514 Germany July 24, 1936 UNITED STATES PATENT OFFICE CERTIFICATE OF CURRECTION Patent No; 3,, 129 126 April 141 1964 Harold G, Garlevato error appears in the above numbered pat- It is hereby certified that t the said Letters Patent should read as en't requiring correction and the, corrected below.
Column 4 line 21 strike out cereal productsfit Signed and sealed thi s 8th day of S'ep tember 1964 (SEAL) Attest:
ERNEST w. .sw'IDER' EDWARD J. BRENNER Attesting Officer Commissioner of Patents UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent N0; 3 129 g 126 April 14 1964 Harold G, Carlevato hat error appears in the above numbered pat- 1 It is hereby certified 0 0 that the said Letters Patent should read as 5 ant requiring correctien and corrected below Column 4 line 21 strike out cereal products;",
Signed and sealed this 8th day of September 1964,
(SEAL) Attest:
EDWARD J. BRENNER ERNEST w. swiDER Attesting Officer Commissioner of Patents

Claims (1)

1. AN AQUEOUS SLURRY BLASTING COMPOSITION, EACH 100 PARTS BY WEIGHT THEREOF CONSISTING ESSENTIALLY OF: (A) ABOUT FROM 20 TO 30 PARTS BY WEIGHT OF AMMONIUM NITRATE, (B) ABOUT FROM 10 TO 25 PARTS BY WEIGHT OF SODIUM NITRATE, (C) ABOUT FROM 20 TO 30 PARTS BY WEIGHT OF TRINITROTOLUENE, (D) ABOUT FROM 10 TO 30 PARTS BY WEIGHT OF FERROPHOSPHORUS, AND (E) ABOUT FROM 8 TO 20 PARTS BY WEIGHT OF WATER.
US161378A 1961-12-22 1961-12-22 Blasting composition Expired - Lifetime US3129126A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3235423A (en) * 1964-03-24 1966-02-15 Hercules Powder Co Ltd Stabilized aqueous slurry blasting agent and process
US3249476A (en) * 1964-02-25 1966-05-03 Robert B Clay Composition of low crystalization point and method of preparation
US3467559A (en) * 1965-10-22 1969-09-16 African Explosives & Chem Method of preparing slurried explosives mixtures
US4439254A (en) * 1982-04-05 1984-03-27 Atlas Powder Company Solid sensitizers in water gel explosives and method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE633514C (en) * 1932-10-12 1936-07-29 Elektrochemische Ges M B H Flammable fog substances containing phosphorus
US2095302A (en) * 1934-12-04 1937-10-12 Remington Arms Co Inc Ammunition
US2103698A (en) * 1931-08-29 1937-12-28 Schmid Alfred Safety ignition composition containing semi-pyrophoric metal
US2768073A (en) * 1952-04-21 1956-10-23 Ici Ltd Explosive compositions
US2867172A (en) * 1954-07-19 1959-01-06 Joseph R Hradel Detonation of unprimed base charges
US2930685A (en) * 1958-10-13 1960-03-29 Canada Iron Ore Co Explosive composition

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2103698A (en) * 1931-08-29 1937-12-28 Schmid Alfred Safety ignition composition containing semi-pyrophoric metal
DE633514C (en) * 1932-10-12 1936-07-29 Elektrochemische Ges M B H Flammable fog substances containing phosphorus
US2095302A (en) * 1934-12-04 1937-10-12 Remington Arms Co Inc Ammunition
US2768073A (en) * 1952-04-21 1956-10-23 Ici Ltd Explosive compositions
US2867172A (en) * 1954-07-19 1959-01-06 Joseph R Hradel Detonation of unprimed base charges
US2930685A (en) * 1958-10-13 1960-03-29 Canada Iron Ore Co Explosive composition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3249476A (en) * 1964-02-25 1966-05-03 Robert B Clay Composition of low crystalization point and method of preparation
US3235423A (en) * 1964-03-24 1966-02-15 Hercules Powder Co Ltd Stabilized aqueous slurry blasting agent and process
US3467559A (en) * 1965-10-22 1969-09-16 African Explosives & Chem Method of preparing slurried explosives mixtures
US4439254A (en) * 1982-04-05 1984-03-27 Atlas Powder Company Solid sensitizers in water gel explosives and method

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