US2823993A - Steel alloy usable for valve seats and the like - Google Patents

Steel alloy usable for valve seats and the like Download PDF

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Publication number
US2823993A
US2823993A US599931A US59993156A US2823993A US 2823993 A US2823993 A US 2823993A US 599931 A US599931 A US 599931A US 59993156 A US59993156 A US 59993156A US 2823993 A US2823993 A US 2823993A
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Prior art keywords
steel
steel alloy
molybdenum
chrome
valve seats
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US599931A
Inventor
Kubera Gerhard
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Continental Teves AG and Co oHG
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Alfred Teves GmbH
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten

Definitions

  • the present invention relates to the manufacture of steel alloys, and has particular reference to a novel composition of matter for forming steel alloys usable, for instance, in valve cones.
  • valve cones In many instances it has therefore been necessary to employ in the manufacture of valve cones a nickel-chrome steel of 0.4-0.5%, 1.2-3.5 silicon, 0.6-1% manganese, 14-17% chromium, 12-15% nickel, 23% molybdenum, and the balance iron, to obtain the required resistance to deformation at high temperatures and resistance to scaling.
  • a steel of this composition is very expensive and, in addition, has the disadvantage of being incapable of hardening or heat treatment and therefore must be manufactured With a built in natural stress resistance of 80 kg. per sq. mm. (mmfi).
  • a steel alloy has a very low stress limit as well as a high heat conductivity, poor resistance to wear and abrasion and may be machined only with difliculty.
  • An important object of my invention is to produce a steel alloy possessing resistance to deformation at high temperatures.
  • Another object of my invention is to produce a steel alloy having good non-scaling properties.
  • Another object of my invention is to produce a steel alloy lending itself well to hardening or heat-treatment.
  • Another object of my invention is to produce a steel alloy having a high stress limit.
  • Another object of my invention is to produce a steel alloy possessing good heat conductivity.
  • Another object of my invention is to produce a steel alloy which will resist wear and abrasion.
  • Yet another object of my invention is to produce a steel alloy of a fine-grained texture which may be easily machined.
  • a further object of my invention is to produce a steel alloy resistant to corrosion.
  • Still another object of my invention is to produce an alloy steel which is inexpensive to manufacture.
  • my steel alloy comprises carbon, manganese, chrome, molybdenum, vanadium, and iron within the proportion limits hereinafter recited:
  • a chrome-molybdenum steel comprising 0.7-0.8% carbon, 1.0-1.5 manganese, l8-20% chromium, 2.3-2.7% molybdenum, 0.4-0.6% vanadium, balance iron.
  • a chrome-molybdenum steel comprising 0.8% carbon, 1.5% manganese, 20% chromium, 2.7% molybdenum, 0.6% vanadium, balance iron.
  • a chrome-molybdenum steel alloy for valve cones and the like comprising chromium 18-20%, molybdenum 23-27%, vanadium 0.4-0.6%, manganese l.0-1.5%, carbon 0.7-0.8%, and balance iron.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Soft Magnetic Materials (AREA)

Description

2,823,993 Patented Feb. 18, 1958 [ice 2,823,993 STEEL ALLOY USABLE FOR VALVE SEATS THE LIKE Gerhard Kubera, Blumberg, Baden, Germany, assignor to Alfred Teves, Maschinenund Armaturenfabrik K. G., Frankfurt am Main, Germany No Drawing. Application July 25, 1956 Serial No. 599,931
Claims priority, application Germany July 16,1955 4 Claims. (Cl. 75-126) The present invention relates to the manufacture of steel alloys, and has particular reference to a novel composition of matter for forming steel alloys usable, for instance, in valve cones.
It has heretofore been customary in the manufacture of valve cones to employ as a rule, a chrome-silicon steel consisting of 0.4-0.5% carbon, 3-3.5 silicon, 0.3-0.5% manganese, 8-9% chromium and the remainder iron. A steel of this composition has sufliced until lately, but is now no longer satisfactory due to constantly increasing casting strains in the motor, particularly With respect to resistance to deformation at high temperature and with relation to non-scaling properties. In many instances it has therefore been necessary to employ in the manufacture of valve cones a nickel-chrome steel of 0.4-0.5%, 1.2-3.5 silicon, 0.6-1% manganese, 14-17% chromium, 12-15% nickel, 23% molybdenum, and the balance iron, to obtain the required resistance to deformation at high temperatures and resistance to scaling. A steel of this composition, however, is very expensive and, in addition, has the disadvantage of being incapable of hardening or heat treatment and therefore must be manufactured With a built in natural stress resistance of 80 kg. per sq. mm. (mmfi). In addition such a steel alloy has a very low stress limit as well as a high heat conductivity, poor resistance to wear and abrasion and may be machined only with difliculty.
An important object of my invention is to produce a steel alloy possessing resistance to deformation at high temperatures.
Another object of my invention is to produce a steel alloy having good non-scaling properties.
Another object of my invention is to produce a steel alloy lending itself well to hardening or heat-treatment.
Another object of my invention is to produce a steel alloy having a high stress limit.
Another object of my invention is to produce a steel alloy possessing good heat conductivity.
Another object of my invention is to produce a steel alloy which will resist wear and abrasion.
Yet another object of my invention is to produce a steel alloy of a fine-grained texture which may be easily machined.
A further object of my invention is to produce a steel alloy resistant to corrosion.
Still another object of my invention is to produce an alloy steel which is inexpensive to manufacture.
Other objects of the invention will be apparent during the course of the following description.
To these ends my steel alloy comprises carbon, manganese, chrome, molybdenum, vanadium, and iron within the proportion limits hereinafter recited:
C Mn Cr Mn Va Fe In effecting the present invention I have employed successfully on some occasions the following:
Percent C 0.7 Mn 1 Cr 18 Mo 2.3 Va 0.4 Fe Balanc On other occasions I have successfully employed the following combination:
Percent C 0.8 Mn 1.5 Cr 20 Mo 2.7 Va 0.6 Fe Balance I have found that the chrome molybdenum steel, manufactured within the proportion limits described above, possesses marked advantages. A content in my steel alloy of molybdenum within the limits from 2.3% to 2.7% provides it with resistance to deformation at high temperatutres and the addition to it of chrome within the limits of 18-20%, brings about a high resistance to scaling. I have also discovered that it matches in these properties the earlier described highly expensive nickelchrome steel. In contrast with the said nickel-chrome steel, I have found that another advantage of my alloy steel consists in its ability to harden well, so that the normally required armor of chrome-nickel steel at the stem-end of valves, may be dispensed with. My alloy steel possesses resistance to abrasion and special operating characteristics at the stem part of valves. The heat conductivity of my steel alloy is superior to that of the above-mentioned chrome-nickel steel.
Due to the fine-grained texture of my steel alloy it is corrosion-resistant and is superior in that respect to the nickel-chrorne steel which is made coarse during forging and has therefore a tendency to inter-granular corrosion.
The invention has thus been fully described in a number of examples, but it should be understood that these are given by way of illustration and not of limitation and that many changes can be made in the details without departing from the spirit of the invention.
Having thus described the invention, I claim:
1. As a novel composition of matter, a chrome-molybdenum steel comprising 0.7-0.8% carbon, 1.0-1.5 manganese, l8-20% chromium, 2.3-2.7% molybdenum, 0.4-0.6% vanadium, balance iron.
2. As a novel composition of matter a chrome-molybdenum steel comprising 0.7% carbon, 1% manganese, 18% chromium, 2.3% molybdenum, 0.4% vanadium, balance iron.
3. As a novel composition of matter, a chrome-molybdenum steel comprising 0.8% carbon, 1.5% manganese, 20% chromium, 2.7% molybdenum, 0.6% vanadium, balance iron.
4. A chrome-molybdenum steel alloy for valve cones and the like comprising chromium 18-20%, molybdenum 23-27%, vanadium 0.4-0.6%, manganese l.0-1.5%, carbon 0.7-0.8%, and balance iron.
References Cited in the file of this patent UNITED STATES PATENTS 2,590,835 Kirby Apr. 1, 1952 FOREIGN PATENTS 693,146 Germany July 4, 1940

Claims (1)

1. AS A NOVEL COMPOSITION OF MATTER, A CHROME-MOLYBDENUM STEEL COMPRISING 0.7-0.8% CARBON, 1.0-1.5% MANGANESE, 18-20% CHROMIUM, 2.3-2.7% MOLYBDENUM, 0.4-0.6% VANADIUM, BALANCE IRON.
US599931A 1955-07-16 1956-07-25 Steel alloy usable for valve seats and the like Expired - Lifetime US2823993A (en)

Applications Claiming Priority (1)

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DE2823993X 1955-07-16

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US2823993A true US2823993A (en) 1958-02-18

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE693146C (en) * 1936-01-29 1940-07-04 Ed Doerrenberg Soehne Corrosion-resistant objects with good hardenability, great hardness and easy processing
US2590835A (en) * 1948-12-16 1952-04-01 Firth Vickers Stainless Steels Ltd Alloy steels

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE693146C (en) * 1936-01-29 1940-07-04 Ed Doerrenberg Soehne Corrosion-resistant objects with good hardenability, great hardness and easy processing
US2590835A (en) * 1948-12-16 1952-04-01 Firth Vickers Stainless Steels Ltd Alloy steels

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