US2825408A - Oil recovery by subsurface thermal processing - Google Patents
Oil recovery by subsurface thermal processing Download PDFInfo
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- US2825408A US2825408A US341113A US34111353A US2825408A US 2825408 A US2825408 A US 2825408A US 341113 A US341113 A US 341113A US 34111353 A US34111353 A US 34111353A US 2825408 A US2825408 A US 2825408A
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- sands
- subsurface
- sand
- gases
- oil
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- 238000012545 processing Methods 0.000 title description 3
- 239000007789 gas Substances 0.000 claims description 54
- 230000015572 biosynthetic process Effects 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 239000011261 inert gas Substances 0.000 claims description 10
- 238000005336 cracking Methods 0.000 claims description 9
- 230000008016 vaporization Effects 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 230000000750 progressive effect Effects 0.000 claims description 5
- 239000004576 sand Substances 0.000 description 39
- 239000003921 oil Substances 0.000 description 36
- 238000005755 formation reaction Methods 0.000 description 22
- 238000012360 testing method Methods 0.000 description 20
- 238000002485 combustion reaction Methods 0.000 description 12
- 239000011269 tar Substances 0.000 description 12
- 239000011275 tar sand Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 9
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 239000006096 absorbing agent Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000008186 active pharmaceutical agent Substances 0.000 description 5
- 230000003628 erosive effect Effects 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
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- 239000000446 fuel Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
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- 239000000047 product Substances 0.000 description 2
- 238000005029 sieve analysis Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 241000857797 Mycobacterium phage Watson Species 0.000 description 1
- HRSANNODOVBCST-UHFFFAOYSA-N Pronethalol Chemical compound C1=CC=CC2=CC(C(O)CNC(C)C)=CC=C21 HRSANNODOVBCST-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 TeflonĀ® Polymers 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 229910052802 copper Inorganic materials 0.000 description 1
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- 230000003292 diminished effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
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Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
Definitions
- I My invention provides a readilyapplied in situ system for recovery of oil from tar sands by thermal means. It comprises drilling an input bore from the 7 surface through the overburden to the subsurface sands and then is essentially characterized by the establishment of; a zoneof heated'circulating sand, vapors and gases through the erosive action of hot inert gases injected throughan input pipe lowered through the input bore into the formation.
- a fluidized or turbulent regionof moving sand is set up by the action of the hot input gases in melting the tar, vaporizing and cracking the hydrocarbons and eroding the sand structure in combination withthe simultaneous release of vapors and gasesfrom the upper portion of the heated region,
- the release of vapors and gases is advantageously effected through the input bore, for example by means of an annulus surrounding the input pipe and connections.
- My invention further is essentially characterizedby progressively enlarging the eroded and'heated region of moving sand by vertical movement of the input pipe within the formation.
- Fig. l a simplified schematic sketch of an input Well with 'fje ion or pmcnt at an early stage of the operation, thawing part of thgsubsurfac'e' structure in section.
- Fig 2 is a similar view "at a later. stagof the operation illusti ting utilization of output wells for release of vapors snag ssh p,
- Fig. 3 is similar to Fig. 2 but also shows aii arrange:
- an input well 10 is drilled throughthe overburden into the formation and is; cased to provide an annular section ll surrounding input pipe 12.
- fuel gas and air are conducted by separate gas and air lines 13 and 14 respectively to a burner pipe which comprises the last section of the input pipe 12;
- the mixture of air and fuel gas can be burned above the surface of the ground to provide a mixture of hot inert flue gases for injection by the input pipe 12 into the formation. 7 p
- an injection gas stream at a temperature higher than the cracking temperature is desired and hence is most conveniently provided by combustion of a fuel gas with air either at the surface or below the surlface at the point of injection into the formation.
- a fuel gas with air either at the surface or below the surlface at the point of injection into the formation.
- the pressure of the input gas stream is limited by the overburden. In the absence of cap rock sealing the formation approximately one pound of pressure can be tolerated for each foot of overburden thickness. in the tar sands typically occurring in Canada and the United States there is about 50 to 700 feet of overburden.
- the injection of hot inert gases and simultaneous release of vapors and gases through the annulus ilsurrounding input pipe 12 results in melting of the tar, vaporization and cracking of the hydrocarbons and destruction of the sand structure by erosion.
- the vapors and gases are released from annulus 11 into pipe 15 which may be one of a series of gathering pipes leading to an oil separation and gas recovery system.
- the non-condensible gas recovered may be recycled, if this is desired, but if it is substantially inert, it should be blended with the combustion gas mixture after combustion rather than beforehand if satisfactory combustion control is to be expected.
- the condensate separated in separator 24 may be gas recovery system; V V
- the amount of heat necessary for a given formation may be '7 calculated from determinations of the heat capacityof the sand and the heats, of vaporization and reaction of the tar contained in the sand. Ordinarily, an
- the gas temperature may be-gradually reduced to about ll50 to l200 F. It should be maintained aboverabout 1000 F.
- Fig. 3 in the initial stages of the operation; the vapors and gases produced are recovered through an annulus in the input well but as the subsurface cone is formed and enlarges duringprocessing, recovery is effected through a plurality of perimeter wells
- the hot stream of vapors and gases advantageously is first passed by means of line 20' through one or more cyclone separators 21 wherein sand and othersolid patticles are removed from the gas stream
- the gas stream then may be passed by means of line 22 through air 'cooler '23 and thence into separating drum 24.
- Separator .24 also is advantageously ro I very lines 17 connecting thexoil separation and 7 I v 7 cover'was a thermowell made of Af'stainless tubing The method of recovery of vapors and gases produced equipped with metal fabric demisting wires to eliminate fog. Nevertheless it usually will be found desirable to pass the nncondensed stream, by means of connection 25,'through an electrical precipitation system 26, followed introduced by means of connection 2?
- Heat may be introduced to the tower by conventional means such as a steam or bottoms reboiler;
- a stripped heavy oil fraction is removed as bottoms'by means of line 36 from'which a portion is returned through line 37 as absorber oil to the top of absorber tower 30.
- the overhead from tower. is passed through condenser-38 to separating drum 39.
- Uncondensed gas' may be returned to absorber 30 by means of ā by small scale testing of my invention are providedi i
- the size distribution of the sand'present in a sample 7 of Athabasca tar sand was determined by extracting the oil with benzene and then running a sieve analysis on the remaining sand.
- the burner usedi in-this test could be pushed down through the bed through a seal. Also located on the flange which extended to the bottom of the sand bed. f In order to ignite the top surface of the tar sand the flange cover was propped up. to, leave a two-inch gapbetween the'flange faces. The burner was then-lighted, using acetylene and air as the'fuel. After the thermocouple in the upper por tion of the sand bed indicated that .at leastltwo inches.ā 1
- the combustion zone of the burner consisted of a six-inch length of zirconia oxide refractory. The inside diameter of this refractory was A" and the outside diameter was one inch. The refractory was slipped into a seven-inch length of standard one inch stainless steel pipe.
- the one inch stainlesssteel pipe in turn was slipped into another section of l /t-inch standard stainless steel pipe.
- the A annular space between the. outside of the one-inch pipe and the inside .of I A-inch pipe served as a passage for the inert gas, nitrogen or fine gas which was blended into the combustion gases in order to lower the temperature of the gases emerging from the burner.
- This inert gas used for blending also served to cool the burner thus enabling it to withstand hours of operation without apparent damage.
- a two-inch coupling was welded to the center of this cover plate.
- a two-inch T was connected to this coupling.
- the burner was introduced into the drum through the top of this T. There was an O-ring seal around the burner pipe, making it possible to move the burner down into the sand bed during the course of the test.
- the side of the T was the exit for the produced gases.
- Also located on the cover plate of the drum were four collecting lines for the produced gas. These consisted of four /2-inch couplings, located on a 10 diameter circle, welded to the plate. The four collecting lines were connected to a common line with which was also connected the line from the two-inch T.
- the produced gas passed into a cyclone sand trap in order to remove the sand blown out of the drum and then into a water cooled condenser.
- a block valve was installed on the line which connected the side of the T located above the center of the cover plate to the four collecting lines on the cover plate. This block valve was left open while the burner was being forced into the sand bed in order to allow sand to be blown out but as soon as the burner was forced to the bottom of the bed this valve was blocked, thus causing all the hot gases to pass through the sand before emerging through the collecting lines.
- the sand bed temperatures in the drum quantity runs were determined by thermocouples inserted in thermo- Wells which pass the entire depth of the bed.
- thermowells were introduced into the drum through Ts located on the four collector lines.
- the uncondensed gas, along with the smoke produced by the heating went into a Cottrell precipitator.
- This precipitator consisted of a 24" section of 2" copper tubing which was insulated by means of Teflon from a fine wire electrode suspended axially through it. The center electrode was maintained at a potential of 13,000 volts D. C.
- This Cottrell proved to be very efiective in condensing the smoke fog given oif by the sand mass when it was heated.
- the 100# grease drum of synthetic tar sand was placed in a 30 6 gallon open top oil drum and then the open annular. space filled in with looseinsulation for. these tests.
- the oil recovered by the condensers and Cottrell weighed 11# with water content of 20.0%, having a gravity of 26 API compared to the 143 APT of the starting 'oil.
- a process for the recovery of oil from a subsurface formation of unconsolidated oil-containing sands which comprises providing an input bore to the said subsurface sands, inserting an input pipe in the said bore to extend to the said subsurface sands, injecting hot inert gases through the said input pipe into the said subsurface sands to raise the temperature thereof to a hydrocarbon vaporizing and cracking temperature of about 700 to 1200 F.
- a process for the recovery of oil from a subsurface formation 'of unconsolidated oil-containing sands which comprises providing an input bore and an output bore to the said subsurface sands, inserting an input pipe in the said input bore to extend to the said subsurface sands, injecting hot inert gases through the said input pipe into the said subsurface sands to raise the temperature thereof to a hydrocarbon vaporizing and cracking temperature of about 700 to 1200 F.
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
March 4, 1958 K. M. WATSON OIL RECOVERY BY SUBSURF'ACE THERMAL PROCESSING 2 she ts-sheet 1 Filed March 9, 1953 INVENTOR KEN NETH M. WA TSON ATTO RN EYS ilnite States Pate 'rit 2,825,463 on. nscavssv av son sunraca THERMAL PRGCESSING Kenneth M. 'Watson, LakeZurich, lli., assign'or'to'Sinclair Gil & Gas Company, a corporation of Maine s pu'csaonrueichs, i953, senu No. 341,11:
Claims. (fil. 166 11)' This inventiton relates to the recovery of oil from subsurface formations of unconsolidated oil-containing sands, e. g. tar sands, by subsurface thermal processing.
In the region surrounding the Athabasca River in Alberta, Canada,there el tist very large deposits of tar sands; The significance of these deposits as potential source of world oil is apparent from these dataz The deposits,--it has been estimated, contain about ZOO billion barrels of oil. Theoil present on Athabasca tar sand has a gravity of between 8 and 12 API and is present to the extent of 14 to lSWeight percent. j I V ;The r ecovery problem however presents a number of difiiculties, both from the technical andeconomic standpoint, Proposals have been'made to mine the sands and recover oil from the mined sand aggregates by various operations requiringmechanical preparation followed by washing or heating methods. The cost of these operations, were they to be performed on a large scale, would be excessive both in terms of capital investment and operating expenses. Although the recovery problem in the Athabasca region is aggravated by the climate and by transportation dilficulties, similar considerations apply to the recovery of oil from the similar tar sands occurring in theWestern region of the United States. ,7 V
I My invention provides a readilyapplied in situ system for recovery of oil from tar sands by thermal means. It comprises drilling an input bore from the 7 surface through the overburden to the subsurface sands and then is essentially characterized by the establishment of; a zoneof heated'circulating sand, vapors and gases through the erosive action of hot inert gases injected throughan input pipe lowered through the input bore into the formation. In effect, a fluidized or turbulent regionof moving sand is set up by the action of the hot input gases in melting the tar, vaporizing and cracking the hydrocarbons and eroding the sand structure in combination withthe simultaneous release of vapors and gasesfrom the upper portion of the heated region, During the initiation of the operation, the release of vapors and gases is advantageously effected through the input bore, for example by means of an annulus surrounding the input pipe and connections. As theprocess proceeds and the area of heated moving sand is enlarged; one or more output wells advantageously are drilled in a manner permittingrelease of vapors and gases through them. My invention further is essentially characterizedby progressively enlarging the eroded and'heated region of moving sand by vertical movement of the input pipe within the formation. I
My invention will be further described reference to the accompanying drawings of which Fig. l a simplified schematic sketch of an input Well with 'fje ion or pmcnt at an early stage of the operation, thawing part of thgsubsurfac'e' structure in section.
Fig 2 is a similar view "at a later. stagof the operation illusti ting utilization of output wells for release of vapors snag ssh p,
Fig. 3 is similar to Fig. 2 but also shows aii arrange:
hydrocarbon gases and non-condensible gases in simplified diagrammatic fiow plan form. I b
As shown in the drawings, an input well 10 is drilled throughthe overburden into the formation and is; cased to provide an annular section ll surrounding input pipe 12. As shown, fuel gas and air are conducted by separate gas and air lines 13 and 14 respectively to a burner pipe which comprises the last section of the input pipe 12; Alternatively, the mixture of air and fuel gas can be burned above the surface of the ground to provide a mixture of hot inert flue gases for injection by the input pipe 12 into the formation. 7 p
In the operation, an injection gas stream at a temperature higher than the cracking temperature is desired and hence is most conveniently provided by combustion of a fuel gas with air either at the surface or below the surlface at the point of injection into the formation. I have tound however that it is important to control the combustion in a manner avoiding the presence of excess 03ygen so that an inert input gas stream is provided. The pressure of the input gas stream is limited by the overburden. In the absence of cap rock sealing the formation approximately one pound of pressure can be tolerated for each foot of overburden thickness. in the tar sands typically occurring in Canada and the United States there is about 50 to 700 feet of overburden. Because of the limi ration placed on the pressure of the injection gases by the thickness of overburden, it is advantageous to drillfthe input Well to the foot of the formation in order to initiate the operation and then to conduct the progressive extension of the hot eroded zone by raising the input pipe or burner gradually up through the formation to the overburden. 7
As shown in Figs. 1 and 2, the injection of hot inert gases and simultaneous release of vapors and gases through the annulus ilsurrounding input pipe 12 results in melting of the tar, vaporization and cracking of the hydrocarbons and destruction of the sand structure by erosion. The vapors and gases are released from annulus 11 into pipe 15 which may be one of a series of gathering pipes leading to an oil separation and gas recovery system. The non-condensible gas recovered may be recycled, if this is desired, but if it is substantially inert, it should be blended with the combustion gas mixture after combustion rather than beforehand if satisfactory combustion control is to be expected. The release of vapors and gas directly frorn the input or eroded region, rather than by attempted passage through the formation to a spaced output well as in conventional gas pressuring operations, in the course of the injection process is essential if an enlarging eroded region of hot-circulating or fluidized sand is to be created. As the operation proceeds and the temperature level in the input region raised to about the cracking temperature, i. e. about 700 to 1200 F., the progressive erosion of the subsurface structure is gradually eittended by lowering the input pipe gradually deeper into the format on, or conversely by gradually raising the input pipe up through the structure if the well has been originally drilled to the foot of the formation. In this way, the serious problem of formation iniperrneabilit-y is overcome, and t.e heat introduced by the hot inert gases can reach the oil in successive increments by continuous convection while the products of vaporization and cracking are carried away by gas flow. The effect of the traveling action of the input pipe is to produce a continuously enlarging erosion zone within the formation in roughly conical form. As shown in Figs. 2. and 3, output wells 16 which are representative of a number of wells drilled about the perimetei' of eroded zone are desirably cased and connected to valved "around the subsurface cone.
by cooler 27 into a secondary separator 28. The condensate separated in separator 24 may be gas recovery system; V V
The amount of heat necessary for a given formation may be '7 calculated from determinations of the heat capacityof the sand and the heats, of vaporization and reaction of the tar contained in the sand. Ordinarily, an
input gas stream at about 1800 to 1900" F. is desirable, 7
but as temperature equilibrium is approached the gas temperature may be-gradually reduced to about ll50 to l200 F. It should be maintained aboverabout 1000 F.
' 7 Approximately a month or more maybe required/to approach temperature equilibrium. The progress of the subsurface operation can be followed by gas analysis or by drilling window wells and inserting thermocouples or other analytical equipment at formation level. Advarr, tage ously, a patternof input and output wells is planned that will efiiciently cover an entire field or selected area or a large field.
in the process for subsequent separation of oil and recycle of non-condensible gases, if desired, is illustrated in diagrammatic form'in Fig. 3. "In the initial stages of the operation; the vapors and gases produced are recovered through an annulus in the input well but as the subsurface cone is formed and enlarges duringprocessing, recovery is effected through a plurality of perimeter wells The hot stream of vapors and gases advantageously is first passed by means of line 20' through one or more cyclone separators 21 wherein sand and othersolid patticles are removed from the gas stream The gas stream then may be passed by means of line 22 through air 'cooler '23 and thence into separating drum 24. It may be desirable to supplement the air cooler with a water-cooled exchanger system although the conditions maybe controlled in separator 24 by means of reflux to provide addi tional' cooling. Separator .24 also is advantageously ro I very lines 17 connecting thexoil separation and 7 I v 7 cover'was a thermowell made of Af'stainless tubing The method of recovery of vapors and gases produced equipped with metal fabric demisting wires to eliminate fog. Nevertheless it usually will be found desirable to pass the nncondensed stream, by means of connection 25,'through an electrical precipitation system 26, followed introduced by means of connection 2? to an upper portion of absiorber tower wherein it is contacted countercurrently with the'treated gas stream 05 separator 28 which is introduced at the foot of absorber'3t) by means of line 31. The condensed mist collected in separator 28 may be introduced into anintermediate section of absorber 30 by connection 32. Uncondensed gaseous components arevented from absorber 36 by means of line 33, to be utilized in part as recycle gas if: desired, or to be otherwise disposed of. The oil stream from the bottom of absorber 30 is passed by connection 34 to distillation lower 35. Heat may be introduced to the tower by conventional means such as a steam or bottoms reboiler; A stripped heavy oil fraction is removed as bottoms'by means of line 36 from'which a portion is returned through line 37 as absorber oil to the top of absorber tower 30. The overhead from tower. is passed through condenser-38 to separating drum 39. Uncondensed gas'may be returned to absorber 30 by means of {by small scale testing of my invention are providedi i The size distribution of the sand'present in a sample 7 of Athabasca tar sand was determined by extracting the oil with benzene and then running a sieve analysis on the remaining sand. It was:found that the sieve analysis of the original sand could be closely approximated by a mixture of Wausau graded sand. This mixture was made with nineparts of No. 1/2 grade and one part of No-2/O grade sand.. The physical characteristics of the Athabasca crude were approximated'byblending 57 weight ithese thermaltests ona small scale in a section'of pipe,
percent of a vacuum still bottoms with 43 weight percent of a straight run residuum. The gravity of this blend was 14.3 API. The synthetic tar' sand used in these tests was made with 86 weightpercent of the graded sand mixture and 14 percent of the blended heavy hydrocarbons.
The first series of tests was run inan insulatedise'c- 1 tion of four-inch pipe, four feet long. This section of pipe, which had a flange opening at the top, was mounted in .a vertical position within a tripod frame; .In this test elevenpounds of the: synthetic tar'sand were tamped into 7 p the pipe. This tar sand section-was 40'. in depth; :The-
flanged cover for this pipe had twoopening's; jonefor admitting the burner and the other to provide an exit for 'the flue gases along with the. liberated hydrocarbon vapors."
The burner usedi in-this test could be pushed down through the bed through a seal. Also located on the flange which extended to the bottom of the sand bed. f In order to ignite the top surface of the tar sand the flange cover was propped up. to, leave a two-inch gapbetween the'flange faces. The burner was then-lighted, using acetylene and air as the'fuel. After the thermocouple in the upper por tion of the sand bed indicated that .at leastltwo inches." 1
of the bed was over 1100 F., the flangecover was bolted down. The acetylene was turned off and only air at the rate of 45 cu. ft. per hour was fed to the lance type. burner. Temperaturerreadings indicated that thesand bed was ignited and combustion could 'be sustained by air alone. The lance was then pushed down throughthe bed at the rate'of'abo'ut one inch perminute. The tem'- perature readings made, indicated that. the bed temperatures were above 120 0 R, which was the limit of the available recorder; The hydrocarbons were driven-oif'a's a dense brown smoke whichfcould not be condensed; In-
dicationswere thatthe hydrocarbons on the sand that In the second test, the section of the pipe was packed with synthetic tar sand in the same manner as .in the first test. The object of this second test was to determine whether or' not itwas possible to ignite'the bottom of the sand section and burn upthrough the tar sand; taking the vaporized oil and products of combustion out the was provided to the bottom top. in this'test a connection of the pipe section, '7 When cold, the tamped synthetic tar sands in the pipe had suflicient permeability to allow about cu.;ft. per
hour to pass through the 40 sand section with a 273 p. s. i. pressure drop. "The bottom of the pip'e's'ection was heatedexternally. byan acetylene torchfuntil the 7 thermocouple in the bottomof the sandindicatedra.12 00. F. plus temperature. At that temperature the heating was discontinued andair wasstarted into the bed at about cu. ft. .per hour. Within fifteenminutes the pressure drop on the bed increased so that only about35 'cu. fL'
per hour of air could pass through'the bed with a total pressure drop of 90 p. s. i. across the sand sectionfl'As time went on. the air rate diminished so'that at the end of one hour the. flow through the bed was practically nil. j a
This blocking of the sand to the passage ofthe air'was due to oil which was being released from the. hot'sand p a at the bottom of pipe condensing on cold tar sand higher; in the pipe. Temperature surveys made during the course ofthe a'ir' blowing indicated that ignition of the tarsa'nds had not been established. M 7 7 Because of the difliculties attendant with carrying out it was decided to repeat this. series of tests on a larger scale. In the larger scaletests a new burner" was utilized in which the gaseous fuel. and the air were introduced:
through three stainless steel tubes 6" in insidefdiameter.
One was used to bring the'gas to the combustion zone while two were used to introduce the 'air into the combustion zone. In order to promote proper burning within the combustion zone the gas and air must be introduced into the combustion zone so that they produce a rotary mixing current. This was done by taking the three tubes, the gas line being sandwiched between the two air lines, and giving them a three-quarter corkscrew twist as they entered the combustion zone. The combustion zone of the burner consisted of a six-inch length of zirconia oxide refractory. The inside diameter of this refractory was A" and the outside diameter was one inch. The refractory was slipped into a seven-inch length of standard one inch stainless steel pipe. The one inch stainlesssteel pipe in turn was slipped into another section of l /t-inch standard stainless steel pipe. The A annular space between the. outside of the one-inch pipe and the inside .of I A-inch pipe served as a passage for the inert gas, nitrogen or fine gas which was blended into the combustion gases in order to lower the temperature of the gases emerging from the burner. This inert gas used for blending also served to cool the burner thus enabling it to withstand hours of operation without apparent damage.
The larger scale tests were run with the synthetic tar sands contained in 100# grease drums. These drums are 15" in diameter and 20" in depth. Two fire bricks were placed on the bottom of the drum prior to packing it with the synthetic tar sand mixture. It was intended that these bricks would protect the drum bottom from the hot gases emerging from the burner. The drum was then loaded with 205 of synthetic tar sand which was tamped very firmly. After the drum was loaded, a cover made of A" steel plate was welded to the top of the drum. A cylindrical baflie 7 in diameter and 4" deep was welded into the lid of the drum. This was to prevent gases from bypassing travel through the sand by going across the top of sand below the cover plate.
A two-inch coupling was welded to the center of this cover plate. A two-inch T was connected to this coupling. The burner was introduced into the drum through the top of this T. There was an O-ring seal around the burner pipe, making it possible to move the burner down into the sand bed during the course of the test. The side of the T was the exit for the produced gases. Also located on the cover plate of the drum were four collecting lines for the produced gas. These consisted of four /2-inch couplings, located on a 10 diameter circle, welded to the plate. The four collecting lines were connected to a common line with which was also connected the line from the two-inch T. The produced gas passed into a cyclone sand trap in order to remove the sand blown out of the drum and then into a water cooled condenser. A block valve was installed on the line which connected the side of the T located above the center of the cover plate to the four collecting lines on the cover plate. This block valve was left open while the burner was being forced into the sand bed in order to allow sand to be blown out but as soon as the burner was forced to the bottom of the bed this valve was blocked, thus causing all the hot gases to pass through the sand before emerging through the collecting lines. The sand bed temperatures in the drum quantity runs were determined by thermocouples inserted in thermo- Wells which pass the entire depth of the bed. These thermowells were introduced into the drum through Ts located on the four collector lines. The uncondensed gas, along with the smoke produced by the heating went into a Cottrell precipitator. This precipitator consisted of a 24" section of 2" copper tubing which was insulated by means of Teflon from a fine wire electrode suspended axially through it. The center electrode was maintained at a potential of 13,000 volts D. C. This Cottrell proved to be very efiective in condensing the smoke fog given oif by the sand mass when it was heated. The 100# grease drum of synthetic tar sand was placed in a 30 6 gallon open top oil drum and then the open annular. space filled in with looseinsulation for. these tests.
In a test on the dr'um sized sample, the burnerswas adjusted to give flue gaseswith a temperature. of 1 300" F. with no oxygen present. Thiswas done .by feeding the theoretical mixture of gas, in this case hydrogen, and .air plus sufiicient nitrogen to bring the temperature down to 1300 F. These qualities weremeasured by means .of rotometers. The total of flue gases at standardconditions was 210 cu. ft. per hour. After heating 12 /2 hours at this rate, this run was interruptedand the oilrecovered in the sand trap was weighed and found to total 9.#. Practically no oil was recovered from the system beyond this trap. Since examination of this oil showed that it was essentially as viscous as the material mixed with the sand, the test was'resumed and the inert gas temperature was raised to l-500 with a total volume of :300..cu. ft. perhour. This heating period totaled l3hours. The
additional oil recoveredweighed l7# but did not show any appreciable viscosity reduction. The total oil recovered was 26;? out of the 30# originally mixed with the sand. This recovered oil was extracted with benzene and found to contain 8% sand. No water was recovered with this oil. The total oil recovered with of the original charge. Original gravity as 14.3" API; final gravity 8.0 API.
Because the oil recovered in the previous test was essentially unaltered, it was decided to make another test at a higher temperature. For this run the drum was packed with tar sand as in the previous test. The burner was adjusted to give a flue gas temperature of about 1850 F. with a volume of about 380 cu. ft. per hour. This test lasted 12 hours. The back pressure on the burner inlet pipe was 3 to 54 per square inch during this test.
The oil recovered by the condensers and Cottrell weighed 11# with water content of 20.0%, having a gravity of 26 API compared to the 143 APT of the starting 'oil.
I claim:
1. A process for the recovery of oil from a subsurface formation of unconsolidated oil-containing sands which comprises providing an input bore to the said subsurface sands, inserting an input pipe in the said bore to extend to the said subsurface sands, injecting hot inert gases through the said input pipe into the said subsurface sands to raise the temperature thereof to a hydrocarbon vaporizing and cracking temperature of about 700 to 1200 F. thereby establishing a zone of eroded and heated circulating sands, vapors and gases within said subsurface sands providing an exit for said released vapors and gases to the earths surface, enlarging the said eroded and heated zone by the progressive vertical movement of the said input pipe within the subsurface sands and thereafter recovering oil produced by the process from the released and withdrawn vapors and gases.
2. The process of claim 1 in which the point of injection is initially near the upper surface of the formation and is moved progressively downwardly into the formation in the course of the process.
3. The process of claim 1 in which the point of injection is initially near the lower surface of the formation and is progressively moved upwardly through the formation in the course of the operation.
4. A process for the recovery of oil from a subsurface formation 'of unconsolidated oil-containing sands which comprises providing an input bore and an output bore to the said subsurface sands, inserting an input pipe in the said input bore to extend to the said subsurface sands, injecting hot inert gases through the said input pipe into the said subsurface sands to raise the temperature thereof to a hydrocarbon vaporizing and cracking temperature of about 700 to 1200 F. thereby establishing a zone of eroded and heated circulating sands, vapors and gases within said subsurface sands providing an exit for said released vapors and gases through the output bore provided in .theregion or the heated circulating samenlarging the said eroded and heated zone by theprogre'ssive verticalfimovement of the said input pipe the subsurface sands and thereafter recovering oil produced 'by the process fromthe-releasedand withdrawn vapors i and gases. 7 s V I Sr A' process for the'recovery of 'oil from a'subsurface formation of unconsolidated oil-containing sands which thereby forming anannulus between said input pipe and a 'said input boreQinjcting hot inert gases through the said input pipe into the 'said subsurface sandsto raise the temperature'thereof to a hydrocarbon vaporizing and sands, vapors andgases within said ,subsurface'sands, enlarging the said eroded and heated zone by the progressive 7' comprises providing aninput bore andanoutput bore to V the saidsubsur face sands, inserting an input pipe in the I said input bore to extend to' the said subsurface sands 15'- 'cracking temperatureof about 700 to 1200' F. thereby t establishing a zone of eroded and heatedicirculating vertical movement ofthe said, inputpipe sub- 4 surface sands;;'providing-'an-rexit for said released vapors :out'put bore provided in the;region10f ;heatedcirculating sandsand thei-eafterrrecovering' oil produced :by' the jpro- ReferencesCitedin fileiof this patent UNITEDLS'IATESPATENISI bass ,from the released and withdrawnvapors and gases.
V: :tn'lr 5h 'a 1" sit ear m
Claims (1)
1. A PROCESS FOR THE RECOVERY OF OIL FROM A SUBSURFACE FORMATION OF UNCONSOLIDATED OIL-CONTAINING SANDS WHICH COMPRISES PROVIDING AN INPUT BORE TO THE SAID SUBSURFACE SANDS, INSERTING AN INPUT PIPE IN THE SAID BORE TO EXTEND TO THE SAID SUBSURFACE SANDS, INJECTING HOT INERT GASES THROUGH THE SAID INPUT PIPE INTO THE SAID SUBSURFACE SANDS TO RAISE THE TEMPERATURE THEREOF TO A HYDROCARBON VAPORIZING AND CRACKING TEMPERATURE OF ABOUT 700 TO 1200* F. THEREBY ESTABLISHING A ZONE OF ERODED AND HEATED CIRCULATING SANDS, VAPORS AND GASES WITHIN SAID SUBSURFACE SANDS PROVIDING AN EXIT FOR SAID RELEASE VAPORSS AND GASES TO THE EARTH''S SURFACE ENLARGINGTE SAID ERODED AND HEATED ZONE BY TE PROGRESSIVE VERTICAL MOVEMENT OF THE SAID INPUT PIPE WITHIN THE SUBSURFACE SANDS AND THEREAFTER RECOVERING OIL PRODUCED BY THE PROCESS FROM THE RELEASED AND WITHDRAWN VAPORS AND GASES.
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US341113A US2825408A (en) | 1953-03-09 | 1953-03-09 | Oil recovery by subsurface thermal processing |
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