US2838455A - Textiles and conditioning compositions therefor - Google Patents
Textiles and conditioning compositions therefor Download PDFInfo
- Publication number
- US2838455A US2838455A US347849A US34784953A US2838455A US 2838455 A US2838455 A US 2838455A US 347849 A US347849 A US 347849A US 34784953 A US34784953 A US 34784953A US 2838455 A US2838455 A US 2838455A
- Authority
- US
- United States
- Prior art keywords
- weight
- ester
- alcohols
- textile
- conditioning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10S156/91—Bonding tire cord and elastomer: improved adhesive system
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2962—Silane, silicone or siloxane in coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2965—Cellulosic
Definitions
- esters of a saturated fatty acid containing at least 16 carbon atoms with a polyhydric alcohol selected from a group consisting of hexahydric alcohols and the anhydro derivatives of such alcohols to yarns, such as of rayon, increases the oven-dry strength of cords produced therefrom.
- compositions comprising an ester of the type mentioned above atent
- a more specific object is to proin which the high oven-dr tensile strengths of the treated cords have been maintained while the wettability and dip pick-up has been rendered adequate for the production of suitably impregnated cords or fabrics for the production of rubber goods such as tires. This has been accomplished by the incorporation with the compositions containing the ester of the type defined above of a small amount of a liquid polydialkyl siloxane hereinafter more particularly defined and sometimes referred to simply as a silicone.
- the composition may be made up in the form of an emulsion in water comprising from 0.1 to 1% of the ester with 0.001' to 0.5% of the liquid silicone defined above and 0.01'to 1% of an emulsifying agent or agents.
- a water-soluble or dispersible binder or colloid in an amount from 0.2 to 2%.
- water-soluble or dispersible binding colloid there may be used polyvinyl alcohol, carboxymethyl cellulose, water-soluble cellulose ethers, such as hydroxyethyl cellulose, and methyl cellulose, and/or copolymers of styrene and fumaric (maleic) acids, (such as the product available under the trade name Stymer), polymethacrylic acid, polyvinyl acetates which have been partially deaeylated sufiiciently to render them water-dispersible or preferably water-soluble, also the salts of such copolymers and polymers, gelatine, chromated gelatines, starch, and starch degradation products such as dextrines.
- polyvinyl alcohol carboxymethyl cellulose
- water-soluble cellulose ethers such as hydroxyethyl cellulose, and methyl cellulose
- copolymers of styrene and fumaric (maleic) acids such as the product available under the trade name Stymer
- the ester is a hard wax-like solid such as those ob tained by the reaction of asaturated fatty acid having at least 16 carbon atoms of which palmitic and stearic representative with sorbitol, mannitol, dulcitol, sorbitan, mannitan, sorbide, mannide or the like.
- the esters may be either predominantly mono-, di-, tri-esters, or mixtures thereof and should have a melting point above 30 C. Examples of specific esters are sorbitol tetrastearate, sorbitan monopalmitate, mannitan monopalmitate, sorbide dipalmitate, sorbide distearate, and sorbitan monostearate.
- Any suitable emulsifying agent may be applied, examples being ethylene oxide modified higher fatty alcohols, such as lauryl alcohol etherified with from 2 to 50' or more oxyethylene units per mol of lauryl alcohol, fatty esters of ethylene oxide derivatives of hexitols or their inner anhydrides such. as those mentioned above used in producing the ester, such derivatives containing from 2 to 50 or more ethylene oxide units per molecule of the hexitol or inner anhydride. Soaps such as sodium or potassium oleate, sodium or potassium stearate, sodium or potassium palmitate or the like may be used.
- Sulfonated fatty compounds or sulfonated aromatic-aliphatic compounds as well as sulfated higher fatty alcohols may be used. Examples of these are dodecyl naphthalene sulfonate, Gardinol LA (sodium oleyl alcohol sulfate) and Igepon T (ROONCH2CH2SOaNa in which R-CO is the acyl radical derived from oleic acid). Mixtures of the emulsifying agents may be used or if desired a single emulsifying agent can be employed.
- the composition be stable to heat; for example, when the composition is applied to yarns to be used in making tire cord, it is necessary that the composition withstand the temperatures required for vulcanization of the rubber.
- the soaps such as sodium oleate, the ethylene oxide derivatives of the higher fatty alcohols, and some of the sulfonates, such as Igepon T above, are particularly suitable.
- liquid silicones that are useful in carrying out For this the invention are the polydialkylsiloxanes wherein the alkyl group has from 1 to 3 carbon atoms, namely methyl, ethyl, isopropyl or propyl.
- These polydialkylsiloxanes have the following formula:
- x is from 80 to 800.
- These silicones are liquids which are stable and resistant to the temperatures to which the textile fabric is subjected, such as vulcanization temperatures for rubber.
- the compositions of the present invention are to be applied to yarns which comprises untwisted or negligibly twisted filaments or fibers (that is those having less than 1 /2 turns per inch) for the purpose of preparing such yarns for twisting into cords and imparting to the treated cords adequate wettability to enable the cord to pick up large amounts of latex to prepare them for incorporation in reinforced rubber goods, such as tires
- the preferred proportions in the composition are as follows:
- the composition of the present invention is of wide applicability in the textile industry. It is useful "wherever it is desired to apply a wax-type of finish to textile materials. It may be used, as pointed out above, for sizing yarns for textile operations, such as additional When the composition is to twisting, weaving, knitting or other textile operations, and one of its important characteristics is that it is easily scourable so that the textile structures made from the treated yarns can be subjected to normal scouring operations to remove the conditioning material or finish whenever desired. Because of its ready dispersibility it can be left in the textile structures during dyeing operations without interfering with the uniform dyeing of the structures.
- the finish may or may not be removed.
- it is of primary importance as a preparatory finish for yarns whether twisted or untwisted to render them amenable to doubling operations to produce tire cord.
- the maintenance of the maximum or optimum ovcndry tensile strength of the twisted cord carrying the conditioning material in combination with maximum or optimum wettability to facilitate the impregnation of such treated cords with latex is extremely important.
- Tire cords or the like prepared by the use of this conditioning medium or finish produce tires which have good flex life and in which the reinforcement has maximum tensile strength and adherence to the rubber in the body of the article throughout the life thereof.
- the textile structures may comprise filaments or fibers of rayon produced either from viscose, cupramrnonium cellulose, or by the saponification of cellulose esters, such as cellulose acetate; cotton; casein or other protein fibers; cellulose ester fibers, such as those of celluloseacetate; nylon-type materials, such as polyamides; vinyl resins, such as copolymers of vinyl chloride with vinyl acetate or acrylonitrile, copolymers of acrylonitrile with vinyl pyridine, methacrylonitrile, vinyl acetate, vinyl chloride, or mixtures of these monomers, polyethylene; glycol terephthalate; or two mixtures of these different types of fibers, especially to those which comprise a predominant proportion of hydrophilic materials, such as cellulosic materials.
- cellulose esters such as cellulose acetate; cotton; casein or other protein fibers
- cellulose ester fibers such as those of celluloseacetate
- nylon-type materials such as polyamides
- vinyl resins
- the amount of the solid materials left upon the textile structure after impregnation with the dispersion or emulsion and drying thereof upon the structure may vary from about to 3% or more based on the weight of the structure.
- the application of from /2 to 1% based on the weight of the textile structure is preferred.
- Example I There were mixed together 5 parts of the condensation product of lauryl alcohol with an ethylene oxide having an average of 4 oxyethylene units per molecule of the alcohol, 5 /2 parts of the condensation product of lauryl alcohol with ethylene oxide having an average of 23 oxyethylene units per molecule of the alcohol, and 89 parts of polydimethylsiloxane having an average molecular weight of about 6600 in which the average value of x in the formula given above is about 90.
- An emulsion in Water is made by incorporating into 99.45 parts of water 0.05 parts of the mixture containing the silicone, 0.15 parts sodium oleate, and 0.3 parts of sorbitan monopalmitate.
- the final oven-dry cord has a tensile strength of 3.07 grams per denier and picked up 7.8% of solids from a 14% solids rubber latex dispersion at room temperature (approximately 25 C.) when the cord was passed through such dispersion at a rate of 98 feet per minute.
- the product was used as reinforcement for tires.
- Example II A composition identical with that of Example I was prepared with the exception that in the aqueous emulsion 0.005 parts of the mixture containing the silicone was incorporated into the emulsion instead of 0.05 parts.
- An 185 O-denier regenerated cellulose rayon yarn having about 2 /2 twists per inch was impregnated with the composition in a slashing operation as in Example I and the yarn was further twisted and plied to form a cord having a total denier of 3793.
- the oven-dry cord had a tensile strength of 3.00 grams per denier.
- the cord was made into a fabric which was impregnated with latex, picking up 6.2% thereof under the conditions of Example I, and made into rubber tires which had good flex life, high strength and durability.
- Example III Cotton yarns were passed as a warp through a slasher in the sizing box of which the above emulsion was contained. Upon drying, the yarn retained 3% by weight of the solids contained in the sizing bath. The yarns were woven into fabric and the fabric upon scouring became substantially free of the composition.
- Example 1'V An emulsion was made with the following ingredients:
- Example V An emulsion was made with the following ingredients:
- the yarns were twisted and formed into tire cords as in Example I above.
- the cords were passed through a rubber latex which was readily picked up in adequate amounts and the impregnated cords were made into tires.
- Such tires had high flex life, strength and durability.
- An aqueous emulsion for conditioning textile structures consisting essentially of 0.1 to 1 part by weight of an ester of a saturated fatty acid containing at least 16 carbon atoms with a polyhydric alcohol selected from the group consisting of hexahydric alcohols and the anhydro derivatives of such-alcohols, 0.001 to 0.5 parts by weight of a liquid po-lydialkylsiloxane having the following form- Lllil wherein is an integer having a value of from to 800 and R is selected from the group consisting of methyl, ethyl, isopropyl and propyl, 0.01 to -1 part by weight of an emulsifying agent and sufiicient water to make a total of parts by weight.
- An aqueous emulsion for conditioning textile structures consisting essentially of 0.2 to 0.5 part by weight of an ester of a saturated fatty acid containing at least 16 carbon atoms with a polyhydric alcohol selected from the group consisting of hexahydric alcohols and the anhydro derivatives or" such alcohols, 0.005 to 0.05 parts by weight of a liquid polydialkylsiloxane having the following formula carbon atoms with a polyhydric alcohol selected from the group consisting of hcxahydric alcohols and the anhydro derivatives of such alcohols, 0.2 to 2 parts by weight of a watevdispersible binder, 0.05 to 0.5 part by weight of a liquid polydialltylsiloxane having the following formula wherein x is an integer having a value of from 80 to 800 and R is selected from the group consisting of methyl, ethyl, isopropyl and propyl, 0.05 to 0.5 part by weight of an emulsifying agent
- An aqueous emulsion for conditioning textile structures consisting essentially of 0.2 to 0.5 part by weight of an ester of a saturated fatty acid containing at least 16 carbon atoms with a polyhydric alcohol selected from the group consisting of hexahydric alcohols and the anhydro derivatives of such alcohols, 0.05 to 0.5 parts by weight of a liquid polydialkylsiloxane having the following formula and R is selected from the group consisting of methyl,
- ethyl, isopropyl and propyl 0.2 to 0.6 part by weight of a ⁇ vater-dispersible colloid material, 0.05 to 0.5 part by weight of an emulsifyling agent and sufiicient water to make a total of 100 parts by weight.
- a textile structure comprising a filamentary bundle carrying a coating of a conditioning agent consisting essentially of 0.1 to 1 part by weight of an ester of a saturated fatty acid containing at least 16 carbon atoms with a polyhydric alcohol selected from the group consisting of hexahydric alcohols and the anhydro derivatives of such alcohols, 0.001' to 0.5 part by weight of a liquid polydialkylsiloxane having the following formula wherein x is an integer having a value of from 80 to 800 and R is selected from the group consisting of methyl, ethyl, isopropyl and propyl, and 0.01 to 1 part by weight of an emulsifying agent.
- a liquid polydialkylsiloxane having the following formula wherein at is an integer having a value of from 80 to 800 and R is selected from the group consisting of methyl, ethyl, isopropyl and propyl and 0.1 to 0.3 parts by weight of an emulsifying agent.
- a textile structure comprising a filamentary bundle carrying a coating of a conditioning agent consisting essentially of 0.1 to 1 part by weight of an ester of a saturated fatty acid containing at least 16 carbon atoms with a polyhydric alcohol selected from the group consisting of hexahydric alcoholsand the anhydro derivatives of such alcohols, 0.2 to 2 part by weight of a Water-dispersible binder, 0.05 to 0.5 part by weight of a liquid polydialkylsiloxane having the following formula Cit wherein x is an integer having a value of from 80 to 800 and R is selected from the group consisting of methyl, ethyl, isopropyl and propyl and 0.05 to 0.5 part by weight of an emulsifying agent.
- a textile structure comprising a filamentary bundle carrying a' coating of a conditioning agent consisting essentially of 0.2 to 0.5 part by Weight of an ester of a saturated fatty acid containing at least 16 carbon atoms with a polyhydric alcohol selected from the group consisting of hewaahytlric alcohols and the anhydro derivatives of such alcohols, 0.05 to 0.5 part by weight of a liquid polydialkylsiloxane having the following formula wherein at is an integer having a value of from 80 to 800 and R is selected from the group consisting of methyl, ethyl, isopropyl and propyl, 0.2 to 0.6 part by weight of a water-dispersible colloid material, and 0.05 to 0.5 part by weight of an emulsifying agent.
- the method of increasing the strength and of increasing the wettability and dip pickup of rubber latex of rayon textile structures which includes applying to the rayon textile structure a conditioning agent consisting essentially of 0.1 to 1 part by weight of an ester of a saturated fatty acid containing at least 16 carbon atoms with a polyhydric alcohol selected from the group consisting of hexahydric alcohols and the anhydro derivatives of such alcohols, 0.001 to 0.5 part by weight of aliquid polydialkylsiloxane having the following formula wherein x is an integer having a value of from 80 to 800 and R is selected from the group consisting of methyl, ethyl, isopropyl and propyl, and 0.01 to 1 part by weight of an emulsifying agent.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US347849A US2838455A (en) | 1953-04-09 | 1953-04-09 | Textiles and conditioning compositions therefor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US347849A US2838455A (en) | 1953-04-09 | 1953-04-09 | Textiles and conditioning compositions therefor |
Publications (1)
Publication Number | Publication Date |
---|---|
US2838455A true US2838455A (en) | 1958-06-10 |
Family
ID=23365541
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US347849A Expired - Lifetime US2838455A (en) | 1953-04-09 | 1953-04-09 | Textiles and conditioning compositions therefor |
Country Status (1)
Country | Link |
---|---|
US (1) | US2838455A (en) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3113369A (en) * | 1960-05-02 | 1963-12-10 | Monsanto Chemicals | Yarn manufacture and products obtained thereby |
US3218222A (en) * | 1960-06-09 | 1965-11-16 | Monsanto Co | Rubber article reinforced with nylon filaments |
US3267189A (en) * | 1959-11-03 | 1966-08-16 | Celanese Corp | Wet spinning of cellulose triesters |
US3306850A (en) * | 1964-12-17 | 1967-02-28 | Du Pont | Composition |
US3423314A (en) * | 1966-01-19 | 1969-01-21 | Dow Corning | Antistatic lubricant as a process finish for synthetic fibers |
US3425787A (en) * | 1964-09-18 | 1969-02-04 | American Enka Corp | Process for improving the creep resistance in rayon industrial yarns,cords and the like |
US4039715A (en) * | 1973-08-29 | 1977-08-02 | Eastman Kodak Company | Textile treating composition and textile yarn treated therewith |
US4053678A (en) * | 1974-10-17 | 1977-10-11 | Hoechst Aktiengesellschaft | Fiber tow for stuffing purposes and process for producing it |
US4064057A (en) * | 1975-12-10 | 1977-12-20 | Th. Goldschmidt Ag | Textile fiber finishes |
US4105567A (en) * | 1976-02-12 | 1978-08-08 | Th. Goldschmidt Ag | Organosilicon compounds and textile fiber finishes containing them |
US4111819A (en) * | 1977-11-14 | 1978-09-05 | Shell Oil Company | Textile fiber lubricant |
US4122018A (en) * | 1976-05-17 | 1978-10-24 | Henkel Kommanditgesellschaft Auf Aktien | Smoothing agents for treating textile fiber material |
US4186238A (en) * | 1973-12-24 | 1980-01-29 | Hoechst Aktiengesellschaft | Hydrophilic articles of water-insoluble polymers |
US4194024A (en) * | 1973-12-24 | 1980-03-18 | Hoechst Aktiengesellschaft | Method of making hydrophilic articles of water-insoluble polymers |
US4201680A (en) * | 1976-05-17 | 1980-05-06 | Henkel Kommanditgesellschaft Auf Aktien | Smoothing agents for treating textile fiber material |
EP0372890A2 (en) * | 1988-12-08 | 1990-06-13 | Chisso Corporation | Durable hydrophilic fibers |
US5009954A (en) * | 1985-07-12 | 1991-04-23 | Ohio University | Sheath core fiber and its method of manufacture |
US5190676A (en) * | 1989-11-30 | 1993-03-02 | Kao Corporation | High-speed spinning oil composition containing an organophosphoric ester salt and an oxyalkylene polymer |
US5507989A (en) * | 1992-04-01 | 1996-04-16 | Teijin Limited | High speed process for producing polyester filaments |
EP0738800A2 (en) * | 1995-04-17 | 1996-10-23 | Chisso Corporation | A water-repellent fibre and nonwovens made of the fibre |
US20020108985A1 (en) * | 2001-02-13 | 2002-08-15 | Garcia Steven E. | Wire feed mechanism and method used for fabricating electrical connectors |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2051389A (en) * | 1932-12-30 | 1936-08-18 | Ig Farbenindustrie Ag | Fulling fabrics |
US2233676A (en) * | 1940-02-12 | 1941-03-04 | Charles L Horn | Softening and finishing of textile materials and compositions therefor |
US2285357A (en) * | 1938-06-02 | 1942-06-02 | Nat Oil Prod Co | Processing of textile fibers |
US2523281A (en) * | 1950-09-26 | automobile polish | ||
US2597614A (en) * | 1947-02-06 | 1952-05-20 | Harris Res Lab | Method of rendering organic textile material water repellent and composition therefor |
US2666038A (en) * | 1950-08-08 | 1954-01-12 | American Viscose Corp | Textile-finishing compositions, finished articles, and methods of producing them |
US2698817A (en) * | 1951-02-28 | 1955-01-04 | Coats & Clark | Sewing thread and method for producing same |
US2702276A (en) * | 1951-04-10 | 1955-02-15 | Du Pont | Water-dispersible emulsions of polysiloxanes |
US2731367A (en) * | 1951-12-20 | 1956-01-17 | Owens Corning Fiberglass Corp | Sized and anti-static coated synthetic fiber and process of coating |
-
1953
- 1953-04-09 US US347849A patent/US2838455A/en not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2523281A (en) * | 1950-09-26 | automobile polish | ||
US2051389A (en) * | 1932-12-30 | 1936-08-18 | Ig Farbenindustrie Ag | Fulling fabrics |
US2285357A (en) * | 1938-06-02 | 1942-06-02 | Nat Oil Prod Co | Processing of textile fibers |
US2233676A (en) * | 1940-02-12 | 1941-03-04 | Charles L Horn | Softening and finishing of textile materials and compositions therefor |
US2597614A (en) * | 1947-02-06 | 1952-05-20 | Harris Res Lab | Method of rendering organic textile material water repellent and composition therefor |
US2666038A (en) * | 1950-08-08 | 1954-01-12 | American Viscose Corp | Textile-finishing compositions, finished articles, and methods of producing them |
US2698817A (en) * | 1951-02-28 | 1955-01-04 | Coats & Clark | Sewing thread and method for producing same |
US2702276A (en) * | 1951-04-10 | 1955-02-15 | Du Pont | Water-dispersible emulsions of polysiloxanes |
US2731367A (en) * | 1951-12-20 | 1956-01-17 | Owens Corning Fiberglass Corp | Sized and anti-static coated synthetic fiber and process of coating |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3267189A (en) * | 1959-11-03 | 1966-08-16 | Celanese Corp | Wet spinning of cellulose triesters |
US3113369A (en) * | 1960-05-02 | 1963-12-10 | Monsanto Chemicals | Yarn manufacture and products obtained thereby |
US3218222A (en) * | 1960-06-09 | 1965-11-16 | Monsanto Co | Rubber article reinforced with nylon filaments |
US3425787A (en) * | 1964-09-18 | 1969-02-04 | American Enka Corp | Process for improving the creep resistance in rayon industrial yarns,cords and the like |
US3306850A (en) * | 1964-12-17 | 1967-02-28 | Du Pont | Composition |
US3423314A (en) * | 1966-01-19 | 1969-01-21 | Dow Corning | Antistatic lubricant as a process finish for synthetic fibers |
US4039715A (en) * | 1973-08-29 | 1977-08-02 | Eastman Kodak Company | Textile treating composition and textile yarn treated therewith |
US4186238A (en) * | 1973-12-24 | 1980-01-29 | Hoechst Aktiengesellschaft | Hydrophilic articles of water-insoluble polymers |
US4194024A (en) * | 1973-12-24 | 1980-03-18 | Hoechst Aktiengesellschaft | Method of making hydrophilic articles of water-insoluble polymers |
US4053678A (en) * | 1974-10-17 | 1977-10-11 | Hoechst Aktiengesellschaft | Fiber tow for stuffing purposes and process for producing it |
US4064057A (en) * | 1975-12-10 | 1977-12-20 | Th. Goldschmidt Ag | Textile fiber finishes |
US4105567A (en) * | 1976-02-12 | 1978-08-08 | Th. Goldschmidt Ag | Organosilicon compounds and textile fiber finishes containing them |
US4122018A (en) * | 1976-05-17 | 1978-10-24 | Henkel Kommanditgesellschaft Auf Aktien | Smoothing agents for treating textile fiber material |
US4201680A (en) * | 1976-05-17 | 1980-05-06 | Henkel Kommanditgesellschaft Auf Aktien | Smoothing agents for treating textile fiber material |
US4111819A (en) * | 1977-11-14 | 1978-09-05 | Shell Oil Company | Textile fiber lubricant |
US5009954A (en) * | 1985-07-12 | 1991-04-23 | Ohio University | Sheath core fiber and its method of manufacture |
EP0372890A2 (en) * | 1988-12-08 | 1990-06-13 | Chisso Corporation | Durable hydrophilic fibers |
EP0372890A3 (en) * | 1988-12-08 | 1991-10-30 | Chisso Corporation | Durable hydrophilic fibers |
US5190676A (en) * | 1989-11-30 | 1993-03-02 | Kao Corporation | High-speed spinning oil composition containing an organophosphoric ester salt and an oxyalkylene polymer |
US5507989A (en) * | 1992-04-01 | 1996-04-16 | Teijin Limited | High speed process for producing polyester filaments |
US5607634A (en) * | 1992-04-01 | 1997-03-04 | Teijin Limited | High speed process for producing polyester filaments |
EP0738800A2 (en) * | 1995-04-17 | 1996-10-23 | Chisso Corporation | A water-repellent fibre and nonwovens made of the fibre |
EP0738800A3 (en) * | 1995-04-17 | 1997-07-02 | Chisso Corp | A water-repellent fibre and nonwovens made of the fibre |
US20020108985A1 (en) * | 2001-02-13 | 2002-08-15 | Garcia Steven E. | Wire feed mechanism and method used for fabricating electrical connectors |
US6530511B2 (en) * | 2001-02-13 | 2003-03-11 | Medallion Technology, Llc | Wire feed mechanism and method used for fabricating electrical connectors |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2838455A (en) | Textiles and conditioning compositions therefor | |
US2663989A (en) | Coated articles and textiles and emulsions for producing them | |
US2807865A (en) | Sized textile and method of fabricating yarn into fabric | |
US4081383A (en) | Anti-soiling treatment for carpets and carpet yarns | |
US2252999A (en) | Article and process for the manufacture thereof | |
US2324601A (en) | Sizing | |
US2666038A (en) | Textile-finishing compositions, finished articles, and methods of producing them | |
US2461043A (en) | Process of conditioning cellulose ester filaments | |
US2343090A (en) | Treatment of textiles and composition useful therefor | |
US2469409A (en) | Treatment of textile materials | |
KR960013472B1 (en) | Composition for the surface treatment of polymer fibers | |
DE2707150C2 (en) | Method for sizing textile fibers | |
US2399084A (en) | Production of shaped structures from proteins | |
US2597708A (en) | Antistatic agent, treatment of shaped articles therewith, and treated articles | |
US3061554A (en) | Water-dispersible emulsions of pinane hydroperoxide | |
US2980556A (en) | Sizing of textile yarn | |
US2368948A (en) | Process for increasing the transparency of fabrics containing filament yarns | |
US2436978A (en) | Reinforcing cord and process of manufacture | |
US3322554A (en) | Process for preparing electrically conductive flock for electrostatic flocking | |
US3971093A (en) | Mop having a washing resistance | |
US2436979A (en) | Tire cord and method of manufacture | |
US2436219A (en) | Textile product and process | |
US2438968A (en) | Production of textile filaments, fibers, and yarns | |
US2436980A (en) | Tire cord and method of manufacture | |
US2497536A (en) | Yarn conditioning |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: WESTERN AND SOUTHERN LIFE INSURANCE COMPANY THE C/ Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: JOHN HANCOCK MUTUAL LIFE INSURANCE COMPANY JOHN HA Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: NEW ENGLAND MUTUAL LIFE INSURANCE COMPANY 501 BOYL Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: PROVIDENT ALLIANCE LIFE INSURANCE COMPANY C/O THE Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: PAUL REVERE LIFE INSURANCE COMPANY THE C/O THE PAU Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: BALBOA INSURANCE COMPANY C/O THE PAUL REVERE EQUIT Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: KELLOGG CREDIT CORPORATION A DE CORP. Free format text: AGREEMENT WHEREBY SAID HELLER AND RAYONIER RELEASES ALL MORTGAGES AND SECURITY INTERESTS HELD BY AVTEX ON APRIL 28, 1978, AND JAN. 11, 1979, RESPECTIVELY AND ASSIGNS ITS ENTIRE INTEREST IN SAID MORT-AGAGE AGREEMENT TO ASSIGNEE;ASSIGNORS:WALTER E. HELLER & COMPANY, INC. A NY CORP.;ITT RAYONIER INCORPORATED, A DE CORP.;AVTEX FIBERS INC., A NY CORP.;REEL/FRAME:003959/0350 Effective date: 19800326 Owner name: WALTER E. HELLER & COMPANY, INC., A CORP. OF DEL. Free format text: AGREEMENT WHEREBY AETNA RELEASES AVTEX FROM ALL MORTAGES AND SECURITY INTERESTS IN SAID INVENTIONS AS OF JANUARY 11,1979, AND ASSIGNS TO ASSIGNEE THE ENTIRE INTEREST IN SAID MORTAGE AGREEMENT TO ASSIGNEE;ASSIGNORS:AETNA BUSINESS CREDIT, INC., A CORP. OF N.Y.;AVTEX FIBERS, INC, A CORP. OF NY;KELLOGG CREDIT CORP., A CORP. OF DEL.;REEL/FRAME:003959/0250 Effective date: 19800326 |